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Open AccessCommunication
Materials 2015, 8(11), 7250-7256; doi:10.3390/ma8115378

1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes

Center for Advanced Technologies, Adam Mickiewicz University, Umultowska 89c, Poznan 61-614, Poland
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Author to whom correspondence should be addressed.
Academic Editor: Łukasz John
Received: 8 August 2015 / Accepted: 14 October 2015 / Published: 28 October 2015
(This article belongs to the Special Issue Organometallic Compounds 2015)
View Full-Text   |   Download PDF [2249 KB, uploaded 28 October 2015]   |  

Abstract

A convenient methodology for the highly stereoselective synthesis of unsymmetrical (1E,3E)-1,4-disubstituted 1,3-dienes based on palladium-catalyzed Hiyama cross-coupling reaction of 1-(triethoxysilyl)-substituted buta-1,3-dienes with aryl iodides is reported. View Full-Text
Keywords: buta-1,3-dienes; organosilicon dienes; C–C bond formation; Hiyama cross-coupling; palladium catalyst buta-1,3-dienes; organosilicon dienes; C–C bond formation; Hiyama cross-coupling; palladium catalyst
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Szudkowska-Frątczak, J.; Taczała, M.; Pawluć, P. 1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes. Materials 2015, 8, 7250-7256.

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