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Materials 2013, 6(4), 1205-1236; doi:10.3390/ma6041205
Review

Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics

1
, 2
, 2
 and 1,*
Received: 14 February 2013; in revised form: 12 March 2013 / Accepted: 18 March 2013 / Published: 25 March 2013
(This article belongs to the Section Materials for Energy Applications)
Download PDF [1639 KB, uploaded 25 March 2013]
Abstract: In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile synthetic protocol to prepare a wide series of π-conjugated compounds, selectively fluorinated on the aromatic and/or vinylene units. The impact of fluoro-functionalization on properties, the solid state organization and intermolecular interactions of the synthesized compounds are discussed, also in comparison with the non-fluorinated counterparts. Luminescent and photovoltaic applications are also discussed, highlighting the role of fluorine on the performance of devices.
Keywords: arylenevinylenes; fluorinated materials; Stille cross-coupling; organic semiconductors; conjugated materials. arylenevinylenes; fluorinated materials; Stille cross-coupling; organic semiconductors; conjugated materials.
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Martinelli, C.; Farinola, G.M.; Pinto, V.; Cardone, A. Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics. Materials 2013, 6, 1205-1236.

AMA Style

Martinelli C, Farinola GM, Pinto V, Cardone A. Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics. Materials. 2013; 6(4):1205-1236.

Chicago/Turabian Style

Martinelli, Carmela; Farinola, Gianluca M.; Pinto, Vita; Cardone, Antonio. 2013. "Synthetic Aspects and Electro-Optical Properties of Fluorinated Arylenevinylenes for Luminescence and Photovoltaics." Materials 6, no. 4: 1205-1236.


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