Materials 2011, 4(5), 825-844; doi:10.3390/ma4050825

Electrochemically Formed Porous Silica

Physique de la Matière Condensée, Ecole Polytechnique, CNRS, 91128 Palaiseau, France
* Author to whom correspondence should be addressed.
Received: 7 March 2011; in revised form: 6 April 2011 / Accepted: 20 April 2011 / Published: 26 April 2011
(This article belongs to the Special Issue Porous Materials 2011)
PDF Full-text Download PDF Full-Text [1209 KB, Updated Version, uploaded 3 May 2011 11:15 CEST]
The original version is still available [1208 KB, uploaded 26 April 2011 17:07 CEST]
Abstract: Controlled electrochemical formation of porous silica can be realized in dilute aqueous, neutral-pH, fluoride medium. Formation of a porous film is initiated by sweeping the potential applied to silicon to values higher than 20 V. Film formation, reaching a steady state, may be pursued in a wide range of potentials, including lower potentials. The origin of a threshold potential for porous film initiation has been explained quantitatively. All of the films appear mesoporous. Films grown at high potentials exhibit a variety of macrostructures superimposed on the mesoporosity. These macrostructures result from selective dissolution of silica induced by local pH lowering due to oxygen evolution. Films grown at potentials lower than 15 V appear uniform on the micrometer scale. However, all of the films also exhibit a stratified structure on the scale of a few tens of nanometres. This periodic structure can be traced back to the oscillatory behavior observed during the electrochemical dissolution of silicon in fluoride medium. It suggests that periodic breaking of the growing film may be responsible for this morphology.
Keywords: silicon; anodic oxide; electrochemical dissolution; morphologies

Article Statistics

Load and display the download statistics.

Citations to this Article

Cite This Article

MDPI and ACS Style

Chazalviel, J.-N.; Ozanam, F. Electrochemically Formed Porous Silica. Materials 2011, 4, 825-844.

AMA Style

Chazalviel J-N, Ozanam F. Electrochemically Formed Porous Silica. Materials. 2011; 4(5):825-844.

Chicago/Turabian Style

Chazalviel, Jean-Noël; Ozanam, François. 2011. "Electrochemically Formed Porous Silica." Materials 4, no. 5: 825-844.

Materials EISSN 1996-1944 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert