Abstract: Polycrystalline bulk copper aluminate Cu1-x-yAgxByAlO2 with B = Ni or Zn were prepared by spark plasma sintering and subsequent thermal treatment. The influence of partial substitution of Ag, Ni and Zn for Cu-sites in CuAlO2 on the high temperature thermoelectric properties has been studied. The addition of Ag and Zn was found to enhance the formation of CuAlO2 phase and to increase the electrical conductivity. The addition of Ag or Ag and Ni on the other hand decreases the electrical conductivity. The highest power factor of 1.26 × 10-4 W/mK2 was obtained for the addition of Ag and Zn at 1,060 K, indicating a significant improvement compared with the non-doped CuAlO2 sample.
Keywords: copper aluminate; oxide material; element addition; thermoelectric properties
This is an open access article distributed under the
Creative Commons Attribution License which permits unrestricted use, distribution,
and reproduction in any medium, provided the original work is properly cited.
Export to BibTeX
MDPI and ACS Style
Yanagiya, S.-I.; Van Nong, N.; Xu, J.; Pryds, N. The Effect of (Ag, Ni, Zn)-Addition on the Thermoelectric Properties of Copper Aluminate. Materials 2010, 3, 318-328.
Yanagiya S-I, Van Nong N, Xu J, Pryds N. The Effect of (Ag, Ni, Zn)-Addition on the Thermoelectric Properties of Copper Aluminate. Materials. 2010; 3(1):318-328.
Yanagiya, Shun-ichi; Van Nong, Ngo; Xu, Jianxiao; Pryds, Nini. 2010. "The Effect of (Ag, Ni, Zn)-Addition on the Thermoelectric Properties of Copper Aluminate." Materials 3, no. 1: 318-328.