Next Article in Journal
Novel Nanocomposite Materials for Advanced Li-Ion Rechargeable Batteries
Next Article in Special Issue
Reversible Thermochromic Nanocomposites Based on Thiolate-Capped Silver Nanoparticles Embedded in Amorphous Polystyrene
Previous Article in Journal
Two-Way Bending Properties of Shape Memory Composite with SMA and SMP
Materials 2009, 2(3), 1193-1204; doi:10.3390/ma2031193
Article

Optimization of Optical Properties of Polycarbonate Film with Thiol Gold-Nanoparticles

1
, 1,2
, 1
 and 1,2,*
Received: 10 July 2009; in revised form: 28 August 2009 / Accepted: 31 August 2009 / Published: 2 September 2009
(This article belongs to the Special Issue Nanocomposites of Polymers and Inorganic Particles)
Download PDF [235 KB, uploaded 1 September 2009]
Abstract: A new nanostructured composite film based on thiol gold nanoparticles dispersed in polycarbonate and prepared by evaporating a solution of 1-dodecanthiol gold nanoparticles and polycarbonate was developed for applications as optical lenses. Lenses with superior mechanical properties, coloring and UV ray absorption and with the same transparency as the matrix were obtained. The supporting highly transparent polycarbonate matrix and the chloroform solution of thiol gold nanoparticles, 3 nm mean size, was mixed according to a doping protocol employing different concentrations of thiol gold nanoparticles vs. polycarbonate. The presence of nanoparticles in the polymer films was confirmed by the spectrophotometric detection of the characteristic absorbance marker peak at 540–580 nm. The nanostructured films obtained show a better coverage in the UV-vis range (250–450 nm) even at very low doping ratios, of the order of 1:1,000. These results offer a very promising approach towards the development of efficient nanostructured materials for applications to optical lenses.
Keywords: thiol gold-nanoparticles; polycarbonate; UV-vis plasmon absorption band thiol gold-nanoparticles; polycarbonate; UV-vis plasmon absorption band
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |
EndNote


MDPI and ACS Style

Larosa, C.; Stura, E.; Eggenhöffner, R.; Nicolini, C. Optimization of Optical Properties of Polycarbonate Film with Thiol Gold-Nanoparticles. Materials 2009, 2, 1193-1204.

AMA Style

Larosa C, Stura E, Eggenhöffner R, Nicolini C. Optimization of Optical Properties of Polycarbonate Film with Thiol Gold-Nanoparticles. Materials. 2009; 2(3):1193-1204.

Chicago/Turabian Style

Larosa, Claudio; Stura, Enrico; Eggenhöffner, Roberto; Nicolini, Claudio. 2009. "Optimization of Optical Properties of Polycarbonate Film with Thiol Gold-Nanoparticles." Materials 2, no. 3: 1193-1204.


Materials EISSN 1996-1944 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert