Fabrication of Lead-Free Bi0.5Na0.5TiO3 Thin Films by Aqueous Chemical Solution Deposition
Department of Materials Science and Engineering, NTNU Norwegian University of Science and Technology, Trondheim NO-7491, Norway
Author to whom correspondence should be addressed.
Academic Editor: Lorena Pardo
Received: 25 November 2016 / Revised: 23 January 2017 / Accepted: 16 February 2017 / Published: 22 February 2017
Piezoelectric ceramics are widely used in actuator applications, and currently the vast majority of these devices are based on
, which constitutes environmental and health hazards due to the toxicity of lead. One of the most promising lead-free material systems for actuators is based on
(BNT), and here we report on successful fabrication of BNT thin films by aqueous chemical solution deposition. The precursor solution used in the synthesis is based on bismuth citrate stabilized by ethanolamine,
, and a Ti-citrate prepared from titanium tetraisopropoxide and citric acid. BNT thin films were deposited on
and platinized silicon substrates by spin-coating, and the films were pyrolized and annealed by rapid thermal processing. The BNT perovskite phase formed after calcination at 500 °C in air. The deposited thin films were single phase according to X-ray diffraction, and the microstructures of the films shown by electron microscopy were homogeneous and dense. Decomposition of the gel was thoroughly investigated, and the conditions resulting in phase pure materials were identified. This new aqueous deposition route is low cost, robust, and suitable for development of BNT based thin film for actuator applications.
This is an open access article distributed under the Creative Commons Attribution License
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).
Scifeed alert for new publications
Never miss any articles
matching your research from any publisher
- Get alerts for new papers matching your research
- Find out the new papers from selected authors
- Updated daily for 49'000+ journals and 6000+ publishers
Define your Scifeed now
Share & Cite This Article
MDPI and ACS Style
Christensen, M.; Einarsrud, M.-A.; Grande, T. Fabrication of Lead-Free Bi0.5Na0.5TiO3 Thin Films by Aqueous Chemical Solution Deposition. Materials 2017, 10, 213.
Christensen M, Einarsrud M-A, Grande T. Fabrication of Lead-Free Bi0.5Na0.5TiO3 Thin Films by Aqueous Chemical Solution Deposition. Materials. 2017; 10(2):213.
Christensen, Mads; Einarsrud, Mari-Ann; Grande, Tor. 2017. "Fabrication of Lead-Free Bi0.5Na0.5TiO3 Thin Films by Aqueous Chemical Solution Deposition." Materials 10, no. 2: 213.
Show more citation formats
Show less citations formats
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.
[Return to top]
For more information on the journal statistics, click here
Multiple requests from the same IP address are counted as one view.