1. Introduction
Sludge is a sort of solid waste which is a byproduct of municipal and industrial waste water treatment processes and is of great harm to human life [
1]. With the development of the national industrial economy and the acceleration of urbanization in China, the discharge of sludge is also increasing. According to statistics, China’s sludge output with a water content of 80% has exceeded 65 million tons in 2020, and it is expected that China’s annual sludge output will exceed 90 million tons in 2025. Improper sludge disposal seriously pollutes the surrounding environment, which has become a common problem in many localities.
Sludge treatment technologies mainly include concentration, fermentation, drying and so on. Drying technology is safe and stable and has strong adaptability to different kinds of sludges; therefore, it is one of the most widely used and mature technologies in the sludge treatment field. Sludge drying refers to the process of evaporating water in sludge by heating, which can be divided into direct drying and indirect drying according to whether the sludge is in contact with the heat source medium. A paddle dryer is an indirect drying technology, which is one of the most mature and widely used sludge drying devices. The drying process of sludge in the paddle dryer belongs to the dividing wall-type heating and drying process. Steam or heat transfer oil are usually used as the hot medium in paddle dryers. While the dryer is operating, steam or heat transfer oil flows into the cavities inside the dryer housing interlayer and paddles, transferring heat to the sludge by heat conduction though the wall of interlayer and paddles. The sludge is cut and stirred by the rotation of paddles during the moving process and dried by the heat conduction with the water evaporation [
2].
In order to realize the rational design and optimization of the paddle dryer, it is of great significance to develop a computational model which can accurately describe the heat and mass transfer of sludge in a paddle dryer. However, the heat and mass transfer behavior, and the movement process of sludge in a paddle dryer, are very complex and are mainly affected by the geometric structure, the mechanical operating parameters, the physical and chemical characteristics of the sludge itself, the heat source, the carrier gas and so on. To simplify the complex physical phenomena, the sludge drying process in a paddle dryer can be decomposed into the heat transfer, mass transfer and mixing process of sludge in time, as well as the movement behavior of sludge in space.
To accurately simulate the heat and mass transfer behavior of sludge in a paddle dryer, a series of research has been carried out by worldwide scholars in the past decades. Schlünder and his group members [
3,
4,
5] developed the so-called penetration model, which was used to simulate the indirect drying process of non-porous granular materials under vacuum and inert gas atmosphere. In the penetration model, it is assumed that the mass transfer resistance and heat transfer resistance of a single particle in the particle layer are zero, and only the contact thermal resistance between the bottom layer of the particle layer and the heating surface and the thermal resistance of the material layer are considered. The continuous mixing of the material by mechanical agitation in the drying process can be divided into many discontinuous mixing processes. In the single discontinuous mixing process, mixing of the material is assumed to be completed in an instant. The penetration model has been proven to simulate the drying process in mechanically agitated devices such as a paddle dryer. To develop a new method for the thermal design of paddle dryers, Arlabosse et al. [
6,
7] developed a simple model to simulate the drying kinetics of sludge in the lab-scale paddle dryer. In this method, the drying process is divided into two parts according to the sludge consistency: first, a constant evaporating flow rate is assumed in the pasty zone and, second, a linear decrease with the moisture content is taken into account in the granular zone. The calculation results are in agreement with the experimental data. Arlabosse and Chitu [
8] also used the penetration model to simulate the drying characteristics of sludge in a batch agitated dryer with steam used as the hot side working medium. They found that the model could describe the sludge drying kinetics well. Milhé et al. [
9] developed a model based on the theory of Markov chains to predict the residence time distribution (RTD) of sewage sludge in a paddle dryer. In this model, the flow process of sludge was described by a chain of
n perfectly mixed cells, with
n corresponding to the number of paddles installed the shaft. They found that the model could describe the sludge flow well in a continuous lab-scale paddle dryer. After that, Milhé et al. [
10] also coupled the one-dimensional Markov chain model with the penetration model, thus establishing a one-dimensional penetration model used to simulate the drying characteristics of sludge in a uniaxial continuous paddle dryer. The modified model can better simulate the water content distribution of sludge in the dryer. Chen et al. [
11,
12] presented a series of experiments on drying characteristics in a continuous paddle dryer and developed a coupled model of the penetration model and the Markov chain in order to study the drying behavior. The simulation results of the new model showed good agreement with the experimental results. The impact of various drying parameters on the sludge drying kinetics were also investigated in their study. Lyu et al. [
13] developed a two-dimensional model based on the theory of Markov chain to predict the Residence Time Distribution (RTD) of sludge in the continuous paddle dryer. The results showed that the two-dimensional model demonstrated its ability to describe the sludge flow in the paddle dryer based on the comparison between calculation and experiment results. The thermal and mass transfer properties of sludge are the important input parameters to model the sludge drying. Layth et al. [
14] carried out a series of experiments to determine the thermo-physical properties of sludge such as shrinkage coefficient, density, apparent moisture diffusivity, effective thermal conductivity and heat capacity. The mathematical relationships between sludge properties and the water content/temperature are established, and they could be applied in a numerical drying model.
According to the literature, it has been found that many studies on sludge model development have been presented. However, most of the existing models for heat and mass transfer simulation of sludge are complex, and the relevant studies were still in the lab stage. The applicability of a model for practical engineering design required further improvement. Meanwhile, the heat transfer in the paddle dryer is a coupled heat transfer process between the hot side and the sludge side. There are few reports on a bilateral coupled model for heat and mass transfer simulation in the paddle dryer. Therefore, to accurately predict the heat transfer and drying behavior of sludge in a paddle dryer, it is necessary to continue to make efforts on the heat and mass transfer model development of sludge, which lays a theoretical foundation for the performance optimization design of industrial paddle dryers.
2. Model Description
2.1. Basic Equation
The heat and mass transfer process of sludge in a paddle dryer is very complex. On the one hand, when the sludge enters the dryer, the sludge temperature will rise and the water in the sludge will begin to evaporate owing to the heating effect of high-temperature steam or heat transfer oil. On the other hand, due to the arrangement of several wedge-shaped paddles inside the dryer, the sludge will be driven to stir by paddles, making the heat and mass transfer process more complex and difficult to describe with precise mathematical equations. The temperature and the water content evolve continuously during drying, not only along the radial direction but also along the axial direction.
According to the features of the drying process of sludge in the paddle dryer, in the present model, we divided the drying of sludge in the paddle dryer into two processes: heat and mass transfer and mixing. For the model development, the sludge is assumed to be a porous water-contained media. The physical quantities describing the state of the sludge are water content (X) and temperature (T). To simplify the physical process, we make the following assumptions:
- (1)
The movement of sludge in the axial direction in the dryer is assumed to be a uniform linear motion.
- (2)
The mixing phenomenon of sludge in the vertical and axial directions is described based on the penetration theory, which will be introduced in detail in the next section.
- (3)
The water in the sludge becomes gaseous after evaporation after heating and leaves the sludge directly without heat and mass transfer with the sludge.
- (4)
Physical properties are functions of water content.
Based on the above assumptions, the sludge control equations can be given. First, the water content equation is as follows:
where
X is water content.
X0 is the initial water content.
D is the apparent diffusivity coefficient.
u is the sludge movement velocity. Under defined operating conditions, the sludge movement velocity is constant, depending on the sludge flowrate.
is the evaporation mass rate, which is defined as [
15]:
where
stands for the initial sludge mass.
ρ is the density of sludge.
T is the temperature of sludge.
r is an empirical coefficient.
Meanwhile, the energy equation can be defined as:
where
is density of the sludge.
T is temperature of the sludge.
is the effective thermal conductivity.
is the total evaporation heat, which is determined by the following equation [
16]:
is the water’s latent heat of evaporation, which is 2256.43 kJ/kg at standard atmospheric pressure.
is the binding energy of water. A TGA-DSC method and curve fitting was used to calculate the sludge water binding energy [
11]:
2.2. Boundary Conditions
The boundary conditions of the above model are determined according to the actual situation of the paddle dryer. First, sludge flows from the inlet. Due to the stable inlet conditions, the inlet boundary condition is defined as a Dirichlet boundary condition for
T and
X:
For the outlet boundary condition, a homogeneous Neumann condition on
T and
X can be defined as:
For the heating wall, heat is transferred from steam to sludge through the paddle wall. Since the heat transfer coefficient on the steam side is much greater than that of the sludge side, the boundary conditions on the sludge side can be simplified to a constant temperature boundary (Saturation Temperature of steam). The boundary condition for
X remains Neumann condition, given as:
For the upper wall (unheated wall), we simplify the boundary condition to the Neumann boundary condition, given as:
As a summary, the boundary conditions for the two-dimensional sludge model are shown in
Figure 1.
2.3. Penetration Theory
The above heat and mass transfer model was suitable for simulating sludge drying processes under a static condition. In the actual paddle dryer, the sludge is mixed at the same time and the heat and mass transfer process is accelerated owing to the stirring effect of the paddles on the sludge. In order to describe the mixing of sludge, the penetration theory [
3,
4,
5] has been used for reference in the present model.
As mentioned before, the penetration model is a theory model to describe the contact drying of mechanically agitated particulate material by a hot surface. The basic idea of the penetration model is to decompose the continuous macroscopic mixing characteristics of sludge into several discontinuous mixing processes. In the penetration model, a time interval is firstly defined as the contact time, during which the material is assumed to be at rest and heat is transferred to the material by heat conduction. After this, the material immediately finishes the macro and uniform mixing processes with the time interval considered as 0. By repeating the process above, a new heat transfer and mixing cycle is formed until the material dries.
Based on the penetration theory, the contact time
can be calculated as follows:
where
and
n are the mixing number and the stirrer velocity, respectively.
is defined as a function of Froud number:
where
is the Froud number:
Figure 2 shows the difference in calculation results of whether the penetration model was applicable to describe sludge mixing in the dryer. As shown in the figure, when the penetration model was used, the temperature and water content of sludge could be fully mixed along the radial direction, which is consistent with the physical phenomenon in the actual paddle dryer. Hence, it is believed that the penetration model can describe the mixing process of sludge in the paddle dryer. Coupled with the two-dimensional sludge model proposed in this paper, the complex heat and mass transfer process in the paddle dryer is expected to be accurately described.
5. Conclusions
In this paper, a concise but general two-dimensional model was proposed based on the penetration model in order to simulate the heat and mass transfer and drying kinetics of sludge in the paddle dryer. Experimental data from the existing study was used to validate the new model. The parametric study on sludge drying kinetics was also presented. The main conclusions can be summarized as follows.
The drying process of sludge in the paddle dryer was divided into heat and mass transfer and mixing, and sludge was assumed as a porous water-contained media. The sludge control equations, including the water content equation and the energy equation, were proposed to simulate the heat and mass transfer of sludge, and the penetration model was introduced to describe the mixing of sludge. Compared to the experimental results in the existing literature, the drying kinetics simulated by the present model were in good agreement with the experimental data under various operation conditions.
The effects of four key parameters, including sludge inlet flow rate, stirring velocity, wall temperature and sludge density, on drying kinetics in the paddle dryer were studied by using the present model. The results showed that the water content increased with the increase of sludge flowrate and the decrease of wall temperature and sludge density. Meanwhile, the stirring velocity had little effect on the drying kinetics of the sludge.
The present study can contribute to the understanding of sludge drying kinetics in a paddle dryer and it provides guidance for the optimal design of industrial paddle dryers.