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<article xmlns:xlink="http://www.w3.org/1999/xlink" xml:lang="en" article-type="research-article">
<front>
<journal-meta>
<journal-id journal-id-type="nlm-ta">Sensors</journal-id>
<journal-title>Sensors</journal-title>
<issn pub-type="epub">1424-8220</issn>
<publisher>
<publisher-name>Molecular Diversity Preservation International (MDPI)</publisher-name></publisher></journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.3390/s110606197</article-id>
<article-id pub-id-type="publisher-id">sensors-11-06197</article-id>
<article-categories>
<subj-group>
<subject>Article</subject></subj-group></article-categories>
<title-group>
<article-title>A Standard CMOS Humidity Sensor without Post-Processing</article-title></title-group>
<contrib-group>
<contrib contrib-type="author">
<name><surname>Nizhnik</surname><given-names>Oleg</given-names></name><xref ref-type="corresp" rid="c1-sensors-11-06197"><sup>*</sup></xref></contrib>
<contrib contrib-type="author">
<name><surname>Higuchi</surname><given-names>Kohei</given-names></name></contrib>
<contrib contrib-type="author">
<name><surname>Maenaka</surname><given-names>Kazusuke</given-names></name></contrib>
<aff id="af1-sensors-11-06197">Maenaka Human-sensing Fusion Project, 8111, Shosha 2167, Himeji-shi, 671-2280 Hyogo-ken, Japan; E-Mails: <email>higuchi@eratokm.jp</email> (K.H.); <email>maenaka@eng.u-hyogo.ac.jp</email> (K.M.)</aff></contrib-group>
<author-notes>
<corresp id="c1-sensors-11-06197">
<label>*</label>Author to whom correspondence should be addressed; E-Mail: <email>oleg@eratokm.jp</email>; Tel.: +81-079-267-6019; Fax: +81-079-229-9021.</corresp></author-notes>
<pub-date pub-type="collection">
<year>2011</year></pub-date>
<pub-date pub-type="epub">
<day>8</day>
<month>6</month>
<year>2011</year></pub-date>
<volume>11</volume>
<issue>6</issue>
<fpage>6197</fpage>
<lpage>6202</lpage>
<history>
<date date-type="received">
<day>20</day>
<month>4</month>
<year>2011</year></date>
<date date-type="rev-recd">
<day>1</day>
<month>6</month>
<year>2011</year></date>
<date date-type="accepted">
<day>3</day>
<month>6</month>
<year>2011</year></date></history>
<permissions>
<copyright-statement>© 2011 by the authors; licensee MDPI, Basel, Switzerland.</copyright-statement>
<copyright-year>2011</copyright-year>
<license>
<p>This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).</p></license></permissions>
<abstract>
<p>A 2 μW power dissipation, voltage-output, humidity sensor accurate to 5% relative humidity was developed using the LFoundry 0.15 μm CMOS technology without post-processing. The sensor consists of a woven lateral array of electrodes implemented in CMOS top metal, a Intervia Photodielectric 8023–10 humidity-sensitive layer, and a CMOS capacitance to voltage converter.</p></abstract>
<kwd-group>
<kwd>capacitive sensors</kwd>
<kwd>microsensors</kwd>
<kwd>humidity measurement</kwd>
<kwd>CMOS integrated circuits</kwd></kwd-group></article-meta></front>
<body>
<sec sec-type="intro">
<label>1.</label>
<title>Introduction</title>
<p>The history of humidity sensor integration with CMOS is at least 23 years old [<xref ref-type="bibr" rid="b1-sensors-11-06197">1</xref>]. After nearly a quarter of a century of development, three main sensing designs have emerged in CMOS. One solution is a water-absorbing film-based design as seen in [<xref ref-type="bibr" rid="b1-sensors-11-06197">1</xref>]. Another type of design exploits the difference in thermal conductivity between air and water vapor, as proposed in [<xref ref-type="bibr" rid="b2-sensors-11-06197">2</xref>]. The third main design measures the dew point with a hybrid CMOS/MEMS chip, and can be used in very precise systems [<xref ref-type="bibr" rid="b3-sensors-11-06197">3</xref>]. For mass-produced humidity sensors, like those found in air-conditioning units [<xref ref-type="bibr" rid="b4-sensors-11-06197">4</xref>], low power dissipation and low price is obligatory. To reduce price, the amount of CMOS post-processing and packaging should be kept to minimum. However, the existing proposals for CMOS-based sensors require a porous metal on the top layer [<xref ref-type="bibr" rid="b1-sensors-11-06197">1</xref>], or complex multilayer geometries over the wafer [<xref ref-type="bibr" rid="b5-sensors-11-06197">5</xref>,<xref ref-type="bibr" rid="b6-sensors-11-06197">6</xref>]. In [<xref ref-type="bibr" rid="b7-sensors-11-06197">7</xref>], by virtue of using CMOS with the thick top metal option, only one additional layer (sensing polymer) is deposited, but then a precision mask is still needed to remove the sacrificial layer.</p>
<p>In the current work, we investigated the possibility of employing the standard passivation layer of the CMOS chip as the humidity sensing element with electrodes shaped similar to those described in [<xref ref-type="bibr" rid="b5-sensors-11-06197">5</xref>,<xref ref-type="bibr" rid="b6-sensors-11-06197">6</xref>], but using the CMOS thick top metal option in a similar fashion as described in [<xref ref-type="bibr" rid="b7-sensors-11-06197">7</xref>]. The implementation has resulted in a functional humidity sensor with voltage output.</p></sec>
<sec>
<label>2.</label>
<title>Circuit and Layout</title>
<p>Sensing of humidity with hygroscopic polymer films is the most suitable approach for integrating humidity sensors in CMOS, but this approach has problems to solve. First, most hygroscopic films produce humidity-dependent capacitance, so a capacitance-to-voltage on-chip converter is necessary for simplified processing of the sensor output. Second, implementation of the sensing element is not straightforward. To obtain a large relative capacitance change, the electrical flux must be confined to the hygroscopic film. The simplest way to achieve this objective is if electrodes enclose the hygroscopic film from all sides, but for the moist air to gain access to the sensing film, a large area of the polymer must be exposed to the air. In the implemented humidity sensor, the electrical flux reaching the CMOS substrate was confined by the woven electrode mesh below the main sensing electrodes (see <xref ref-type="fig" rid="f1-sensors-11-06197">Figure 1</xref>). The woven mesh creates a two-dimensional multipole field distribution, with an exponentially falling intensity below the mesh. With the implemented mesh geometry, a 60% electrodes-to-substrate capacitance reduction is expected. This is more effective compared to the classical comb structure, producing one-dimensional multipole field, which is expected to close only 46% of the electrical flux lines above the substrate.</p>
<p>Furthermore, previously proposed comb-type electrodes have a 50%metal density if sensitivity is maximized [<xref ref-type="bibr" rid="b6-sensors-11-06197">6</xref>]. For the LFoundry 0.15 μm CMOS, the specified maximal density for the thick metal is 10%. Therefore, in the proposed design the CMOS thick metal has a density of 20%, providing a sensitivity equal to that of the classical comb pattern (see <xref ref-type="fig" rid="f2-sensors-11-06197">Figure 2</xref>). Positive and negative cube-like electrodes were placed in a checker-board pattern. The humidity sensing polymer was an 11 μm-thick coating of Intervia Photodielectric 8023–10, which was included in the LFoundry CMOS process as part of the pads mask. This material has a specified moisture absorption of 0.5% and a relative dielectric permittivity equal to 3.2. A sensor with comb-shaped electrodes was also manufactured, but although visually free of defects, it was found to be nonfunctional because of the short-circuits developed between electrodes.</p>
<p>A C/V (capacitance-to-voltage) converter derived from [<xref ref-type="bibr" rid="b8-sensors-11-06197">8</xref>] was developed (see <xref ref-type="fig" rid="f3-sensors-11-06197">Figure 3</xref> for schematic and <xref ref-type="fig" rid="f4-sensors-11-06197">Figure 4</xref> for control waveforms). Compared to the design in [<xref ref-type="bibr" rid="b8-sensors-11-06197">8</xref>], the proposed circuit was adapted for differential operation and a sample-and-hold circuit at output was implemented instead of the multiplexer.</p></sec>
<sec sec-type="results">
<label>3.</label>
<title>Experimental Results</title>
<p>Experimental results from the manufactured humidity sensors are briefly summarized in <xref ref-type="table" rid="t1-sensors-11-06197">Table 1</xref>.</p>
<p><xref ref-type="fig" rid="f5-sensors-11-06197">Figure 5</xref> shows typical absorption-desorption characteristic of a single humidity sensor. The hysteresis mentioned in <xref ref-type="table" rid="t1-sensors-11-06197">Table 1</xref> was found to be worst in the 45–65 °C temperature range. <xref ref-type="fig" rid="f6-sensors-11-06197">Figure 6</xref> shows how output voltage of the sensor varies with the temperature. The larger temperature coefficient at temperatures below 25 °C requires some sort of the temperature compensation.</p>
<p>Humidity range was limited by dryer capability of the humidity chamber and surface condensation. Performance measurements were done only in the 5–100 °C range. At 100–120 °C, only reliability testing was done. The accuracy mentioned in <xref ref-type="table" rid="t2-sensors-11-06197">Table 2</xref> is defined as nonlinearity plus half the hysteresis. The 70 s response time of the designed sensor is slow compared to other designs, but still more than enough for environmental monitoring. All measurements were done using a SH-24 temperature-humidity chamber. After 52 cycles of the humidity and temperature cycling, no detectable drift was found.</p></sec></body>
<back>
<ack>
<p>This work was supported in part by JST (Japan Science and Technology Agency), ERATO (Exploratory Research for Advanced Technology), Maenaka Human-sensing Fusion Project, VLSI Design and Education Center (VDEC) in collaboration with the University of Tokyo and Cadence Corporation.</p></ack>
<ref-list>
<title>References</title>
<ref id="b1-sensors-11-06197"><label>1.</label><citation citation-type="confproc"><person-group person-group-type="author"><name><surname>Silverthorne</surname><given-names>SV</given-names></name><name><surname>Watson</surname><given-names>CW</given-names></name><name><surname>Baxter</surname><given-names>RD</given-names></name></person-group><article-title>Integrated Relative Humidity Sensor, Technique Digest</article-title><conf-name>Proceedings of IEEE Solid-state Sensor and Actuator Workshop</conf-name><conf-loc>Hilton Head Island, SC, USA</conf-loc><conf-date>6–9 June 1998</conf-date><fpage>67</fpage><lpage>71</lpage></citation></ref>
<ref id="b2-sensors-11-06197"><label>2.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Okcan</surname><given-names>B</given-names></name><name><surname>Akin</surname><given-names>T</given-names></name></person-group><article-title>A Low-Power Robust Humidity Sensor in a Standard CMOS Process</article-title><source>IEEE Trans. Electron Devices</source><year>2007</year><volume>54</volume><fpage>3071</fpage><lpage>3078</lpage><pub-id pub-id-type="doi">10.1109/TED.2007.907165</pub-id></citation></ref>
<ref id="b3-sensors-11-06197"><label>3.</label><citation citation-type="confproc"><person-group person-group-type="author"><name><surname>Baglio</surname><given-names>S</given-names></name><name><surname>Castorina</surname><given-names>S</given-names></name><name><surname>Sacco</surname><given-names>V</given-names></name><name><surname>Savalli</surname><given-names>N</given-names></name><name><surname>Tringali</surname><given-names>C</given-names></name></person-group><article-title>Dew-point Relative Humidity CMOS Microsensors</article-title><conf-name>Proceedings of 2004 IEEE Sensors</conf-name><conf-loc>Vienna, Austria</conf-loc><conf-date>24–27 October 2004</conf-date><fpage>103</fpage><lpage>106</lpage></citation></ref>
<ref id="b4-sensors-11-06197"><label>4.</label><citation citation-type="book"><source>SHT1x/SHT7x Humidity &amp; Temperature Sensor</source><comment>Sensirion Technical Report Datasheet;</comment><publisher-name>Sensirion AG</publisher-name><publisher-loc>Staefa, Switzerland</publisher-loc><month>March</month><year>2003</year></citation></ref>
<ref id="b5-sensors-11-06197"><label>5.</label><citation citation-type="confproc"><person-group person-group-type="author"><name><surname>Zhao</surname><given-names>C-L</given-names></name><name><surname>Huang</surname><given-names>H-A</given-names></name><name><surname>Qin</surname><given-names>M</given-names></name><name><surname>Li</surname><given-names>WH</given-names></name></person-group><article-title>A CMOS Interdigital Capacitive Humidity Sensor with Polysilicon Heaters</article-title><conf-name>Proceedings of 2010 IEEE Sensors</conf-name><conf-loc>Kona, HI, USA</conf-loc><conf-date>1–4 November 2010</conf-date><fpage>382</fpage><lpage>385</lpage></citation></ref>
<ref id="b6-sensors-11-06197"><label>6.</label><citation citation-type="confproc"><person-group person-group-type="author"><name><surname>Laconte</surname><given-names>J</given-names></name><name><surname>Wilmart</surname><given-names>V</given-names></name><name><surname>Raskin</surname><given-names>J-P</given-names></name><name><surname>Flandre</surname><given-names>D</given-names></name></person-group><article-title>Capacitive Humidity Sensor Using a Polyimide Sensing Film</article-title><conf-name>Proceedings of Design, Test, Integration &amp; Packaging of MEMS/MOEMS</conf-name><conf-loc>Aix-en-Provence, France</conf-loc><conf-date>11–13 May 2011</conf-date><fpage>223</fpage><lpage>228</lpage></citation></ref>
<ref id="b7-sensors-11-06197"><label>7.</label><citation citation-type="confproc"><person-group person-group-type="author"><name><surname>Dai</surname><given-names>C-L</given-names></name><name><surname>Lu</surname><given-names>D-H</given-names></name></person-group><article-title>Fabrication of a Micro Humidity Sensor with Polypyrrole Using the CMOS Process</article-title><conf-name>Proceedings of 5th IEEE International Conference on Nano/Micro Engineered and Molecular Systems</conf-name><conf-loc>Xiamen, China</conf-loc><conf-date>20–23 January 2010</conf-date><fpage>110</fpage><lpage>113</lpage></citation></ref>
<ref id="b8-sensors-11-06197"><label>8.</label><citation citation-type="confproc"><person-group person-group-type="author"><name><surname>Kodama</surname><given-names>R</given-names></name><name><surname>Miyao</surname><given-names>H</given-names></name><name><surname>Sawada</surname><given-names>K</given-names></name><name><surname>Ishida</surname><given-names>M</given-names></name><name><surname>Takao</surname><given-names>H</given-names></name></person-group><article-title>Highly Sensitive Micro Force Sensor Array with In-pixel Type CV Conversion Circuits</article-title><conf-name>Proceedings of 27th Conference on the Electrical Engineering and Micromachining</conf-name><conf-loc>Matsue, Japan</conf-loc><conf-date>14–15 October 2010</conf-date><fpage>161</fpage><lpage>166</lpage></citation></ref></ref-list>
<sec sec-type="display-objects">
<title>Figures and Tables</title>
<fig id="f1-sensors-11-06197" position="float">
<label>Figure 1.</label>
<caption>
<p>Side-view cross-section of the humidity sensor.</p></caption>
<graphic xlink:href="sensors-11-06197f1.gif"/></fig>
<fig id="f2-sensors-11-06197" position="float">
<label>Figure 2.</label>
<caption>
<p>Microphotograph of the humidity-sensing surface.</p></caption>
<graphic xlink:href="sensors-11-06197f2.gif"/></fig>
<fig id="f3-sensors-11-06197" position="float">
<label>Figure 3.</label>
<caption>
<p>Schematic of the CMOS humidity sensor.</p></caption>
<graphic xlink:href="sensors-11-06197f3.gif"/></fig>
<fig id="f4-sensors-11-06197" position="float">
<label>Figure 4.</label>
<caption>
<p>Typical input waveforms for the developed C/V converter.</p></caption>
<graphic xlink:href="sensors-11-06197f4.gif"/></fig>
<fig id="f5-sensors-11-06197" position="float">
<label>Figure 5.</label>
<caption>
<p>Hysteresis of humidity sensor at 25 °C.</p></caption>
<graphic xlink:href="sensors-11-06197f5.gif"/></fig>
<fig id="f6-sensors-11-06197" position="float">
<label>Figure 6.</label>
<caption>
<p>Temperature dependence of the sensor output.</p></caption>
<graphic xlink:href="sensors-11-06197f6.gif"/></fig>
<table-wrap id="t1-sensors-11-06197" position="float">
<label>Table 1.</label>
<caption>
<p>Performance Summary 1st Batch of five Humidity Sensors.</p></caption>
<table frame="hsides" rules="groups">
<thead>
<tr>
<th align="left" valign="bottom"><bold>Parameter</bold></th>
<th align="left" valign="middle"><bold>Min.</bold></th>
<th align="left" valign="middle"><bold>Typ.</bold></th>
<th align="left" valign="middle"><bold>Max.</bold></th></tr></thead>
<tbody>
<tr>
<td align="left" valign="top">Humidity range, RH%</td>
<td align="left" valign="top">10</td>
<td align="left" valign="top">−</td>
<td align="left" valign="top">95</td></tr>
<tr>
<td align="left" valign="top">Operating temperature range, °C</td>
<td align="left" valign="top">5</td>
<td align="left" valign="top">−</td>
<td align="left" valign="top">120</td></tr>
<tr>
<td align="left" valign="top">Hysteresis, RH%</td>
<td align="left" valign="top">4.4</td>
<td align="left" valign="top">5.5</td>
<td align="left" valign="top">6.6</td></tr>
<tr>
<td align="left" valign="top">Voltage Temperature Coefficient, RH%/°C</td>
<td align="left" valign="top">−0.61</td>
<td align="left" valign="top">0.07</td>
<td align="left" valign="top">0.19</td></tr>
<tr>
<td align="left" valign="top">Accuracy (best fit straight line), RH%</td>
<td align="left" valign="top">1.1</td>
<td align="left" valign="top">1.3</td>
<td align="left" valign="top">1.7</td></tr>
<tr>
<td align="left" valign="top">Response time, 1/e at 95% to 45% RH change, s</td>
<td align="left" valign="top">−</td>
<td align="left" valign="top">70</td>
<td align="left" valign="top">−</td></tr>
<tr>
<td align="left" valign="top">Voltage at 0% RH (extrapolated), mV</td>
<td align="left" valign="top">146</td>
<td align="left" valign="top">160</td>
<td align="left" valign="top">168</td></tr>
<tr>
<td align="left" valign="top">Gain, mV/RH%</td>
<td align="left" valign="top">0.34</td>
<td align="left" valign="top">0.37</td>
<td align="left" valign="top">0.39</td></tr>
<tr>
<td align="left" valign="top">Output impedance, MOhm</td>
<td align="left" valign="top">−</td>
<td align="left" valign="top">1</td>
<td align="left" valign="top">−</td></tr>
<tr>
<td align="left" valign="top">Power dissipation at 1V power supply, uW</td>
<td align="left" valign="top">1.3</td>
<td align="left" valign="top">1.6</td>
<td align="left" valign="top">1.9</td></tr>
<tr>
<td align="left" valign="top">Power supply voltage range, Vρ</td>
<td align="left" valign="top">0.8</td>
<td align="left" valign="top">1</td>
<td align="left" valign="top">1.8</td></tr>
<tr>
<td align="left" valign="top">Chip area with pads, mm2 (6 0.1 × 0.1 mm pads)</td>
<td align="left" valign="top"/>
<td align="left" valign="top">0.52</td>
<td align="left" valign="top"/></tr></tbody></table></table-wrap>
<table-wrap id="t2-sensors-11-06197" position="float">
<label>Table 2.</label>
<caption>
<p>Comparison of the Humidity Sensors.</p></caption>
<table frame="hsides" rules="groups">
<thead>
<tr>
<th align="center" valign="middle"><bold>Device Name</bold></th>
<th align="center" valign="middle"><bold>Power</bold></th>
<th align="center" valign="middle"><bold>Accuracy</bold></th>
<th align="center" valign="middle"><bold>Price, USD</bold></th></tr></thead>
<tbody>
<tr>
<td align="center" valign="top">This work</td>
<td align="center" valign="top">1.6</td>
<td align="center" valign="top">5</td>
<td align="center" valign="top">1.7 (estimated)</td></tr>
<tr>
<td align="center" valign="top">[<xref ref-type="bibr" rid="b4-sensors-11-06197">4</xref>] (SHT11)</td>
<td align="center" valign="top">28</td>
<td align="center" valign="top">5</td>
<td align="center" valign="top">36</td></tr>
<tr>
<td align="center" valign="top">HIH5030</td>
<td align="center" valign="top">540</td>
<td align="center" valign="top">3</td>
<td align="center" valign="top">6</td></tr>
<tr>
<td align="center" valign="top">CHS-UGS</td>
<td align="center" valign="top">3,000</td>
<td align="center" valign="top">4.5</td>
<td align="center" valign="top">17</td></tr></tbody></table></table-wrap></sec></back></article>
