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• Tebbani, D
• Mosset, P
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Molbank 2012, 2012(4), M790; doi:10.3390/M790

Short Note

5-(tert-Butyldimethylsilyloxy)-1-(2-chloro-5,8-dimethoxyquinolin-3-yl)-3-methylenepentan-1-ol

Linda Bouarata ¹ , Dahmane Tebbani ^1,*  and Paul Mosset ²

¹ Département de chimie, Faculté des sciences, Université de Constantine 1, Constantine 25000, Algeria ² Université de Rennes 1, Institut des Sciences Chimiques de Rennes, CNRS UMR 6226, Avenue du Général Leclerc, 35042 Rennes Cedex, France

* Author to whom correspondence should be addressed.

Received: 30 October 2012 / Accepted: 4 December 2012 / Published: 14 December 2012

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Abstract: Novel 5-(tert-butyldimethylsilyloxy)-1-(2-chloro-5,8-dimethoxyquinolin-3-yl)-3-methylenepentan-1-ol (7) was prepared via allylation of 2-chloro-5,8-dimethoxyquinoline-3-carbaldehyde (6) with functionalized allylic iodide as tert-butyl-(3-(iodomethyl)but-3-enyloxy)dimethylsilane (5), in the presence of metallic indium in anhydrous DMF as solvent at ambient temperature. The structure of the synthesized compound was assigned on the basis of elemental analysis and spectral data.

Keywords: functionalized allylic iodide; allylation; indium; quinoline derivatives

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