Abstract: Herein, we synthesized 2,3-diaminophenazine (DAP) from o-phenylenediamine (OP) using fungal laccase as a biocatalyst. The conversion ratio of OP monomer was 85% and the yield of the final purified product, DAP, was 63%. The structure of the main product, DAP, was confirmed by using several spectroscopy techniques (UV-VIS, IR, 2D-NMR, and MS).
Keywords: 2,3-diaminophenazine; laccase; o-phenylenediamine; biosynthesis
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Zhou, P.; Liu, H.; Chen, S.; Lucia, L.; Zhan, H.; Fu, S. 2,3-Diaminophenazine. Molbank 2011, 2011, M730.
Zhou P, Liu H, Chen S, Lucia L, Zhan H, Fu S. 2,3-Diaminophenazine. Molbank. 2011; 2011(3):M730.
Zhou, Pandeng; Liu, Hao; Chen, Shicheng; Lucia, Lucian; Zhan, Huaiyu; Fu, Shiyu. 2011. "2,3-Diaminophenazine." Molbank 2011, no. 3: M730.