3-Methyl-1-phenyl-1H-pyrazol-5-yl 2-Bromo-3-furan-carboxylate

doi:10.3390/M603

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Molbank 2009, 2009(3), M603; doi:10.3390/M603

Short Note

3-Methyl-1-phenyl-1H-pyrazol-5-yl 2-Bromo-3-furan-carboxylate

Wolfgang Holzer ¹^,* , Changbin Guo ^1,2 and Karin Schalle ¹

¹ Department of Drug and Natural Product Synthesis, University of Vienna, Althanstrasse 14, A-1090 Vienna, Austria
² Department of Chemistry, Capital Normal University, Xisanhuanbei Road 105, Beijing 100048, China

^* Author to whom correspondence should be addressed.

Received: 29 May 2009 / Accepted: 1 July 2009 / Published: 3 July 2009

Download PDF Full-Text [207 KB, Version of Record, uploaded 3 July 2009 02:14 CET]

Abstract: The reaction of 3-methyl-1-phenyl-2-pyrazolin-5-one and 2-bromo-3-furoyl chloride in the presence of Ca(OH)₂ in 1,4-dioxane gave the title compound. The latter was also obtained in much higher yield upon reaction of the starting materials in the system dichloromethane / triethylamine. Detailed spectroscopic data (¹H NMR, ¹³C NMR, ¹⁵N NMR, IR, MS) are presented.

Keywords: pyrazolones; aroylation; NMR spectroscopy

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Cite This Article

MDPI and ACS Style

Holzer, W.; Guo, C.; Schalle, K. 3-Methyl-1-phenyl-1H-pyrazol-5-yl 2-Bromo-3-furan-carboxylate. Molbank 2009, 2009, M603.

AMA Style

Holzer W., Guo C., Schalle K. 3-Methyl-1-phenyl-1H-pyrazol-5-yl 2-Bromo-3-furan-carboxylate. Molbank. 2009; 2009(3):M603.

Chicago/Turabian Style

Holzer, Wolfgang; Guo, Changbin; Schalle, Karin. 2009. "3-Methyl-1-phenyl-1H-pyrazol-5-yl 2-Bromo-3-furan-carboxylate." Molbank 2009, no. 3: M603.

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