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Molbank 2006, 2006(6), M521; doi:10.3390/M521

The First Example of Oxidative Nucleophilic Substitution of Hydrogen in meso-Aryl Ring of the 5,10,15,20-Tetraphenylporphyrin Derivatives

Institute of Chemistry, University of Podlasie, ul. 3 Maja 54, 08-110 Siedlce, Poland
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Received: 11 October 2006 / Accepted: 20 October 2006 / Published: 1 December 2006
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Abstract

A synthesis of [2-nitro-5-(10,15,20-triphenylporphyrin-5-yl)-phenyl]phenyl-acetonitrile zinc complex by the reaction of the respective nitroporphyrin with the anion of benzyl cyanide, followed by addition of DDQ, is described. This is the first example of this type of process in the nitrophenyl side ring of meso-tetraarylporphyrin derivatives. View Full-Text
Keywords: Porphyrins; Carbanions; Oxidative Nucleophilic Substitution of Hydrogen; Zinc Porphyrins; Carbanions; Oxidative Nucleophilic Substitution of Hydrogen; Zinc
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Mikus, A.; Kisielińska, E.; Ostrowski, S. The First Example of Oxidative Nucleophilic Substitution of Hydrogen in meso-Aryl Ring of the 5,10,15,20-Tetraphenylporphyrin Derivatives. Molbank 2006, 2006, M521.

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