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Int. J. Mol. Sci. 2003, 4(3), 107-118; doi:10.3390/i4030107
Article

Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants

 and *
Received: 5 August 2002; Accepted: 5 November 2002 / Published: 25 February 2003
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Abstract: Complete analysis of 1H-NMR spectra of trans-1,2-dichlorocyclopentane and trans-1,2-dibromocyclopentane was performed with use of our total lineshape fitting algorithm VALISA. The resulting high precision spin-spin coupling constants were then applied to the problem of conformational analysis, yielding a continuos potential of pseudorotation for the studied compounds in CDCl3, CCl4, and CD3CN solutions.
Keywords: High resolution NMR; pseudorotation; NMR lineshape; cyclopentane conformations; VALISA High resolution NMR; pseudorotation; NMR lineshape; cyclopentane conformations; VALISA
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Zubkov, S.V.; Chertkov, V.A. Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants. Int. J. Mol. Sci. 2003, 4, 107-118.

AMA Style

Zubkov SV, Chertkov VA. Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants. International Journal of Molecular Sciences. 2003; 4(3):107-118.

Chicago/Turabian Style

Zubkov, Sergei V.; Chertkov, Vyacheslav A. 2003. "Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants." Int. J. Mol. Sci. 4, no. 3: 107-118.


Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert