Int. J. Mol. Sci. 2003, 4(3), 107-118; doi:10.3390/i4030107
Article

Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants

NMR laboratory, Department of Chemistry, Moscow State University, Moscow, 119899, Russia
* Author to whom correspondence should be addressed.
Received: 5 August 2002; Accepted: 5 November 2002 / Published: 25 February 2003
PDF Full-text Download PDF Full-Text [417 KB, uploaded 28 August 2008 16:06 CEST]
Abstract: Complete analysis of 1H-NMR spectra of trans-1,2-dichlorocyclopentane and trans-1,2-dibromocyclopentane was performed with use of our total lineshape fitting algorithm VALISA. The resulting high precision spin-spin coupling constants were then applied to the problem of conformational analysis, yielding a continuos potential of pseudorotation for the studied compounds in CDCl3, CCl4, and CD3CN solutions.
Keywords: High resolution NMR; pseudorotation; NMR lineshape; cyclopentane conformations; VALISA

Article Statistics

Load and display the download statistics.

Citations to this Article

Cite This Article

MDPI and ACS Style

Zubkov, S.V.; Chertkov, V.A. Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants. Int. J. Mol. Sci. 2003, 4, 107-118.

AMA Style

Zubkov SV, Chertkov VA. Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants. International Journal of Molecular Sciences. 2003; 4(3):107-118.

Chicago/Turabian Style

Zubkov, Sergei V.; Chertkov, Vyacheslav A. 2003. "Experimental Determination of Pseudorotation Potentials for Disubstituted Cyclopentanes Based on Spin–Spin Coupling Constants." Int. J. Mol. Sci. 4, no. 3: 107-118.

Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert