Int. J. Mol. Sci. 2012, 13(5), 5878-5898; doi:10.3390/ijms13055878
Article

A Comparative Study on the Mechanical, Thermal and Morphological Characterization of Poly(lactic acid)/Epoxidized Palm Oil Blend

1 Department of Chemistry, Faculty of Science, University Putra Malaysia, UPM Serdang, Selangor 43400, Malaysia 2 Chemistry Department, Center for Defence Foundation Studies, National Defence University of Malaysia, Kuala Lumpur 57000, Malaysia 3 Advanced Oleochemical Technology Division, Malaysian Palm Oil Board, Bandar Baru Bangi 43650, Malaysia
* Authors to whom correspondence should be addressed.
Received: 29 March 2012; in revised form: 24 April 2012 / Accepted: 8 May 2012 / Published: 16 May 2012
PDF Full-text Download PDF Full-Text [1296 KB, uploaded 16 May 2012 11:09 CEST]
Abstract: In this work, poly(lactic acid) (PLA) a fully biodegradable thermoplastic polymer matrix was melt blended with three different epoxidized palm oil (EPO). The aim of this research was to enhance the flexibility, mechanical and thermal properties of PLA. The blends were prepared at various EPO contents of 1, 2, 3, 4 and 5 wt% and characterized. The SEM analysis evidenced successful modification on the neat PLA brittle morphology. Tensile tests indicate that the addition of 1 wt% EPO is sufficient to improve the strength and flexibility compared to neat PLA. Additionally, the flexural and impact properties were also enhanced. Further, DSC analysis showed that the addition of EPO results in a decrease in Tg, which implies an increase in the PLA chain mobility. In the presence of 1 wt% EPO, TGA results revealed significant increase in the thermal stability by 27%. Among the three EPOs used, EPO(3) showed the best mechanical and thermal properties compared to the other EPO’s, with an optimum loading of 1 wt%. Conclusively, EPO showed a promising outcome to overcome the brittleness and improve the overall properties of neat PLA, thus can be considered as a potential plasticizer.
Keywords: melt blending; plasticizer; bioplastic; biodegradable plastic

Article Statistics

Load and display the download statistics.

Citations to this Article

Cite This Article

MDPI and ACS Style

Silverajah, V.S.G.; Ibrahim, N.A.; Yunus, W.M.Z.W.; Hassan, H.A.; Woei, C.B. A Comparative Study on the Mechanical, Thermal and Morphological Characterization of Poly(lactic acid)/Epoxidized Palm Oil Blend. Int. J. Mol. Sci. 2012, 13, 5878-5898.

AMA Style

Silverajah VSG, Ibrahim NA, Yunus WMZW, Hassan HA, Woei CB. A Comparative Study on the Mechanical, Thermal and Morphological Characterization of Poly(lactic acid)/Epoxidized Palm Oil Blend. International Journal of Molecular Sciences. 2012; 13(5):5878-5898.

Chicago/Turabian Style

Silverajah, V. S. Giita; Ibrahim, Nor Azowa; Yunus, Wan Md Zin Wan; Hassan, Hazimah Abu; Woei, Chieng Buong. 2012. "A Comparative Study on the Mechanical, Thermal and Morphological Characterization of Poly(lactic acid)/Epoxidized Palm Oil Blend." Int. J. Mol. Sci. 13, no. 5: 5878-5898.

Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert