Next Article in Journal
Synthesis of “Acetylene-Expanded” Tridentate Ligands
Previous Article in Journal
A New Palladium-Catalyzed Phenyl-Alkene Bond Formation
Article Menu

Article Versions

Export Article

Open AccessArticle
Molecules 2002, 7(5), 437-446; doi:10.3390/70500437

Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside

1
Institute of Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-84238 Bratislava, Slovakia
2
Department of Inorganic Environmental Chemistry, Chalmers University of Technology, SE-41296 Göteborg, Sweden
3
Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-84236 Bratislava, Slovakia
*
Author to whom correspondence should be addressed.
Received: 14 November 2001 / Revised: 13 May 2002 / Accepted: 13 May 2002 / Published: 31 May 2002
Download PDF [345 KB, uploaded 18 June 2014]

Abstract

Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside was prepared in high yield from methyl 6-deoxy-2,3-O-isopropylidene-α-D-lyxopentodialdo-1,4-furanoside. The configuration at the C5 atom was unambiguosly established by single crystal X-ray analysis of the corresponding 5-O-acetyl derivative. The conformation of the furanose and 1,3-dioxolane rings is also discussed.
Keywords: Saccharide cyanohydrins; methyl 2; 3-O-isopropylidene-β-L-gulofuranoside; Xray crystallography; conformation Saccharide cyanohydrins; methyl 2; 3-O-isopropylidene-β-L-gulofuranoside; Xray crystallography; conformation
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Mičová, J.; Steiner, B.; Koóš, M.; Gajdoš, J.; Langer, V.; Gyepesová, D. Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside. Molecules 2002, 7, 437-446.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top