Molecules 2002, 7(5), 437-446; doi:10.3390/70500437
Article

Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside

Received: 14 November 2001; in revised form: 13 May 2002 / Accepted: 13 May 2002 / Published: 31 May 2002
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside was prepared in high yield from methyl 6-deoxy-2,3-O-isopropylidene-α-D-lyxopentodialdo-1,4-furanoside. The configuration at the C5 atom was unambiguosly established by single crystal X-ray analysis of the corresponding 5-O-acetyl derivative. The conformation of the furanose and 1,3-dioxolane rings is also discussed.
Keywords: Saccharide cyanohydrins; methyl 2; 3-O-isopropylidene-β-L-gulofuranoside; Xray crystallography; conformation
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MDPI and ACS Style

Mičová, J.; Steiner, B.; Koóš, M.; Gajdoš, J.; Langer, V.; Gyepesová, D. Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside. Molecules 2002, 7, 437-446.

AMA Style

Mičová J, Steiner B, Koóš M, Gajdoš J, Langer V, Gyepesová D. Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside. Molecules. 2002; 7(5):437-446.

Chicago/Turabian Style

Mičová, Júlia; Steiner, Bohumil; Koóš, Miroslav; Gajdoš, Ján; Langer, Vratislav; Gyepesová, Dalma. 2002. "Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside." Molecules 7, no. 5: 437-446.

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