Environments

The Dismantling and Decommissioning (D&D) of nuclear facilities poses several challenges for radioactivity measurement laboratories involved in environmental radiation monitoring plans. One of them is the definition of the detection limits to be achieved for the radionuclides analysis in different samples. The detection limits should be set in such a way that the obtained concentration values for each radionuclide are easily discriminated from certain maximum activity concentration levels. These maximum activity concentration levels are usually set in view of the respective dose contributions from each radionuclide. There are some national legislations that settle detection limits for drinking water. However, there is no regulation containing detection limits for groundwater or surface water. In this way, different institutions or companies require very different detection limits for radioactivity concentration assessment in those types of water associated with D&D activities. In this work, we focus on the detection limits required for the D&D activities in rainwater, surface water and groundwater. We propose detection limits obtained by applying the WHO methodology for maximum activity concentration levels and compare with those requested by radioactive waste management agencies and regulatory bodies. Some real cases where our proposal allows identification of events are analysed and conclusions are extracted. Full article

Recently exposed reservoir sediments, prone to colonization by invasive species, provide novel settings to test hypotheses related to soil conditions and propagule supply as potential drivers of plant assembly in disturbed ecosystems. We used a dam removal site in southwestern Wisconsin to examine the relationship between the physiochemical properties of dewatered sediments, seeding density, and plant community assembly. The plant communities from five seed densities (1000, 500, 250, 125, and 0 seed m⁻²) were annually assessed over four years. We hypothesized (1) that the native aboveground biomass and the proportion of native to invasive (non-seeded species) aboveground biomass would increase with the seeding density and (2) that the diversity of seeded native species would increase with a higher seeding density. We found evidence that sowing at least 500 seeds m⁻² of prairie species increased their abundance, establishment, and plot diversity compared to non-seeded plants that persisted four years after seeding (p < 0.05). The seeding density treatments led to the assembly of two distinct communities: “native” and “invasive”. The “native” community, assembled in plots seeded with at least 500 seeds m⁻², had a greater aboveground biomass and diversity (i.e., richness) of seeded plants compared to plots with lower seed densities, and its productivity was positively related to this richness. In the “weedy” community, the diversity of invasive species had no relationship to their aboveground biomass, likely because these species share similar traits (i.e., redundancy) and may have performed similar functions within the plant community. These findings suggest that the seeding density interacted with the disturbed soil resources to increase the diversity and productivity of seeded native species and may serve as a positive feedback mechanism for the establishment of native communities in dewatered sediments. Full article

This study investigates the environmental impacts caused by the scaling up of the photocatalytic purification of drinking water using ultraviolet light-emitting diode technology. The life cycle assessment methodology was utilised to estimate the environmental impacts of two different reactor setups commonly used in lab-scale studies: an immobilised and a suspended TiO₂ catalytic system. The functional unit adopted was the treatment of 1 L of water with an initial 7.8 mg/L concentration of natural organic matter, achieving a final 1 mg/L concentration. The use of a suspended photocatalyst was found to have an environmental footprint that was 87% lower than that of the immobilised one. From the sensitivity analysis, the environmental hotspots of the treatment process were the electricity usage and immobilised catalyst production. Therefore, alternative scenarios investigating the use of a renewable electricity mix and recyclable materials were explored to enhance the environmental performance of the photocatalytic treatment process. Using a renewable electricity mix, a decrease of 55% and 15% for the suspended and immobilised catalyst, respectively, was observed. Additionally, the process of recycling the glass used to support the immobilised catalyst achieved a maximum reduction of 22% in the environmental impact from the original scenario, with 100 glass reuses appearing to provide diminishing returns on the environmental impact savings. Full article

Copepods dominate marine zooplankton in abundance and play key roles in pelagic food webs. These small crustaceans show high taxonomic and functional diversity. Although there has been considerable research on their taxonomy, only a few studies have focused on their functional traits. In this study, we analyzed the functional traits of 95 copepod species, considering their body size, trophic regime, feeding behavior, and spawning strategy. Based on samples collected during two surveys (autumn 2020 and summer 2021) located in the coastal waters of three gulfs (Gaeta, Naples, and Salerno) in the highly populated Campania region (the central Tyrrhenian Sea, NW Mediterranean), we identified nine functional groups of copepods with different characteristics. The group that comprised herbivorous copepods with feeding currents and a broadcast strategy was the most abundant in both seasons and all gulfs. This group was dominated by Acartia clausi, Centropages typicus, Temora stylifera, and the Paracalanus parvus complex. The other functional groups showed differences in their temporal and spatial distribution. Our study reports the functional diversity of copepods along the Campania coast, thus contributing to advancing our knowledge of the planktonic trophic structure in a region of considerable importance due to its marine resources and services. Full article

Background: Escalating global plastic production, expected to reach 34,000 million tons by 2050, poses a significant threat to human and environmental well-being, particularly in aquatic ecosystems. Microplastics (MP) and nanoplastics (NP), which originate from the degradation of plastics, are of concern due to their potential bioaccumulation and uptake of pollutants. This study addresses identification methods and focuses on insect meal, a raw material for aquaculture feed. Methods: By using different techniques, the study was able to detect MP and NP in insect meal samples. Chemical digestion with KOH at 60 °C efficiently removed organic matter without affecting the synthetic polymer polyethylene (PE). Filtration, confocal Raman microscopy, SEM, and TEM were used for comprehensive analysis, and integrity tests on PE films were performed using Raman and FTIR spectroscopy. The results showed the presence of PE microplastic particles in the insect meal, which was confirmed by correlative Raman and SEM mapping on a positively charged surface. In addition, the increased resolution of the Raman microscope identified submicrometric PE NP (800 nm). Transmission electron microscopy (TEM) with energy-dispersive X-ray spectroscopy (EDX) confirmed plastic-like structures in the insect meal, highlighting the presence of PE plastics characterized by irregular shapes and some agglomeration. The higher carbon concentration in the EDX analysis supported the plastic nature, which was also confirmed by Raman spectroscopy. Conclusions: The study provides a robust method for the detection of MP and NP in insect meal and provides valuable insight into the possible presence of plastics in insect-based aquafeeds. The combination of different analytical methods increases the reliability of the results and sets the stage for future investigations that could focus on the quantification of NP and the assessment of their potential environmental impact. Full article

This article seeks to provide an improved and more comprehensive understanding of the concept and theories on wasteland. It achieves this by focusing on the Indian context, allowing us to unpack the importance of including multiple perspectives of wasteland narratives; this means including more positive narratives of the potential of wasteland to inform and improve prospects for land policies in the Global South. Wasteland is commonly recognized as an underutilized category of land that may transform into a valuable resource base with proper management measures. The term waste has multiple angles that carry different notions ranging from fallow to agroforestry land in the Global South and brownfield to green space in the Global North. We conduct a narrative review approach to qualitatively analyze the concept of wastelands, which has been studied in the pre-existing literature from 1970 to the present. This unsystematic literature review approach incorporates multiple elements of wasteland discourse, like understanding the meaning of the term on a global scale, setting out the meaning of the term waste into multiple perspectives explicitly in the Indian context, along with different classes and management approaches to wasteland from a national perspective. The multiple perspectives of wasteland not only generate misconceptions of land resources but spawn difficulties in land-use policy, particularly for the Indian scenario. For sustainable land-use policy, reclaiming wasteland would be the best possible way for India and other countries in the Global South, which requires a comprehensive methodological overview on wasteland narrative. Full article

Cultures in Mediterranean climate zones (MCZs) around the world have long been reliant on groundwater and springs as freshwater sources. While their ecology and cultural sustainability are recognized as critically important, inter-relationships between springs and culture in MCZs have received less attention. Here we augmented a global literature review with case studies in MCZ cultural landscapes to examine the diversity and intensity of cultural and socio-economic relationships on spring ecohydrogeology. MCZs are often oriented on western and southern coasts in tectonically active landscapes which control aquifer structure, the prevalence of westerly winds, and aridity, and generally expose associated habitats and cultures to harsh afternoon sunlight. Cultural appreciation and appropriation of springs ranges widely, from their use as subsistence water supplies to their roles in profound traditions such as Greco-Roman nymphalea as well as Asian and Abrahamic spiritual cleansing and baptism. The abandonment of traditional ways of life, such as rural livestock production, for urban ones has shifted impacts on aquifers from local to regional groundwater exploitation. The commoditization of water resources for regional agricultural, industrial (e.g., mining, water bottling, geothermal resorts), and urban uses is placing ever-increasing unsustainable demands on aquifers and spring ecosystems. When the regional economic value of springs approaches or exceeds local cultural values, these irreplaceable aquatic ecosystems are often degraded, over-looked, and lost. Sustainable stewardship of springs and the aquifers that support them is a poorly recognized but central conservation challenge for modern Mediterranean societies as they face impending impacts of global climate change. Solutions to this crisis require education, societal dialogue, and improved policy and implementation. Full article

The long-term use of copper (Cu)-based fungicide sprays in orchards is associated with changes in soil Cu levels. However, there is a gap in knowledge regarding the potential accumulation of Cu in orchards and the associated impacts on the soil microbial structure. This study assessed the possibility of Cu accumulation in different avocado orchard farms and further evaluated the potential effect on soil microbial activities. Soil Cu levels were quantified in Tauranga and Northland, and three avocado orchards were analysed in each experimental location. All avocado farms in both sites received Cu-based fungicide sprays for over eight years. Soil samples were collected at a 0–20 cm depth from all six orchards. The soil total and bioavailable Cu, changes in soil chemical properties, microbial biomass, dehydrogenase activity, alkaline phosphatase activity, and acid phosphatase activity were measured. The results revealed that the total Cu and bioavailable Cu concentrations in Tauranga orchards were 81.3 and 0.32, 196.7 and 0.82, and 33.6 and 0.31 mg Cu kg⁻¹ in Farms 1, 2, and 3, respectively. In Northland orchards, the total Cu and bioavailable Cu were 54.5 and 0.06, 18.4 and 0.77, and 46 and 0.34 mg Cu kg⁻¹ in Farm 1, 2, and 3, respectively. Five out of six of the avocado orchard farms assessed in this study had total Cu concentrations greater than 30 mg Cu kg⁻¹ reported in New Zealand native land. The magnitude of Cu accumulation was linked with soil pH and C content. No clear trend was observed between soil Cu concentrations and the soil microbial activity. Our study results demonstrated that the long-term use of Cu-based fungicide sprays can elevate Cu concentrations in orchard soils. Mitigation strategies need to be explored to abate the accumulation of Cu in orchard soils. Full article

In light of growing concerns regarding greenhouse gas emissions and the increasingly severe impacts of climate change, the global situation demands immediate action to transition towards sustainable energy solutions. In this sense, hydrogen could play a fundamental role in the energy transition, offering a potential clean and versatile energy carrier. This paper reviews the recent results of Life Cycle Assessment studies of different hydrogen production pathways, which are trying to define the routes that can guarantee the least environmental burdens. Steam methane reforming was considered as the benchmark for Global Warming Potential, with an average emission of 11 kg_CO2eq/kg_H2. Hydrogen produced from water electrolysis powered by renewable energy (green H₂) or nuclear energy (pink H₂) showed the average lowest impacts, with mean values of 2.02 kg_CO2eq/kg_H2 and 0.41 kg_CO2eq/kg_H2, respectively. The use of grid electricity to power the electrolyzer (yellow H₂) raised the mean carbon footprint up to 17.2 kg_CO2eq/kg_H2, with a peak of 41.4 kg_CO2eq/kg_H2 in the case of countries with low renewable energy production. Waste pyrolysis and/or gasification presented average emissions three times higher than steam methane reforming, while the recourse to residual biomass and biowaste significantly lowered greenhouse gas emissions. The acidification potential presents comparable results for all the technologies studied, except for biomass gasification which showed significantly higher and more scattered values. Regarding the abiotic depletion potential (mineral), the main issue is the lack of an established recycling strategy, especially for electrolysis technologies that hamper the inclusion of the End of Life stage in LCA computation. Whenever data were available, hotspots for each hydrogen production process were identified. Full article

In this study, a Long Short-Term Memory (LSTM) network approach is employed to evaluate the prediction performance of PM_2.5 in the Beijing–Tianjin–Hebei region (BTH). The proposed method is evaluated using the hourly air quality datasets from the China National Environmental Monitoring Center, European Center for Medium-range Weather Forecasts ERA5 (ECMWF-ERA5), and Multi-resolution Emission Inventory for China (MEIC) for the years 2016 and 2017. The predicted PM_2.5 concentrations demonstrate a strong correlation with the observed values (R² = 0.871–0.940) in the air quality dataset. Furthermore, the model exhibited the best performance in situations of heavy pollution (PM_2.5 > 150 μg/m³) and during the winter season, with respective R² values of 0.689 and 0.915. In addition, the influence of ECMWF-ERA5’s hourly meteorological factors was assessed, and the results revealed regional heterogeneity on a large scale. Further evaluation was conducted by analyzing the chemical components of the MEIC inventory on the prediction performance. We concluded that the same temporal profile may not be suitable for addressing emission inventories in a large area with a deep learning method. Full article

Rapid urbanization and car-centric mobility solutions have resulted in the degradation of environmental urban quality, impacting people’s health and well-being and city economies and harming urban ecosystems. Faced with the need to tackle traffic pollution, more than 300 low emission zones (LEZs) have been implemented, causing some social controversy. Nonetheless, researchers have focused their studies on evaluating LEZ efficacy towards urban congestion and air pollutants reduction, health and well-being improvement. This study presents a literature review of what is known about acceptability and acceptance of the population regarding the implementation of LEZs, along with the main issues, best practices, and suggestions to promote a better perception and mobility behavior change. Based on research conducted in the Web of Science and Scopus databases, only 36 of 540 peer-reviewed articles on LEZs address public attitudes. Among the main findings, the following stand out: the existing gap in environmental urban quality approaches between countries, namely the Global North; the existence of few studies that evaluate perceptions before and after LEZ implementation; the lack of LEZ studies that consider noise and biodiversity, seeking a broader approach to this measure; and the importance of developing a support package measures that involves affected stakeholders and are adapted to each city’s characteristics. Full article

This study explores the potential of storage lagoons as a quaternary treatment step in wastewater treatment plants (WWTPs), focusing on compliance with the recent European Urban Wastewater Treatment Directive (UWWTD), which mandates an 80% reduction in specific micropollutants. While conventional treatments effectively remove residual nutrients and solids, the potential of storage lagoons as an additional treatment is not fully defined. This research aims to address this gap by assessing the efficacy of storage lagoons in refining the effluent quality at the Cabezo Beaza WWTP, considering recent UWWTD requirements. We conduct a comprehensive assessment of the water quality parameters and micropollutants, before and after the storage lagoon stage, at the Cabezo Beaza WWTP. The results indicate that this strategy of prolonged storage in lagoons manages to meet the reduction objectives established by the Directive, reaching elimination percentages greater than 80% for the majority of the analyzed micropollutants. Our findings suggest that lagoons significantly improve water quality and reduce contaminants beyond conventional treatments, offering environmental and economic benefits. This paper discusses the mechanisms behind these improvements, such as natural sedimentation, microbial activity, and potential phytoremediation. This study contributes to the research on advanced wastewater treatment and supports the integration of storage lagoons as a viable quaternary treatment solution that meets the UWWTD standards. Full article

A review of the last 399 years (1624–2023) on fin whales (Balaenoptera physalus) in the Mediterranean Sea was conducted, based on an extensive compilation of records published in the scientific literature, technical reports, public databases, journals, and social media. A total of 10,716 sightings and 575 mortality events have been computed, analysed by semesters and mapped in order to compare the summer–winter seasons especially and their implications on migration–residence. Visual and acoustic detections, feedings, migrations, primary production areas (chlorophyll), threats and causes of death and their relations have been addressed, and a mini-review on heavy metals and pollutants has been carried out on fin whales in the Mediterranean Sea. Mortality events were most frequent between November and April, coinciding with the decreased sighting period. Ship strikes posed the greatest threat, peaking between May and October, when marine traffic tends to increase in the Mediterranean Sea. Two populations coexist in the Mediterranean Sea, one resident and the other migratory, the latter using the Strait of Gibraltar for its biannual movements. Two areas with a presence of calves (up to 7 m in length) between October and February were detected: one scattered in the northern Mediterranean and the Strait of Gibraltar and its surroundings. A critical zone for collisions has been established according to the results for fin whales in the Mediterranean Sea. Full article

San Francisco Bay’s sediment is currently monitored for a variety of contaminants; however, data regarding the microplastics (MPs) in the area are still scarce. MPs’ occurrence in sediment samples has gained recognition as a reservoir for MP accumulation. Moreover, Bay sediment is also an important matrix for monitoring because sediment tends to accumulate certain contaminants and act as a source of contaminants in the Bay food web. This study analyzed MPs ranging from 25 µm to 5 mm in surface sediment grab samples (n = 8) and two sediment core samples (n = 2 cores analyzed with 11 samples from different depths). Our findings provide an evaluation of MP levels in different regions of the bay. The MP levels detected in Bay surface grab samples ranged from 2.1 to 11.9 MPs/g dry weight (n = 8), with a mean value of 6.2 MPs/g. The most abundant morphology was fibers, followed by fragments and films. Full article

A commercial activated carbon (AC) was modified through iron oxide incorporation to obtain microwave absorbers (MWAs) for microwave-assisted pyrolysis. The influence of iron oxide content (5 and 20 wt% Fe₃O₄) and the modification methods were tested as follows: (1) in situ co-precipitation + washing step with Milli-Q; (2) in situ co-precipitation + washing step with Milli-Q/ethanol; and (3) physical iron oxide blending. The resulting MWAs were evaluated on the microwave-assisted pyrolysis of hardwood in a Milestone Flexiwave microwave reactor. The biochar yield varied from 24 wt% to 89 wt% and was influenced by the modification method rather than the iron oxide addition. The MWAs with physically blended iron oxide resulted in biochar yields comparable to conventional biochar (450 °C). Furthermore, the addition of iron oxide-activated carbon composites during the microwave-assisted pyrolysis caused a significant decrease in the biochar’s 16 EPA polycyclic aromatic hydrocarbons, mainly by reducing the amount of pyrene in the biochar. Full article

In recent decades, the pollution of water with micropollutants has become an increasing environmental concern. Since 2019, increased stormwater pollution from chlorine-based disinfectants has been recorded due to the COVID-19 pandemic. Runoff from disinfected areas and the residual chlorine present in stormwater are transported to surface water bodies, posing a risk to aquatic flora and fauna. The objectives of this study were (1) to evaluate the efficiency of different low-cost and recyclable filter materials in removing residual chlorine, and (2) to test plants’ ability to reduce residual chlorine concentrations through phytoremediation. Experiments were conducted in the laboratory (column and batch) and in the field (raised garden bed) to assess the efficiency of various filter materials (peat, wood chips, sawdust and the lightweight aggregates) in retaining residual chlorine to be implemented in green infrastructure. The best retainers of chlorine were sawdust (96%) and the LWA Leca (76%). No harmful effects of residual chlorine (changes in growth, color, leaf size, etc.) on plants (Tagetes patula or Pisum savitum) were observed and the residual chlorine in the leachate samples was below the equipment’s detection limit. Our research results will contribute to future studies aiming to remove various micropollutants from stormwater using remediation technologies. Full article

Wastewater-based epidemiology has garnered considerable research interest, concerning the COVID-19 pandemic. Restrictive public health interventions and mobility limitations are measures to avert a rising case prevalence. The current study integrates WBE monitoring strategies, Google mobility data, and restriction information to assess the epidemiological development of COVID-19. Various SARIMAX models were employed to predict SARS-CoV-2 cases in Liechtenstein and two Austrian regions. This study analyzes four primary strategies for examining the progression of the pandemic waves, described as follows: 1—a univariate model based on active cases; 2—a multivariate model incorporating active cases and WBE data; 3—a multivariate model considering active cases and mobility data; and 4—a sensitivity analysis of WBE and mobility data incorporating restriction policies. Our key discovery reveals that, while WBE for SARS-CoV-2 holds immense potential for monitoring COVID-19 on a societal level, incorporating the analysis of mobility data and restriction policies enhances the precision of the trained models in predicting the state of public health during the pandemic. Full article

Arsenic (As) is considered one of the most toxic chemicals to both human and environmental health. Mining activities represent one of the main anthropogenic sources of As; the concentration of As in mine soil can reach 9300 mg kg⁻¹. To overcome the major issue of soil As pollution, soil restoration is required. Biological restoration approaches are generally more cost-effective and environmentally sustainable than physical and chemical methods. In particular, phytoremediation, an environmentally friendly technique based on the use of plants to uptake contaminants from soil, has been successfully implemented to restore As-contaminated soils at mine sites. However, mine soils are generally depleted in essential plant nutrients, such as nitrogen (N). Recent research suggests that phytoremediation can be combined with other techniques (physical, chemical, and biological) to enhance the N content and plant biomass. The aim of this review is to assess the current state of knowledge in the field of the restoration of arsenic-impacted mine site soils, focusing on phytoremediation. We critically assess recent work examining the potential of the co-application of amendments with phytoremediation and identify promising technologies and key research gaps. More studies are required to test the effectiveness of using various soil additives to enhance the phytoremediation of As, not only in pot-scale experiments but also in the field, to enable an improved management strategy for mine site restoration in the future. Full article

Reducing greenhouse gas emissions is a crucial challenge in urban areas characterized by high energy consumption and reduced exposure to nature. In this context, the urban green system could play a pivotal role. In the literature, scholars have analyzed both the ability of species-specific and layout-specific green infrastructure to increase carbon sequestration and the best location sites for new green infrastructure to increase the provision of overall ecosystem services. There is a lack of studies helping green urban planners and designers choose where and which green infrastructure to implement based on vegetation species-specific performance and the local carbon emissions of city components. This paper uses tree inventory data from a medium-sized city in central Italy (Perugia) to develop a spatial analysis of urban park performance in carbon sequestration. Then, the method evaluates the carbon emission of a public city building to generate a spatialized balance between building demand and tree supply to support local decisions about the best locations for new green infrastructure and the choice between species. The paper contributes to GIS-based tools that vary the recommended location sites and species for new green infrastructure based on the demanded ecosystem service. Full article