Next Article in Journal
Next Article in Special Issue
Previous Article in Journal
Previous Article in Special Issue
Materials 2011, 4(9), 1599-1618; doi:10.3390/ma4091599
Review

Phase Stability and Elasticity of TiAlN

,
,
,
,
,
 and *
Received: 11 July 2011; in revised form: 29 August 2011 / Accepted: 31 August 2011 / Published: 15 September 2011
(This article belongs to the Special Issue Hard Materials: Advances in Synthesis and Understanding)
Download PDF [777 KB, uploaded 15 September 2011]
Abstract: We review results of recent combined theoretical and experimental studies of Ti1−xAlxN, an archetypical alloy system material for hard-coating applications. Theoretical simulations of lattice parameters, mixing enthalpies, and elastic properties are presented. Calculated phase diagrams at ambient pressure, as well as at pressure of 10 GPa, show a wide miscibility gap and broad region of compositions and temperatures where the spinodal decomposition takes place. The strong dependence of the elastic properties and sound wave anisotropy on the Al-content offers detailed understanding of the spinodal decomposition and age hardening in Ti1−xAlxN alloy films and multilayers. TiAlN/TiN multilayers can further improve the hardness and thermal stability compared to TiAlN since they offer means to influence the kinetics of the favorable spinodal decomposition and suppress the detrimental transformation to w-AlN. Here, we show that a 100 degree improvement in terms of w-AlN suppression can be achieved, which is of importance when the coating is used as a protective coating on metal cutting inserts.
Keywords: hard coatings; spinodal decomposition; ab initio calculations; thermodynamics; multilayer; TiN hard coatings; spinodal decomposition; ab initio calculations; thermodynamics; multilayer; TiN
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |
EndNote


MDPI and ACS Style

Abrikosov, I.A.; Knutsson, A.; Alling, B.; Tasnádi, F.; Lind, H.; Hultman, L.; Odén, M. Phase Stability and Elasticity of TiAlN. Materials 2011, 4, 1599-1618.

AMA Style

Abrikosov IA, Knutsson A, Alling B, Tasnádi F, Lind H, Hultman L, Odén M. Phase Stability and Elasticity of TiAlN. Materials. 2011; 4(9):1599-1618.

Chicago/Turabian Style

Abrikosov, Igor A.; Knutsson, Axel; Alling, Björn; Tasnádi, Ferenc; Lind, Hans; Hultman, Lars; Odén, Magnus. 2011. "Phase Stability and Elasticity of TiAlN." Materials 4, no. 9: 1599-1618.


Materials EISSN 1996-1944 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert