Polydopamine/SWCNT Ink Functionalization of Silk Fabric to Obtain Electroconductivity at a Low Percolation Threshold
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Functionalization of Silk Fabric with SWCNT Ink
3.2. Characterization of Pure Silk Fabric and Silk Fabric Functionalized with SWCNTs
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Eghan, B.; Ofori, E.A.; Seidu, R.K.; Acquaye, R. Recent Progress to Address the Challenges of Conductive Inks for E-Textiles. Eng. Proc. 2023, 52, 3. [Google Scholar]
- Rouhi, N.; Jain, D.; Burke, P.J. High-Performance Semiconducting Nanotube Inks: Progress and Prospects. ACS Nano 2011, 5, 8471–8487. [Google Scholar] [CrossRef] [PubMed]
- Liang, X.; Li, H.; Dou, J.; Wang, Q.; He, W.; Wang, C.; Li, D.; Lin, J.; Zhang, Y. Stable and Biocompatible Carbon Nanotube Ink Mediated by Silk Protein for Printed Electronics. Adv. Mater. 2020, 32, e2000165. [Google Scholar] [CrossRef] [PubMed]
- Horita, Y.; Fukase, T.; Kisaka, H.; Kuromatsu, S.; Sato, Y.; Endo, K.; Watanabe, T.; Suga, R.; Koh, S. Fabrication of highly conductive polyester fabrics using single-wall carbon nanotubes inks for EMI shielding. Jpn. J. Appl. Phys. 2024, 63, 04SP01. [Google Scholar] [CrossRef]
- Talsma, W.; Sengrian, A.A.; Salazar-Rios, J.M.; Duim, H.; Abdu-Aguye, M.; Jung, S.; Allard, S.; Scherf, U.; Loi, M.A. Remarkably Stable, High-Quality Semiconducting Single-Walled Carbon Nanotube Inks for Highly Reproducible Field-Effect Transistors. Adv. Electron. Mater. 2019, 5, 1900288. [Google Scholar] [CrossRef]
- Dragoman, M.; Flahaut, E.; Dragoman, D.; Al Ahmad, M.; Plana, R. Writing simple RF electronic devices on paper with carbon nanotube ink. Nanotechnology 2009, 20, 375203. [Google Scholar] [CrossRef] [PubMed]
- Park, K.T.; Choi, J.; Lee, B.; Ko, Y.; Jo, K.; Lee, Y.M.; Lim, J.A.; Park, C.R.; Kim, H. High-performance thermoelectric bracelet based on carbon nanotube ink printed directly onto a flexible cable. J. Mater. Chem. A 2018, 6, 19727–19734. [Google Scholar] [CrossRef]
- Han, J.-W.; Kim, B.; Li, J.; Meyyappan, M. Carbon nanotube ink for writing on cellulose paper. Mater. Res. Bull. 2014, 50, 249–253. [Google Scholar] [CrossRef]
- Kim, S.J.; Moon, D.-I.; Seol, M.-L.; Kim, B.; Han, J.-W.; Meyyappan, M. Wearable UV Sensor Based on Carbon Nanotube-Coated Cotton Thread. ACS Appl. Mater. Interfaces 2018, 10, 40198–40202. [Google Scholar] [CrossRef]
- Dias, A.C.M.; Gomes-Filho, S.L.; Silva, M.M.; Dutra, R.F. A sensor tip based on carbon nanotube-ink printed electrode for the dengue virus NS1 protein. Biosens. Bioelectron. 2013, 44, 216–221. [Google Scholar] [CrossRef]
- Meng, Y.; Xu, X.-B.; Li, H.; Wang, Y.; Ding, E.-X.; Zhang, Z.-C.; Geng, H.-Z. Optimisation of carbon nanotube ink for large-area transparent conducting films fabricated by controllable rod-coating method. Carbon 2014, 70, 103–110. [Google Scholar] [CrossRef]
- Zhu, C.; Wu, J.; Yan, J.; Liu, X. Advanced Fiber Materials for Wearable Electronics. Adv. Fiber Mater. 2022, 5, 12–35. [Google Scholar] [CrossRef]
- Wen, D.-L.; Sun, D.-H.; Huang, P.; Huang, W.; Su, M.; Wang, Y.; Han, M.-D.; Kim, B.; Brugger, J.; Zhang, H.-X.; et al. Recent progress in silk fibroin-based flexible electronics. Microsystems Nanoeng. 2021, 7, 35. [Google Scholar] [CrossRef] [PubMed]
- Baranowska-Korczyc, A.; Nejman, A.; Rosowski, M.; Cieślak, M. Multifunctional silk textile composites functionalized with silver nanowires. J. Appl. Polym. Sci. 2023, 140, 53882. [Google Scholar] [CrossRef]
- Chen, R.; Lin, B.; Luo, R. Recent progress in polydopamine-based composites for the adsorption and degradation of industrial wastewater treatment. Heliyon 2022, 8, e12105. [Google Scholar] [CrossRef] [PubMed]
- Hong, M.-S.; Park, Y.; Kim, T.; Kim, K.; Kim, J.-G. Polydopamine/carbon nanotube nanocomposite coating for corrosion resistance. J. Materiomics 2020, 6, 158–166. [Google Scholar] [CrossRef]
- Zhao, H.; Chao, Y.; Liu, J.; Huang, J.; Pan, J.; Guo, W.; Wu, J.; Sheng, M.; Yang, K.; Wang, J.; et al. Polydopamine Coated Single-Walled Carbon Nanotubes as a Versatile Platform with Radionuclide Labeling for Multimodal Tumor Imaging and Therapy. Theranostics 2016, 6, 1833–1843. [Google Scholar] [CrossRef]
- Kowalczyk, D.; Fortuniak, W.; Mizerska, U.; Kaminska, I.; Makowski, T.; Brzezinski, S.; Piorkowska, E. Modification of cotton fabric with graphene and reduced graphene oxide using sol–gel method. Cellulose 2017, 24, 4057–4068. [Google Scholar] [CrossRef]
- Shahriar, A. The Optimization of Silk Fabric Production Process. Int. J. Curr. Eng. Technol. 2019, 9, 440–447. [Google Scholar] [CrossRef]
- Baranowska-Korczyc, A.; Hudecki, A.; Kamińska, I.; Cieślak, M. Silk Powder from Cocoons and Woven Fabric as a Potential Bio-Modifier. Materials 2021, 14, 6919. [Google Scholar] [CrossRef]
- Koperska, M.; Pawcenis, D.; Bagniuk, J.; Zaitz, M.; Missori, M.; Łojewski, T.; Łojewska, J. Degradation markers of fibroin in silk through infrared spectroscopy. Polym. Degrad. Stab. 2014, 105, 185–196. [Google Scholar] [CrossRef]
- Zhang, X.; Wyeth, P. Using FTIR spectroscopy to detect sericin on historic silk. Sci. China Chem. 2010, 53, 626–631. [Google Scholar] [CrossRef]
- Das, A.; Pal, A.; Saha, S.; Maji, S.K. Behaviour of fixed-bed column for the adsorption of malachite green on surfactant-modified alumina. J. Environ. Sci. Health Part A 2009, 44, 265–272. [Google Scholar] [CrossRef] [PubMed]
- Gao, X.; Chorover, J. Adsorption of sodium dodecyl sulfate (SDS) at ZnSe and α-Fe2O3 surfaces: Combining infrared spectroscopy and batch uptake studies. J. Colloid Interface Sci. 2010, 348, 167–176. [Google Scholar] [CrossRef] [PubMed]
- Dresselhaus, M.S.; Dresselhaus, G.; Saito, R.; Jorio, A. Raman spectroscopy of carbon nanotubes. Phys. Rep. 2005, 409, 47–99. [Google Scholar] [CrossRef]
- Brown, S.D.M.; Jorio, A.; Dresselhaus, M.S.; Dresselhaus, G. Observations of the D-band feature in the Raman spectra of carbon nanotubes. Phys. Rev. B 2001, 64, 073403. [Google Scholar] [CrossRef]
- Mo, M.; Zhao, W.; Chen, Z.; Yu, Q.; Zeng, Z.; Wu, X.; Xue, Q. Excellent tribological and anti-corrosion performance of polyurethane composite coatings reinforced with functionalized graphene and graphene oxide nanosheets. RSC Adv. 2015, 5, 56486–56497. [Google Scholar] [CrossRef]
- Hussain, S.; Shah, K.A.; Islam, S.S. Investigation of effects produced by chemical functionalization in single-walled and multi-walled carbon nanotubes using Raman spectroscopy. Mater. Sci. 2013, 31, 276–280. [Google Scholar] [CrossRef]
- Sinha, S.K.; Kumar, D.; Patnaik, A. An investigation on thermal stability of single wall carbon nanotubes (SWCNTs) by molecular dynamics simulations. Mater. Today Proc. 2021, 44, 4940–4944. [Google Scholar] [CrossRef]
- Liew, K.M.; Wong, C.H.; He, X.Q.; Tan, M.J. Thermal stability of single and multi-walled carbon nanotubes. Phys. Rev. B 2005, 71, 075424. [Google Scholar] [CrossRef]
- Kang, S.M.; You, I.; Cho, W.K.; Shon, H.K.; Lee, T.G.; Choi, I.S.; Karp, J.M.; Lee, H. One-Step Modification of Superhydrophobic Surfaces by a Mussel-Inspired Polymer Coating. Angew. Chem. Int. Ed. 2010, 49, 9401–9404. [Google Scholar] [CrossRef] [PubMed]
- Zhang, L.; Mehanna, Y.A.; Crick, C.R.; Poole, R.J. Surface Tension and Viscosity Dependence of Slip Length over Irregularly Structured Superhydrophobic Surfaces. Langmuir 2022, 38, 11873–11881. [Google Scholar] [CrossRef] [PubMed]
- PN-EN 1149-1:2008; Protective Clothing–Electrostatic Properties–Part 1: Test Method for Measurement of Surface Resistivity. Polish Committee for Standardization: Warszawa, Poland, 2008.
- PN-EN 1149-2:1999/Ap1:2001; Protective Clothing–Electrostatic Properties–Part 2: Test Method for Measurement of Electrical Resistance. Crossmark: Plano, TX, USA, 2001.
- Eom, T.; Lee, J.; Lee, S.; Ozlu, B.; Kim, S.; Martin, D.C.; Shim, B.S. Highly Conductive Polydopamine Coatings by Direct Electrochemical Synthesis on Au. ACS Appl. Polym. Mater. 2022, 4, 5319–5329. [Google Scholar] [CrossRef]
- Zhang, Q.; Rastogi, S.; Chen, D.; Lippits, D.; Lemstra, P.J. Low percolation threshold in single-walled carbon nanotube/high density polyethylene composites prepared by melt processing technique. Carbon 2006, 44, 778–785. [Google Scholar] [CrossRef]
- Mohan, L.; Kumar, P.N.; Karakkad, S.; Krishnan, S.T. Determination of electrical percolation threshold of carbon nanotube-based epoxy nanocomposites and its experimental validation. IET Sci. Meas. Technol. 2019, 13, 1299–1304. [Google Scholar] [CrossRef]
- Hermant, M.C.; Klumperman, B.; Kyrylyuk, A.V.; van der Schoot, P.; Koning, C.E. Lowering the percolation threshold of single-walled carbon nanotubes using polystyrene/poly(3,4-ethylenedioxythiophene): Poly(styrene sulfonate) blends. Soft Matter 2009, 5, 878–885. [Google Scholar] [CrossRef]
- Elechiguerra, J.L.; Larios-Lopez, L.; Liu, C.; Garcia-Gutierrez, D.; Camacho-Bragado, A.; Yacaman, M.J. Corrosion at the Nanoscale: The Case of Silver Nanowires and Nanoparticles. Chem. Mater. 2005, 17, 6042–6052. [Google Scholar] [CrossRef]
- Maheswaran, R.; Shanmugavel, B.P. A Critical Review of the Role of Carbon Nanotubes in the Progress of Next-Generation Electronic Applications. J. Electron. Mater. 2022, 51, 2786–2800. [Google Scholar] [CrossRef]
Sample Name (Sample Coated with PDA and SWCNT Ink) | Solution for Functionalization, SWCNT Ink/Water (v/v) | SWCNT Ink Deposition on Silk Fabric (g/m2) | Nominal SWCNT Deposition on Silk Fabric (mg/m2) | Nominal SWCNT on Silk Fabric (wt.%) |
---|---|---|---|---|
SWCNT0.01 | 1:7 | 0.44 ± 0.02 | 9 | 0.01 |
SWCNT0.02 | 1:3 | 0.71 ± 0.03 | 14 | 0.02 |
SWCNT0.12 | 1:1.6 | 3.65 ± 0.08 | 73 | 0.12 |
SWCNT0.17 | 1:1 | 5.57 ± 0.05 | 111 | 0.17 |
SWCNT0.21 | 1:0.6 | 6.87 ± 0.12 | 137 | 0.21 |
C (wt.%) | N (wt.%) | O (wt.%) | Na (wt.%) | S (wt.%) | |
---|---|---|---|---|---|
Silk | 48.12 ± 0.14 | 20.97 ± 0.22 | 30.51 ± 0.14 | 0.32 ± 0.01 | 0.08 ± 0.01 |
Silk_PDA | 48.39 ± 0.03 | 20.94 ± 0.16 | 30.60 ± 0.13 | 0.00 | 0.07 ± 0.01 |
SWCNT0.01 | 48.68 ± 0.19 | 20.59 ± 0.32 | 30.47 ± 0.26 | 0.09 ± 0.01 | 0.18 ± 0.00 |
SWCNT0.02 | 48.78 ± 0.12 | 20.67 ± 0.06 | 30.21 ± 0.10 | 0.12 ± 0.00 | 0.22 ± 0.01 |
SWCNT0.12 | 48.99 ± 0.22 | 20.10 ± 0.15 | 30.34 ± 0.20 | 0.23 ± 0.02 | 0.34 ± 0.02 |
SWCNT0.17 | 48.80 ± 0.28 | 20.17 ± 0.27 | 30.33 ± 0.07 | 0.28 ± 0.01 | 0.42 ± 0.03 |
SWCNT0.21 | 48.97 ± 0.23 | 19.77 ± 0.35 | 30.47 ± 0.13 | 0.33 ± 0.01 | 0.46 ± 0.02 |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Baranowska-Korczyc, A.; Kowalczyk, D.; Cieślak, M. Polydopamine/SWCNT Ink Functionalization of Silk Fabric to Obtain Electroconductivity at a Low Percolation Threshold. Int. J. Mol. Sci. 2024, 25, 5024. https://doi.org/10.3390/ijms25095024
Baranowska-Korczyc A, Kowalczyk D, Cieślak M. Polydopamine/SWCNT Ink Functionalization of Silk Fabric to Obtain Electroconductivity at a Low Percolation Threshold. International Journal of Molecular Sciences. 2024; 25(9):5024. https://doi.org/10.3390/ijms25095024
Chicago/Turabian StyleBaranowska-Korczyc, Anna, Dorota Kowalczyk, and Małgorzata Cieślak. 2024. "Polydopamine/SWCNT Ink Functionalization of Silk Fabric to Obtain Electroconductivity at a Low Percolation Threshold" International Journal of Molecular Sciences 25, no. 9: 5024. https://doi.org/10.3390/ijms25095024