Applications of Functionalized Carbon Nanomaterials: Advances and Perspectives

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "2D and Carbon Nanomaterials".

Deadline for manuscript submissions: closed (30 August 2023) | Viewed by 6225

Special Issue Editor


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Guest Editor
Centre for Advanced Material Application (CEMEA), Slovak Academy of Sciences, Dúbravská Cesta 5807/9, 845 11 Bratislava, Slovakia
Interests: carbon nanomaterials; carbon nanotubes; graphene; chemical functionalization; Raman spectroscopy; growth kinetics; electronic properties
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Special Issue Information

Dear Colleagues,

Excellent carrier mobility, high conductivity and tunable electronic structures allow metallic single-walled carbon nanotubes (SWCNTs) to be used as source/drain and gate electrodes, and semiconducting nanotubes as semiconducting channels, in stretchable and transparent transistors, leading to their outstanding electrical properties and growth kinetics studied inside metallocene-filled SWCNTs. The ability of carbon nanomaterials to effectively collect the photogenerated charges from the active layer in solar cells allows them to be utilized as interfacial materials between the active layer and electrode, or directly as transparent conductive electrodes in solar cells, which can lead to high power conversion efficiency. The large Seebeck coefficient, high carrier conductivity and the high thermal stability of carbon nanomaterials makes them a promising thermoelectric material, which can result in large power factors in thermoelectric devices. The tunability of the emission wavelength as a function of diameter and chirality of SWCNTs allows them to be employed in light-emitting devices. The utilization of graphene and nanotubes in light-emitting p–n diodes, where the p- and n-type regions in the nanotubes are formed by doping to create a p–n junction, can also lead to significantly reduced power dissipation, zero threshold current, negligible self-heating and high carrier-to-photon conversion efficiencies. Investigation of the electronic properties of chemically functionalized carbon nanomaterials can be performed by Raman spectroscopy, near-edge X-ray absorption fine-structure spectroscopy, photoemission spectroscopy, and optical absorption spectroscopy. The high surface area and nanoscale dimensions of carbon nanomaterials additionally provide the opportunity to load and deliver diagnostic and therapeutic agents to the tissues and organs. As a result, carbon nanomaterials have the ability to cross the cellular membrane, possess a capacity for Raman scattering, strong near-infrared optical absorption, photoluminescence and photoacoustic response. This makes them a useful tool for bioimaging, drug delivery and anticancer therapy.

This Special Issue will focus on the applications of chemically functionalized carbon nanomaterials, advances and perspectives. Chemically functionalized carbon nanomaterials include carbon nanotubes, graphene, graphene nanoribbons, 2D heterostructures, fullerenes, and nanodiamonds. The Issue is intended to provide a comprehensive overview of the recent and forthcoming progress in the field. It will help researchers to quickly find and identify related and relevant publications for their own work on carbon nanomaterials.

We invite interested authors to submit their original experimental and theoretical papers, as well as review articles within the subject, for inclusion in this Special Issue, which will boost the visibility of their work.

Dr. Marianna Kharlamova
Guest Editor

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Keywords

  • application
  • carbon nanostructure
  • growth kinetics
  • electronic properties
  • Raman spectroscopy
  • near-edge X-ray absorption fine-structure spectroscopy
  • photoemission spectroscopy
  • optical absorption spectroscopy
  • chemical properties, physical properties

Published Papers (4 papers)

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Editorial

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4 pages, 1076 KiB  
Editorial
Filled Carbon Nanotubes: Promising Material for Applications
by Marianna V. Kharlamova
Nanomaterials 2023, 13(17), 2472; https://doi.org/10.3390/nano13172472 - 1 Sep 2023
Cited by 2 | Viewed by 1008
Abstract
Carbon nanotubes (CNTs) were first filled with a number of metals starting in 1993 [...] Full article
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Research

Jump to: Editorial, Review

17 pages, 2749 KiB  
Article
Graphene Amination towards Its Grafting by Antibodies for Biosensing Applications
by Maxim K. Rabchinskii, Nadezhda A. Besedina, Maria Brzhezinskaya, Dina Yu. Stolyarova, Sergei A. Ryzhkov, Sviatoslav D. Saveliev, Grigorii A. Antonov, Marina V. Baidakova, Sergei I. Pavlov, Demid A. Kirilenko, Aleksandr V. Shvidchenko, Polina D. Cherviakova and Pavel N. Brunkov
Nanomaterials 2023, 13(11), 1730; https://doi.org/10.3390/nano13111730 - 25 May 2023
Cited by 3 | Viewed by 1308
Abstract
The facile synthesis of biografted 2D derivatives complemented by a nuanced understanding of their properties are keystones for advancements in biosensing technologies. Herein, we thoroughly examine the feasibility of aminated graphene as a platform for the covalent conjugation of monoclonal antibodies towards [...] Read more.
The facile synthesis of biografted 2D derivatives complemented by a nuanced understanding of their properties are keystones for advancements in biosensing technologies. Herein, we thoroughly examine the feasibility of aminated graphene as a platform for the covalent conjugation of monoclonal antibodies towards human IgG immunoglobulins. Applying core-level spectroscopy methods, namely X-ray photoelectron and absorption spectroscopies, we delve into the chemistry and its effect on the electronic structure of the aminated graphene prior to and after the immobilization of monoclonal antibodies. Furthermore, the alterations in the morphology of the graphene layers upon the applied derivatization protocols are assessed by electron microscopy techniques. Chemiresistive biosensors composed of the aerosol-deposited layers of the aminated graphene with the conjugated antibodies are fabricated and tested, demonstrating a selective response towards IgM immunoglobulins with a limit of detection as low as 10 pg/mL. Taken together, these findings advance and outline graphene derivatives’ application in biosensing as well as hint at the features of the alterations of graphene morphology and physics upon its functionalization and further covalent grafting by biomolecules. Full article
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Review

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19 pages, 4849 KiB  
Review
Direct Application of Carbon Nanotubes (CNTs) Grown by Chemical Vapor Deposition (CVD) for Integrated Circuits (ICs) Interconnection: Challenges and Developments
by Zhenbang Chu, Baohui Xu and Jie Liang
Nanomaterials 2023, 13(20), 2791; https://doi.org/10.3390/nano13202791 - 19 Oct 2023
Cited by 1 | Viewed by 1499
Abstract
With the continuous shrinkage of integrated circuit (IC) dimensions, traditional copper interconnect technology is gradually unable to meet the requirements for performance improvement. Carbon nanotubes have gained widespread attention and research as a potential alternative to copper, due to their excellent electrical and [...] Read more.
With the continuous shrinkage of integrated circuit (IC) dimensions, traditional copper interconnect technology is gradually unable to meet the requirements for performance improvement. Carbon nanotubes have gained widespread attention and research as a potential alternative to copper, due to their excellent electrical and mechanical properties. Among various methods for producing carbon nanotubes, chemical vapor deposition (CVD) has the advantages of mild reaction conditions, low cost, and simple reaction operations, making it the most promising approach to achieve compatibility with integrated circuit manufacturing processes. Combined with through silicon via (TSV), direct application of CVD-grown carbon nanotubes in IC interconnects can be achieved. In this article, based on the above background, we focus on discussing some of the main challenges and developments in the application of CVD-grown carbon nanotubes in IC interconnects, including low-temperature CVD, metallicity enrichment, and contact resistance. Full article
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23 pages, 4110 KiB  
Review
Phemenology of Filling, Investigation of Growth Kinetics and Electronic Properties for Applications of Filled Single-Walled Carbon Nanotubes
by Marianna V. Kharlamova and Christian Kramberger
Nanomaterials 2023, 13(2), 314; https://doi.org/10.3390/nano13020314 - 12 Jan 2023
Cited by 9 | Viewed by 2005
Abstract
This review discusses the phemenology of filling, the investigation of kinetics, and the electronic properties for applications of filled single-walled carbon nanotubes (SWCNTs), and summarizes five main achievements that were obtained in processing the spectroscopic data of SWCNTs filled with metal halogenide, metal [...] Read more.
This review discusses the phemenology of filling, the investigation of kinetics, and the electronic properties for applications of filled single-walled carbon nanotubes (SWCNTs), and summarizes five main achievements that were obtained in processing the spectroscopic data of SWCNTs filled with metal halogenide, metal chalcogenide, metal and metallocenes. First, the methods of processing kinetic data were developed to reveal precise trends in growth rates and activation energies of the growth of SWCNTs. Second, the metal-dependence of kinetics was revealed. Third, metallicity-sorted (metallic and semiconducting) SWCNTs were filled with a range of substances and the electronic properties were investigated. Fourth, new approaches to processing the data of spectroscopic investigations of filled SWCNTs were developed, which allowed more reliable and precise analysis of the experimental results. Fifth, the correlation between the physical and chemical properties of encapsulated substances and the electronic properties of SWCNTs were elucidated. These points are highlighted in the review. Full article
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