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Polymers, Volume 13, Issue 24

2021 December-2 - 199 articles

Cover Story: A model of the polymerization process during the formation of opposing polymer brushes was designed and investigated. Monte Carlo simulations using the dynamic lattice liquid model were employed using a dedicated parallel machine ARUZ in a large size and time scale. The chains were increasingly compressed for high grafting densities, and there was surprisingly little interpenetration of chains from opposite surfaces. View this paper
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Articles (199)

  • Article
  • Open Access
5 Citations
3,772 Views
27 Pages

20 December 2021

Complex electrical impedance and dielectric spectroscopy were applied to study the dielectric relaxations and their thermal behavior in ion-conducting composites/complexes from polymer poly(ethylene oxide) (PEO) and E8 nematic liquid crystals (LCs),...

  • Article
  • Open Access
17 Citations
4,022 Views
19 Pages

20 December 2021

Electrically conductive polymeric nanocomposites with nanoparticles are adaptable types of nanomaterials that are prospective for various applications. The extraordinary features of copper oxide (CuO) and aluminium oxide (Al2O3) nanostructures, encou...

  • Article
  • Open Access
13 Citations
5,441 Views
16 Pages

20 December 2021

The use of wood plastic composites (WPC) is growing very rapidly in recent years, in addition, the use of plastics of renewable origin is increasingly implemented because it allows to reduce the carbon footprint. In this context, this work reports on...

  • Article
  • Open Access
18 Citations
4,276 Views
16 Pages

Hydrogels Based on Alginates and Carboxymethyl Cellulose with Modulated Drug Release—An Experimental and Theoretical Study

  • Cătălina Anișoara Peptu,
  • Elena Simona Băcăiță,
  • Corina-Lenuta Savin (Logigan),
  • Marian Luțcanu and
  • Maricel Agop

20 December 2021

New hydrogels films crosslinked with epichlorohydrin were prepared based on alginates and carboxymethyl cellulose with properties that recommend them as potential drug delivery systems (e.g., biocompatibility, low toxicity, non-immunogenicity, hemost...

  • Article
  • Open Access
27 Citations
4,773 Views
16 Pages

Rice Hull-Derived Carbon for Supercapacitors: Towards Sustainable Silicon-Carbon Supercapacitors

  • Changwei Li,
  • Honglei Chen,
  • Liqiong Zhang,
  • Shenghui Jiao,
  • Huixin Zhang,
  • Junliu Zhang,
  • Peng Li,
  • Yubo Tao and
  • Xin Zhao

20 December 2021

A simple and effective mixing carbonization-activation process was developed to prepare rice hull-derived porous Si–carbon materials. The morphologies and pore structures of the materials were controlled effectively without any loading or addit...

  • Article
  • Open Access
7 Citations
3,687 Views
19 Pages

20 December 2021

In this study, we investigate the thermo-mechanical relaxation and crystallization behavior of polyethylene using mesoscale molecular dynamics simulations. Our models specifically mimic constraints that occur in real-life polymer processing: After st...

  • Article
  • Open Access
15 Citations
4,141 Views
14 Pages

Development of Cerium Oxide/Corncob Nanocomposite: A Cost-Effective and Eco-Friendly Adsorbent for the Removal of Heavy Metals

  • Sidra Gran,
  • Rukhsanda Aziz,
  • Muhammad Tariq Rafiq,
  • Maryam Abbasi,
  • Abdul Qayyum,
  • Ashraf Y. Elnaggar,
  • Hussein H. Elganzory,
  • Zeinhom M. El-Bahy and
  • Enas E. Hussein

20 December 2021

This research aims to assess the efficiency of the synthesized corncob as a cost-effective and eco-friendly adsorbent for the removal of heavy metals. Therefore, to carry out the intended research project, initially, the corncob was doped with nanopa...

  • Article
  • Open Access
17 Citations
5,048 Views
25 Pages

Finite Element Analysis of Glass Fiber-Reinforced Polymer-(GFRP) Reinforced Continuous Concrete Beams

  • Hazem Ahmad,
  • Amr Elnemr,
  • Nazam Ali,
  • Qudeer Hussain,
  • Krisada Chaiyasarn and
  • Panuwat Joyklad

20 December 2021

Fiber-reinforced concrete (FRC) is a competitive solution for the durability of reinforced structures. This paper aims to observe the moment redistribution behavior occurring due to flexural and shear loading in Glass Fiber-Reinforced Polymer- (GFRP)...

  • Article
  • Open Access
7 Citations
5,374 Views
16 Pages

Poly(ionic liquid) Based Composite Electrolytes for Lithium Ion Batteries

  • Robert Löwe,
  • Thomas Hanemann,
  • Tatiana Zinkevich and
  • Andreas Hofmann

20 December 2021

Polymerized ionic liquids (PIL) are an interesting substance class, which is discussed to transfer the outstanding properties and tunability of ionic liquids into a solid material. In this study we extend our previous research on ammonium based PIL a...

  • Article
  • Open Access
3 Citations
3,211 Views
9 Pages

20 December 2021

A simple and hands-on one-step process has been implemented to fabricate polymer-templated hydrophobic nanostructures as hydrogen gas sensing platforms. Topographic measurements have confirmed irregular hills and dips of various dimensions that are r...

  • Article
  • Open Access
51 Citations
6,776 Views
16 Pages

Aging of 3D Printed Polymers under Sterilizing UV-C Radiation

  • Catalin Gheorghe Amza,
  • Aurelian Zapciu,
  • Florin Baciu,
  • Mihai Ion Vasile and
  • Diana Popescu

20 December 2021

In the context of the COVID-19 pandemic, shortwave ultraviolet radiation with wavelengths between 200 nm and 280 nm (UV-C) is seeing increased usage in the sterilization of medical equipment, appliances, and spaces due to its antimicrobial effect. Du...

  • Article
  • Open Access
9 Citations
7,745 Views
11 Pages

Use of Novel Non-Toxic Bismuth Catalyst for the Preparation of Flexible Polyurethane Foam

  • Said El Khezraji,
  • Suman Thakur,
  • Mustapha Raihane,
  • Miguel Angel López-Manchado,
  • Larbi Belachemi,
  • Raquel Verdejo and
  • Mohammed Lahcini

20 December 2021

Foam products are one of the largest markets for polyurethane (PU) and are heavily used in many sectors. However, current PU formulations use highly toxic and environmentally unfriendly production processes. Meanwhile, the increasing environmental co...

  • Article
  • Open Access
23 Citations
5,523 Views
12 Pages

19 December 2021

The Hummers method is the most commonly used method to prepare graphene oxide (GO). However, many waste acids remain in the raw reaction mixture after the completion of this reaction. The aim of this study was to reuse these waste acids efficiently....

  • Article
  • Open Access
10 Citations
3,669 Views
19 Pages

19 December 2021

Polymer extrudate swelling is a rheological phenomenon that occurs after polymer melt flow emerges at the die exit of extrusion equipment due to molecular stress relaxations and flow redistributions. Specifically, with the growing demand for large sc...

  • Article
  • Open Access
37 Citations
7,224 Views
23 Pages

Highly Stretchable Bacterial Cellulose Produced by Komagataeibacter hansenii SI1

  • Izabela Cielecka,
  • Małgorzata Ryngajłło,
  • Waldemar Maniukiewicz and
  • Stanisław Bielecki

19 December 2021

A new strain of bacteria producing cellulose was isolated from Kombucha and identified as Komagataeibacter hansenii, named SI1. In static conditions, the strain synthesises bacterial nanocellulose with an improved ability to stretch. In this study, u...

  • Review
  • Open Access
15 Citations
6,269 Views
27 Pages

19 December 2021

This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-ole...

  • Article
  • Open Access
12 Citations
5,504 Views
13 Pages

19 December 2021

Construction of oil and gas wells at offshore fields often involves high formation pressure and the presence of swellable clay rocks in the section. In addition, productivity preservation is also an important aspect. For this purpose, it is necessary...

  • Article
  • Open Access
6 Citations
4,410 Views
16 Pages

19 December 2021

The synthesis of surface-grafted polymers with variable functionality requires the careful selection of polymerization methods that also enable spatially controlled grafting, which is crucial for the fabrication of, e.g., nano (micro) sensor or nanoe...

  • Article
  • Open Access
5 Citations
3,759 Views
18 Pages

18 December 2021

Capillary rheometers have been widely used for the rheological measurement of polymer melts. However, when micro capillary dies are used, the results are usually neither accurate nor consistent, even under the same measurement conditions. In this wor...

  • Article
  • Open Access
19 Citations
4,004 Views
16 Pages

A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters

  • Tatyana O. Ershova,
  • Anton A. Anisimov,
  • Maxim N. Temnikov,
  • Maxim A. Novikov,
  • Mikhail I. Buzin,
  • Galina G. Nikiforova,
  • Yulia S. Dyuzhikova,
  • Ivan E. Ushakov,
  • Olga I. Shchegolikhina and
  • Aziz M. Muzafarov

18 December 2021

A versatile equilibrium method for synthesizing ladder-like polyphenylsilsesquioxanes (L-PPSQs) with various molecular weights (from 4 to 500 kDa) in liquid ammonia was developed. The effect of diverse parameters, such as temperature, monomer concent...

  • Article
  • Open Access
9 Citations
3,752 Views
13 Pages

Characterization of Polyhydroxybutyrate-Based Composites Prepared by Injection Molding

  • Marcos M. Hernandez,
  • Nevin S. Gupta,
  • Kwan-Soo Lee,
  • Aaron C. Pital,
  • Babetta L. Marrone,
  • Carl N. Iverson and
  • Joseph H. Dumont

18 December 2021

The waste generated by single-use plastics is often non-recyclable and non-biodegradable, inevitably ending up in our landfills, ecosystems, and food chain. Through the introduction of biodegradable polymers as substitutes for common plastics, we can...

  • Review
  • Open Access
6 Citations
3,064 Views
11 Pages

Polymer-Based Bone Substitutes in Periodontal Infrabony Defects: A Systematic Evaluation of Clinical Studies

  • Florin Onisor,
  • Simion Bran,
  • Ileana Mitre,
  • Alexandru Mester,
  • Andrada Voina-Tonea,
  • Gabriel Armencea and
  • Mihaela Baciut

18 December 2021

Background and Objectives: The aim was to systematically review the available literature regarding the use of polymers as a bone substitute for the treatment of periodontal infrabony defect. Materials and methods: Three databases (PubMed, Scopus and...

  • Article
  • Open Access
33 Citations
4,754 Views
24 Pages

18 December 2021

An environmentally friendly, hydrophobic polyvinyl alcohol (PVA) film was developed as an alternative to commercial straws for mitigating the issue of plastic waste. Nontoxic and biodegradable cellulose nanocrystals (CNCs) and nanofibers (CNFs) were...

  • Article
  • Open Access
10 Citations
3,457 Views
16 Pages

18 December 2021

Engineering polymers reinforced with renewable fibres (RF) are an attractive class of materials, due to their excellent mechanical performance and low environmental impact. However, the successful preparation of such composites has proven to be chall...

  • Article
  • Open Access
22 Citations
5,133 Views
13 Pages

18 December 2021

Cellulose films regenerated from aqueous alkali–urea solution possess different properties depending on coagulation conditions. However, the correlation between coagulant species and properties of regenerated cellulose (RC) films has not been c...

  • Article
  • Open Access
9 Citations
4,056 Views
20 Pages

18 December 2021

In composite materials, the use of failure criteria is necessary to determine the failure forces. Various failure criteria are known, from the simplest ones that compare individual stresses with the corresponding strength, to more complex ones that t...

  • Article
  • Open Access
203 Citations
7,662 Views
32 Pages

18 December 2021

Novel Cyanoguanidine-modified chitosan (CCs) adsorbent was successfully prepared via a four-step procedure; first by protection of the amino groups of chitosan, second by insertion of epoxide rings, third by opening the latter with cyanoguanidine, an...

  • Communication
  • Open Access
3 Citations
2,924 Views
10 Pages

17 December 2021

This paper focuses on the linking of zinc phthalocyanine (ZnPc) to N-vinylpyrrolidone (N-VP): acryloyl chloride (ClAC) copolymer. The synthesis of binary N-VP:ClAC copolymer was performed by the radical polymerization method and then grafted to ZnPc...

  • Article
  • Open Access
8 Citations
3,280 Views
15 Pages

Novel Amphiphilic Polyfluorene-Graft-(Polymethacrylic Acid) Brushes: Synthesis, Conformation, and Self-Assembly

  • Maria Simonova,
  • Dmitry Ilgach,
  • Ksenia Kaskevich,
  • Maria Nepomnyashaya,
  • Larisa Litvinova,
  • Alexander Filippov and
  • Alexander Yakimansky

17 December 2021

Novel polyfluorene polymer brushes with polymethacrylic acid side chains were obtained by atom transfer radical polymerization (ATRP) and activator generated by electron transfer (AGET) ATRP of tert-butyl methacrylate on polyfluorene multifunctional...

  • Article
  • Open Access
48 Citations
7,864 Views
17 Pages

17 December 2021

There are forecasts for the exponential increase in the generation of carbon fibre-reinforced polymer (CFRP) and glass fibre-reinforced polymer (GFRP) composite wastes containing valuable carbon and glass fibres. The recent adoption of these composit...

  • Article
  • Open Access
3 Citations
3,766 Views
14 Pages

Three-Axis Tension-Measuring Vitreoretinal Forceps Using Strain Sensor for Corneal Surgery

  • Seongjin Yang,
  • Suhyeon Kim,
  • Seong Kyung Hong,
  • Hyungkook Jeon,
  • Seong J. Cho and
  • Geunbae Lim

17 December 2021

Precise motion control is important in robotic surgery, especially corneal surgery. This paper develops a new tension-measurement system for forceps used in corneal surgery, wherein contact force is applied only to a specific location for precise con...

  • Article
  • Open Access
7 Citations
3,181 Views
31 Pages

17 December 2021

The ability of PLLA, either amorphous or semicrystalline, to plastic deformation to large strain was investigated in a wide temperature range (Td = 70–140 °C). Active deformation mechanisms have been identified and compared for two differen...

  • Article
  • Open Access
49 Citations
8,606 Views
16 Pages

Development of Dental Poly(methyl methacrylate)-Based Resin for Stereolithography Additive Manufacturing

  • Kentaro Hata,
  • Hiroshi Ikeda,
  • Yuki Nagamatsu,
  • Chihiro Masaki,
  • Ryuji Hosokawa and
  • Hiroshi Shimizu

17 December 2021

Poly(methyl methacrylate) (PMMA) is widely used in dental applications. However, PMMA specialized for stereolithography (SLA) additive manufacturing (3D-printing) has not been developed yet. This study aims to develop a novel PMMA-based resin for SLA...

  • Article
  • Open Access
26 Citations
5,054 Views
13 Pages

Improvement of Properties and Performances of Polyethersulfone Ultrafiltration Membrane by Blending with Bio-Based Dragonbloodin Resin

  • Aulia Chintia Ambarita,
  • Sri Mulyati,
  • Nasrul Arahman,
  • Muhammad Roil Bilad,
  • Norazanita Shamsuddin and
  • Noor Maizura Ismail

17 December 2021

Polyethersulfone (PES) is the most commonly used polymer for membrane ultrafiltration because of its superior properties. However, it is hydrophobic, as such susceptible to fouling and low permeation rate. This study proposes a novel bio-based additi...

  • Article
  • Open Access
19 Citations
6,916 Views
18 Pages

17 December 2021

This paper discusses a new synthesis of bisphenol A-free polycarbonates based on four aliphatic-aromatic systems. In the first stage, different types of monomers (with/without sulfur) derived from diphenylmethane were synthesized. Then, new polycarbo...

  • Article
  • Open Access
28 Citations
5,971 Views
15 Pages

17 December 2021

Closed-cell rigid polyimide foams with excellent thermal stability and combined properties were prepared by thermal foaming of a reactive end-capped polyimide precursor powder in a closed mold. The precursor powder was obtained by thermal treatment o...

  • Article
  • Open Access
3 Citations
3,348 Views
12 Pages

Selected Properties of Cement Bound Spruce and Larch Bark Bio-Aggregates

  • Johannes Urstöger,
  • Marius Cătălin Barbu,
  • Thomas Pacher,
  • Alexander Petutschnigg,
  • Johannes Jorda and
  • Eugenia Mariana Tudor

17 December 2021

The aim of this study is to investigate the suitability of spruce and larch bark for the production of cement-bonded composites. At the beginning of this research, the curing behaviour of the admixtures was quantified with temperature profiles when t...

  • Article
  • Open Access
5 Citations
2,694 Views
14 Pages

17 December 2021

The trend across the whole of society is to focus on natural and/or biodegradable materials such as cellulose (Cell) over synthetic polymers. Among other usage scenarios, Cell can be combined with electroactive components such as multiwall carbon nan...

  • Article
  • Open Access
19 Citations
3,265 Views
16 Pages

Improving Fracture Toughness of Tetrafunctional Epoxy with Functionalized 2D Molybdenum Disulfide Nanosheets

  • Megha Sahu,
  • Lakshmi Narasimhan,
  • Ashok M. Raichur,
  • Alexandru Sover,
  • Romeo C. Ciobanu,
  • Nicolae Lucanu and
  • Mihaela Aradoaei

17 December 2021

In this work, improved fracture toughness of tetra-functional epoxy polymer was obtained using two-dimensional (2H polytype) molybdenum disulfide (MoS2) nano-platelets as a filler. Simultaneous in-situ exfoliation and functionalization of MoS2 were a...

  • Article
  • Open Access
1 Citations
3,465 Views
19 Pages

A Multi-Analytical Approach for Studying the Effect of New LED Lighting Systems on Modern Paints: Chemical Stability Investigations

  • Valentina Pintus,
  • Ferenc Szabó,
  • Dávid Noel Tóth,
  • Karin Wieland,
  • Péter Csuti,
  • Marta Anghelone,
  • Ottavia Santorelli,
  • Carlotta Salvadori,
  • Christoph Haisch and
  • Manfred Schreiner
  • + 1 author

17 December 2021

This study aims to investigate the chemical stability of some modern paint samples exposed to a new Light Emitting Diode (LED)-lighting system and a halogen lamp by using micro-attenuated total reflectance of Fourier transform infrared spectroscopy (...

  • Article
  • Open Access
18 Citations
5,346 Views
13 Pages

Organosolv Lignin Barrier Paper Coatings from Waste Biomass Resources

  • Gregor Lavrič,
  • Aleksandra Zamljen,
  • Janja Juhant Grkman,
  • Edita Jasiukaitytė-Grojzdek,
  • Miha Grilc,
  • Blaž Likozar,
  • Diana Gregor-Svetec and
  • Urška Vrabič-Brodnjak

17 December 2021

The aim of the study was to isolate lignin from organosolv, beech tree (Fagus sylvatica), and Japanese knotweed (Reynoutria japonica), to use it for paper surface and to replace part of the non-renewable product resources with bio-based ones. A total...

  • Article
  • Open Access
38 Citations
5,697 Views
14 Pages

Preparation and Physicochemical Properties of Modified Corn Starch–Chitosan Biodegradable Films

  • Enrique Javier Jiménez-Regalado,
  • Carolina Caicedo,
  • Abril Fonseca-García,
  • Claudia Cecilia Rivera-Vallejo and
  • Rocio Yaneli Aguirre-Loredo

17 December 2021

Starch is a biopolymer with enormous potential for generating new biodegradable packages due to its easy availability and low cost. However, due to its weak functional properties, limitation of its interaction with some hydroxyl groups and evaluation...

  • Article
  • Open Access
67 Citations
8,526 Views
14 Pages

3D Bioprinting of Polycaprolactone-Based Scaffolds for Pulp-Dentin Regeneration: Investigation of Physicochemical and Biological Behavior

  • Zohre Mousavi Nejad,
  • Ali Zamanian,
  • Maryam Saeidifar,
  • Hamid Reza Vanaei and
  • Mehdi Salar Amoli

17 December 2021

In this study, two structurally different scaffolds, a polycaprolactone (PCL)/45S5 Bioglass (BG) composite and PCL/hyaluronic acid (HyA) were fabricated by 3D printing technology and were evaluated for the regeneration of dentin and pulp tissues, res...

  • Article
  • Open Access
5 Citations
2,367 Views
17 Pages

16 December 2021

GFRP bars will be damaged due to a series of irreversible hygroscopic chemical reactions under humid and hot curing environmental conditions. The multiple factors related to the moisture absorption model were established through the moisture absorpti...

  • Article
  • Open Access
84 Citations
8,025 Views
20 Pages

16 December 2021

Three-dimensional (3D) printing technology is highly regarded in the field of dentistry. Three-dimensional printed resin restorations must undergo a washing process to remove residual resin on the surface after they have been manufactured. However, t...

  • Review
  • Open Access
173 Citations
11,774 Views
27 Pages

A Review on the Thermal Characterisation of Natural and Hybrid Fiber Composites

  • Jorge S. S. Neto,
  • Henrique F. M. de Queiroz,
  • Ricardo A. A. Aguiar and
  • Mariana D. Banea

16 December 2021

The thermal stability of natural fiber composites is a relevant aspect to be considered since the processing temperature plays a critical role in the manufacturing process of composites. At higher temperatures, the natural fiber components (cellulose...

  • Review
  • Open Access
104 Citations
8,346 Views
20 Pages

16 December 2021

Nanoclay-reinforced polymers have attracted considerable universal attention in academic and industrial research due to their outstanding properties and their ever-expanding utilization in diversified applications. In that regard, in the present revi...

  • Article
  • Open Access
22 Citations
6,312 Views
17 Pages

16 December 2021

This study used a mechanochemical method to analyze the recycling mechanism of polyurethane foam and optimize the recycling process. The use of mechanochemical methods to regenerate the polyurethane foam powder breaks the C–O bond of the polyur...

  • Article
  • Open Access
11 Citations
4,604 Views
11 Pages

Development of Quebracho (Schinopsis balansae) Tannin-Based Thermoset Resins

  • Emanuele Cesprini,
  • Primož Šket,
  • Valerio Causin,
  • Michela Zanetti and
  • Gianluca Tondi

16 December 2021

One of the major challenges currently in the field of material science is finding natural alternatives to the high-performing plastics developed in the last century. Consumers trust synthetic products for their excellent properties, but they are beco...

  • Article
  • Open Access
10 Citations
5,628 Views
11 Pages

Photoreactive UV-Crosslinkable Acrylic Pressure-Sensitive Adhesives (PSA) Containing Multifunctional Photoinitiators

  • Marcin Bartkowiak,
  • Zbigniew Czech,
  • Hyun-Joong Kim,
  • Gyu-Seong Shim,
  • Małgorzata Nowak and
  • Adrian Krzysztof Antosik

16 December 2021

The use of ultraviolet radiation (UV) technology for the crosslinking of acrylic pressure-sensitive adhesives (PSA) is the one of various crosslinking methods, being the alternative to the conventional crosslinking process of solvent-based acrylic sy...

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Polymers - ISSN 2073-4360