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Materials, Volume 9, Issue 3

2016 March - 95 articles

Cover Story: Electrospun composite fuel cell membranes can overcome many limitations of conventional, solution cast films. Nanofibers not only mechanically reinforce the membrane but also reduce swelling, thus minimizing fuel crossover and improving durability. Dual-fiber electrospinning, developed at Vanderbilt University, enables morphological control over a wide range of polymer compositions. High performance electrospun Nafion/PPSU membranes are cost-competitive with solution cast and commercial Nafion membranes for regenerative H2/Br2 and conventional H2/air fuel cells. View the paper
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Articles (95)

  • Communication
  • Open Access
14 Citations
9,367 Views
14 Pages

Synthesis of Porous Carbon Monoliths Using Hard Templates

  • Olaf Klepel,
  • Nina Danneberg,
  • Matti Dräger,
  • Marcel Erlitz and
  • Michael Taubert

21 March 2016

The preparation of porous carbon monoliths with a defined shape via template-assisted routes is reported. Monoliths made from porous concrete and zeolite were each used as the template. The porous concrete-derived carbon monoliths exhibited high grav...

  • Article
  • Open Access
18 Citations
6,904 Views
20 Pages

On the Behavior of Different PCMs in a Hot Water Storage Tank against Thermal Demands

  • Jacobo Porteiro,
  • José Luis Míguez,
  • Bárbara Crespo,
  • José De Lara and
  • José María Pousada

21 March 2016

Advantages, such as thermal storage improvement, are found when using PCMs (Phase Change Materials) in storage tanks. The inclusion of three different types of materials in a 60 l test tank is studied. Two test methodologies were developed, and four...

  • Article
  • Open Access
5 Citations
5,864 Views
12 Pages

Site-Control of InAs/GaAs Quantum Dots with Indium-Assisted Deoxidation

  • Sajid Hussain,
  • Alessandro Pozzato,
  • Massimo Tormen,
  • Valentina Zannier and
  • Giorgio Biasiol

18 March 2016

Site-controlled epitaxial growth of InAs quantum dots on GaAs substrates patterned with periodic nanohole arrays relies on the deterministic nucleation of dots into the holes. In the ideal situation, each hole should be occupied exactly by one single...

  • Article
  • Open Access
15 Citations
7,142 Views
10 Pages

Effect of Curing Mode on Shear Bond Strength of Self-Adhesive Cement to Composite Blocks

  • Jin-Young Kim,
  • Ga-Young Cho,
  • Byoung-Duck Roh and
  • Yooseok Shin

18 March 2016

To overcome the disadvantages of computer-aided design/computer-aided manufacturing (CAD/CAM) processed indirect restorations using glass-ceramics and other ceramics, resin nano ceramic, which has high strength and wear resistance with improved polis...

  • Article
  • Open Access
13 Citations
5,413 Views
12 Pages

18 March 2016

An electrochemical treatment (EC) was applied at different intensities to degrade the chromophoric groups of dyes C.I. Reactive Black 5 (RB5) and C.I. Reactive Blue 7 (Rb7) until uncolored species were obtained. Decolorization rate constants of the a...

  • Article
  • Open Access
2 Citations
5,743 Views
11 Pages

18 March 2016

FePt-Ag nanocomposite films with large perpendicular magnetic anisotropy have been fabricated by alternate-atomic-layer electron beam evaporation onto MgO(100) substrates at the low temperature of 300 °C. Their magnetization behavior and microstructu...

  • Feature Paper
  • Article
  • Open Access
15 Citations
7,471 Views
14 Pages

Polystyrene-co-Divinylbenzene PolyHIPE Monoliths in 1.0 mm Column Formats for Liquid Chromatography

  • Sidratul Choudhury,
  • Laurence Fitzhenry,
  • Blánaid White and
  • Damian Connolly

18 March 2016

The reversed phase liquid chromatographic (RP-HPLC) separation of small molecules using a polystyrene-co-divinylbenzene (PS-co-DVB) polyHIPE stationary phases housed within 1.0 mm i.d. silcosteel columns is presented within this study. A 90% PS-co-DV...

  • Article
  • Open Access
8 Citations
6,063 Views
11 Pages

Cavitation Erosion of Cermet-Coated Aluminium Bronzes

  • Ion Mitelea,
  • Octavian Oancă,
  • Ilare Bordeaşu and
  • Corneliu M. Crăciunescu

17 March 2016

The cavitation erosion resistance of CuAl10Ni5Fe2.5Mn1 following plasma spraying with Al2O3·30(Ni20Al) powder and laser re-melting was analyzed in view of possible improvements of the lifetime of components used in hydraulic environments. The cavitat...

  • Article
  • Open Access
49 Citations
8,711 Views
11 Pages

Nitric Acid-Treated Carbon Fibers with Enhanced Hydrophilicity for Candida tropicalis Immobilization in Xylitol Fermentation

  • Le Wang,
  • Na Liu,
  • Zheng Guo,
  • Dapeng Wu,
  • Weiwei Chen,
  • Zheng Chang,
  • Qipeng Yuan,
  • Ming Hui and
  • Jinshui Wang

17 March 2016

Nitric acid (HNO3)-treated carbon fiber (CF) rich in hydrophilic groups was applied as a cell-immobilized carrier for xylitol fermentation. Using scanning electron microscopy, we characterized the morphology of the HNO3-treated CF. Additionally, we e...

  • Feature Paper
  • Article
  • Open Access
8 Citations
6,229 Views
21 Pages

Computational Study of the Effect of Cortical Porosity on Ultrasound Wave Propagation in Healthy and Osteoporotic Long Bones

  • Vassiliki T. Potsika,
  • Konstantinos N. Grivas,
  • Theodoros Gortsas,
  • Gianluca Iori,
  • Vasilios C. Protopappas,
  • Kay Raum,
  • Demosthenes Polyzos and
  • Dimitrios I. Fotiadis

17 March 2016

Computational studies on the evaluation of bone status in cases of pathologies have gained significant interest in recent years. This work presents a parametric and systematic numerical study on ultrasound propagation in cortical bone models to inves...

  • Article
  • Open Access
17 Citations
6,770 Views
23 Pages

17 March 2016

In this paper, the fatigue life of fiber-reinforced ceramic-matrix composites (CMCs) with different fiber preforms, i.e., unidirectional, cross-ply, 2D (two dimensional), 2.5D and 3D CMCs at room and elevated temperatures in air and oxidative environ...

  • Feature Paper
  • Article
  • Open Access
18 Citations
7,747 Views
13 Pages

Controlled Photocatalytic Synthesis of Core–Shell SiC/Polyaniline Hybrid Nanostructures

  • Attila Kormányos,
  • Balázs Endrődi,
  • Róbert Ondok,
  • András Sápi and
  • Csaba Janáky

16 March 2016

Hybrid materials of electrically conducting polymers and inorganic semiconductors form an exciting class of functional materials. To fully exploit the potential synergies of the hybrid formation, however, sophisticated synthetic methods are required...

  • Feature Paper
  • Article
  • Open Access
29 Citations
8,795 Views
13 Pages

Study of Polydiacetylene-Poly (Ethylene Oxide) Electrospun Fibers Used as Biosensors

  • A K M Mashud Alam,
  • Janet P. Yapor,
  • Melissa M. Reynolds and
  • Yan Vivian Li

16 March 2016

Polydiacetylene (PDA) is an attractive conjugated material for use in biosensors due to its unique characteristic of undergoing a blue-to-red color change in response to external stimuli. 10,12-Pentacosadiynoic acid (PCDA) and poly (ethylene oxide) (...

  • Article
  • Open Access
14 Citations
5,090 Views
17 Pages

16 March 2016

A new method, powder thixoforming, has been proposed to fabricate an in situ Al3Tip/2024Al composite. During partial remelting, the microstructural evolution of the bulk alloy prepared by cold pressing of the Ti, Al, 2024Al powder mixture was investi...

  • Article
  • Open Access
22 Citations
5,171 Views
8 Pages

Surface Morphology and Tooth Adhesion of a Novel Nanostructured Dental Restorative Composite

  • Marco Salerno,
  • Patrizia Loria,
  • Giunio Matarazzo,
  • Francesco Tomè,
  • Alberto Diaspro and
  • Roberto Eggenhöffner

16 March 2016

Recently, a novel dental restorative composite based on nanostructured micro-fillers of anodic porous alumina has been proposed. While its bulk properties are promising thanks to decreased aging and drug delivery capabilities, its surface properties...

  • Article
  • Open Access
56 Citations
7,778 Views
14 Pages

16 March 2016

The novel Cr-containing low alloy steels have exhibited good corrosion resistance in CO2 environment, mainly owing to the formation of Cr-enriched corrosion film. In order to evaluate whether it is applicable to the CO2 and H2S coexistence conditions...

  • Article
  • Open Access
21 Citations
6,549 Views
26 Pages

Molecular Mobility in Hyperbranched Polymers and Their Interaction with an Epoxy Matrix

  • Frida Román,
  • Pere Colomer,
  • Yolanda Calventus and
  • John M. Hutchinson

15 March 2016

The molecular mobility related to the glass transition and secondary relaxations in a hyperbranched polyethyleneimine, HBPEI, and its relaxation behaviour when incorporated into an epoxy resin matrix are investigated by dielectric relaxation spectros...

  • Article
  • Open Access
32 Citations
6,933 Views
11 Pages

15 March 2016

All-biomass soy protein-based films were prepared using soy protein isolate (SPI), glycerol, hydroxypropyl cellulose (HPC) and epoxy castor oil acid sodium (ECOS). The effect of the incorporated HPC and ECOS on the properties of the SPI film was inve...

  • Article
  • Open Access
25 Citations
7,142 Views
11 Pages

Development and Characterization of a Bioinspired Bone Matrix with Aligned Nanocrystalline Hydroxyapatite on Collagen Nanofibers

  • Hsi-Chin Wu,
  • Tzu-Wei Wang,
  • Jui-Sheng Sun,
  • Yi-Hsuan Lee,
  • Meng-Han Shen,
  • Zong-Ruei Tsai,
  • Chih-Yu Chen and
  • Horng-Chaung Hsu

15 March 2016

Various kinds of three-dimensional (3D) scaffolds have been designed to mimic the biological spontaneous bone formation characteristics by providing a suitable microenvironment for osteogenesis. In view of this, a natural bone-liked composite scaffol...

  • Feature Paper
  • Article
  • Open Access
4 Citations
4,837 Views
13 Pages

15 March 2016

Holographic transmission gratings with a spatial frequency of 2658 lines/mm and reflection gratings with a spatial frequency of 4553 lines/mm were stored in a polyvinyl alcohol (PVA)/acrylamide (AA) based photopolymer. This material can reach diffrac...

  • Article
  • Open Access
102 Citations
12,298 Views
19 Pages

Post Processing and Biological Evaluation of the Titanium Scaffolds for Bone Tissue Engineering

  • Bartłomiej Wysocki,
  • Joanna Idaszek,
  • Karol Szlązak,
  • Karolina Strzelczyk,
  • Tomasz Brynk,
  • Krzysztof J. Kurzydłowski and
  • Wojciech Święszkowski

15 March 2016

Nowadays, post-surgical or post-accidental bone loss can be substituted by custom-made scaffolds fabricated by additive manufacturing (AM) methods from metallic powders. However, the partially melted powder particles must be removed in a post-process...

  • Feature Paper
  • Article
  • Open Access
13 Citations
5,256 Views
12 Pages

Blazed Gratings Recorded in Absorbent Photopolymers

  • Roberto Fernández,
  • Sergi Gallego,
  • Andrés Márquez,
  • Víctor Navarro-Fuster and
  • Augusto Beléndez

15 March 2016

Phase diffractive optical elements, which have many interesting applications, are usually fabricated using a photoresist. In this paper, they were made using a hybrid optic-digital system and a photopolymer as recording medium. We analyzed the charac...

  • Article
  • Open Access
18 Citations
8,806 Views
11 Pages

Nanotextured Shrink Wrap Superhydrophobic Surfaces by Argon Plasma Etching

  • Jolie M. Nokes,
  • Himanshu Sharma,
  • Roger Tu,
  • Monica Y. Kim,
  • Michael Chu,
  • Ali Siddiqui and
  • Michelle Khine

14 March 2016

We present a rapid, simple, and scalable approach to achieve superhydrophobic (SH) substrates directly in commodity shrink wrap film utilizing Argon (Ar) plasma. Ar plasma treatment creates a stiff skin layer on the surface of the shrink film. When t...

  • Article
  • Open Access
8 Citations
5,569 Views
8 Pages

11 March 2016

This work illustrates the effect of thermal mechanical processing parameters on the microstructure and mechanical properties of the Ti-22Al-25Nb alloy prepared by reactive sintering with element powders, consisting of O, B2 and Ti3Al phases. Tensile...

  • Review
  • Open Access
19 Citations
8,251 Views
11 Pages

11 March 2016

Recent research has shown that fully developed organs can be decellularized, resulting in a complex scaffold and extracellular matrix (ECM) network capable of being populated with other cells. This work has resulted in a growing field in bioengineeri...

  • Article
  • Open Access
23 Citations
8,928 Views
15 Pages

A Novel HA/β-TCP-Collagen Composite Enhanced New Bone Formation for Dental Extraction Socket Preservation in Beagle Dogs

  • Ko-Ning Ho,
  • Eisner Salamanca,
  • Kuo-Chi Chang,
  • Tsai-Chin Shih,
  • Yu-Chi Chang,
  • Haw-Ming Huang,
  • Nai-Chia Teng,
  • Che-Tong Lin,
  • Sheng-Wei Feng and
  • Wei-Jen Chang

11 March 2016

Past studies in humans have demonstrated horizontal and vertical bone loss after six months following tooth extraction. Many biomaterials have been developed to preserve bone volume after tooth extraction. Type I collagen serves as an excellent deliv...

  • Article
  • Open Access
39 Citations
8,535 Views
10 Pages

PEEK Primary Crowns with Cobalt-Chromium, Zirconia and Galvanic Secondary Crowns with Different Tapers—A Comparison of Retention Forces

  • Veronika Stock,
  • Patrick R. Schmidlin,
  • Susanne Merk,
  • Christina Wagner,
  • Malgorzata Roos,
  • Marlis Eichberger and
  • Bogna Stawarczyk

10 March 2016

In prosthetic dentistry, double crown systems have proved their suitability as retainers for removable partial dentures. However, investigations in this context, regarding polyetheretherketone, are scarce. Therefore, the aim of this study was to test...

  • Article
  • Open Access
31 Citations
7,138 Views
11 Pages

10 March 2016

In this study, ground granulated blast-furnace slag (GGBFS) samples from Singapore, Korea, and the United Arab Emirates were hydrated with purified water to estimate the cementing capabilities without activators. Raw GGBFS samples and hardened pastes...

  • Article
  • Open Access
68 Citations
8,602 Views
22 Pages

Topological Design of Cellular Phononic Band Gap Crystals

  • Yang Fan Li,
  • Xiaodong Huang and
  • Shiwei Zhou

10 March 2016

This paper systematically investigated the topological design of cellular phononic crystals with a maximized gap size between two adjacent bands. Considering that the obtained structures may sustain a certain amount of static loadings, it is desirabl...

  • Feature Paper
  • Article
  • Open Access
7 Citations
7,112 Views
16 Pages

10 March 2016

We report on an experimental investigation of spatial frequency responses of anisotropic transmission refractive index gratings formed in holographic polymer dispersed liquid crystals (HPDLCs). We studied two different types of HPDLC materials employ...

  • Feature Paper
  • Review
  • Open Access
30 Citations
8,668 Views
16 Pages

9 March 2016

All surfaces exposed to ambient conditions are covered by a thin film of water. Other than at high humidity conditions, i.e., relative humidity higher than 80%, those water films have nanoscale thickness. Nevertheless, even the thinnest film can prof...

  • Article
  • Open Access
37 Citations
7,468 Views
13 Pages

Influence of Specimen Preparation and Test Methods on the Flexural Strength Results of Monolithic Zirconia Materials

  • Christine Schatz,
  • Monika Strickstrock,
  • Malgorzata Roos,
  • Daniel Edelhoff,
  • Marlis Eichberger,
  • Isabella-Maria Zylla and
  • Bogna Stawarczyk

9 March 2016

The aim of this work was to evaluate the influence of specimen preparation and test method on the flexural strength results of monolithic zirconia. Different monolithic zirconia materials (Ceramill Zolid (Amann Girrbach, Koblach, Austria), Zenostar Z...

  • Article
  • Open Access
15 Citations
6,932 Views
18 Pages

The Influence of Conjugated Polymer Side Chain Manipulation on the Efficiency and Stability of Polymer Solar Cells

  • Ilona M. Heckler,
  • Jurgen Kesters,
  • Maxime Defour,
  • Morten V. Madsen,
  • Huguette Penxten,
  • Jan D’Haen,
  • Bruno Van Mele,
  • Wouter Maes and
  • Eva Bundgaard

9 March 2016

The stability of polymer solar cells (PSCs) can be influenced by the introduction of particular moieties on the conjugated polymer side chains. In this study, two series of donor-acceptor copolymers, based on bis(thienyl)dialkoxybenzene donor and ben...

  • Article
  • Open Access
162 Citations
15,159 Views
8 Pages

Rapid Synthesis of Carbon Dots by Hydrothermal Treatment of Lignin

  • Wenxin Chen,
  • Chaofan Hu,
  • Yunhua Yang,
  • Jianghu Cui and
  • Yingliang Liu

9 March 2016

A rapid approach has been developed for the fluorescent carbon dots (CDs) by the hydrothermal treatment of lignin in the presence of H2O2. The as-synthesized CDs were found to emit blue photoluminescence with excellent photostability. Moreover, the C...

  • Article
  • Open Access
46 Citations
8,029 Views
10 Pages

9 March 2016

Novel nanocomposites comprised of bacterial cellulose (BC) with carboxylic multi-walled carbon nanotubes (c-MWCNTs) incorporated into the BC matrix were prepared through a simple method of biosynthesis. The biocathode and bioanode for the enzyme biol...

  • Article
  • Open Access
19 Citations
9,605 Views
12 Pages

Preparation and Evaluation of Dexamethasone-Loaded Electrospun Nanofiber Sheets as a Sustained Drug Delivery System

  • Jin Woo Lee,
  • Hye Yun Lee,
  • Seung Hun Park,
  • Ji Hoon Park,
  • Jae Ho Kim,
  • Byoung Hyun Min and
  • Moon Suk Kim

8 March 2016

Recently, electrospinning technology has been widely used as a processing method to make nanofiber sheets (NS) for biomedical applications because of its unique features, such as ease of fabrication and high surface area. To develop a sustained dexam...

  • Feature Paper
  • Article
  • Open Access
14 Citations
8,350 Views
14 Pages

8 March 2016

Plane and crossed polarization are the two standard light modes in polarized light microscopy that are widely used to characterize crystalline and amorphous phases in cement-based materials. However, the use of the crossed polarized light mode has be...

  • Article
  • Open Access
15 Citations
7,200 Views
15 Pages

8 March 2016

Damage to carbon nanotubes (CNTs) during the fabrication process of CNT reinforced composites has great influence on their mechanical properties. In this study, the 2014 Al with powder sizes of 20, 9 and 5 μm was selected to study the effect of initi...

  • Article
  • Open Access
9 Citations
6,041 Views
15 Pages

8 March 2016

Effects of Ca content (in the reactant mixture) on the formation and the photoluminescence properties of CaAlSiN3:Eu2+ phosphor (CASIN) were investigated by a combustion synthesis method. Ca, Al, Si, Eu2O3, NaN3, NH4Cl and Si3N4 powders were used as...

  • Feature Paper
  • Article
  • Open Access
26 Citations
7,733 Views
12 Pages

Compositional Design of Dielectric, Ferroelectric and Piezoelectric Properties of (K, Na)NbO3 and (Ba, Na)(Ti, Nb)O3 Based Ceramics Prepared by Different Sintering Routes

  • José A. Eiras,
  • Rosimeire B. Z. Gerbasi,
  • Jaciele M. Rosso,
  • Daniel M. Silva,
  • Luiz F. Cótica,
  • Ivair A. Santos,
  • Camila A. Souza and
  • Manuel H. Lente

8 March 2016

Lead free piezoelectric materials are being intensively investigated in order to substitute lead based ones, commonly used in many different applications. Among the most promising lead-free materials are those with modified NaNbO3, such as (K, Na)NbO...

  • Feature Paper
  • Article
  • Open Access
5 Citations
5,893 Views
13 Pages

Image Charge Effects in the Wetting Behavior of Alkanes on Water with Accounting for Water Solubility

  • Kirill A. Emelyanenko,
  • Alexandre M. Emelyanenko and
  • Ludmila B. Boinovich

8 March 2016

Different types of surface forces, acting in the films of pentane, hexane, and heptane on water are discussed. It is shown that an important contribution to the surface forces originates from the solubility of water in alkanes. The equations for the...

  • Article
  • Open Access
178 Citations
10,793 Views
12 Pages

7 March 2016

Recycling waste tire rubber by incorporating it into concrete has become the preferred solution to dispose of waste tires. In this study, the effect of the volume content of crumb rubber and pretreatment methods on the performances of concrete was ev...

  • Article
  • Open Access
7 Citations
7,178 Views
14 Pages

7 March 2016

An effective retarded suspension of ground granulated blast-furnace slag (GGBFS) needs a strong activator to reactivate the hydration. In this research study, sodium hydroxide (NaOH) as an alkali activator in two different concentrations (30 and 50 w...

  • Article
  • Open Access
27 Citations
6,670 Views
15 Pages

Polyamide Fiber Reinforced Shotcrete for Tunnel Application

  • Joong Kyu Jeon,
  • WooSeok Kim,
  • Gyu Yong Kim and
  • Chan Ki Jeon

5 March 2016

This study intends to establish the mechanical properties of polyamide fiber reinforced shotcrete (PAFRS) in terms of compressive and flexural strengths, in accordance with ASTM C1609/C1609M-12. The mechanical properties identified the influence of p...

  • Article
  • Open Access
162 Citations
9,004 Views
16 Pages

5 March 2016

Microstructural and mechanical properties of alkali activated binders based on blends of Colombian granulated blast furnace slag (GBFS) and fly ash (FA) were investigated. The synthesis of alkali activated binders was conducted at 85 °C for 24 h with...

  • Article
  • Open Access
9 Citations
6,551 Views
17 Pages

5 March 2016

This work investigated experimentally and theoretically the fire hazards of thermal-insulation materials used in diesel locomotives under different radiation heat fluxes. Based on the experimental results, the critical heat flux for ignition was dete...

  • Article
  • Open Access
29 Citations
8,147 Views
16 Pages

Silica-Gentamicin Nanohybrids: Synthesis and Antimicrobial Action

  • Dina Ahmed Mosselhy,
  • Yanling Ge,
  • Michael Gasik,
  • Katrina Nordström,
  • Olli Natri and
  • Simo-Pekka Hannula

5 March 2016

Orthopedic applications commonly require the administration of systemic antibiotics. Gentamicin is one of the most commonly used aminoglycosides in the treatment and prophylaxis of infections associated with orthopedic applications, but gentamicin ha...

  • Article
  • Open Access
18 Citations
7,152 Views
9 Pages

Integrated Effects of Two Additives on the Enhanced Performance of PTB7:PC71BM Polymer Solar Cells

  • Lin Wang,
  • Suling Zhao,
  • Zheng Xu,
  • Jiao Zhao,
  • Di Huang and
  • Ling Zhao

5 March 2016

Organic photovoltaics (OPVs) are fabricated with blended active layers of poly [[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl] thieno[3,4-b]thiophenediyl]]: [6,6]-phenylC71-butyric acid methyl...

  • Article
  • Open Access
13 Citations
5,045 Views
8 Pages

4 March 2016

This research was carried out to investigate the influence of Sr–Sb on the microstructures and mechanical properties of Al–18 wt % Mg2Si–4.5Cu alloys. After the addition of 0.2 wt % Sr–Sb, the morphologies of primary Mg2Si transformed from equiaxed d...

  • Article
  • Open Access
5 Citations
6,066 Views
8 Pages

4 March 2016

Cubic boron nitride (cBN) is widely applied in cutting and grinding tools. cBN grains plated by pure Ni and Ni/SiC composite were produced under the same conditions from an additive-free nickel Watts type bath. The processed electroplating products w...

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Materials - ISSN 1996-1944