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25 pages, 2458 KiB  
Article
Numerical Analysis of Heat Transfer in a Double-Pipe Heat Exchanger for an LPG Fuel Supply System
by Seongwoo Lee, Younghun Kim, Ancheol Choi and Sungwoong Choi
Energies 2025, 18(15), 4179; https://doi.org/10.3390/en18154179 - 6 Aug 2025
Abstract
LPG fuel supply systems are increasingly important for improving energy efficiency and reducing carbon emissions in the shipping industry. The primary objective of this research is to investigate the heat transfer phenomena to enhance the thermal performance of double-pipe heat exchangers (DPHEs) in [...] Read more.
LPG fuel supply systems are increasingly important for improving energy efficiency and reducing carbon emissions in the shipping industry. The primary objective of this research is to investigate the heat transfer phenomena to enhance the thermal performance of double-pipe heat exchangers (DPHEs) in LPG fuel supply systems. This study investigates the heat transfer performance of a glycol–steam double-pipe heat exchanger (DPHE) within an LPG fuel supply system under varying operating conditions. A computational model and methodology were developed and validated by comparing the numerical results with experimental data obtained from commissioning tests. Additionally, the effects of turbulence models and parametric variations were evaluated by analyzing the glycol–water mixing ratio and flow direction—both of which are critical operational parameters for DPHE systems. Numerical validation against the commissioning data showed a deviation of ±2% under parallel-flow conditions, confirming the reliability of the proposed model. With respect to the glycol–water mixing ratio and flow configuration, thermal conductance (UA) decreased by approximately 11% in parallel flow and 13% in counter flow for every 20% increase in glycol concentration. Furthermore, parallel flow exhibited approximately 0.6% higher outlet temperatures than counter flow, indicating superior heat transfer efficiency under parallel-flow conditions. Finally, the heat transfer behavior of the DPHE was further examined by considering the effects of geometric characteristics, pipe material, and fluid properties. This study offers significant contributions to the engineering design of double-pipe heat exchanger systems for LPG fuel supply applications. Full article
(This article belongs to the Collection Advances in Heat Transfer Enhancement)
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30 pages, 9692 KiB  
Article
Integrating GIS, Remote Sensing, and Machine Learning to Optimize Sustainable Groundwater Recharge in Arid Mediterranean Landscapes: A Case Study from the Middle Draa Valley, Morocco
by Adil Moumane, Abdessamad Elmotawakkil, Md. Mahmudul Hasan, Nikola Kranjčić, Mouhcine Batchi, Jamal Al Karkouri, Bojan Đurin, Ehab Gomaa, Khaled A. El-Nagdy and Youssef M. Youssef
Water 2025, 17(15), 2336; https://doi.org/10.3390/w17152336 - 6 Aug 2025
Abstract
Groundwater plays a crucial role in sustaining agriculture and livelihoods in the arid Middle Draa Valley (MDV) of southeastern Morocco. However, increasing groundwater extraction, declining rainfall, and the absence of effective floodwater harvesting systems have led to severe aquifer depletion. This study applies [...] Read more.
Groundwater plays a crucial role in sustaining agriculture and livelihoods in the arid Middle Draa Valley (MDV) of southeastern Morocco. However, increasing groundwater extraction, declining rainfall, and the absence of effective floodwater harvesting systems have led to severe aquifer depletion. This study applies and compares six machine learning (ML) algorithms—decision trees (CART), ensemble methods (random forest, LightGBM, XGBoost), distance-based learning (k-nearest neighbors), and support vector machines—integrating GIS, satellite data, and field observations to delineate zones suitable for groundwater recharge. The results indicate that ensemble tree-based methods yielded the highest predictive accuracy, with LightGBM outperforming the others by achieving an overall accuracy of 0.90. Random forest and XGBoost also demonstrated strong performance, effectively identifying priority areas for artificial recharge, particularly near ephemeral streams. A feature importance analysis revealed that soil permeability, elevation, and stream proximity were the most influential variables in recharge zone delineation. The generated maps provide valuable support for irrigation planning, aquifer conservation, and floodwater management. Overall, the proposed machine learning–geospatial framework offers a robust and transferable approach for mapping groundwater recharge zones (GWRZ) in arid and semi-arid regions, contributing to the achievement of Sustainable Development Goals (SDGs))—notably SDG 6 (Clean Water and Sanitation), by enhancing water-use efficiency and groundwater recharge (Target 6.4), and SDG 13 (Climate Action), by supporting climate-resilient aquifer management. Full article
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17 pages, 4105 KiB  
Article
Evaluation of the Effect of X-Ray Therapy on Glioma Rat Model Using Chemical Exchange Saturation Transfer and Diffusion-Weighted Imaging
by Kazuki Onishi, Koji Itagaki, Sachie Kusaka, Tensei Nakano, Junpei Ueda and Shigeyoshi Saito
Cancers 2025, 17(15), 2578; https://doi.org/10.3390/cancers17152578 - 5 Aug 2025
Abstract
Background/Objectives: This study aimed to examine the changes in brain metabolites and water molecule diffusion using chemical exchange saturation transfer (CEST) imaging and diffusion-weighted imaging (DWI) after 15 Gy of X-ray irradiation in a rat model of glioma. Methods: The glioma-derived [...] Read more.
Background/Objectives: This study aimed to examine the changes in brain metabolites and water molecule diffusion using chemical exchange saturation transfer (CEST) imaging and diffusion-weighted imaging (DWI) after 15 Gy of X-ray irradiation in a rat model of glioma. Methods: The glioma-derived cell line, C6, was implanted into the striatum of the right brain of 7-week-old male Wistar rats. CEST imaging and DWI were performed on days 8, 10, and 17 after implantation using a 7T-magnetic resonance imaging. X-ray irradiation (15 Gy) was performed on day 9. Magnetization transfer ratio (MTR) and apparent diffusion coefficient (ADC) values were calculated for CEST and DWI, respectively. Results: On day 17, the MTR values at 1.2 ppm, 1.5 ppm, 1.8 ppm, 2.1 ppm, and 2.4 ppm in the irradiated group decreased significantly compared with those of the control group. The standard deviation for the ADC values on a pixel-by-pixel basis increased from day 8 to day 17 (0.6 ± 0.06 → 0.8 ± 0.17 (×10−3 mm2/s)) in the control group, whereas it remained nearly unchanged (0.6 ± 0.06 → 0.8 ± 0.11 (×10−3 mm2/s)) in the irradiated group. Conclusions: This study revealed the effects of 15 Gy X-ray irradiation in a rat model of glioma using CEST imaging and DWI. Full article
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19 pages, 4451 KiB  
Article
Assessment of the Payments for Watershed Services Policy from a Perspective of Ecosystem Services: A Case Study of the Liaohe River Basin, China
by Manman Guo, Xu Lu and Qing Ma
Water 2025, 17(15), 2328; https://doi.org/10.3390/w17152328 - 5 Aug 2025
Abstract
Payments for Watershed services (PWSs) have been emerging as a critical tool for environmental governance in watershed, yet their comparative effectiveness across implementation models has remained poorly understood. Based on a comparative analysis of Eco-Compensation (EC) and Payments for Ecosystem Services (PESs) frameworks, [...] Read more.
Payments for Watershed services (PWSs) have been emerging as a critical tool for environmental governance in watershed, yet their comparative effectiveness across implementation models has remained poorly understood. Based on a comparative analysis of Eco-Compensation (EC) and Payments for Ecosystem Services (PESs) frameworks, examining both theoretical foundations and implementation practices, this study aims to quantitatively assess and compare the effectiveness of two dominant PWSs models—the EC-like model (Phase I: October 2008–April 2017) and the PESs-like model (Phase II: 2017–December 2021). Using the Liaohe River in China as a case study, utilizing ecosystem service value (ESV) as an indicator and employing the corrected unit-value transfer method, we compare the effectiveness of different PWSs models from October 2008 to December 2021. The results reveal the following: (1) Policy Efficiency: The PESs-like model demonstrated significantly greater effectiveness than the EC-like model, with annual average increases in ESV of 3.23 billion CNY (491 million USD) and 1.79 billion CNY (272 million USD). (2) Functional Drivers: Water regulation (45.1% of total ESV growth) and climate regulation (24.3%) were dominant services, with PESs-like interventions enhancing multifunctionality. (3) Stakeholder Impact: In the PESs-like model, the cities implementing inter-county direct payment showed higher growth efficiency than those without it. The operational efficiency of PWSs increases with the number of participating stakeholders, which explains why the PESs-like model demonstrates higher effectiveness than the EC-like model. Our findings offer empirical evidence and actionable policy implications for designing effective PWSs models across global watershed ecosystems. Full article
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20 pages, 3248 KiB  
Article
Experimental Study on the Hydrodynamic Analysis of a Floating Offshore Wind Turbine Under Focused Wave Conditions
by Hanbo Zhai, Chaojun Yan, Wei Shi, Lixian Zhang, Xinmeng Zeng, Xu Han and Constantine Michailides
Energies 2025, 18(15), 4140; https://doi.org/10.3390/en18154140 - 5 Aug 2025
Abstract
The strong nonlinearity of shallow-water waves significantly affects the dynamic response of floating offshore wind turbines (FOWTs), introducing additional complexity in motion behavior. This study presents a series of 1:80-scale experiments conducted on a 5 MW FOWT at a 50 m water depth, [...] Read more.
The strong nonlinearity of shallow-water waves significantly affects the dynamic response of floating offshore wind turbines (FOWTs), introducing additional complexity in motion behavior. This study presents a series of 1:80-scale experiments conducted on a 5 MW FOWT at a 50 m water depth, under regular, irregular, and focused wave conditions. The tests were conducted under regular, irregular, and focused wave conditions. The results show that, under both regular and irregular wave conditions, the platform’s motion and mooring tension increased as the wave period became longer, indicating a greater energy transfer and stronger coupling effects at lower wave frequencies. Specifically, in irregular seas, mooring tension increased by 16% between moderate and high sea states, with pronounced surge–pitch coupling near the natural frequency. Under focused wave conditions, the platform experienced significant surge displacement due to the impact of large wave crests, followed by free-decay behavior. Meanwhile, the pitch amplitude increased by up to 27%, and mooring line tension rose by 16% as the wave steepness intensified. These findings provide valuable insights for the design and optimization of FOWTs in complex marine environments, particularly under extreme wave conditions. Additionally, they contribute to the refinement of relevant numerical simulation methods. Full article
(This article belongs to the Topic Wind, Wave and Tidal Energy Technologies in China)
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18 pages, 2365 KiB  
Article
Integrated Environmental–Economic Assessment of CO2 Storage in Chinese Saline Formations
by Wentao Zhao, Zhe Jiang, Tieya Jing, Jian Zhang, Zhan Yang, Xiang Li, Juan Zhou, Jingchao Zhao and Shuhui Zhang
Water 2025, 17(15), 2320; https://doi.org/10.3390/w17152320 - 4 Aug 2025
Abstract
This study develops an integrated environmental–economic assessment framework to evaluate the life cycle environmental impacts and economic costs of CO2 geological storage and produced water treatment in saline formations in China. Using a case study of a saline aquifer carbon storage project [...] Read more.
This study develops an integrated environmental–economic assessment framework to evaluate the life cycle environmental impacts and economic costs of CO2 geological storage and produced water treatment in saline formations in China. Using a case study of a saline aquifer carbon storage project in the Ordos Basin, eight full-chain carbon capture, utilization, and storage (CCUS) scenarios were analyzed. The results indicate that environmental and cost performance are primarily influenced by technology choices across carbon capture, transport, and storage stages. The scenario employing potassium carbonate-based capture, pipeline transport, and brine reinjection after a reverse osmosis treatment (S5) achieved the most balanced outcome. Breakeven analyses under three carbon price projection models revealed that carbon price trajectories critically affect project viability, with a steadily rising carbon price enabling earlier profitability. By decoupling CCUS from power systems and focusing on unit CO2 removal, this study provides a transparent and transferable framework to support cross-sectoral deployment. The findings offer valuable insights for policymakers aiming to design effective CCUS support mechanisms under future carbon neutrality targets. Full article
(This article belongs to the Special Issue Mine Water Treatment, Utilization and Storage Technology)
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13 pages, 1674 KiB  
Article
Impact of Substrate Amount and Fruiting Induction Methods in Lentinula edodes Cultivation
by Bruno de Souza Rocha, Wagner Gonçalves Vieira Junior, Adriano Taffarel Camargo de Paula, Asser Botelho Santana, Marcos Antônio da Silva Freitas, Milton Mineo Hirai, Lucas da Silva Alves and Diego Cunha Zied
Horticulturae 2025, 11(8), 915; https://doi.org/10.3390/horticulturae11080915 (registering DOI) - 4 Aug 2025
Abstract
Mushroom production is a sustainable practice but requires improvements, such as in Lentinula edodes (Berk) Pegler cultivation, which has high water and labor demands. In this context, this study proposed replacing the traditional primordia induction method by submersion with a water injection method. [...] Read more.
Mushroom production is a sustainable practice but requires improvements, such as in Lentinula edodes (Berk) Pegler cultivation, which has high water and labor demands. In this context, this study proposed replacing the traditional primordia induction method by submersion with a water injection method. Two primordia induction methods (submersion and injection) and two cultivation block formats were compared: rectangular cube (2 kg) and cylindrical (3.5 kg). The substrate, composed of eucalyptus sawdust (72%), wheat bran (12.5%), rice bran (12.5%), CaCO3 (1%), and CaSO4 (2%), was inoculated with strain LED 19/11 and incubated for 80 days at 26 ± 5 °C and 85 ± 15% humidity. After this period, the blocks were washed and transferred to the production environment. Fruiting was induced either by submersion or water injection, and production was evaluated over four harvest flushes. The 2 kg blocks had higher yields with submersion (16.62%), while the 3.5 kg blocks responded better to injection (13.01%), showing more homogeneous production. Increasing the substrate quantity contributes to greater harvest stability across production cycles. Water injections proved to be a viable alternative, reducing handling and facilitating large-scale production. The use of this technique demonstrates great importance in reducing water use and also the need for labor in cultivation. Full article
(This article belongs to the Section Vegetable Production Systems)
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25 pages, 2973 KiB  
Article
Application of a DPSIR-Based Causal Framework for Sustainable Urban Riparian Forests: Insights from Text Mining and a Case Study in Seoul
by Taeheon Choi, Sangin Park and Joonsoon Kim
Forests 2025, 16(8), 1276; https://doi.org/10.3390/f16081276 - 4 Aug 2025
Abstract
As urbanization accelerates and climate change intensifies, the ecological integrity of urban riparian forests faces growing threats, underscoring the need for a systematic framework to guide their sustainable management. To address this gap, we developed a causal framework by applying text mining and [...] Read more.
As urbanization accelerates and climate change intensifies, the ecological integrity of urban riparian forests faces growing threats, underscoring the need for a systematic framework to guide their sustainable management. To address this gap, we developed a causal framework by applying text mining and sentence classification to 1001 abstracts from previous studies, structured within the DPSIR (Driver–Pressure–State–Impact–Response) model. The analysis identified six dominant thematic clusters—water quality, ecosystem services, basin and land use management, climate-related stressors, anthropogenic impacts, and greenhouse gas emissions—which reflect the multifaceted concerns surrounding urban riparian forest research. These themes were synthesized into a structured causal model that illustrates how urbanization, land use, and pollution contribute to ecological degradation, while also suggesting potential restoration pathways. To validate its applicability, the framework was applied to four major urban streams in Seoul, where indicator-based analysis and correlation mapping revealed meaningful linkages among urban drivers, biodiversity, air quality, and civic engagement. Ultimately, by integrating large-scale text mining with causal inference modeling, this study offers a transferable approach to support adaptive planning and evidence-based decision-making under the uncertainties posed by climate change. Full article
(This article belongs to the Section Forest Economics, Policy, and Social Science)
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11 pages, 1539 KiB  
Article
Heat Exchange and Flow Resistance in a Heat Exchanger Based on a Minimal Surface of the Gyroid Type—Results of Experimental Studies
by Krzysztof Dutkowski, Marcin Kruzel and Marcin Walczak
Energies 2025, 18(15), 4134; https://doi.org/10.3390/en18154134 - 4 Aug 2025
Abstract
The gyroid minimal surface is one type of triply periodic minimal surface (TPMS). TPMS is a minimal surface replicated in the three main directions of the Cartesian coordinate system. The minimal surface is a surface stretched between two objects, known as the smallest [...] Read more.
The gyroid minimal surface is one type of triply periodic minimal surface (TPMS). TPMS is a minimal surface replicated in the three main directions of the Cartesian coordinate system. The minimal surface is a surface stretched between two objects, known as the smallest possible area (e.g., a soap bubble with a saddle shape stretched between two parallel circles). The complicated shape of the TPMS makes its production possible only by additive methods (3D printing). This article presents the results of experimental studies on heat transfer and flow resistance in a heat exchanger made of stainless steel. The heat exchange surface, a TPMS gyroid, separates two working media: hot and cold water. The water flow rate was varied in the range from 8 kg/h to 25 kg/h (Re = 246–1171). The water temperature at the inlet to the exchanger was maintained at a constant level of 8.8 ± 0.3 °C and 49.5 ± 0.5 °C for cold and hot water, respectively. The effect of water flow rate on the change in its temperature, the heat output of the exchanger, the average heat transfer coefficient, pressure drop, and overall resistance factor was presented. Full article
(This article belongs to the Section J1: Heat and Mass Transfer)
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27 pages, 3653 KiB  
Review
Design and Application of Atomically Dispersed Transition Metal–Carbon Cathodes for Triggering Cascade Oxygen Reduction in Wastewater Treatment
by Shengnan Huang, Guangshuo Lyu, Chuhui Zhang, Chunye Lin and Hefa Cheng
Molecules 2025, 30(15), 3258; https://doi.org/10.3390/molecules30153258 - 4 Aug 2025
Viewed by 54
Abstract
The precise synthesis of non-precious metal single-atom electrocatalysts is crucial for enhancing the yield of highly active reactive oxygen species (ROSs). Conventional oxidation methods, such as Fenton or NaClO processes, suffer from poor efficiency, high energy demand, and secondary pollution. In contrast, heterogeneous [...] Read more.
The precise synthesis of non-precious metal single-atom electrocatalysts is crucial for enhancing the yield of highly active reactive oxygen species (ROSs). Conventional oxidation methods, such as Fenton or NaClO processes, suffer from poor efficiency, high energy demand, and secondary pollution. In contrast, heterogeneous electro-Fenton systems based on cascade oxygen reduction reactions (ORRs), which require low operational voltage and cause pollutant degradation through both direct electron transfer and ROS generation, have emerged as a promising alternative. Recent studies showed that carbon cathodes decorated with atomically dispersed transition metals can effectively integrate the excellent conductivity of carbon supports with the tunable surface chemistry of metal centers. However, the electronic structure of active sites intrinsically hinders the simultaneous achievement of high activity and selectivity in cascade ORRs. This review summarizes the advances, specifically from 2020 to 2025, in understanding the mechanism of cascade ORRs and the synthesis of transition metal-based single-atom catalysts in cathode electrocatalysis for efficient wastewater treatment, and discusses the key factors affecting treatment performance. While employing atomically engineered cathodes is a promising approach for energy-efficient wastewater treatment, future efforts should overcome the barriers in active site control and long-term stability of the catalysts to fully exploit their potential in addressing water pollution challenges. Full article
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15 pages, 4207 KiB  
Article
Impact Analysis of Inter-Basin Water Transfer on Water Shortage Risk in the Baiyangdian Area
by Yuhang Shi, Lixin Zhang and Jinping Zhang
Water 2025, 17(15), 2311; https://doi.org/10.3390/w17152311 - 4 Aug 2025
Viewed by 70
Abstract
This study quantitatively assesses the risk of water shortage (WSR) in the Baiyangdian area due to the Inter-Basin Water Transfer (IBWT) project, focusing on the impact of water transfer on regional water security. The actual evapotranspiration (ETa) is calculated, and the correlation simulation [...] Read more.
This study quantitatively assesses the risk of water shortage (WSR) in the Baiyangdian area due to the Inter-Basin Water Transfer (IBWT) project, focusing on the impact of water transfer on regional water security. The actual evapotranspiration (ETa) is calculated, and the correlation simulation using Archimedes’ Copula function is implemented in Python 3.7.1, with optimization using the sum of squares of deviations (OLS) and the AIC criterion. The joint distribution model between ETa and three water supply scenarios is constructed. Key findings include (1) ETa increased by 27.3% after water transfer, far exceeding the slight increase in water supply before the transfer; (2) various Archimedean Copulas effectively capture the dependence and joint probability distribution between water supply and ETa; (3) water shortage risk increased after water transfer, with rainfall and upstream water unable to alleviate the problem in Baiyangdian; and (4) cross-basin water transfer reduced risk, with a reduction of 8.90% in the total probability of three key water resource scheduling combinations. This study establishes a Copula-based framework for water shortage risk assessment, providing a scientific basis for water allocation strategies in ecologically sensitive areas affected by human activities. Full article
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21 pages, 3755 KiB  
Article
Thermal and Expansion Analysis of the Lebanese Flatbread Baking Process Using a High-Temperature Tunnel Oven
by Yves Mansour, Pierre Rahmé, Nemr El Hajj and Olivier Rouaud
Appl. Sci. 2025, 15(15), 8611; https://doi.org/10.3390/app15158611 (registering DOI) - 4 Aug 2025
Viewed by 74
Abstract
This study investigates the thermal dynamics and material behavior involved in the baking process for Lebanese flatbread, focusing on the heat transfer mechanisms, water loss, and dough expansion under high-temperature conditions. Despite previous studies on flatbread baking using impingement or conventional ovens, this [...] Read more.
This study investigates the thermal dynamics and material behavior involved in the baking process for Lebanese flatbread, focusing on the heat transfer mechanisms, water loss, and dough expansion under high-temperature conditions. Despite previous studies on flatbread baking using impingement or conventional ovens, this work presents the first experimental investigation of the traditional Lebanese flatbread baking process under realistic industrial conditions, specifically using a high-temperature tunnel oven with direct flame heating, extremely short baking times (~10–12 s), and peak temperatures reaching ~650 °C, which are essential to achieving the characteristic pocket formation and texture of Lebanese bread. This experimental study characterizes the baking kinetics of traditional Lebanese flatbread, recording mass loss pre- and post-baking, thermal profiles, and dough expansion through real-time temperature measurements and video recordings, providing insights into the dough’s thermal response and expansion behavior under high-temperature conditions. A custom-designed instrumented oven with a steel conveyor and a direct flame burner was employed. The dough, prepared following a traditional recipe, was analyzed during the baking process using K-type thermocouples and visual monitoring. Results revealed that Lebanese bread undergoes significant water loss due to high baking temperatures (~650 °C), leading to rapid crust formation and pocket development. Empirical equations modeling the relationship between baking time, temperature, and expansion were developed with high predictive accuracy. Additionally, an energy analysis revealed that the total energy required to bake Lebanese bread is approximately 667 kJ/kg, with an overall thermal efficiency of only 21%, dropping to 16% when preheating is included. According to previous CFD (Computational Fluid Dynamics) simulations, most heat loss in similar tunnel ovens occurs via the chimney (50%) and oven walls (29%). These findings contribute to understanding the broader thermophysical principles that can be applied to the development of more efficient baking processes for various types of bread. The empirical models developed in this study can be applied to automating and refining the industrial production of Lebanese flatbread, ensuring consistent product quality across different baking environments. Future studies will extend this work to alternative oven designs and dough formulations. Full article
(This article belongs to the Special Issue Chemical and Physical Properties in Food Processing: Second Edition)
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22 pages, 5293 KiB  
Article
Membrane Distillation for Water Desalination: Assessing the Influence of Operating Conditions on the Performance of Serial and Parallel Connection Configurations
by Lebea N. Nthunya and Bhekie B. Mamba
Membranes 2025, 15(8), 235; https://doi.org/10.3390/membranes15080235 - 4 Aug 2025
Viewed by 164
Abstract
Though the pursuit of sustainable desalination processes with high water recovery has intensified the research interest in membrane distillation (MD), the influence of module connection configuration on performance stability remains poorly explored. The current study provided a comprehensive multiparameter assessment of hollow fibre [...] Read more.
Though the pursuit of sustainable desalination processes with high water recovery has intensified the research interest in membrane distillation (MD), the influence of module connection configuration on performance stability remains poorly explored. The current study provided a comprehensive multiparameter assessment of hollow fibre membrane modules connected in parallel and series in direct contact membrane distillation (DCMD) for the first time. The configurations were evaluated under varying process parameters such as temperature (50–70 °C), flow rates (22.1–32.3 mL·s−1), magnesium concentration as scalant (1.0–4.0 g·L−1), and flow direction (co-current and counter-current), assessing their influence on temperature gradients (∆T), flux and pH stability, salt rejection, and crystallisation. Interestingly, the parallel module configuration maintained high operational stability with uniform flux and temperature differences (∆T) even at high recovery factors (>75%). On one hand, the serial configuration experienced fluctuating ∆T caused by thermal and concentration polarisation, causing an early crystallisation (abrupt drop in feed conductivity). Intensified polarisation effects with accelerated crystallisation increased the membrane risk of wetting, particularly at high recovery factors. Despite these changes, the salt rejection remained relatively high (99.9%) for both configurations across all tested conditions. The findings revealed that acidification trends caused by MgSO4 were configuration-dependent, where the parallel setup-controlled rate of pH collapse. This study presented a novel framework connecting membrane module architecture to mass and heat transfer phenomena, providing a transformative DCMD module configuration design in water desalination. These findings not only provide the critical knowledge gaps in DCMD module configurations but also inform optimisation of MD water desalination to achieve high recovery and stable operation conditions under realistic brine composition. Full article
(This article belongs to the Special Issue Membrane Distillation: Module Design and Application Performance)
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23 pages, 2663 KiB  
Article
How Nanofluids May Enhance Energy Efficiency and Carbon Footprint in Buildings?
by Sylwia Wciślik
Sustainability 2025, 17(15), 7035; https://doi.org/10.3390/su17157035 - 2 Aug 2025
Viewed by 257
Abstract
Nanofluids are an innovative working medium in solar hot water installations (DHWs), thanks to their increased thermal conductivity and heat transfer coefficient. The aim of this work was to assess the effect of Al2O3 nanofluids in a water–ethylene glycol base [...] Read more.
Nanofluids are an innovative working medium in solar hot water installations (DHWs), thanks to their increased thermal conductivity and heat transfer coefficient. The aim of this work was to assess the effect of Al2O3 nanofluids in a water–ethylene glycol base (40:60%) and with the addition of Tween 80 surfactant (0.2 wt%) on thermal efficiency (ε) and exergy (ηex) in a plate heat exchanger at DHW flows of 3 and 12 L/min. The numerical NTU–ε model was used with dynamic updating of thermophysical properties of nanofluids and the solution of the ODE system using the ode45 method, and the validation was carried out against the literature data. The results showed that the nanofluids achieved ε ≈ 0.85 (vs. ε ≈ 0.87 for the base fluid) and ηex ≈ 0.72 (vs. ηex ≈ 0.74), with higher entropy generation. The addition of Tween 80 reduced the viscosity by about 10–15%, resulting in a slight increase of Re and h-factor; however, the impact on ε and ηex was marginal. The environmental analysis with an annual demand of Q = 3000 kWh/year and an emission factor of 0.2 kg CO2/kWh showed that for ε < 0.87 the nanofluids increased the emissions by ≈16 kg CO2/year, while at ε ≈ 0.92, a reduction of ≈5% was possible. This paper highlights the need to optimize nanofluid viscosity and exchanger geometry to maximize energy and environmental benefits. Nowadays, due to the growing problems of global warming, the analysis of energy efficiency and carbon footprint related to the functioning of a building seems to be crucial. Full article
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20 pages, 3586 KiB  
Article
Enhanced NiFe2O4 Catalyst Performance and Stability in Anion Exchange Membrane Water Electrolysis: Influence of Iron Content and Membrane Selection
by Khaja Wahab Ahmed, Aidan Dobson, Saeed Habibpour and Michael Fowler
Molecules 2025, 30(15), 3228; https://doi.org/10.3390/molecules30153228 - 1 Aug 2025
Viewed by 237
Abstract
Anion exchange membrane (AEM) water electrolysis is a potentially inexpensive and efficient source of hydrogen production as it uses effective low-cost catalysts. The catalytic activity and performance of nickel iron oxide (NiFeOx) catalysts for hydrogen production in AEM water electrolyzers were [...] Read more.
Anion exchange membrane (AEM) water electrolysis is a potentially inexpensive and efficient source of hydrogen production as it uses effective low-cost catalysts. The catalytic activity and performance of nickel iron oxide (NiFeOx) catalysts for hydrogen production in AEM water electrolyzers were investigated. The NiFeOx catalysts were synthesized with various iron content weight percentages, and at the stoichiometric ratio for nickel ferrite (NiFe2O4). The catalytic activity of NiFeOx catalyst was evaluated by linear sweep voltammetry (LSV) and chronoamperometry for the oxygen evolution reaction (OER). NiFe2O4 showed the highest activity for the OER in a three-electrode system, with 320 mA cm−2 at 2 V in 1 M KOH solution. NiFe2O4 displayed strong stability over a 600 h period at 50 mA cm−2 in a three-electrode setup, with a degradation rate of 15 μV/h. In single-cell electrolysis using a X-37 T membrane, at 2.2 V in 1 M KOH, the NiFe2O4 catalyst had the highest activity of 1100 mA cm−2 at 45 °C, which increased with the temperature to 1503 mA cm−2 at 55 °C. The performance of various membranes was examined, and the highest performance of the tested membranes was determined to be that of the Fumatech FAA-3-50 and FAS-50 membranes, implying that membrane performance is strongly correlated with membrane conductivity. The obtained Nyquist plots and equivalent circuit analysis were used to determine cell resistances. It was found that ohmic resistance decreases with an increase in temperature from 45 °C to 55 °C, implying the positive effect of temperature on AEM electrolysis. The FAA-3-50 and FAS-50 membranes were determined to have lower activation and ohmic resistances, indicative of higher conductivity and faster membrane charge transfer. NiFe2O4 in an AEM water electrolyzer displayed strong stability, with a voltage degradation rate of 0.833 mV/h over the 12 h durability test. Full article
(This article belongs to the Special Issue Water Electrolysis)
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