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17 pages, 3817 KiB  
Article
The Distribution Characteristics of Frost Heaving Forces on Tunnels in Cold Regions Based on Thermo-Mechanical Coupling
by Yujia Sun, Lei Peng and Qionglin Li
Appl. Sci. 2025, 15(15), 8537; https://doi.org/10.3390/app15158537 (registering DOI) - 31 Jul 2025
Viewed by 136
Abstract
To address the freezing damage to tunnel lining caused by frost heaving of the surrounding rock in water-rich tunnels in cold regions, a numerical thermo-mechanical coupling model for tunnel-surrounding rock that considers the anisotropy of frost heave deformation was established by examining overall [...] Read more.
To address the freezing damage to tunnel lining caused by frost heaving of the surrounding rock in water-rich tunnels in cold regions, a numerical thermo-mechanical coupling model for tunnel-surrounding rock that considers the anisotropy of frost heave deformation was established by examining overall frost heaves in a freeze–thaw cycle. Using a COMSOL Multiphysics 6.0 platform and the sequential coupling method, the temperature field evolution of tunnel-surrounding rock, freezing cycle development, and distribution characteristics of the frost heaving force of a tunnel lining under different minimum temperatures, numbers of negative temperature days, frost heave ratios, and anisotropy coefficients of frost heave deformation were systematically simulated. The results revealed that the response of the temperature field of tunnel-surrounding rock to the external temperature varies spatially with time lags, the shallow surface temperatures and the area around the lining fluctuate with the climate, and the temperature of the deep surrounding rock is dominated by the geothermal gradient. The extent of the freezing cycle and the frost heaving force increase significantly when lowering the minimum temperature. The maximum frost heaving force usually occurs in the region of the side wall and the spring line, and tensile stress is prone to be generated at the spring line; the influence of slight fluctuations in the minimum temperature or the short shift in the coldest day on the frost heaving force is limited. A substantial increase in frost heaving force is observed with higher frost heave ratios; for example, an increase from 0.25% to 2.0% results in a 116% rise at the sidewall. Although the increase in the anisotropy coefficient of frost heave deformation does not change the overall distribution pattern of frost heaving force, it can exacerbate the directional concentration of frost heave strain, which can increase the frost heaving force at the periphery of the top arch of the lining. This study revealed the distribution pattern and key influencing factors of the freezing cycle and frost heaving force for tunnels, providing a theoretical basis and data reference for the frost resistance design of tunnels in cold regions. Full article
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26 pages, 12136 KiB  
Article
Integrated Analysis of Satellite and Geological Data to Characterize Ground Deformation in the Area of Bologna (Northern Italy) Using a Cluster Analysis-Based Approach
by Alberto Manuel Garcia Navarro, Celine Eid, Vera Rocca, Christoforos Benetatos, Claudio De Luca, Giovanni Onorato and Riccardo Lanari
Remote Sens. 2025, 17(15), 2645; https://doi.org/10.3390/rs17152645 - 30 Jul 2025
Viewed by 276
Abstract
This study investigates ground deformations in the southeastern Po Plain (northern Italy), focusing on the Bologna area—a densely populated region affected by natural and anthropogenic subsidence. Ground deformations in the area result from geological processes (e.g., sediment compaction and tectonic activity) and human [...] Read more.
This study investigates ground deformations in the southeastern Po Plain (northern Italy), focusing on the Bologna area—a densely populated region affected by natural and anthropogenic subsidence. Ground deformations in the area result from geological processes (e.g., sediment compaction and tectonic activity) and human activities (e.g., ground water production and underground gas storage—UGS). We apply a multidisciplinary approach integrating subsurface geology, ground water production, advanced differential interferometry synthetic aperture radar—DInSAR, gas storage data, and land use information to characterize and analyze the spatial and temporal variations in vertical ground deformations. Seasonal and trend decomposition using loess (STL) and cluster analysis techniques are applied to historical DInSAR vertical time series, targeting three representatives areas close to the city of Bologna. The main contribution of the study is the attempt to correlate the lateral extension of ground water bodies with seasonal ground deformations and water production data; the results are validated via knowledge of the geological characteristics of the uppermost part of the Po Plain area. Distinct seasonal patterns are identified and correlated with ground water production withdrawal and UGS operations. The results highlight the influence of superficial aquifer characteristics—particularly the geometry, lateral extent, and hydraulic properties of sedimentary bodies—on the ground movements behavior. This case study outlines an effective multidisciplinary approach for subsidence characterization providing critical insights for risk assessment and mitigation strategies, relevant for the future development of CO2 and hydrogen storage in depleted reservoirs and saline aquifers. Full article
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36 pages, 9354 KiB  
Article
Effects of Clouds and Shadows on the Use of Independent Component Analysis for Feature Extraction
by Marcos A. Bosques-Perez, Naphtali Rishe, Thony Yan, Liangdong Deng and Malek Adjouadi
Remote Sens. 2025, 17(15), 2632; https://doi.org/10.3390/rs17152632 - 29 Jul 2025
Viewed by 157
Abstract
One of the persistent challenges in multispectral image analysis is the interference caused by dense cloud cover and its resulting shadows, which can significantly obscure surface features. This becomes especially problematic when attempting to monitor surface changes over time using satellite imagery, such [...] Read more.
One of the persistent challenges in multispectral image analysis is the interference caused by dense cloud cover and its resulting shadows, which can significantly obscure surface features. This becomes especially problematic when attempting to monitor surface changes over time using satellite imagery, such as from Landsat-8. In this study, rather than simply masking visual obstructions, we aimed to investigate the role and influence of clouds within the spectral data itself. To achieve this, we employed Independent Component Analysis (ICA), a statistical method capable of decomposing mixed signals into independent source components. By applying ICA to selected Landsat-8 bands and analyzing each component individually, we assessed the extent to which cloud signatures are entangled with surface data. This process revealed that clouds contribute to multiple ICA components simultaneously, indicating their broad spectral influence. With this influence on multiple wavebands, we managed to configure a set of components that could perfectly delineate the extent and location of clouds. Moreover, because Landsat-8 lacks cloud-penetrating wavebands, such as those in the microwave range (e.g., SAR), the surface information beneath dense cloud cover is not captured at all, making it physically impossible for ICA to recover what is not sensed in the first place. Despite these limitations, ICA proved effective in isolating and delineating cloud structures, allowing us to selectively suppress them in reconstructed images. Additionally, the technique successfully highlighted features such as water bodies, vegetation, and color-based land cover differences. These findings suggest that while ICA is a powerful tool for signal separation and cloud-related artifact suppression, its performance is ultimately constrained by the spectral and spatial properties of the input data. Future improvements could be realized by integrating data from complementary sensors—especially those operating in cloud-penetrating wavelengths—or by using higher spectral resolution imagery with narrower bands. Full article
(This article belongs to the Section Environmental Remote Sensing)
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27 pages, 2565 KiB  
Review
The Role of ESG in Driving Sustainable Innovation in Water Sector: From Gaps to Governance
by Gabriel Minea, Elena Simina Lakatos, Roxana Maria Druta, Alina Moldovan, Lucian Marius Lupu and Lucian Ionel Cioca
Water 2025, 17(15), 2259; https://doi.org/10.3390/w17152259 - 29 Jul 2025
Viewed by 444
Abstract
The water sector is facing a convergence of systemic challenges generated by climate change, increasing demand, and increasingly stringent regulations, which threaten its operational and strategic sustainability. In this context, the article examines how ESG (environmental, social, governance) principles are integrated into the [...] Read more.
The water sector is facing a convergence of systemic challenges generated by climate change, increasing demand, and increasingly stringent regulations, which threaten its operational and strategic sustainability. In this context, the article examines how ESG (environmental, social, governance) principles are integrated into the governance, financing, and management of water resources, with a comparative focus on Romania and the European Union. It aims to assess the extent to which ESG practices contribute to the sustainable transformation of the water sector in the face of growing environmental and socio-economic challenges. The methodology is based on a systematic analysis of policy documents, regulatory frameworks, and ESG standards applicable to the water sector at both national (Romania) and EU levels. This study also investigates investment strategies and their alignment with the EU Taxonomy for Sustainable Activities, enabling a comparative perspective on implementation, gaps and strengths. Findings reveal that while ESG principles are increasingly recognized across Europe, their implementation remains uneven (particularly in Romania) due to unclear standards, limited funding mechanisms, and fragmented policy coordination. ESG integration shows clear potential to foster innovation, improve governance transparency, and support long-term resilience in the water sector. These results underline the need for coherent, integrated policies and stronger institutional coordination to ensure consistent ESG adoption across Member States. Policymakers should prioritize the development of clear guidelines and supportive funding instruments to accelerate sustainable outcomes. The originality of our study lies in its comparative approach, offering an in-depth analysis of ESG integration in the water sector across different governance contexts. It provides valuable insights for advancing policy coherence, investment alignment, and sustainable water resource management at both national and European levels. Full article
(This article belongs to the Section Water Resources Management, Policy and Governance)
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18 pages, 1597 KiB  
Article
Influence Mechanism of Coexisting Ions on the Extraction Efficiency of Lithium from Oil and Gas Field Water
by Qiaoli Shan, Guocheng Zhu, Pengjun Fan, Mengyu Liang, Xin Zhang, Jie Liu and Guizhi Wu
Water 2025, 17(15), 2258; https://doi.org/10.3390/w17152258 - 29 Jul 2025
Viewed by 124
Abstract
Oil and gas field water not only contains low concentrations of lithium but also a lot of suspended matter, inorganic salt, and organic matter. Both inorganic ions and organic substances influence the extraction of lithium. To improve the extraction efficiency of low-concentration lithium [...] Read more.
Oil and gas field water not only contains low concentrations of lithium but also a lot of suspended matter, inorganic salt, and organic matter. Both inorganic ions and organic substances influence the extraction of lithium. To improve the extraction efficiency of low-concentration lithium in oil and gas field water, the effects of Na+, K+, Ca2+, Mg2+, Cl, Br, SO42−, NO3, and organic substances on the extraction efficiency of lithium were studied. The results showed that Na+ can promote the extraction of lithium to a certain extent, and lithium ions competed with K+ for extraction; however, the separation coefficient remained more than 13. Ca2+ and Mg2+ have a significant influence on the extraction of lithium and should be removed prior to extraction. Cl, SO42−, and NO3 have little influence on the extraction solution of lithium. Among the organic components, a high concentration of long-chain alkane has a certain effect on the extraction efficiency of lithium, while other substances have little effect. On this basis, the first step for precipitating impurity ions and the second step for solvent extraction of lithium were established. After removing the impurity ions, the extraction efficiency of lithium can reach over 90%. Taking 15L of oil and gas field water as the research object, after extraction, back extraction, concentration, depth impurities removal by extraction, and precipitation drying, the purity of the lithium carbonate product can be achieved at 99.28%. This study can provide technical support for the efficient extraction of low-concentration lithium from oil and gas field water. Full article
(This article belongs to the Special Issue Science and Technology for Water Purification, 2nd Edition)
17 pages, 6929 KiB  
Article
The Application and Effects of Aerogel in Ultra-Lightweight Mineralised Foams
by Tongyu Xu, Harald Garrecht, Chao Jiang and Chuanyuan Lu
Buildings 2025, 15(15), 2671; https://doi.org/10.3390/buildings15152671 - 28 Jul 2025
Viewed by 208
Abstract
This study aims to explore the potential of aerogel to optimise the thermal conductivity of mineralised foam materials. Experiments were conducted with (i) addition methods of aerogel, (ii) proportion of aerogels in cement slurry, and (iii) water/cement ratio as influencing parameters for mineralised [...] Read more.
This study aims to explore the potential of aerogel to optimise the thermal conductivity of mineralised foam materials. Experiments were conducted with (i) addition methods of aerogel, (ii) proportion of aerogels in cement slurry, and (iii) water/cement ratio as influencing parameters for mineralised foam. Additionally, mixed Ordinary Portland Cement (OPC)/Calcium Sulphoaluminate Cement (CSA) slurries were used to test whether a synergy could be achieved. In this study, the defoaming effect of the aerogel and its mitigation to a certain extent by pre-mixing the aerogel with cement slurry were confirmed. The thermal conductivity of the mineralised foams was reduced from 0.049 to 0.036 W/(m·K) when the aerogel was up to 10 wt.% of the cement. In the specimens prepared from the mixed OPC/CSA slurry, a homogeneous circular pore structure was observed under the microscope along with a reduction in the thermal conductivity. The use of aerogels and CSA cements can effectively reduce the thermal conductivity of ultra-low-density mineralised foams to levels comparable with certain plastic foams that dominate the building insulation market. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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25 pages, 13635 KiB  
Article
Microplastics in Nearshore and Subtidal Sediments in the Salish Sea: Implications for Marine Habitats and Exposure
by Frances K. Eshom-Arzadon, Kaitlyn Conway, Julie Masura and Matthew R. Baker
J. Mar. Sci. Eng. 2025, 13(8), 1441; https://doi.org/10.3390/jmse13081441 - 28 Jul 2025
Viewed by 367
Abstract
Plastic debris is a pervasive and persistent threat to marine ecosystems. Microplastics (plastics < 5 mm) are increasing in a variety of marine habitats, including open water systems, shorelines, and benthic sediments. It remains unclear how microplastics distribute and accumulate in marine systems [...] Read more.
Plastic debris is a pervasive and persistent threat to marine ecosystems. Microplastics (plastics < 5 mm) are increasing in a variety of marine habitats, including open water systems, shorelines, and benthic sediments. It remains unclear how microplastics distribute and accumulate in marine systems and the extent to which this pollutant is accessible to marine taxa. We examined subtidal benthic sediments and beach sediments in critical nearshore habitats for forage fish species—Pacific sand lance (Ammodytes personatus), Pacific herring (Clupea pallasi), and surf smelt (Hypomesus pretiosus)—to quantify microplastic concentrations in the spawning and deep-water habitats of these fish and better understand how microplastics accumulate and distribute in nearshore systems. In the San Juan Islands, we examined an offshore subtidal bedform in a high-flow channel and beach sites of protected and exposed shorelines. We also examined 12 beach sites proximate to urban areas in Puget Sound. Microplastics were found in all samples and at all sample sites. Microfibers were the most abundant, and flakes were present proximate to major shipyards and marinas. Microplastics were significantly elevated in Puget Sound compared to the San Juan Archipelago. Protected beaches had elevated concentrations relative to exposed beaches and subtidal sediments. Microplastics were in higher concentrations in sand and fine-grain sediments, poorly sorted sediments, and artificial sediments. Microplastics were also elevated at sites confirmed as spawning habitats for forage fish. The model results indicate that both current speed and proximate urban populations influence nearshore microplastic concentrations. Our research provides new insights into how microplastics are distributed, deposited, and retained in marine sediments and shorelines, as well as insight into potential exposure in benthic, demersal, and shoreline habitats. Further analyses are required to examine the relative influence of urban populations and shipping lanes and the effects of physical processes such as wave exposure, tidal currents, and shoreline geometry. Full article
(This article belongs to the Special Issue Benthic Ecology in Coastal and Brackish Systems—2nd Edition)
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22 pages, 1882 KiB  
Article
Assessing Pharmaceuticals in Bivalves and Microbial Sewage Contamination in Hout Bay, Cape Town: Identifying Impact Zones in Coastal and Riverine Environments
by Cecilia Y. Ojemaye, Amy Beukes, Justin Moser, Faith Gara, Jo Barnes, Lesley Petrik and Lesley Green
Environments 2025, 12(8), 257; https://doi.org/10.3390/environments12080257 - 28 Jul 2025
Viewed by 1065
Abstract
This study investigates the implications of sewage contamination in the coastal and riverine environments of Hout Bay, Cape Town, South Africa. Chemical analyses were applied to quantify the presence of pollutants such as pharmaceutical and personal care products (PPCPs) in sentinel marine organisms [...] Read more.
This study investigates the implications of sewage contamination in the coastal and riverine environments of Hout Bay, Cape Town, South Africa. Chemical analyses were applied to quantify the presence of pollutants such as pharmaceutical and personal care products (PPCPs) in sentinel marine organisms such as mussels, as well as microbial indicators of faecal contamination in river water and seawater, for estimating the extent of impact zones in the coastal environment of Hout Bay. This research investigated the persistent pharmaceuticals found in marine outfall wastewater effluent samples in Hout Bay, examining whether these substances were also detectable in marine biota, specifically focusing on Mytilus galloprovincialis mussels. The findings reveal significant levels of sewage-related pollutants in the sampled environments, with concentrations ranging from 32.74 to 43.02 ng/g dry weight (dw) for acetaminophen, up to 384.96 ng/g for bezafibrate, and as high as 338.56 ng/g for triclosan. These results highlight persistent PPCP contamination in marine organisms, with increasing concentrations observed over time, suggesting a rise in population and pharmaceutical use. Additionally, microbial analysis revealed high levels of E. coli in the Hout Bay River, particularly near stormwater from the Imizamo Yethu settlement, with counts exceeding 8.3 million cfu/100 mL. These findings underscore the significant impact of untreated sewage on the environment. This study concludes that current sewage treatment is insufficient to mitigate pollution, urging the implementation of more effective wastewater management practices and long-term monitoring of pharmaceutical levels in marine biota to protect both the environment and public health. Full article
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21 pages, 5274 KiB  
Article
Sediment Flushing Operation Mode During Sediment Peak Processes Aiming Towards the Sustainability of Three Gorges Reservoir
by Bingjiang Dong, Lingling Zhu, Shi Ren, Jing Yuan and Chaonan Lv
Sustainability 2025, 17(15), 6836; https://doi.org/10.3390/su17156836 - 28 Jul 2025
Viewed by 262
Abstract
Asynchrony between the movement of water and sediment in a reservoir will affect long-term maintenance of the reservoir’s capacity to a certain extent. Based on water and sediment data on the Three Gorges Reservoir (TGR) measured over the years and a river network [...] Read more.
Asynchrony between the movement of water and sediment in a reservoir will affect long-term maintenance of the reservoir’s capacity to a certain extent. Based on water and sediment data on the Three Gorges Reservoir (TGR) measured over the years and a river network model, optimization of the dispatching mode of the reservoir’s sand peak process was studied, and the corresponding water and sediment dispatching indicators were provided. The results show that (1) sand peak discharge dispatching of the TGR can be divided roughly into three stages, namely the flood detention period, the sediment transport period, and the sediment discharge period. (2) According to the process of the flood peak and the sand peak, a division method for each period is proposed. (3) A corresponding scheduling index is proposed according to the characteristics of the sand peak process and the needs of flood control scheduling. This research can provide operational indicators for the operation and management of the sediment load in the TGR and also provide technical support for sustainable reservoirs similar to TGR. Full article
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24 pages, 6552 KiB  
Article
Assessing Flooding from Changes in Extreme Rainfall: Using the Design Rainfall Approach in Hydrologic Modeling
by Anna M. Jalowska, Daniel E. Line, Tanya L. Spero, J. Jack Kurki-Fox, Barbara A. Doll, Jared H. Bowden and Geneva M. E. Gray
Water 2025, 17(15), 2228; https://doi.org/10.3390/w17152228 - 26 Jul 2025
Viewed by 390
Abstract
Quantifying future changes in extreme events and associated flooding is challenging yet fundamental for stormwater managers. Along the U.S. Atlantic Coast, Eastern North Carolina (ENC) is frequently exposed to catastrophic floods from extreme rainfall that is typically associated with tropical cyclones. This study [...] Read more.
Quantifying future changes in extreme events and associated flooding is challenging yet fundamental for stormwater managers. Along the U.S. Atlantic Coast, Eastern North Carolina (ENC) is frequently exposed to catastrophic floods from extreme rainfall that is typically associated with tropical cyclones. This study presents a novel approach that uses rainfall data from five dynamically and statistically downscaled (DD and SD) global climate models under two scenarios to visualize a potential future extent of flooding in ENC. Here, we use DD data (at 36-km grid spacing) to compute future changes in precipitation intensity–duration–frequency (PIDF) curves at the end of the 21st century. These PIDF curves are further applied to observed rainfall from Hurricane Matthew—a landfalling storm that created widespread flooding across ENC in 2016—to project versions of “Matthew 2100” that reflect changes in extreme precipitation under those scenarios. Each Matthew-2100 rainfall distribution was then used in hydrologic models (HEC-HMS and HEC-RAS) to simulate “2100” discharges and flooding extents in the Neuse River Basin (4686 km2) in ENC. The results show that DD datasets better represented historical changes in extreme rainfall than SD datasets. The projected changes in ENC rainfall (up to 112%) exceed values published for the U.S. but do not exceed historical values. The peak discharges for Matthew-2100 could increase by 23–69%, with 0.4–3 m increases in water surface elevation and 8–57% increases in flooded area. The projected increases in flooding would threaten people, ecosystems, agriculture, infrastructure, and the economy throughout ENC. Full article
(This article belongs to the Section Water and Climate Change)
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24 pages, 10881 KiB  
Article
Dynamics of Water Quality in the Mirim–Patos–Mangueira Coastal Lagoon System with Sentinel-3 OLCI Data
by Paula Andrea Contreras Rojas, Felipe de Lucia Lobo, Wesley J. Moses, Gilberto Loguercio Collares and Lino Sander de Carvalho
Geomatics 2025, 5(3), 36; https://doi.org/10.3390/geomatics5030036 - 25 Jul 2025
Viewed by 342
Abstract
The Mirim–Patos–Mangueira coastal lagoon system provides a wide range of ecosystem services. However, its vast territorial extent and the political boundaries that divide it hinder integrated assessments, especially during extreme hydrological events. This study is divided into two parts. First, we assessed the [...] Read more.
The Mirim–Patos–Mangueira coastal lagoon system provides a wide range of ecosystem services. However, its vast territorial extent and the political boundaries that divide it hinder integrated assessments, especially during extreme hydrological events. This study is divided into two parts. First, we assessed the spatial and temporal patterns of water quality in the lagoon system using Sentinel-3/OLCI satellite imagery. Atmospheric correction was performed using ACOLITE, followed by spectral grouping and classification into optical water types (OWTs) using the Sentinel Applications Platform (SNAP). To explore the behavior of water quality parameters across OWTs, Chlorophyll-a and turbidity were estimated using semi-empirical algorithms specifically designed for complex inland and coastal waters. Results showed a gradual increase in mean turbidity from OWT 2 to OWT 6 and a rise in chlorophyll-a from OWT 2 to OWT 4, with a decline at OWT 6. These OWTs correspond, in general terms, to distinct water masses: OWT 2 to clearer waters, OWT 3 and 4 to intermediate/mixed conditions, and OWT 6 to turbid environments. In the second part, we analyzed the response of the Patos Lagoon to flooding in Rio Grande do Sul during an extreme weather event in May 2024. Satellite-derived turbidity estimates were compared with in situ measurements, revealing a systematic underestimation, with a negative bias of 2.6%, a mean relative error of 78%, and a correlation coefficient of 0.85. The findings highlight the utility of OWT classification for tracking changes in water quality and support the use of remote sensing tools to improve environmental monitoring in data-scarce regions, particularly under extreme hydrometeorological conditions. Full article
(This article belongs to the Special Issue Advances in Ocean Mapping and Hydrospatial Applications)
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26 pages, 13192 KiB  
Article
Investigating a Large-Scale Creeping Landmass Using Remote Sensing and Geophysical Techniques—The Case of Stropones, Evia, Greece
by John D. Alexopoulos, Ioannis-Konstantinos Giannopoulos, Vasileios Gkosios, Spyridon Dilalos, Nicholas Voulgaris and Serafeim E. Poulos
Geosciences 2025, 15(8), 282; https://doi.org/10.3390/geosciences15080282 - 25 Jul 2025
Viewed by 315
Abstract
The present paper deals with an inhabited, creeping mountainous landmass with profound surface deformation that affects the local community. The scope of the paper is to gather surficial and subsurface information in order to understand the parameters of this creeping mass, which is [...] Read more.
The present paper deals with an inhabited, creeping mountainous landmass with profound surface deformation that affects the local community. The scope of the paper is to gather surficial and subsurface information in order to understand the parameters of this creeping mass, which is usually affected by several parameters, such as its geometry, subsurface water, and shear zone. Therefore, a combined aerial and surface investigation has been conducted. The aerial investigation involves UAV’s LiDAR acquisition for the terrain model and a comparison of historical aerial photographs for land use changes. The multi-technique surface investigation included resistivity (ERT) and seismic (SRT, MASW) measurements and density determination of geological formations. This combination of methods proved to be fruitful since several aspects of the landslide were clarified, such as water flow paths, the internal geological structure of the creeping mass, and its geometrical extent. The depth of the shear zone of the creeping mass is delineated at the first five to ten meters from the surface, especially from the difference in diachronic resistivity change. Full article
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19 pages, 1849 KiB  
Article
A Simultaneous Determination of the B1 and B6 Vitamers Reveals Their Loss During a Single Peritoneal Dialysis Session: Chromatographic and Chemometric Approach
by Paweł Rudnicki-Velasquez, Karol Krzymiński, Magdalena Jankowska, Anna Baraniak and Paulina Czaplewska
Int. J. Mol. Sci. 2025, 26(15), 7177; https://doi.org/10.3390/ijms26157177 - 25 Jul 2025
Viewed by 202
Abstract
This study aimed to assess the extent of vitamin B1 and B6 vitamer loss during a single peritoneal dialysis (PD) session using a combination of chromatographic techniques and chemometric analysis. Dialysis effluent samples were collected from 41 PD patients (22 on [...] Read more.
This study aimed to assess the extent of vitamin B1 and B6 vitamer loss during a single peritoneal dialysis (PD) session using a combination of chromatographic techniques and chemometric analysis. Dialysis effluent samples were collected from 41 PD patients (22 on continuous ambulatory peritoneal dialysis (CAPD) and 19 on automated peritoneal dialysis (APD)) during a standardised peritoneal equilibration test. Concentrations of thiamine monophosphate, thiamine diphosphate (ThDP), pyridoxine, pyridoxal (PL), and pyridoxamine were determined using high-performance liquid chromatography with a fluorescence detector. The analytical method was validated in terms of sensitivity, linearity, accuracy, and recovery. Multiple regression analysis was employed to identify potential clinical and demographic predictors of vitamin washout. All vitamers except pyridoxal 5-phosphate (PLP) were detectable in dialysis effluents. ThDP exhibited the greatest loss among the B1 forms (ca. 0.05–0.57 mg/24 h), while PL exhibited the most significant loss among the B6 forms (ca. 0.01–0.19 mg/24 h). Vitamin losses varied depending on the dialysis modality (continuous ambulatory peritoneal dialysis, or CAPD, versus automated peritoneal dialysis, or APD) and the peritoneal transport category. Regression analysis identified body weight, haemoglobin, and haematocrit as independent predictors of ThDP washout (R2 = 0.58). No statistically robust models were established for the other vitamers. Even short medical procedures (such as single PD) can result in measurable losses of water-soluble vitamins, particularly ThDP and PL. The results emphasise the importance of personalised vitamin supplementation for PD patients and suggest that body composition and haematological parameters significantly influence the loss of thiamine. Full article
(This article belongs to the Section Bioactives and Nutraceuticals)
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18 pages, 15284 KiB  
Article
Two-Dimensional Flood Modeling of a Piping-Induced Dam Failure Triggered by Seismic Deformation: A Case Study of the Doğantepe Dam
by Fatma Demir, Suleyman Sarayli, Osman Sonmez, Melisa Ergun, Abdulkadir Baycan and Gamze Tuncer Evcil
Water 2025, 17(15), 2207; https://doi.org/10.3390/w17152207 - 24 Jul 2025
Viewed by 478
Abstract
This study presents a scenario-based, two-dimensional flood modeling approach to assess the potential downstream impacts of a piping-induced dam failure triggered by seismic activity. The case study focuses on the Doğantepe Dam in northwestern Türkiye, located near an active branch of the North [...] Read more.
This study presents a scenario-based, two-dimensional flood modeling approach to assess the potential downstream impacts of a piping-induced dam failure triggered by seismic activity. The case study focuses on the Doğantepe Dam in northwestern Türkiye, located near an active branch of the North Anatolian Fault. Critical deformation zones were previously identified through PLAXIS 2D seismic analyses, which served as the physical basis for a dam break scenario. This scenario was modeled using the HEC-RAS 2D platform, incorporating high-resolution topographic data, reservoir capacity, and spatially varying Manning’s roughness coefficients. The simulation results show that the flood wave reaches downstream settlements within the first 30 min, with water depths exceeding 3.0 m in low-lying areas and flow velocities surpassing 6.0 m/s, reaching up to 7.0 m/s in narrow sections. Inundation extents and hydraulic parameters such as water depth and duration were spatially mapped to assess flood hazards. The study demonstrates that integrating physically based seismic deformation data with hydrodynamic modeling provides a realistic and applicable framework for evaluating flood risks and informing emergency response planning. Full article
(This article belongs to the Special Issue Disaster Analysis and Prevention of Dam and Slope Engineering)
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17 pages, 4162 KiB  
Article
Evaluation of Wake Structure Induced by Helical Hydrokinetic Turbine
by Erkan Alkan, Mehmet Ishak Yuce and Gökmen Öztürkmen
Water 2025, 17(15), 2203; https://doi.org/10.3390/w17152203 - 23 Jul 2025
Viewed by 182
Abstract
This study investigates the downstream wake characteristics of a helical hydrokinetic turbine through combined experimental and numerical analyses. A four-bladed helical turbine with a 20 cm rotor diameter and blockage ratio of 53.57% was tested in an open water channel under a flow [...] Read more.
This study investigates the downstream wake characteristics of a helical hydrokinetic turbine through combined experimental and numerical analyses. A four-bladed helical turbine with a 20 cm rotor diameter and blockage ratio of 53.57% was tested in an open water channel under a flow rate of 180 m3/h, corresponding to a Reynolds number of approximately 90 × 103. Velocity measurements were collected at 13 downstream cross-sections using an Acoustic Doppler Velocimeter, with each point sampled repeatedly. Standard error analysis was applied to quantify measurement uncertainty. Complementary numerical simulations were conducted in ANSYS Fluent using a steady-state k-ω Shear Stress Transport (SST) turbulence model, with a mesh of 4.7 million elements and mesh independence confirmed. Velocity deficit and turbulence intensity were employed as primary parameters to characterize the wake structure, while the analysis also focused on the recovery of cross-sectional velocity profiles to validate the extent of wake influence. Experimental results revealed a maximum velocity deficit of over 40% in the near-wake region, which gradually decreased with downstream distance, while turbulence intensity exceeded 50% near the rotor and dropped below 10% beyond 4 m. In comparison, numerical findings showed a similar trend but with lower peak velocity deficits of 16.6%. The root mean square error (RMSE) and mean absolute error (MAE) between experimental and numerical mean velocity profiles were calculated as 0.04486 and 0.03241, respectively, demonstrating reasonable agreement between the datasets. Extended simulations up to 30 m indicated that flow profiles began to resemble ambient conditions around 18–20 m. The findings highlight the importance of accurately identifying the downstream distance at which the wake effect fully dissipates, as this is crucial for determining appropriate inter-turbine spacing. The study also discusses potential sources of discrepancies between experimental and numerical results, as well as the limitations of the modeling approach. Full article
(This article belongs to the Special Issue Optimization-Simulation Modeling of Sustainable Water Resource)
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