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Search Results (944)

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Keywords = vibrations with contact

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26 pages, 8019 KiB  
Article
Tribo-Dynamic Investigation of Cryogenic Ball Bearings Considering Varying Traction Parameters
by Shijie Zhang, Shuangshuang Jia, Yuhao Zhao, Jing Wei and Yanyang Zi
Lubricants 2025, 13(8), 352; https://doi.org/10.3390/lubricants13080352 - 5 Aug 2025
Abstract
The traction behavior in cryogenic solid-lubricated ball bearings (CSLBBs) used in liquid rocket engines (LREs) affects not only the dynamic response of the bearing but also the lubricity and wear characteristics of the solid lubrication coating. The traction coefficient between the ball and [...] Read more.
The traction behavior in cryogenic solid-lubricated ball bearings (CSLBBs) used in liquid rocket engines (LREs) affects not only the dynamic response of the bearing but also the lubricity and wear characteristics of the solid lubrication coating. The traction coefficient between the ball and raceway depends on factors such as contact material, relative sliding velocity, and contact pressure. However, existing traction curve models for CSLBBs typically consider only one or two of these factors, limiting the accuracy and applicability of theoretical predictions. In this study, a novel traction model for CSLBBs is proposed, which incorporates the combined effects of contact material, relative sliding velocity, and contact pressure. Based on this model, a tribo-dynamic framework is developed to investigate the tribological and dynamic behavior of CSLBBs. The model is validated through both theoretical analysis and experimental data. Results show that the inclusion of solid lubricant effects significantly alters the relative sliding and frictional forces between the rolling elements and the raceway. These changes in turn influence the impact dynamics between the rolling elements and the cage, leading to notable variations in the bearing’s vibrational response. The findings may offer valuable insights for the wear resistance and vibration reduction design of CSLBBs. Full article
(This article belongs to the Special Issue Tribological Characteristics of Bearing System, 3rd Edition)
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20 pages, 3903 KiB  
Article
Void Detection of Airport Concrete Pavement Slabs Based on Vibration Response Under Moving Load
by Xiang Wang, Ziliang Ma, Xing Hu, Xinyuan Cao and Qiao Dong
Sensors 2025, 25(15), 4703; https://doi.org/10.3390/s25154703 - 30 Jul 2025
Viewed by 231
Abstract
This study proposes a vibration-based approach for detecting and quantifying sub-slab corner voids in airport cement concrete pavement. Scaled down slab models were constructed and subjected to controlled moving load simulations. Acceleration signals were collected and analyzed to extract time–frequency domain features, including [...] Read more.
This study proposes a vibration-based approach for detecting and quantifying sub-slab corner voids in airport cement concrete pavement. Scaled down slab models were constructed and subjected to controlled moving load simulations. Acceleration signals were collected and analyzed to extract time–frequency domain features, including power spectral density (PSD), skewness, and frequency center. A finite element model incorporating contact and nonlinear constitutive relationships was established to simulate structural response under different void conditions. Based on the simulated dataset, a random forest (RF) model was developed to estimate void size using selected spectral energy indicators and geometric parameters. The results revealed that the RF model achieved strong predictive performance, with a high correlation between key features and void characteristics. This work demonstrates the feasibility of integrating simulation analysis, signal feature extraction, and machine learning to support intelligent diagnostics of concrete pavement health. Full article
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16 pages, 4737 KiB  
Article
An Influence Analysis of the Bearing Waviness on the Vibrations of a Flexible Gear
by Shenlong Li, Yajun Xu, Ruikun Pang and Jing Liu
Machines 2025, 13(8), 661; https://doi.org/10.3390/machines13080661 - 28 Jul 2025
Viewed by 180
Abstract
Roller bearing manufacturing errors have been proven to be critical factors affecting the vibrations of gear systems. Waviness is one main form of manufacturing error affecting the operational performance and life of bearings. However, most previous studies did not completely incorporate the effects [...] Read more.
Roller bearing manufacturing errors have been proven to be critical factors affecting the vibrations of gear systems. Waviness is one main form of manufacturing error affecting the operational performance and life of bearings. However, most previous studies did not completely incorporate the effects of the uneven bearing waviness on the flexible gear system vibrations. To characterize the contribution of the uneven bearing waviness on the vibrations of the gear system, a gear transmission system dynamics model considering shaft flexibility was established. The evenness sinusoidal waviness model (SWM) and uneven sinusoidal waviness model considering the time-varying contact (SWMS) were compared. The influences of the time-varying gear meshing stiffness excitations and flexibilities of shafts on the vibrations of the gear system were considered. A dynamic model was established, and the vibrations of the flexible gear system with the SWM and SWMS were compared. The vibrations induced by different amplitudes and orders of bearing waviness were analyzed. Note that the waviness of the bearing has a great influence on the system vibrations. The vibrations of the flexible gear system intensified with the increase in the bearing waviness order and amplitude. The vibrations from the gear system with the SWMS were bigger than those of the SWM. This paper introduces an alternative dynamic modeling model enabling the vibration analysis of the flexible gear system with evenness and uneven bearing waviness. Full article
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22 pages, 7542 KiB  
Article
Flow-Induced Vibration Stability in Pilot-Operated Control Valves with Nonlinear Fluid–Structure Interaction Analysis
by Lingxia Yang, Shuxun Li and Jianjun Hou
Actuators 2025, 14(8), 372; https://doi.org/10.3390/act14080372 - 25 Jul 2025
Viewed by 155
Abstract
Control valves in nuclear systems operate under high-pressure differentials generating intense transient fluid forces that induce destructive structural vibrations, risking resonance and the valve stem fracture. In this study, computational fluid dynamics (CFD) was employed to characterize the internal flow dynamics of the [...] Read more.
Control valves in nuclear systems operate under high-pressure differentials generating intense transient fluid forces that induce destructive structural vibrations, risking resonance and the valve stem fracture. In this study, computational fluid dynamics (CFD) was employed to characterize the internal flow dynamics of the valve, supported by experiment validation of the fluid model. To account for nonlinear structural effects such as contact and damping, a coupled fluid–structure interaction approach incorporating nonlinear perturbation analysis was applied to evaluate the dynamic response of the valve core assembly under fluid excitation. The results indicate that flow separation, re-circulation, and vortex shedding within the throttling region are primary contributors to structural vibrations. A comparative analysis of stability coefficients, modal damping ratios, and logarithmic decrements under different valve openings revealed that the valve core assembly remains relatively stable overall. However, critical stability risks were identified in the lower-order modal frequency range at 50% and 70% openings. Notably, at a 70% opening, the first-order modal frequency of the valve core assembly closely aligns with the frequency of fluid excitation, indicating a potential for critical resonance. This research provides important insights for evaluating and enhancing the vibration stability and operational safety of control valves under complex flow conditions. Full article
(This article belongs to the Section Control Systems)
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19 pages, 13331 KiB  
Article
Multi-Scale Study on Ultrasonic Cutting of Nomex Honeycomb Composites of Disc Cutters
by Yiying Liang, Feng Feng, Wenjun Cao, Ge Song, Xinman Yuan, Jie Xu, Qizhong Yue, Si Pan, Enlai Jiang, Yuan Ma and Pingfa Feng
Materials 2025, 18(15), 3476; https://doi.org/10.3390/ma18153476 - 24 Jul 2025
Viewed by 203
Abstract
To address the issues of burr formation, structural deformation, and tearing in the conventional machining of Nomex honeycomb composites, this study aims to clarify the mechanisms by which ultrasonic vibration-assisted cutting enhances machining quality. A multi-scale analysis framework is developed to examine the [...] Read more.
To address the issues of burr formation, structural deformation, and tearing in the conventional machining of Nomex honeycomb composites, this study aims to clarify the mechanisms by which ultrasonic vibration-assisted cutting enhances machining quality. A multi-scale analysis framework is developed to examine the effects of ultrasonic vibration on fiber distribution, cell-level shear response, and the overall cutting mechanics. At the microscale, analyses show that ultrasonic vibration mitigates stress concentrations, thereby shortening fiber length. At the mesoscale, elastic buckling and plastic yielding models show that ultrasonic vibration lowers shear strength and modifies the deformation. A macro-scale comparison of cutting behavior with and without ultrasonic vibration was conducted. The results indicate that the intermittent contact effect induced by vibration significantly reduces cutting force. Specifically, at an amplitude of 40 μm, the cutting force decreased by approximately 29.7% compared to the condition without ultrasonic vibration, with an average prediction error below 8.6%. Compared to conventional machining, which causes the honeycomb angle to deform to approximately 130°, ultrasonic vibration preserves the original 120° geometry and reduces burr length by 36%. These results demonstrate that ultrasonic vibration effectively reduces damage through multi-scale interactions, offering theoretical guidance for high-precision machining of fiber-reinforced composites. Full article
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32 pages, 6134 KiB  
Article
Nonlinear Dynamic Modeling and Analysis of Drill Strings Under Stick–Slip Vibrations in Rotary Drilling Systems
by Mohamed Zinelabidine Doghmane
Energies 2025, 18(14), 3860; https://doi.org/10.3390/en18143860 - 20 Jul 2025
Viewed by 317
Abstract
This paper presents a comprehensive study of torsional stick–slip vibrations in rotary drilling systems through a comparison between two lumped parameter models with differing complexity: a simple two-degree-of-freedom (2-DOF) model and a complex high-degree-of-freedom (high-DOF) model. The two models are developed under identical [...] Read more.
This paper presents a comprehensive study of torsional stick–slip vibrations in rotary drilling systems through a comparison between two lumped parameter models with differing complexity: a simple two-degree-of-freedom (2-DOF) model and a complex high-degree-of-freedom (high-DOF) model. The two models are developed under identical boundary conditions and consider an identical nonlinear friction torque dynamic involving the Stribeck effect and dry friction phenomena. The high-DOF model is calculated with the Finite Element Method (FEM) to enable accurate simulation of the dynamic behavior of the drill string and accurate representation of wave propagation, energy build-up, and torque response. Field data obtained from an Algerian oil well with Measurement While Drilling (MWD) equipment are used to guide modeling and determine simulations. According to the findings, the FEM-based high-DOF model demonstrates better performance in simulating basic stick–slip dynamics, such as drill bit velocity oscillation, nonlinear friction torque formation, and transient bit-to-surface contacts. On the other hand, the 2-DOF model is not able to represent these effects accurately and can lead to inappropriate control actions and mitigation of vibration severity. This study highlights the importance of robust model fidelity in building reliable real-time rotary drilling control systems. From the performance difference measurement between low-resolution and high-resolution models, the findings offer valuable insights to optimize drilling efficiency further, minimize non-productive time (NPT), and improve the rate of penetration (ROP). This contribution points to the need for using high-fidelity models, such as FEM-based models, in facilitating smart and adaptive well control strategies in modern petroleum drilling engineering. Full article
(This article belongs to the Section H: Geo-Energy)
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17 pages, 9414 KiB  
Article
Influence of High-Speed Flow on Aerodynamic Lift of Pantograph at 400 km/h
by Zhao Xu, Hongwei Zhang, Wen Wang and Guobin Lin
Infrastructures 2025, 10(7), 188; https://doi.org/10.3390/infrastructures10070188 - 17 Jul 2025
Viewed by 275
Abstract
This study examines pantograph aerodynamic lift at 400 km/h, and uncovers the dynamic behaviors and mechanisms that influence pantograph–catenary performance. Using computational fluid dynamics (CFD) with a compressible fluid model and an SST k-ω turbulence model, aerodynamic characteristics were analyzed. Simulation data at [...] Read more.
This study examines pantograph aerodynamic lift at 400 km/h, and uncovers the dynamic behaviors and mechanisms that influence pantograph–catenary performance. Using computational fluid dynamics (CFD) with a compressible fluid model and an SST k-ω turbulence model, aerodynamic characteristics were analyzed. Simulation data at 300, 350, and 400 km/h showed lift fluctuation amplitude increases with speed, peaking near 50 N at 400 km/h. Power spectral density (PSD) energy, dominated by low frequencies, peaked around 10 dB/Hz in the low-frequency band, highlighting exacerbated lift instability. Component analysis revealed the smallest lift-to-drag ratio and most significant fluctuations at the head, primarily due to boundary-layer separation and vortex shedding from its non-streamlined design. Turbulence energy analysis identified the head and base as main turbulence sources; however, base vibrations are absorbed by the vehicle body, while the head causes pantograph–catenary vibrations due to direct contact. These findings confirm that aerodynamic instability at the head is the main cause of contact force fluctuations. Optimizing head design is necessary to suppress fluctuations, ensuring safe operation at 400 km/h and above. Results provide a theoretical foundation for aerodynamic optimization and improved dynamic performance of high-speed pantographs. Full article
(This article belongs to the Special Issue The Resilience of Railway Networks: Enhancing Safety and Robustness)
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18 pages, 2268 KiB  
Article
Effects of a Novel Mechanical Vibration Technology on the Internal Stress Distribution and Macrostructure of Continuously Cast Billets
by Shuai Liu, Jianliang Zhang, Hui Zhang and Minglin Wang
Metals 2025, 15(7), 794; https://doi.org/10.3390/met15070794 - 14 Jul 2025
Viewed by 257
Abstract
In this paper, a new mechanical vibration technology applied to continuous casting production is studied, which is used to break the dendrite at the solidification front, expand the equiaxed dendrite zone, and improve the center quality of the billet. The exciting force of [...] Read more.
In this paper, a new mechanical vibration technology applied to continuous casting production is studied, which is used to break the dendrite at the solidification front, expand the equiaxed dendrite zone, and improve the center quality of the billet. The exciting force of this vibration technology is provided by a new type of vibration equipment (Vibration roll) independently developed and designed. Firstly, an investigation is conducted into the impacts of vibration acceleration, vibration frequency, and the contact area between the Vibration roll (VR) and the billet surface on the internal stress distribution within the billet shell, respectively. Secondly, the billet with and without vibration treatment was sampled and analyzed through industrial tests. The results show that the area ratio of equiaxed dendrites in transverse specimens treated with vibration technology was 11.96%, compared to 6.55% in untreated specimens. Similarly, for longitudinal samples, the linear ratio of equiaxed dendrites was observed to be 34.56% in treated samples and 22.95% in untreated samples. Compared to the specimens without mechanical vibration, the billet treated with mechanical vibration exhibits an increase in the area ratio and linear ratio of equiaxed dendrite ratio by 5.41% and 11.61%, respectively. Moreover, the probability of bridging at the end of solidification of the billet treated by vibration technology was significantly reduced, and the central porosity and shrinkage cavities of the billet were significantly improved. This study provides the first definitive evidence that the novel mechanical vibration technology can enhance the quality of the billet during the continuous casting process. Full article
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23 pages, 3008 KiB  
Article
Quantitative Analysis of Sulfur Elements in Mars-like Rocks Based on Multimodal Data
by Yuhang Dong, Zhengfeng Shi, Junsheng Yao, Li Zhang, Yongkang Chen and Junyan Jia
Sensors 2025, 25(14), 4388; https://doi.org/10.3390/s25144388 - 14 Jul 2025
Viewed by 364
Abstract
The Zhurong rover of the Tianwen-1 mission has detected sulfates in its landing area. The analysis of these sulfates provides scientific evidence for exploring past hydration conditions and atmospheric evolution on Mars. As a non-contact technique with long-range detection capability, Laser-Induced Breakdown Spectroscopy [...] Read more.
The Zhurong rover of the Tianwen-1 mission has detected sulfates in its landing area. The analysis of these sulfates provides scientific evidence for exploring past hydration conditions and atmospheric evolution on Mars. As a non-contact technique with long-range detection capability, Laser-Induced Breakdown Spectroscopy (LIBS) is widely used for elemental identification on Mars. However, quantitative analysis of anionic elements using LIBS remains challenging due to the weak characteristic spectral lines of evaporite salt elements, such as sulfur, in LIBS spectra, which provide limited quantitative information. This study proposes a quantitative analysis method for sulfur in sulfate-containing Martian analogs by leveraging spectral line correlations, full-spectrum information, and prior knowledge, aiming to address the challenges of sulfur identification and quantification in Martian exploration. To enhance the accuracy of sulfur quantification, two analytical models for high and low sulfur concentrations were developed. Samples were classified using infrared spectroscopy based on sulfur content levels. Subsequently, multimodal deep learning models were developed for quantitative analysis by integrating LIBS and infrared spectra, based on varying concentrations. Compared to traditional unimodal models, the multimodal method simultaneously utilizes elemental chemical information from LIBS spectra and molecular structural and vibrational characteristics from infrared spectroscopy. Considering that sulfur exhibits distinct absorption bands in infrared spectra but demonstrates weak characteristic lines in LIBS spectra due to its low ionization energy, the combination of both spectral techniques enables the model to capture complementary sample features, thereby effectively improving prediction accuracy and robustness. To validate the advantages of the multimodal approach, comparative analyses were conducted against unimodal methods. Furthermore, to optimize model performance, different feature selection algorithms were evaluated. Ultimately, an XGBoost-based feature selection method incorporating prior knowledge was employed to identify optimal LIBS spectral features, and the selected feature subsets were utilized in multimodal modeling to enhance stability. Experimental results demonstrate that, compared to the BPNN, SVR, and Inception unimodal methods, the proposed multimodal approach achieves at least a 92.36% reduction in RMSE and a 46.3% improvement in R2. Full article
(This article belongs to the Section Sensing and Imaging)
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16 pages, 3138 KiB  
Article
Analysis of Vibration Characteristics of Angular Contact Ball Bearings in Aviation Engines Under Changing Conditions
by Yanfang Dong, Zibo Yan, Jianyong Sun, Wei Yu, Hai Zhang, Wenbo Zhou and Jihao Jin
Aerospace 2025, 12(7), 623; https://doi.org/10.3390/aerospace12070623 - 11 Jul 2025
Viewed by 308
Abstract
This paper addresses the vibration characteristics of angular contact ball bearings in aircraft engines under variable load conditions. Based on multibody dynamics theory, a dynamic model of the bearing was established. Vibration data under actual operating conditions were obtained using an experimental test [...] Read more.
This paper addresses the vibration characteristics of angular contact ball bearings in aircraft engines under variable load conditions. Based on multibody dynamics theory, a dynamic model of the bearing was established. Vibration data under actual operating conditions were obtained using an experimental test platform. This study systematically investigated the influence of rotational speed, axial load, and radial load on the vibration acceleration level of the bearing outer ring. Through a comparison of simulation and experimental data (with an error rate below 10%), the reliability of the model was validated. The results indicate that the bearing vibration acceleration level exhibits a nonlinear increasing relationship with rotational speed. An increase in radial load significantly amplifies the amplitude of acceleration-level fluctuations, while appropriately increasing axial load can reduce bearing vibration intensity. Under variable load coupling conditions, the dynamic interaction between axial and radial forces results in complex nonlinear vibration responses, with a 2 s acceleration time achieving the optimal balance between vibration suppression and efficiency (steady-state average of 70.4 dB). Additionally, the morphological characteristics of the cage center-of-gravity trajectory (such as trajectory disorder and poor smoothness) are closely related to vibration characteristics, revealing the critical role of dynamic load changes in bearing stability. The research results provide a theoretical basis for optimizing the operating conditions, vibration control, and reliability design of aircraft engine bearings. Full article
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25 pages, 2616 KiB  
Article
Bio-Fabricated Aluminum Oxide Nanoparticles Derived from Waste Pharmaceutical Packages: Insight into Characterization and Applications
by Jamilah M. Al-Ahmari, Reem M. Alghanmi and Ragaa A. Hamouda
Biomolecules 2025, 15(7), 984; https://doi.org/10.3390/biom15070984 - 10 Jul 2025
Viewed by 363
Abstract
This study examines the environmental challenges posed by azo-dye pollutants and aluminum industrial waste. Aluminum oxide nanoparticles (P/Al2O3-NPs) were produced using a green method that utilized pharmaceutical packaging waste as an aluminum source and marine algae extract (Padina pavonica [...] Read more.
This study examines the environmental challenges posed by azo-dye pollutants and aluminum industrial waste. Aluminum oxide nanoparticles (P/Al2O3-NPs) were produced using a green method that utilized pharmaceutical packaging waste as an aluminum source and marine algae extract (Padina pavonica) as reducing and stabilizing agents and that was characterized by XRD, EDX, SEM, TEM, and zeta potential. Batch biosorption studies were performed to assess the effectiveness of P/Al2O3-NPs in removing CR dye from aqueous solutions. The results demonstrate that the particle sizes range from 58.63 to 86.70 nm and morphologies vary from spherical to elliptical. FTIR analysis revealed Al–O lattice vibrations at 988 and 570 cm−1. The nanoparticles displayed a negative surface charge (−13 mV) and a pHzpc of 4.8. Adsorption experiments optimized parameters for CR dye removal, achieving 97.81% efficiency under native pH (6.95), with a dye concentration of 30 mg/L, an adsorbent dosage of 0.1 g/L, and a contact time of 30 min. Thermodynamic studies confirmed that the process is exothermic and spontaneous. Kinetic data fit well with the pseudo-second-order model, while equilibrium data aligned with the Langmuir isotherm. The adsorption mechanism involved van der Waals forces, hydrogen bonding, and π–π interactions, as supported by the influence of pH, isotherm data, and FTIR spectra. Overall, the study demonstrates the potential of eco-friendly P/Al2O3-NPs to efficiently remove CR dye from aqueous solutions. Full article
(This article belongs to the Section Bio-Engineered Materials)
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17 pages, 3483 KiB  
Article
A Novel Triboelectric–Electromagnetic Hybrid Generator with a Multi-Layered Structure for Wind Energy Harvesting and Wind Vector Monitoring
by Jiaqing Niu, Ribin Hu, Ming Li, Luying Zhang, Bei Xu, Yaqi Zhang, Yi Luo, Jiang Ding and Qingshan Duan
Micromachines 2025, 16(7), 795; https://doi.org/10.3390/mi16070795 - 8 Jul 2025
Viewed by 636
Abstract
High-efficiency wind energy collection and precise wind vector monitoring are crucial for sustainable energy applications, smart agriculture, and environmental management. A novel multi-layered triboelectric–electromagnetic hybrid generator (TEHG) for broadband wind energy collection and wind vector monitoring was built. The TEHG comprises three functional [...] Read more.
High-efficiency wind energy collection and precise wind vector monitoring are crucial for sustainable energy applications, smart agriculture, and environmental management. A novel multi-layered triboelectric–electromagnetic hybrid generator (TEHG) for broadband wind energy collection and wind vector monitoring was built. The TEHG comprises three functional layers corresponding to three modules: a soft-contact rotary triboelectric nanogenerator (S-TEHG), an electromagnetic generator (EMG), and eight flow-induced vibration triboelectric nanogenerators (F-TENGs), which are arranged in a circular array to enable low-wind-speed energy harvesting and multi-directional wind vector monitoring. The TEHG achieves broadband energy harvesting and demonstrates exceptional stability, maintaining a consistent electrical output after 3 h of continuous operation. The EMG charges a 1 mF capacitor to 1.5 V 738 times faster than conventional methods by a boost converter. The TEHG operates for 17.5 s to power a thermohygrometer for 103 s, achieving an average output power of 1.87 W with a power density of 11.2 W/m3, demonstrating an exceptional power supply capability. The F-TENGs can accurately determine the wind direction, with a wind speed detection error below 4.5%. This innovative structure leverages the strengths of both EMG and TENG technologies, offering a durable, multifunctional solution for sustainable energy and intelligent environmental sensing. Full article
(This article belongs to the Special Issue Self-Tuning and Self-Powered Energy Harvesting Devices)
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12 pages, 3405 KiB  
Article
An Experimental Investigation on the Flow Boiling Heat Transfer Performance of Nanofluid in 3D Printing Minichannel Heat Sinks: A Comparative Study
by Jianyang Zhou and Zhixin Yin
Nanomaterials 2025, 15(14), 1054; https://doi.org/10.3390/nano15141054 - 8 Jul 2025
Viewed by 351
Abstract
A minichannel heat sink combining flow boiling heat transfer with nanofluid is an ideal solution for the long-term cooling of high-power equipment. In the present paper, three mass fractions for 0.01 wt%, 0.05 wt%, and 0.1 wt% graphene/R141b and Al2O3 [...] Read more.
A minichannel heat sink combining flow boiling heat transfer with nanofluid is an ideal solution for the long-term cooling of high-power equipment. In the present paper, three mass fractions for 0.01 wt%, 0.05 wt%, and 0.1 wt% graphene/R141b and Al2O3/R141b nanofluids are prepared by ultrasonic vibration. The flow boiling heat transfer performance for graphene/R141b and Al2O3/R141b nanofluids was contrastively investigated in a 3D printing 10-minichannel heat sink with a single channel dimension of 198 mm × 1.5 mm × 1.5 mm. The results indicate that the heat transfer performance of graphene/R141b and Al2O3/R141b nanofluids are enhanced after adding nanoparticles in pure R141b, and the maximum average heat transfer coefficients of graphene/R141b and Al2O3/R141b nanofluids, respectively, increase by 35.4% and 31.7% compared with that of pure R141b. The heat transfer performance of graphene/R141b and Al2O3/R141b nanofluids increases nonlinearly with the increase in mass concentration; the heat transfer coefficient reaches its maximum at the mass concentration of 0.02 wt%, and then, it decreases slightly, which is mainly caused by nanoparticle deposition, leading to silted channel surface cavities during the flow boiling experiment. Moreover, it has been discovered that the heat transfer coefficient of graphene/R141b is larger than that of Al2O3/R141b under the same conditions. The average heat transfer coefficient of graphene/R141b increased by 19.7% compared with that of Al2O3/R141b. The main reason for this is that graphene nanosheets have a larger contact area with the liquid working medium compared with nanoparticle Al2O3, and the graphene/R141b thermal conductivity is also significantly higher than that of Al2O3/R141b nanofluids. The research results can provide a basis for the practical application of nanofluids in heat sinks. Full article
(This article belongs to the Section Theory and Simulation of Nanostructures)
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30 pages, 5942 KiB  
Article
Exploring the Potential of a New Nickel(II):Phenanthroline Complex with L-isoleucine as an Antitumor Agent: Design, Crystal Structure, Spectroscopic Characterization, and Theoretical Insights
by Jayson C. dos Santos, João G. de Oliveira Neto, Ana B. N. Moreira, Luzeli M. da Silva, Alejandro P. Ayala, Mateus R. Lage, Rossano Lang, Francisco F. de Sousa, Fernando Mendes and Adenilson O. dos Santos
Molecules 2025, 30(13), 2873; https://doi.org/10.3390/molecules30132873 - 6 Jul 2025
Viewed by 414
Abstract
This study presents the synthesis, physicochemical characterization, and biological evaluation of a novel ternary nickel(II) complex with isoleucine and 1,10-phenanthroline ligands, [Ni(Phen)(Ile)2]∙6H2O, designed as a potential antitumor agent. Single-crystal X-ray diffraction revealed a monoclinic structure (C2-space group) with an [...] Read more.
This study presents the synthesis, physicochemical characterization, and biological evaluation of a novel ternary nickel(II) complex with isoleucine and 1,10-phenanthroline ligands, [Ni(Phen)(Ile)2]∙6H2O, designed as a potential antitumor agent. Single-crystal X-ray diffraction revealed a monoclinic structure (C2-space group) with an octahedral Ni(II) coordination involving Phen and Ile ligands. A Hirshfeld surface analysis highlighted intermolecular interactions stabilizing the crystal lattice, with hydrogen bonds (H···H and O···H/H···O) dominating (99.1% of contacts). Density functional theory (DFT) calculations, including solvation effects (in water and methanol), demonstrated strong agreement with the experimental geometric parameters and revealed higher affinity to the water solvent. The electronic properties of the complex, such as HOMO−LUMO gaps (3.20–4.26 eV) and electrophilicity (4.54–5.88 eV), indicated a charge-transfer potential suitable for biological applications through interactions with biomolecules. Raman and infrared spectroscopic studies showed vibrational modes associated with Ni–N/O bonds and ligand-specific deformations, with solvation-induced shifts observed. A study using ultraviolet–visible–near-infrared absorption spectroscopy demonstrated that the complex remains stable in solution. In vitro cytotoxicity assays against MCF-7 (breast adenocarcinoma) and HCT-116 (colorectal carcinoma) cells showed dose-dependent activity, achieving 47.6% and 65.3% viability reduction at 100 μM (48 h), respectively, with lower toxicity to non-tumor lung fibroblasts (GM07492A, 39.8%). Supporting the experimental data, we performed computational modeling to examine the pharmacokinetic profile, with particular focus on the absorption, distribution, metabolism, and excretion properties and drug-likeness potential. Full article
(This article belongs to the Special Issue Synthesis and Biological Evaluation of Coordination Compounds)
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30 pages, 4492 KiB  
Article
Hard Preloaded Duplex Ball Bearing Dynamic Model for Space Applications
by Pablo Riera, Luis Maria Macareno, Igor Fernandez de Bustos and Josu Aguirrebeitia
Machines 2025, 13(7), 581; https://doi.org/10.3390/machines13070581 - 4 Jul 2025
Viewed by 334
Abstract
Duplex ball bearings are common components in space satellite mechanisms, and their behaviour impacts the overall performance and reliability of these systems. During rocket launches, these bearings suffer high vibrational loads, making their dynamic response essential for their survival. To predict the dynamic [...] Read more.
Duplex ball bearings are common components in space satellite mechanisms, and their behaviour impacts the overall performance and reliability of these systems. During rocket launches, these bearings suffer high vibrational loads, making their dynamic response essential for their survival. To predict the dynamic behaviour under vibration, simulations and experimental tests are performed. However, published models for space applications fail to capture the variations observed in test responses. This study presents a multi-degree-of-freedom nonlinear multibody model of a hard-preloaded duplex space ball bearing, particularized for this work to the case in which the outer ring is attached to a shaker and the inner ring to a test dummy mass. The model incorporates the Hunt and Crossley contact damping formulation and employs quaternions to accurately represent rotational dynamics. The simulated model response is validated against previously published axial test data, and its response under step, sine, and random excitations is analysed both in the case of radial and axial excitation. The results reveal key insights into frequency evolution, stress distribution, gapping phenomena, and response amplification, providing a deeper understanding of the dynamic performance of space-grade ball bearings. Full article
(This article belongs to the Section Machine Design and Theory)
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