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37 pages, 17890 KB  
Article
Tectonic Control on Ultra-Deep Sub-Salt Trap Architecture: Insights from Multi-Detachment Modeling and Physical Simulations in the Kuqa Foreland Thrust Belt
by Yongxu Mei, Jinning Zhang, Yuan Neng, Wenjie Wang, Ke Xu, Honghan Xiang, Yanna Wu and Peiye Liu
Geosciences 2026, 16(5), 197; https://doi.org/10.3390/geosciences16050197 - 13 May 2026
Viewed by 221
Abstract
Salt-bearing foreland fold–thrust belts represent a critical tectonic system for ultra-deep hydrocarbon exploration. In the Kalasu structural belt of the Kuqa Depression—characterized by the “four extremes” of ultra-high temperature, pressure, salinity, and stress—conventional single-detachment models fail to adequately resolve the complex subsalt structures. [...] Read more.
Salt-bearing foreland fold–thrust belts represent a critical tectonic system for ultra-deep hydrocarbon exploration. In the Kalasu structural belt of the Kuqa Depression—characterized by the “four extremes” of ultra-high temperature, pressure, salinity, and stress—conventional single-detachment models fail to adequately resolve the complex subsalt structures. To address this challenge, this study integrates high-resolution 3D seismic data, field outcrop observations, well logs, balanced cross-sections, and particle image velocimetry (PIV)-monitored physical modeling to propose a ramp–flat multi-detachment model. Our results demonstrate that deformation is governed by four regional detachment horizons: gypsum-salt layers, thick mudstones, coal-bearing strata, and the basement, which vertically partition the basin into six tectonic units: supra-salt, salt, subsalt, supra-coal, coal, and sub-coal basement. The structural architecture is controlled by five key factors: (1) paleo-uplift geometry, (2) distance from the South Tianshan orogenic front, (3) orientation of basin-bounding faults, (4) regional stress regime (pure compression versus transpression), and (5) rheological contrasts among detachment layers. The kinematic evolution follows a progressive sequence: basement-involved thrusting → multi-level ramp–flat detachment folding → cover detachment. Three primary trap levels are identified—subsalt, supra-coal, and sub-coal—hosting six distinct trap styles: pop-up anticlines, imbricate faulted anticlines, structural triangle zones, fault-bend fold anticlines, supra-coal anticlines, and inter-coal/sub-coal anticlines. Notably, under transpressional stress, oblique paleo-uplifts control the formation of enigmatic “fish-scale” arcuate trap belts composed of fault-bend fold anticlines. Full article
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20 pages, 397 KB  
Review
Non-Contact Measurement of Human Vital Signs in Dynamic Conditions Using Microwave Techniques: A Review
by Marek Ostrysz, Zenon Szczepaniak and Tadeusz Sondej
Sensors 2026, 26(2), 359; https://doi.org/10.3390/s26020359 - 6 Jan 2026
Cited by 2 | Viewed by 1668
Abstract
This article reviews recent advances in microwave and radar techniques for non-contact measurement of human vital signs in dynamic conditions. The focus is on solutions that work when the subject is moving or performing everyday activities, rather than lying motionless in clinical settings. [...] Read more.
This article reviews recent advances in microwave and radar techniques for non-contact measurement of human vital signs in dynamic conditions. The focus is on solutions that work when the subject is moving or performing everyday activities, rather than lying motionless in clinical settings. This review covers innovative biodegradable and flexible antenna designs for wearable devices operating in multiple frequency bands and supporting efficient 5G/IoT connectivity. Particular attention is paid to ultra-wideband (UWB) radar, Doppler sensors, and microwave reflectometry combined with advanced signal-processing and deep learning algorithms for robust estimation of respiration, heart rate, and other cardiopulmonary parameters in the presence of body motion. Applications in telemedicine, home monitoring, sports, and search and rescue are discussed, including localization of people trapped under rubble by detecting their vital sign signatures at a distance. This paper also highlights key challenges such as inter-subject anatomical variability, motion artifacts, hardware miniaturization, and energy efficiency, which still limit widespread deployment. Finally, related developments in microwave imaging and early detection of pathological tissue changes are briefly outlined, highlighting the shared components and processing methods. In general, microwave techniques show strong potential for unobtrusive, continuous, and environmentally sustainable monitoring of human physiological activity, supporting future healthcare and safety systems. Full article
(This article belongs to the Special Issue Feature Review Papers in Intelligent Sensors)
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16 pages, 7120 KB  
Article
Ultra-Long, Minor-Diameter, Untethered Growing Continuum Robot via Tip Actuation and Steering
by Pan Zhou, Zhaoyi Lin, Lang Zhou, Haili Li, Michael Basin and Jiantao Yao
Machines 2025, 13(9), 851; https://doi.org/10.3390/machines13090851 - 15 Sep 2025
Viewed by 1354
Abstract
Continuum robots with outstanding compliance, dexterity, and lean bodies are successfully applied in medicine, aerospace engineering, the nuclear industry, rescue operations, construction, service, and manipulation. However, the inherent low stiffness characteristics of continuum bodies make it challenging to develop ultra-long and small-diameter continuum [...] Read more.
Continuum robots with outstanding compliance, dexterity, and lean bodies are successfully applied in medicine, aerospace engineering, the nuclear industry, rescue operations, construction, service, and manipulation. However, the inherent low stiffness characteristics of continuum bodies make it challenging to develop ultra-long and small-diameter continuum robots. To address this size–scale challenge of continuum robots, we developed an 8 m long continuum robot with a diameter of 23 mm by a tip actuation and growth mechanism. Meanwhile, we also realized the untethered design of the continuum robot, which greatly increased its usable space range, portability, and mobility. Demonstration experiments prove that the developed growing continuum robot has good flexibility and manipulability, as well as the ability to cross obstacles and search for targets. Its continuum body can transport liquids over long distances, providing water, medicine, and other rescue items for trapped individuals. The functionality of an untethered growing continuum robot (UGCR) can be expanded by installing multiple tools, such as a grasping tool at its tip to pick up objects in deep wells, pits, and other scenarios. In addition, we established a static model to predict the deformation of UGCR, and the prediction error of its tip position was within 2.6% of its length. We verified the motion performance of the continuum robot through a series of tests involving workspace, disturbance resistance, collision with obstacles, and load performance, thus proving its good anti-interference ability and collision stability. The main contribution of this work is to provide a technical reference for the development of ultra-long continuum robots based on the tip actuation and steering principle. Full article
(This article belongs to the Special Issue Advances and Challenges in Robotic Manipulation)
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17 pages, 3956 KB  
Article
Synergistic LPCVD and PECVD Growth of β-Ga2O3 Thin Films for High-Sensitivity and Low-Dose Direct X-Ray Detection
by Lan Yang, Dingyuan Niu, Yong Zhang, Xueping Zhao, Xinxin Li, Jun Zhu and Hai Zhang
Nanomaterials 2025, 15(17), 1360; https://doi.org/10.3390/nano15171360 - 3 Sep 2025
Cited by 3 | Viewed by 1584
Abstract
Ultra-wide bandgap β-Ga2O3 is a promising low-cost alternative to conventional direct X-ray detector materials that are limited by fabrication complexity, instability, or slow temporal response. Here, we comparatively investigate β-Ga2O3 thin films grown on c-sapphire by low-pressure [...] Read more.
Ultra-wide bandgap β-Ga2O3 is a promising low-cost alternative to conventional direct X-ray detector materials that are limited by fabrication complexity, instability, or slow temporal response. Here, we comparatively investigate β-Ga2O3 thin films grown on c-sapphire by low-pressure chemical vapor deposition (LPCVD) and plasma-enhanced CVD (PECVD), establishing a quantitative linkage between growth kinetics, microstructure, defect landscape, and X-ray detection figures of merit. The LPCVD-grown film (thickness ≈ 0.289 μm) exhibits layered coalesced grains, a narrower rocking curve (FWHM = 1.840°), and deep-level oxygen-vacancy-assisted high photoconductive gain, yielding a high sensitivity of 1.02 × 105 μC Gyair−1 cm−2 at 20 V and a thickness-normalized sensitivity of 3.539 × 105 μCGyair−1 cm−2 μm−1. In contrast, the PECVD-grown film (≈1.57 μm) shows dense columnar growth, higher O/Ga stoichiometric proximity, and shallow-trap dominance, enabling a lower dark current, superior dose detection limit (30.13 vs. 57.07 nGyair s−1), faster recovery, and monotonic SNR improvement with bias. XPS and dual exponential transient analysis corroborate a deep-trap persistent photoconductivity mechanism in LPCVD versus moderated shallow trapping in PECVD. The resulting high-gain vs. low-noise complementary paradigm clarifies defect–gain trade spaces and provides a route to engineer β-Ga2O3 thin-film X-ray detectors that simultaneously target high sensitivity, low dose limit, and temporal stability through trap and electric field management. Full article
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17 pages, 23135 KB  
Article
The Pore Evolution and Pattern of Sweet-Spot Reservoir Development of the Ultra-Tight Sandstone in the Second Member of the Xujiahe Formation in the Eastern Slope of the Western Sichuan Depression
by Bingjie Cheng, Xin Luo, Zhiqiang Qiu, Cheng Xie, Yuanhua Qing, Zhengxiang Lv, Zheyuan Liao, Yanjun Liu and Feng Li
Minerals 2025, 15(7), 681; https://doi.org/10.3390/min15070681 - 25 Jun 2025
Viewed by 863
Abstract
In order to clarify the pore evolution and coupling characteristics with hydrocarbon charging in the deep-buried ultra-tight sandstone reservoirs of the second member of Xujiahe Formation (hereinafter referred to as the Xu 2 Member) on the eastern slope of the Western Sichuan Depression, [...] Read more.
In order to clarify the pore evolution and coupling characteristics with hydrocarbon charging in the deep-buried ultra-tight sandstone reservoirs of the second member of Xujiahe Formation (hereinafter referred to as the Xu 2 Member) on the eastern slope of the Western Sichuan Depression, this study integrates burial history and thermal history with analytical methods including core observation, cast thin section analysis, scanning electron microscopy, carbon-oxygen isotope analysis, and fluid inclusion homogenization temperature measurements. The Xu 2 Member reservoirs are predominantly composed of lithic sandstones and quartz-rich sandstones, with authigenic quartz and carbonates as the main cementing materials. The reservoir spaces are dominated by intragranular dissolution pores. The timing of reservoir densification varies among different submembers. The upper submember underwent compaction during the Middle-Late Jurassic period due to the high ductility of mudstone clasts and other compaction-resistant components. The middle-lower submembers experienced densification in the Late Jurassic period. Late Cretaceous tectonic uplift induced fracture development, which enhanced dissolution in the middle-lower submembers, increasing reservoir porosity to approximately 5%. Two distinct phases of hydrocarbon charging are identified in the Xu 2 Member. The earlier densification of the upper submember created unfavorable conditions for hydrocarbon accumulation. In contrast, the middle-lower submembers received hydrocarbon charging prior to reservoir densification, providing favorable conditions for natural gas enrichment and reservoir formation. Three sweet-spot reservoir development patterns are recognized: paleo-structural trap + (internal source rock) + source-connected fracture assemblage type, paleo-structural trap + internal source rock + late-stage fracture assemblage type, and paleo-structural trap + (internal source rock) + source-connected fracture + late-stage fracture assemblage type. Full article
(This article belongs to the Special Issue Deep Sandstone Reservoirs Characterization)
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15 pages, 2360 KB  
Article
Realization of the Compact Magneto-Optical Trap Based on Single Laser with Frequency Modulation
by Shuning Bao, Bin Wu, Pengfei Cao, Xiaochun Guo, Yingpeng Zhao, Dianrong Li, Jingyu Niu, Cheng Zhang, Bing Cheng, Kanxing Weng, Xiaolong Wang and Qiang Lin
Photonics 2025, 12(2), 98; https://doi.org/10.3390/photonics12020098 - 23 Jan 2025
Viewed by 3582
Abstract
In cold atom physics, the complexity of traditional magneto-optical trap system limits the use of their associated instruments for field applications in atomic physics, such as gravity mapping, space navigation and deep space exploration. This study introduces a novel compact MOT design that [...] Read more.
In cold atom physics, the complexity of traditional magneto-optical trap system limits the use of their associated instruments for field applications in atomic physics, such as gravity mapping, space navigation and deep space exploration. This study introduces a novel compact MOT design that addresses these issues by simplifying the structure and reducing the size. The height of the unit is 0.7 m, the volume is 6.3×102m3 and the mass is 11.32 kg. The new design utilizes a single laser to generate the two different frequencies needed for laser cooling by internally splitting the beam, shifting the frequency and then combining them, effectively controlling both the cooling and repumping beams. The compact vacuum chamber optical path, in conjunction with the magnetic field, facilitates the capture of 87Rb atoms in an ultra-high vacuum environment. Experimental results demonstrate an atom loading rate of up to 1.79×10787Rb atoms per second, confirming the system’s effectiveness in capturing and cooling 87Rb atoms. This design provides a flexible and portable solution, offering valuable insights for the advancement of compact MOT and its applications in cold atom physics. Full article
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16 pages, 2542 KB  
Article
A Comparative Study of the Chemical Composition and Skincare Activities of Red and Yellow Ginseng Berries
by Yu-Dan Wang, Lu-Sheng Han, Gen-Yue Li, Kai-Li Yang, Yan-Long Shen, Hao Zhang, Jian-Feng Hou and En-Peng Wang
Molecules 2024, 29(20), 4962; https://doi.org/10.3390/molecules29204962 - 20 Oct 2024
Cited by 5 | Viewed by 3932
Abstract
This study was conducted to investigate the differences in chemical composition between red (RGBs) and yellow ginseng berries (YGBs) and their whitening and anti-aging skincare effects. The differences in the chemical composition between RGB and YGB were analyzed by ultra-high-performance liquid chromatography tandem [...] Read more.
This study was conducted to investigate the differences in chemical composition between red (RGBs) and yellow ginseng berries (YGBs) and their whitening and anti-aging skincare effects. The differences in the chemical composition between RGB and YGB were analyzed by ultra-high-performance liquid chromatography tandem quadrupole electrostatic field orbit trap mass spectrometry (UHPLC-Q-Exactive-MS/MS) combined with multivariate statistics. An aging model was established using UVB radiation induction, and the whitening and anti-aging effects of the two ginseng berries were verified in vitro and in vivo using cell biology (HaCaT and B16-F10 cells) and zebrafish model organisms. A total of 31 differential compounds, including saponins, flavonoids, phenolic acids, and other chemical constituents, were identified between the two groups. Superoxide dismutase (SOD) activity was more significantly increased (p < 0.05) and malondialdehyde (MDA) content was more significantly decreased (p < 0.01) in RGB more than YGB induced by UVB ultraviolet radiation. In terms of whitening effects, YGB was more effective in inhibiting the melanin content of B16-F10 cells (p < 0.01). The results of zebrafish experiments were consistent with those of in vitro experiments and cell biology experiments. The DCFH fluorescence staining results revealed that both ginseng berries were able to significantly reduce the level of reactive oxygen species (ROS) in zebrafish (p < 0.01). Comparison of chemical composition and skin care activities based on RGB and YGB can provide a theoretical basis for the deep development and utilization of ginseng berry resources. Full article
(This article belongs to the Special Issue Plant Bioactive Compounds in Pharmaceuticals)
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24 pages, 12207 KB  
Article
Geochemical Characteristics of the Paleozoic Marine Source Rocks and Ultra-Deep Hydrocarbon Accumulation Mode of the Awati Sag
by Zezhang Song, Ziyu Zhang, Xiaoheng Ding, Yuanyin Zhang, Zhongkai Bai, Lihong Liu and Yongjin Gao
Energies 2024, 17(9), 2124; https://doi.org/10.3390/en17092124 - 29 Apr 2024
Cited by 2 | Viewed by 1901
Abstract
The Lower Paleozoic of the Awati Sag and its periphery is a region with relatively low levels of exploration and stands as a frontier for ultra-deep hydrocarbon exploration. Based on outcrop and core samples, this study integrated organic geochemical analysis, total organic carbon [...] Read more.
The Lower Paleozoic of the Awati Sag and its periphery is a region with relatively low levels of exploration and stands as a frontier for ultra-deep hydrocarbon exploration. Based on outcrop and core samples, this study integrated organic geochemical analysis, total organic carbon (TOC) logging interpretation, and one-dimensional and two-dimensional hydrocarbon accumulation simulations, to clarify the primary source rock of the Lower Paleozoic and its characteristics, as well as its hydrocarbon accumulation mode. The findings indicate the following: (1) The Lower Paleozoic features two sets of industrial source rocks. The Yuertusi Formation, with its considerable thickness (approximately 200 m), widespread distribution, and elevated TOC (averaging approximately 5% from experimental data and logging interpretation), stands out as the Lower Paleozoic’s most pivotal source rock. (2) The Yuertusi and Saergan Formations are in a high-to-over-mature stage, with the Yuertusi initiating oil generation in the early Silurian and transitioning to gas by the late Permian. The Saergan began producing oil in the Carboniferous, followed by gas in the late Permian. (3) The potential ultra-deep gas reservoirs in the Awati Sag are mainly distributed in the structural traps closer to the deep faults in five potential target formations. Deep natural gas typically exhibits mixed-source signatures, with the mixing notably pronounced along the Shajingzi Fault Belt due to influential basin-controlling faults. Full article
(This article belongs to the Section H: Geo-Energy)
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15 pages, 7617 KB  
Article
Growth of β-Ga2O3 Single-Crystal Microbelts by the Optical Vapor Supersaturated Precipitation Method
by Yongman Pan, Qiang Wang, Yinzhou Yan, Lixue Yang, Lingyu Wan, Rongcheng Yao and Yijian Jiang
Crystals 2023, 13(5), 801; https://doi.org/10.3390/cryst13050801 - 10 May 2023
Cited by 11 | Viewed by 3516
Abstract
Monoclinic β-Ga2O3 microbelts were successfully fabricated using a one-step optical vapor supersaturated precipitation method, which exhibited advantages including a free-standing substrate, prefect surface, and low cost. The as-grown microbelts possessed a well-defined geometry and perfect crystallinity. The dimensions [...] Read more.
Monoclinic β-Ga2O3 microbelts were successfully fabricated using a one-step optical vapor supersaturated precipitation method, which exhibited advantages including a free-standing substrate, prefect surface, and low cost. The as-grown microbelts possessed a well-defined geometry and perfect crystallinity. The dimensions of individual β-Ga2O3 microbelts were a width of ~50 μm, length of ~5 mm, and thickness of ~3 μm. The SEM, XRD, HRTEM, XPS, and Raman spectra demonstrated the high single-crystalline structure of β-Ga2O3 microbelts. Twelve frequency modes were activated in Raman spectra. The optical band gap of the β-Ga2O3 microbelt was calculated to be ~4.45 eV. Upon 266 nm excitation, 2 strong UV emissions occurred in photoluminescence spectra through the radiative recombination of self-trapped excitons, and the blue emission band was attributed to the presence of donor-acceptor-pair transition. The individual β-Ga2O3 microbelt was employed as metal-semiconductor-metal deep-ultraviolet photodetector, which exhibits the photoresponse under 254 nm. This work provides a simple and economical route to fabricate high-quality β-Ga2O3 single-crystal microbelts, which should be a potential synthetic strategy for ultra-wide bandgap semiconductor materials. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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22 pages, 11883 KB  
Article
Effect of Organizational Evolution on the Stress Corrosion Cracking of the Cr-Co-Ni-Mo Series of Ultra-High Strength Stainless Steel
by Shuai Tian, Zhenbao Liu, Renli Fu, Chaofang Dong and Xiaohui Wang
Materials 2022, 15(2), 497; https://doi.org/10.3390/ma15020497 - 10 Jan 2022
Cited by 5 | Viewed by 2870
Abstract
Different microstructures were obtained under various thermal conditions by adjusting the heat treatment parameters of the Cr-Co-Ni-Mo series of ultra-high strength stainless steel. The effect of organizational evolution on the stress corrosion cracking (SCC) of the Cr-Co-Ni-Mo series of ultra-high strength stainless steel [...] Read more.
Different microstructures were obtained under various thermal conditions by adjusting the heat treatment parameters of the Cr-Co-Ni-Mo series of ultra-high strength stainless steel. The effect of organizational evolution on the stress corrosion cracking (SCC) of the Cr-Co-Ni-Mo series of ultra-high strength stainless steel was investigated using potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and other test methods in combination with slow strain rate tensile tests (SSRTs). The results show that the Mo- and Cr-rich clusters and precipitation of the Laves phase reduce the corrosion resistance, while increasing the austenite content can improve the corrosion resistance. The Cr-Co-Ni-Mo series of ultra-high strength stainless steel has a high SCC resistance after quenching at 1080 °C and undergoing deep cooling (DC) treatment at −73 °C. With increasing holding time, the strength of the underaged and peak-aged specimens increases, but the passivation and SCC resistance decreases. At the overaged temperature, the specimen has good SCC resistance after a short holding time, which is attributed to its higher austenite content and lower dislocation density. As a stable hydrogen trap in steel, austenite effectively improves the SCC resistance of steel. However, under the coupled action of hydrogen and stress, martensitic transformation occurs due to the decrease in the lamination energy of austenite, and the weak martensitic interface becomes the preferred location for crack initiation and propagation. Full article
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16 pages, 5888 KB  
Article
Research and Analysis of Pressure-Maintaining Trapping Instrument for Macro-Organisms in Hadal Trenches
by Hao Wang, Jiawang Chen, Yuhong Wang, Jiasong Fang and Yuping Fang
J. Mar. Sci. Eng. 2020, 8(8), 596; https://doi.org/10.3390/jmse8080596 - 10 Aug 2020
Cited by 12 | Viewed by 3338
Abstract
The ecosystem of the abyss is one of the fields that humans hardly know. The ultra-high hydrostatic pressure makes it very difficult to obtain abyssal organisms. Samples are often severely broken during recovery due to changes in environmental pressure, temperature, and other factors. [...] Read more.
The ecosystem of the abyss is one of the fields that humans hardly know. The ultra-high hydrostatic pressure makes it very difficult to obtain abyssal organisms. Samples are often severely broken during recovery due to changes in environmental pressure, temperature, and other factors. Currently, there are no macro-organism samplers suitable for the abyss. The development of a pressure-maintaining sampler for the abyss is a prerequisite for abyssal ecosystem research. This paper mainly proposed a pressure-maintaining trapping instrument (PMTI) designed to work at a depth above 10,000 m. Unlike typical deep-sea equipment, this instrument is lightweight (about 65 kg in water). The instrument adopts a new structure, using a hollow piston as the sampling space and sealing the mechanism with O-rings at both ends of the piston, thus avoiding sealing methods such as ball valves and greatly reducing the weight of the equipment. The structure and working process of the instrument are described in detail in this paper. Meanwhile, in this paper, the movement resistance of the piston (mainly the resistance of the O-ring) is analyzed using a dynamic explicit method in Abaqus. The factors affecting the friction of the O-rings are analyzed via the method of orthogonal tests and ANOVA. In addition, high-pressure tests were conducted on key parts of the instrument, and the results showed that the instrument works well at 100 MPa. Full article
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23 pages, 4055 KB  
Review
Photoluminescence of ZnO Nanowires: A Review
by Andres Galdámez-Martinez, Guillermo Santana, Frank Güell, Paulina R. Martínez-Alanis and Ateet Dutt
Nanomaterials 2020, 10(5), 857; https://doi.org/10.3390/nano10050857 - 29 Apr 2020
Cited by 382 | Viewed by 17264
Abstract
One-dimensional ZnO nanostructures (nanowires/nanorods) are attractive materials for applications such as gas sensors, biosensors, solar cells, and photocatalysts. This is due to the relatively easy production process of these kinds of nanostructures with excellent charge carrier transport properties and high crystalline quality. In [...] Read more.
One-dimensional ZnO nanostructures (nanowires/nanorods) are attractive materials for applications such as gas sensors, biosensors, solar cells, and photocatalysts. This is due to the relatively easy production process of these kinds of nanostructures with excellent charge carrier transport properties and high crystalline quality. In this work, we review the photoluminescence (PL) properties of single and collective ZnO nanowires and nanorods. As different growth techniques were obtained for the presented samples, a brief review of two popular growth methods, vapor-liquid-solid (VLS) and hydrothermal, is shown. Then, a discussion of the emission process and characteristics of the near-band edge excitonic emission (NBE) and deep-level emission (DLE) bands is presented. Their respective contribution to the total emission of the nanostructure is discussed using the spatial information distribution obtained by scanning transmission electron microscopy−cathodoluminescence (STEM-CL) measurements. Also, the influence of surface effects on the photoluminescence of ZnO nanowires, as well as the temperature dependence, is briefly discussed for both ultraviolet and visible emissions. Finally, we present a discussion of the size reduction effects of the two main photoluminescent bands of ZnO. For a wide emission (near ultra-violet and visible), which has sometimes been attributed to different origins, we present a summary of the different native point defects or trap centers in ZnO as a cause for the different deep-level emission bands. Full article
(This article belongs to the Special Issue Growth and Characterization in Nanowires)
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41 pages, 23058 KB  
Article
Gem Corundum Deposits of Greece: Geology, Mineralogy and Genesis
by Panagiotis Voudouris, Constantinos Mavrogonatos, Ian Graham, Gaston Giuliani, Vasilios Melfos, Stefanos Karampelas, Vilelmini Karantoni, Kandy Wang, Alexandre Tarantola, Khin Zaw, Sebastien Meffre, Stephan Klemme, Jasper Berndt, Stefanie Heidrich, Federica Zaccarini, Anthony Fallick, Maria Tsortanidis and Andreas Lampridis
Minerals 2019, 9(1), 49; https://doi.org/10.3390/min9010049 - 15 Jan 2019
Cited by 20 | Viewed by 16822
Abstract
Greece contains several gem corundum deposits set within diverse geological settings, mostly within the Rhodope (Xanthi and Drama areas) and Attico-Cycladic (Naxos and Ikaria islands) tectono-metamorphic units. In the Xanthi area, the sapphire (pink, blue to purple) deposits are stratiform, occurring within marble [...] Read more.
Greece contains several gem corundum deposits set within diverse geological settings, mostly within the Rhodope (Xanthi and Drama areas) and Attico-Cycladic (Naxos and Ikaria islands) tectono-metamorphic units. In the Xanthi area, the sapphire (pink, blue to purple) deposits are stratiform, occurring within marble layers alternating with amphibolites. Deep red rubies in the Paranesti-Drama area are restricted to boudinaged lenses of Al-rich metapyroxenites alternating with amphibolites and gneisses. Both occurrences are oriented parallel to the ultra-high pressure/high pressure (UHP/HP) Nestos suture zone. On central Naxos Island, colored sapphires are associated with desilicated granite pegmatites intruding ultramafic lithologies (plumasites), occurring either within the pegmatites themselves or associated metasomatic reaction zones. In contrast, on southern Naxos and Ikaria Islands, blue sapphires occur in extensional fissures within Mesozoic metabauxites hosted in marbles. Mineral inclusions in corundums are in equilibrium and/or postdate corundum crystallization and comprise: spinel and pargasite (Paranesti), spinel, zircon (Xanthi), margarite, zircon, apatite, diaspore, phlogopite and chlorite (Naxos) and chloritoid, ilmenite, hematite, ulvospinel, rutile and zircon (Ikaria). The main chromophore elements within the Greek corundums show a wide range in concentration: the Fe contents vary from (average values) 1099 ppm in the blue sapphires of Xanthi, 424 ppm in the pink sapphires of Xanthi, 2654 ppm for Paranesti rubies, 4326 ppm for the Ikaria sapphires, 3706 for southern Naxos blue sapphires, 4777 for purple and 3301 for pink sapphire from Naxos plumasite, and finally 4677 to 1532 for blue to colorless sapphires from Naxos plumasites, respectively. The Ti concentrations (average values) are very low in rubies from Paranesti (41 ppm), with values of 2871 ppm and 509 in the blue and pink sapphires of Xanthi, respectively, of 1263 ppm for the Ikaria blue sapphires, and 520 ppm, 181 ppm in Naxos purple, pink sapphires, respectively. The blue to colorless sapphires from Naxos plumasites contain 1944 to 264 ppm Ti, respectively. The very high Ti contents of the Xanthi blue sapphires may reflect submicroscopic rutile inclusions. The Cr (average values) ranges from 4 to 691 ppm in the blue, purple and pink colored corundums from Naxos plumasite, is quite fixed (222 ppm) for Ikaria sapphires, ranges from 90 to 297 ppm in the blue and pink sapphires from Xanthi, reaches 9142 ppm in the corundums of Paranesti, with highest values of 15,347 ppm in deep red colored varieties. Each occurrence has both unique mineral assemblage and trace element chemistry (with variable Fe/Mg, Ga/Mg, Ga/Cr and Fe/Ti ratios). Additionally, oxygen isotope compositions confirm their geological typology, i.e., with, respectively δ18O of 4.9 ± 0.2‰ for sapphire in plumasite, 20.5‰ for sapphire in marble and 1‰ for ruby in mafics. The fluid inclusions study evidenced water free CO2 dominant fluids with traces of CH4 or N2, and low CO2 densities (0.46 and 0.67 g/cm3), which were probably trapped after the metamorphic peak. The Paranesti, Xanthi and central Naxos corundum deposits can be classified as metamorphic sensu stricto (s.s.) and metasomatic, respectively, those from southern Naxos and Ikaria display atypical magmatic signature indicating a hydrothermal origin. Greek corundums are characterized by wide color variation, homogeneity of the color hues, and transparency, and can be considered as potential gemstones. Full article
(This article belongs to the Special Issue Mineralogy and Geochemistry of Gems)
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20 pages, 4021 KB  
Article
Carrier Transport and Molecular Displacement Modulated dc Electrical Breakdown of Polypropylene Nanocomposites
by Daomin Min, Chenyu Yan, Rui Mi, Chao Ma, Yin Huang, Shengtao Li, Qingzhou Wu and Zhaoliang Xing
Polymers 2018, 10(11), 1207; https://doi.org/10.3390/polym10111207 - 30 Oct 2018
Cited by 51 | Viewed by 5042
Abstract
Dielectric energy storage capacitors have advantages such as ultra-high power density, extremely fast charge and discharge speed, long service lifespan and are significant for pulsed power system, smart power grid, and power electronics. Polypropylene (PP) is one of the most widely used dielectric [...] Read more.
Dielectric energy storage capacitors have advantages such as ultra-high power density, extremely fast charge and discharge speed, long service lifespan and are significant for pulsed power system, smart power grid, and power electronics. Polypropylene (PP) is one of the most widely used dielectric materials for dielectric energy storage capacitors. It is of interest to investigate how to improve its electrical breakdown strength by nanodoping and the influencing mechanism of nanodoping on the electrical breakdown properties of polymer nanocomposites. PP/Al2O3 nanocomposite dielectric materials with various weight fraction of nanoparticles are fabricated by melt-blending and hot-pressing methods. Thermally stimulated current, surface potential decay, and dc electrical breakdown experiments show that deep trap properties and associated molecular chain motion are changed by incorporating nanofillers into polymer matrix, resulting in the variations in conductivity and dc electrical breakdown field of nanocomposite dielectrics. Then, a charge transport and molecular displacement modulated electrical breakdown model is utilized to simulate the dc electrical breakdown behavior. It is found that isolated interfacial regions formed in nanocomposite dielectrics at relatively low loadings reduce the effective carrier mobility and strengthen the interaction between molecular chains, hindering the transport of charges and the displacement of molecular chains with occupied deep traps. Accordingly, the electrical breakdown strength is enhanced at relatively low loadings. Interfacial regions may overlap in nanocomposite dielectrics at relatively high loadings so that the effective carrier mobility decreases and the interaction between molecular chains may be weakened. Consequently, the molecular motion is accelerated by electric force, leading to the decrease in electrical breakdown strength. The experiments and simulations reveals that the influence of nanodoping on dc electrical breakdown properties may origin from the changes in the charge transport and molecular displacement characteristics caused by interfacial regions in nanocomposite dielectrics. Full article
(This article belongs to the Special Issue Nanoparticle-Reinforced Polymers)
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Article
A New Occurrence of Terrestrial Native Iron in the Earth’s Surface: The Ilia Thermogenic Travertine Case, Northwestern Euboea, Greece
by Christos Kanellopoulos, Eugenia Valsami-Jones, Panagiotis Voudouris, Christina Stouraiti, Robert Moritz, Constantinos Mavrogonatos and Panagiotis Mitropoulos
Geosciences 2018, 8(8), 287; https://doi.org/10.3390/geosciences8080287 - 31 Jul 2018
Cited by 11 | Viewed by 8022
Abstract
Native iron has been identified in an active thermogenic travertine deposit, located at Ilia area (Euboea Island, Greece). The deposit is forming around a hot spring, which is part of a large active metallogenetic hydrothermal system depositing ore-bearing travertines. The native iron occurs [...] Read more.
Native iron has been identified in an active thermogenic travertine deposit, located at Ilia area (Euboea Island, Greece). The deposit is forming around a hot spring, which is part of a large active metallogenetic hydrothermal system depositing ore-bearing travertines. The native iron occurs in two shapes: nodules with diameter 0.4 and 0.45 cm, and angular grains with length up to tens of μm. The travertine laminae around the spherical/ovoid nodules grow smoothly, and the angular grains are trapped inside the pores of the travertine. Their mineral-chemistry is ultra-pure, containing, other than Fe, only Mn (0.34–0.38 wt.%) and Ni (≤0.05 wt.%). After evaluating all the possible environments where native iron has been reported up until today and taking under consideration all the available data concerning the study area, we propose two possible scenarios: (i) Ilia’s native iron has a magmatic/hydrothermal origin i.e., it is a deep product near the magmatic chamber or a peripheral cooling igneous body that was transferred during the early stages of the geothermal field evolution, from high temperature, reduced gas-rich fluids and deposited along with other metals in permeable structural zones, at shallow levels. Later on, it was remobilized and mechanically transferred and precipitated at the Ilia’s thermogenic travertine by the active lower temperatures geothermal fluids; (ii) the native iron at Ilia is remobilized from deep seated ophiolitic rocks, originated initially from reduced fluids during serpentinization processes; however, its mechanical transport seems less probable. The native iron mineral-chemistry, morphology and the presence of the other mineral phases in the same thermogenic travertine support both hypotheses. Full article
(This article belongs to the Special Issue Magmatic-Hydrothermal Ore Deposits)
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