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23 Results Found

  • Article
  • Open Access
21 Citations
2,640 Views
21 Pages

2 August 2022

Most of the research has evidenced that there is a strong natural correlation among the chemical properties of molecular structures. This study analyses supramolecular chemistry and investigates topological indices of supramolecular structures called...

  • Article
  • Open Access
11 Citations
2,500 Views
16 Pages

3 March 2023

Triazine-based covalent organic frameworks (TriCFs) were synthesized using melamine, and cyanuric acid is a brand-new synthetic lubricant, which is thermo-stable and possesses a lamellar structure. This article demonstrates how topological descriptor...

  • Article
  • Open Access
7 Citations
3,362 Views
17 Pages

Nitrogen-Rich Triazine-Based Covalent Organic Frameworks as Efficient Visible Light Photocatalysts for Hydrogen Peroxide Production

  • Shu Yang,
  • Keke Zhi,
  • Zhimin Zhang,
  • Rukiya Kerem,
  • Qiong Hong,
  • Lei Zhao,
  • Wenbo Wu,
  • Lulu Wang and
  • Duozhi Wang

Covalent organic frameworks (COFs) have been widely used in photocatalytic hydrogen peroxide (H2O2) production due to their favorable band structure and excellent light absorption. Due to the rapid recombination rate of charge carriers, however, thei...

  • Article
  • Open Access
29 Citations
5,696 Views
11 Pages

2 June 2018

In an effort to explore the use of organic high-performance lithium ion battery cathodes as an alternative to resolve the current bottleneck hampering the development of their inorganic counterparts, a rational strategy focusing on the optimal compos...

  • Article
  • Open Access
21 Citations
4,681 Views
16 Pages

28 March 2023

Herein, we report the efficient preparation of π-electron-extended triazine-based covalent organic framework (TFP-TPTPh COF) for photocatalysis and adsorption of the rhodamine B (RhB) dye molecule, as well as for photocatalytic hydrogen generation...

  • Article
  • Open Access
21 Citations
5,744 Views
18 Pages

Synthesis and Characterization of a Crystalline Imine-Based Covalent Organic Framework with Triazine Node and Biphenyl Linker and Its Fluorinated Derivate for CO2/CH4 Separation

  • Stefanie Bügel,
  • Malte Hähnel,
  • Tom Kunde,
  • Nader de Sousa Amadeu,
  • Yangyang Sun,
  • Alex Spieß,
  • Thi Hai Yen Beglau,
  • Bernd M. Schmidt and
  • Christoph Janiak

11 April 2022

A catalyst-free Schiff base reaction was applied to synthesize two imine-linked covalent organic frameworks (COFs). The condensation reaction of 1,3,5-tris-(4-aminophenyl)triazine (TAPT) with 4,4′-biphenyldicarboxaldehyde led to the structure o...

  • Article
  • Open Access
1,679 Views
11 Pages

High-Pressure Gas Adsorption on Covalent Organic Framework CTF-1

  • Gregory S. Deyko,
  • Valery N. Zakharov,
  • Lev M. Glukhov,
  • Dmitry O. Charkin,
  • Dmitry Yu. Kultin,
  • Vladimir V. Chernyshev,
  • Leonid A. Aslanov and
  • Leonid M. Kustov

10 December 2024

Triazine-based covalent organic framework CTF-1 was synthesized via polymerization of 1,4-dicyanobenzene in the presence of zinc chloride. Two different methods of the post-synthesis treatment of the obtained material were compared. It was demonstrat...

  • Article
  • Open Access
12 Citations
3,549 Views
12 Pages

27 September 2021

As a class of redox active materials with some preferable properties, including rigid structure, insoluble characters, and large amounts of nitrogen atoms, covalent triazine frameworks (CTFs) have been frequently adopted as electrode materials in Lit...

  • Article
  • Open Access
12 Citations
3,040 Views
18 Pages

Prominent COF, g-C3N4, and Their Heterojunction Materials for Selective Photocatalytic CO2 Reduction

  • Panagiota Bika,
  • Ilias Papailias,
  • Tatiana Giannakopoulou,
  • Christos Tampaxis,
  • Theodore A. Steriotis,
  • Christos Trapalis and
  • Panagiotis Dallas

29 September 2023

New heterojunction materials (HJs) were synthesized in-situ by molecularly bonding the monomers of a triazine-based covalent organic framework (bulk COF) on the template of exfoliated carbon nitride (g-C3N4). The photocatalysts reduced carbon dioxide...

  • Article
  • Open Access
11 Citations
4,129 Views
15 Pages

Elucidating the Aromatic Properties of Covalent Organic Frameworks Surface for Enhanced Polar Solvent Adsorption

  • Mostafa Yousefzadeh Borzehandani,
  • Emilia Abdulmalek,
  • Mohd Basyaruddin Abdul Rahman and
  • Muhammad Alif Mohammad Latif

3 June 2021

Covalent organic frameworks (COFs) have a distinguished surface as they are mostly made by boron, carbon, nitrogen and oxygen. Many applications of COFs rely on polarity, size, charge, stability and hydrophobicity/hydrophilicity of their surface. In...

  • Article
  • Open Access
4 Citations
1,971 Views
14 Pages

Advanced Stimuli-Responsive Structure Based on 4D Aerogel and Covalent Organic Frameworks Composite for Rapid Reduction in Tetracycline Pollution

  • Wenxin Wang,
  • Wenjing Wang,
  • Ying Liang,
  • Liwen Du,
  • Huan Yang,
  • Haoxiang Ma,
  • Huiting Cheng,
  • Yaqian Yan,
  • Yijun Shen and
  • Qi Chen

19 July 2023

Intelligentization of materials and structures is an important trend. Herein, the stimuli-responsive 4D aerogel is used as a smart substrate for rapid reduction in tetracycline (TC) pollution, in which this smart stimuli-responsive substrate is desig...

  • Article
  • Open Access
935 Views
11 Pages

4 September 2025

Photocatalytic overall water splitting (PWS) offers a green, economical, and sustainable pathway for hydrogen production. However, the efficiency is still hindered by severe charge recombination in catalysts, high energy barriers for water oxidation,...

  • Review
  • Open Access
9 Citations
4,239 Views
22 Pages

Triazine 2D Nanosheets as a New Class of Nanomaterials: Crystallinity, Properties and Applications

  • Valery N. Zakharov,
  • Igor K. Kudryavtsev,
  • Sergey F. Dunaev,
  • Kseniya A. Paseshnichenko and
  • Leonid A. Aslanov

Based on the recent (2015–2021) literature data, the authors analyze the mutual dependence of crystallinity/amorphism and specific surface area and porosity in covalent triazine frameworks (CTFs), taking into account thermodynamic and kinetic c...

  • Feature Paper
  • Review
  • Open Access
4 Citations
1,993 Views
22 Pages

The Construction and Photocatalytic Application of Covalent Triazine Framework (CTF)-Based Composites: A Brief Review

  • Yuchen Wei,
  • Quanmei Zhou,
  • Xinglin Wang,
  • Yifan Liao,
  • Jiayi Meng,
  • Yamei Huang,
  • Linlin Gao and
  • Weilin Dai

5 June 2025

Covalent triazine frameworks (CTFs) are a class of porous organic semiconductors containing a large number of triazine units, which gives them many properties suitable for photocatalysis, such as high porosity, good tunability, and excellent chemical...

  • Feature Paper
  • Review
  • Open Access
24 Citations
5,891 Views
17 Pages

Light-Driven Hydrogen Evolution Assisted by Covalent Organic Frameworks

  • Nuria Romero,
  • Roger Bofill,
  • Laia Francàs,
  • Jordi García-Antón and
  • Xavier Sala

21 June 2021

Covalent organic frameworks (COFs) are crystalline porous organic polymers built from covalent organic blocks that can be photochemically active when incorporating organic semiconducting units, such as triazine rings or diacetylene bridges. The bandg...

  • Article
  • Open Access
1,569 Views
9 Pages

Thiophosphate-Based Covalent Organic Framework (COF) or Porous Organic Polymer (POP)?

  • Christophe Menendez,
  • Yannick Coppel,
  • Baptiste Martin and
  • Anne-Marie Caminade

There are few examples of covalent organic frameworks (COFs) based on phosphorus as the building element, probably because the structure of most phosphorus derivatives is pyramidal, which may prevent the stacking expected for classical 2-dimensional...

  • Article
  • Open Access
63 Citations
5,413 Views
14 Pages

Ultrastable Covalent Triazine Organic Framework Based on Anthracene Moiety as Platform for High-Performance Carbon Dioxide Adsorption and Supercapacitors

  • Mohamed Gamal Mohamed,
  • Santosh U. Sharma,
  • Ni-Yun Liu,
  • Tharwat Hassan Mansoure,
  • Maha Mohamed Samy,
  • Swetha V. Chaganti,
  • Yu-Lung Chang,
  • Jyh-Tsung Lee and
  • Shiao-Wei Kuo

Conductive and porous nitrogen-rich materials have great potential as supercapacitor electrode materials. The exceptional efficiency of such compounds, however, is dependent on their larger surface area and the level of nitrogen doping. To address th...

  • Article
  • Open Access
3 Citations
1,757 Views
16 Pages

16 January 2025

A covalent organic framework (COF) has emerged as a promising photocatalyst for the removal of pharmaceutical and personal care product (PPCP) contaminants; however, high-performance COF photocatalysts are still scarce. In this study, three COF photo...

  • Article
  • Open Access
887 Views
12 Pages

15 October 2025

In this study, hydrophilic covalent organic framework (COF) nanosheets with triazine structures and hydrophobic COF nanosheets with fluorinated imine skeletons were designed to enhance the membrane separation process for ethanol pervaporation. The ma...

  • Review
  • Open Access
6 Citations
3,724 Views
34 Pages

Metal–Organic Frameworks as Fillers in Porous Organic Polymer-Based Hybrid Materials: Innovations in Composition, Processing, and Applications

  • Victor Durán-Egido,
  • Daniel García-Giménez,
  • Juan Carlos Martínez-López,
  • Laura Pérez-Vidal and
  • Javier Carretero-González

15 July 2025

Hybrid materials based on porous organic polymers (POPs) and metal–organic frameworks (MOFs) are increasing attention for advanced separation processes due to the possibility to combine their properties. POPs provide high surface areas, chemica...

  • Article
  • Open Access
33 Citations
3,838 Views
13 Pages

Hydroxyl-Functionalized Covalent Organic Frameworks as High-Performance Supercapacitors

  • Tzu-Ling Yang,
  • Jhu-You Chen,
  • Shiao-Wei Kuo,
  • Chen-Tsyr Lo and
  • Ahmed F. M. El-Mahdy

22 August 2022

Covalent organic frameworks (COFs) have attracted significant interest because of their heteroatom-containing architectures, high porous networks, large surface areas, and capacity to include redox-active units, which can provide good electrochemical...

  • Article
  • Open Access
2 Citations
884 Views
18 Pages

29 April 2025

Covalent organic frameworks hold great promise for heterogeneous catalysis because of their porous structure for gas adsorption and tunable functionality. Two triazine support materials (MAmPA-COF and MAoPA-COF) were prepared by using melamine as the...

  • Feature Paper
  • Article
  • Open Access
985 Views
15 Pages

Constructing Hydrazone-Linked Chiral Covalent Organic Frameworks with Different Pore Sizes for Asymmetric Catalysis

  • Haichen Huang,
  • Kai Zhang,
  • Yuexin Zheng,
  • Hong Chen,
  • Dexuan Cai,
  • Shengrun Zheng,
  • Jun Fan and
  • Songliang Cai

30 June 2025

Chiral covalent organic frameworks (COFs) hold great promise in heterogeneous asymmetric catalysis due to their designable structures and well-defined chiral microenvironments. However, precise control over the pore size of chiral COFs to optimize as...