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18 pages, 993 KiB  
Article
Development and Validation of a Custom-Built System for Real-Time Monitoring of In Vitro Rumen Gas Fermentation
by Zhen-Shu Liu, Bo-Yuan Chen, Jacky Peng-Wen Chan and Po-Wen Chen
Animals 2025, 15(15), 2308; https://doi.org/10.3390/ani15152308 - 6 Aug 2025
Abstract
While the Ankom RF system facilitates efficient high-throughput in vitro fermentation studies, its high cost and limited flexibility constrain its broader applicability. To address these limitations, we developed and validated a low-cost, modular gas monitoring system (FerME), assembled from commercially available components. To [...] Read more.
While the Ankom RF system facilitates efficient high-throughput in vitro fermentation studies, its high cost and limited flexibility constrain its broader applicability. To address these limitations, we developed and validated a low-cost, modular gas monitoring system (FerME), assembled from commercially available components. To evaluate its performance and reproducibility relative to the Ankom RF system (Ankom Technology, Macedon, NY, USA), in vitro rumen fermentation experiments were conducted under strictly controlled and identical conditions. Whole rumen contents were collected approximately 2 h post-feeding from individual mid- or late-lactation dairy cows and immediately transported to the laboratory. Each fermenter received 50 mL of processed rumen fluid, 100 mL of anaerobically prepared artificial saliva buffer, and 1.2 g of the donor cow’s diet. Bottles were sealed with the respective system’s pressure sensors, flushed with CO2, and incubated in a 50 L water bath maintained at 39 °C. FerME (New Taipei City, Taiwan) and Ankom RF fermenters were placed side-by-side to ensure uniform thermal conditions. To assess the effect of filter bag use, an additional trial employed Ankom F57 filter bags (Ankom Technology, Macedon, NY, USA; 25 μm pore size). Trial 1 revealed no significant differences in cumulative gas production, volatile fatty acids (VFAs), NH3-N, or pH between systems (p > 0.05). However, the use of filter bags reduced gas output and increased propionate concentrations (p < 0.05). Trial 2, which employed filter bags in both systems, confirmed comparable results, with the FerME system demonstrating improved precision (CV: 4.8% vs. 13.2%). Gas composition (CH4 + CO2: 76–82%) and fermentation parameters remained consistent across systems (p > 0.05). Importantly, with 12 pressure sensors, the total cost of FerME was about half that of the Ankom RF system. Collectively, these findings demonstrate that FerME is a reliable, low-cost alternative for real-time rumen fermentation monitoring and could be suitable for studies in animal nutrition, methane mitigation, and related applications. Full article
(This article belongs to the Section Animal System and Management)
20 pages, 5638 KiB  
Article
Influence of Heat Treatment on Precipitate and Microstructure of 38CrMoAl Steel
by Guofang Xu, Shiheng Liang, Bo Chen, Jiangtao Chen, Yabing Zhang, Xiaotan Zuo, Zihan Li, Bo Song and Wei Liu
Materials 2025, 18(15), 3703; https://doi.org/10.3390/ma18153703 - 6 Aug 2025
Abstract
To address the central cracking problem in continuous casting slabs of 38CrMoAl steel, high-temperature tensile tests were performed using a Gleeble-3800 thermal simulator to characterize the hot ductility of the steel within the temperature range of 600–1200 °C. The phase transformation behavior was [...] Read more.
To address the central cracking problem in continuous casting slabs of 38CrMoAl steel, high-temperature tensile tests were performed using a Gleeble-3800 thermal simulator to characterize the hot ductility of the steel within the temperature range of 600–1200 °C. The phase transformation behavior was computationally analyzed via the Thermo-Calc software, while the microstructure, fracture morphology, and precipitate characteristics were systematically investigated using a metallographic microscope (MM), a field-emission scanning electron microscope (FE-SEM), and transmission electron microscopy (TEM). Additionally, the effects of different holding times and cooling rates on the microstructure and precipitates of 38CrMoAl steel were also studied. The results show that the third brittle temperature region of 38CrMoAl steel is 645–1009 °C, and the fracture mechanisms can be classified into three types: (I) in the α single-phase region, the thickness of intergranular proeutectoid ferrite increases with rising temperature, leading to reduced hot ductility; (II) in the γ single-phase region, the average size of precipitates increases while the number density decreases with increasing temperature, thereby improving hot ductility; and (III) in the α + γ two-phase region, the precipitation of proeutectoid ferrite promotes crack propagation and the dense distribution of precipitates at grain boundaries causes stress concentration, further deteriorating hot ductility. Heat treatment experiments indicate that the microstructures of the specimen transformed under water cooling, air cooling, and furnace cooling conditions as follows: martensite + proeutectoid ferrite → bainite + ferrite → ferrite. The average size of precipitates first decreased, then increased, and finally decreased again with increasing holding time, while the number density exhibited the opposite trend. Therefore, when the holding time was the same, reducing the cooling rate could increase the average size of the precipitates and decrease their number density, thereby improving the hot ductility of 38CrMoAl steel. Full article
(This article belongs to the Special Issue Microstructure Engineering of Metals and Alloys, 3rd Edition)
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25 pages, 2458 KiB  
Article
Numerical Analysis of Heat Transfer in a Double-Pipe Heat Exchanger for an LPG Fuel Supply System
by Seongwoo Lee, Younghun Kim, Ancheol Choi and Sungwoong Choi
Energies 2025, 18(15), 4179; https://doi.org/10.3390/en18154179 - 6 Aug 2025
Abstract
LPG fuel supply systems are increasingly important for improving energy efficiency and reducing carbon emissions in the shipping industry. The primary objective of this research is to investigate the heat transfer phenomena to enhance the thermal performance of double-pipe heat exchangers (DPHEs) in [...] Read more.
LPG fuel supply systems are increasingly important for improving energy efficiency and reducing carbon emissions in the shipping industry. The primary objective of this research is to investigate the heat transfer phenomena to enhance the thermal performance of double-pipe heat exchangers (DPHEs) in LPG fuel supply systems. This study investigates the heat transfer performance of a glycol–steam double-pipe heat exchanger (DPHE) within an LPG fuel supply system under varying operating conditions. A computational model and methodology were developed and validated by comparing the numerical results with experimental data obtained from commissioning tests. Additionally, the effects of turbulence models and parametric variations were evaluated by analyzing the glycol–water mixing ratio and flow direction—both of which are critical operational parameters for DPHE systems. Numerical validation against the commissioning data showed a deviation of ±2% under parallel-flow conditions, confirming the reliability of the proposed model. With respect to the glycol–water mixing ratio and flow configuration, thermal conductance (UA) decreased by approximately 11% in parallel flow and 13% in counter flow for every 20% increase in glycol concentration. Furthermore, parallel flow exhibited approximately 0.6% higher outlet temperatures than counter flow, indicating superior heat transfer efficiency under parallel-flow conditions. Finally, the heat transfer behavior of the DPHE was further examined by considering the effects of geometric characteristics, pipe material, and fluid properties. This study offers significant contributions to the engineering design of double-pipe heat exchanger systems for LPG fuel supply applications. Full article
(This article belongs to the Collection Advances in Heat Transfer Enhancement)
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17 pages, 2538 KiB  
Article
Influence of Abrasive Flow Rate and Feed Rate on Jet Lag During Abrasive Water Jet Cutting of Beech Plywood
by Monika Sarvašová Kvietková, Ondrej Dvořák, Chia-Feng Lin, Dennis Jones, Petr Ptáček and Roman Fojtík
Appl. Sci. 2025, 15(15), 8687; https://doi.org/10.3390/app15158687 (registering DOI) - 6 Aug 2025
Abstract
Cutting beech plywood using abrasive water jet (AWJ) technology represents a significant area of research due to increasing demands for precision, quality, and environmental sustainability in manufacturing processes within the woodworking industry. AWJ technology enables non-contact cutting of materials without causing thermal deformation [...] Read more.
Cutting beech plywood using abrasive water jet (AWJ) technology represents a significant area of research due to increasing demands for precision, quality, and environmental sustainability in manufacturing processes within the woodworking industry. AWJ technology enables non-contact cutting of materials without causing thermal deformation or mechanical damage, which is crucial for preserving the structural integrity and mechanical properties of the plywood. This article investigates cutting beech plywood using technical methods using an abrasive water jet (AWJ) at 400 MPa pressure, with Australian garnet (80 MESH) as the abrasive material. It examines how abrasive mass flow rate, traverse speed, and material thickness affect AWJ lag, which in turn influences both cutting quality and accuracy. Measurements were conducted with power abrasive mass flow rates of 250, 350, and 450 g/min and traverse speeds of 0.2, 0.4, and 0.6 m/min. Results show that increasing the abrasive mass flow rate from 250 g/min to 350 g/min slightly decreased the AWJ cut width by 0.05 mm, while further increasing to 450 g/min caused a slight increase of 0.1 mm. Changes in traverse speed significantly influenced cut width; increasing the traverse speed from 0.2 m/min to 0.4 m/min widened the AWJ by 0.21 mm, while increasing it to 0.6 m/min caused a slight increase of 0.18 mm. For practical applications, it is recommended to use an abrasive mass flow rate of around 350 g/min combined with a traverse speed between 0.2 and 0.4 m/min when cutting beech plywood with AWJ. This balance minimizes jet lag and maintains high surface quality comparable to conventional milling. For thicker plywood, reducing the traverse speed closer to 0.2 m/min and slightly increasing the abrasive flow should ensure clean cuts without compromising surface integrity. Full article
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38 pages, 2180 KiB  
Review
Ternary Choline Chloride-Based Deep Eutectic Solvents: A Review
by Abdulalim Ibrahim, Marc Mulamba Tshibangu, Christophe Coquelet and Fabienne Espitalier
ChemEngineering 2025, 9(4), 84; https://doi.org/10.3390/chemengineering9040084 (registering DOI) - 6 Aug 2025
Abstract
Ternary choline chloride-based deep eutectic solvents (TDESs) exhibit unique physicochemical properties, including lower viscosities, lower melting points, higher thermal stabilities, and enhanced solvations compared to binary deep eutectic solvents (BDESs). Although BDESs have been widely studied, the addition of a third component in [...] Read more.
Ternary choline chloride-based deep eutectic solvents (TDESs) exhibit unique physicochemical properties, including lower viscosities, lower melting points, higher thermal stabilities, and enhanced solvations compared to binary deep eutectic solvents (BDESs). Although BDESs have been widely studied, the addition of a third component in TDESs offers opportunities to further optimize their performance. This review aims to evaluate the physicochemical properties of TDESs and highlight their potential applications in sustainable industrial processes compared to BDESs. A comprehensive analysis of the existing literature was conducted, focusing on TDES properties, such as phase behavior, density, viscosity, pH, conductivity, and the effect of water, along with their applications in various fields. TDESs demonstrated superior physicochemical characteristics compared to BDESs, including improved solvation and thermal stability. Their applications in biomass conversion, CO2 capture, heavy oil upgrading, refrigeration gases, and as solvents/catalysts in organic reactions show significant promise for enhancing process efficiency and sustainability. Despite their advantages, TDESs face challenges including limited predictive models, potential instability under certain conditions, and scalability hurdles. Overall, TDESs offer significant potential for advancing sustainable and efficient chemical processes for industrial applications. Full article
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19 pages, 1493 KiB  
Article
Development of Biodegradable Foam Trays from Brewer’s Malt Bagasse and Potato Residues from Agricultural Crops
by Evelyn F. Vásquez-Bacilio, Cesar I. Mejia-Llontop, Carlos E. Tirado-Rodríguez, María de Fátima Arévalo-Oliva, Beetthssy Z. Hurtado-Soria, Eudes Villanueva, Gilbert Rodriguez, Delia Rita Tapia-Blácido and Elza Aguirre
Polymers 2025, 17(15), 2146; https://doi.org/10.3390/polym17152146 - 6 Aug 2025
Abstract
In light of the environmental impact of disposable products made from petroleum-based plastics, this study focused on developing biodegradable foam trays made from a starch (PS) derived from potato waste and beer malt flour (BMBF). The objective of this study was to evaluate [...] Read more.
In light of the environmental impact of disposable products made from petroleum-based plastics, this study focused on developing biodegradable foam trays made from a starch (PS) derived from potato waste and beer malt flour (BMBF). The objective of this study was to evaluate the effect of the concentration of BMBF on the physical and mechanical properties of potato starch-based foam trays prepared by the thermoforming process at temperatures of 150 °C (upper plate) and 145 °C (lower plate) for 5 min and 40 s. The results showed that increasing the BMBF concentration from 0 to 40% reduced the moisture content from 4.68% to 3.42%, increased the thickness from 2.63 cm to 4.77 cm, and decreased the density from 0.28 g.cm−3 to 0.15 g.cm−3. Meanwhile, the water absorption capacity increased from 38.7% to 69.7%. In terms of mechanical properties, increasing the BMBF concentration in the PS foam tray resulted in a decrease in hardness from 5.61 N to 2.87 N, a decrease in tensile strength from 2.92 MPa to 0.85 MPa, and a decrease in elongation from 1.42% to 0.59%. Meanwhile, fracturability increased from 2.04 mm to 3.68 mm. FTIR analysis revealed interactions between BMBF and PS in the composite foam tray. Thermogravimetric analysis (TGA) showed two thermal events: one between 20.96 °C and 172.89 °C, and another between 189.14 °C and 517.69 °C, with weight losses of 5.53% and 74.23%, leaving an ash residue of 20.24%. Differential calorimetry analysis (DSC) showed a glass transition at 152.88 °C and a melting at 185.94 °C, with an enthalpy of fusion of 74.11 J.g−1. Higher concentrations of BMBF (>10%) decreased the water resistance, mechanical strength, and flexibility of the PS foam trays. Therefore, a formulation of 90% PS and 10% BMBF was better for producing a foam tray with improved mechanical properties and water resistance, which could be used as a sustainable alternative to conventional single-use plastic. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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19 pages, 1579 KiB  
Article
Plasma-Treated Water Effect on Sporulating Bacillus cereus vs. Non-Sporulating Listeria monocytogenes Biofilm Cell Vitality
by Samantha Nestel, Robert Wagner, Mareike Meister, Thomas Weihe and Uta Schnabel
Appl. Microbiol. 2025, 5(3), 80; https://doi.org/10.3390/applmicrobiol5030080 - 5 Aug 2025
Abstract
Foodborne illness caused by bacterial pathogens is a global health concern and results in millions of infections annually. Therefore, food products typically undergo several processing stages, including sanitation steps, before being distributed in an attempt to remove pathogens. However, many sanitation methods have [...] Read more.
Foodborne illness caused by bacterial pathogens is a global health concern and results in millions of infections annually. Therefore, food products typically undergo several processing stages, including sanitation steps, before being distributed in an attempt to remove pathogens. However, many sanitation methods have compounding effects on the color, texture, flavor, and nutritional quality of the product or do not effectively reduce the pathogens that food can be exposed to. Some bacterial pathogens particularly possess traits and tactics that make them even more difficult to mitigate such as biofilm formation. Non-thermal plasma sanitation techniques, including plasma-treated water (PTW), have proven to be promising methods that significantly reduce pathogenic bacteria that food is exposed to. Published work reveals that PTW can effectively mitigate both gram-positive and gram-negative bacterial biofilms. This study presents a novel analysis of the differences in antimicrobial effects of PTW treatment between biofilm-forming gram-positive bacteria, commonly associated with foodborne illness, that are sporulating (Bacillus cereus) and non-sporulating (Listeria monocytogenes). After treatment with PTW, the results suggest the following hypotheses: (1) that the non-sporulating species experiences less membrane damage but a greater reduction in metabolic activity, leading to a possible viable but non-culturable (VBNC) state, and (2) that the sporulating species undergoes spore formation, which may subsequently convert into vegetative cells over time. PTW treatment on gram-positive bacterial biofilms that persist in food processing environments proves to be effective in reducing the proliferating abilities of the bacteria. However, the variance in PTW’s effects on metabolic activity and cell vitality between sporulating and non-sporulating species suggest that other survival tactics might be induced. This analysis further informs the application of PTW in food processing as an effective sanitation method. Full article
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24 pages, 6492 KiB  
Review
Review on Multifactorial Coupling Effects and the Time-Dependent Behavior of Lateral Pressure on Concrete Formworks
by Kekuo Yuan, Min Zhang, Yichu Lu and Hongdan Yu
Buildings 2025, 15(15), 2764; https://doi.org/10.3390/buildings15152764 - 5 Aug 2025
Abstract
This critical review synthesizes evidence on the multifactorial coupling mechanisms and time-dependent evolution of lateral pressure in concrete formworks, addressing significant limitations in current design standards (GB50666, CIRIA 108, ACI 347). Through a structured analysis of 60+ experimental and theoretical studies, we establish [...] Read more.
This critical review synthesizes evidence on the multifactorial coupling mechanisms and time-dependent evolution of lateral pressure in concrete formworks, addressing significant limitations in current design standards (GB50666, CIRIA 108, ACI 347). Through a structured analysis of 60+ experimental and theoretical studies, we establish that lateral pressure is governed by nonlinear interactions between concrete rheology, casting dynamics, thermal conditions, and formwork geometry. The key findings reveal that (1) casting rate increments >5 m/h amplify peak pressure by 15–27%, while SCC thixotropy (Athix > 0.5) reduces it by 15–27% at <5 m/h; (2) secondary vibration induces 52–61% pressure surges through liquefaction; and (3) sections with a width >2 m exhibit 40% faster pressure decay due to arching effects. (4) Temporal evolution follows three distinct phases—rapid rise (0–2 h), slow decay (2–10 h), and sharp decline (>10 h)—with the temperature critically modulating transition kinetics. Crucially, the existing codes inadequately model temperature dependencies, SCC/HPC rheology, and high-speed casting (>10 m/h). This work proposes a parameter-specific framework integrating rheological thresholds (Athix, Rstr), casting protocols, and real-time monitoring to enhance standard accuracy, enabling an optimized formwork design and risk mitigation in complex scenarios, such as water conveyance construction and slipforming. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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20 pages, 5212 KiB  
Article
Assessing the Land Surface Temperature Trend of Lake Drūkšiai’s Coastline
by Jūratė Sužiedelytė Visockienė, Eglė Tumelienė and Rosita Birvydienė
Land 2025, 14(8), 1598; https://doi.org/10.3390/land14081598 - 5 Aug 2025
Abstract
This study investigates long-term land surface temperature (LST) trends along the shoreline of Lake Drūkšiai, a transboundary lake in eastern Lithuania that formerly served as a cooling reservoir for the Ignalina Nuclear Power Plant (INPP). Although the INPP was decommissioned in 2009, its [...] Read more.
This study investigates long-term land surface temperature (LST) trends along the shoreline of Lake Drūkšiai, a transboundary lake in eastern Lithuania that formerly served as a cooling reservoir for the Ignalina Nuclear Power Plant (INPP). Although the INPP was decommissioned in 2009, its legacy continues to influence the lake’s thermal regime. Using Landsat 8 thermal infrared imagery and NDVI-based methods, we analysed spatial and temporal LST variations from 2013 to 2024. The results indicate persistent temperature anomalies and elevated LST values, particularly in zones previously affected by thermal discharges. The years 2020 and 2024 exhibited the highest average LST values; some years (e.g., 2018) showed lower readings due to localised environmental factors such as river inflow and seasonal variability. Despite a slight stabilisation observed in 2024, temperatures remain higher than those recorded in 2013, suggesting that pre-industrial thermal conditions have not yet been restored. These findings underscore the long-term environmental impacts of industrial activity and highlight the importance of satellite-based monitoring for the sustainable management of land, water resources, and coastal zones. Full article
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17 pages, 2283 KiB  
Article
A Remote Strawberry Health Monitoring System Performed with Multiple Sensors Approach
by Xiao Du, Jun Steed Huang, Qian Shi, Tongge Li, Yanfei Wang, Haodong Liu, Zhaoyuan Zhang, Ni Yu and Ning Yang
Agriculture 2025, 15(15), 1690; https://doi.org/10.3390/agriculture15151690 - 5 Aug 2025
Abstract
Temperature is a key physiological indicator of plant health, influenced by factors including water status, disease and developmental stage. Monitoring changes in multiple factors is helpful for early diagnosis of plant growth. However, there are a variety of complex light interference phenomena in [...] Read more.
Temperature is a key physiological indicator of plant health, influenced by factors including water status, disease and developmental stage. Monitoring changes in multiple factors is helpful for early diagnosis of plant growth. However, there are a variety of complex light interference phenomena in the greenhouse, so traditional detection methods cannot meet effective online monitoring of strawberry health status without manual intervention. Therefore, this paper proposes a leaf soft-sensing method based on a thermal infrared imaging sensor and adaptive image screening Internet of Things system, with additional sensors to realize indirect and rapid monitoring of the health status of a large range of strawberries. Firstly, a fuzzy comprehensive evaluation model is established by analyzing the environmental interference terms from the other sensors. Secondly, through the relationship between plant physiological metabolism and canopy temperature, a growth model is established to predict the growth period of strawberries based on canopy temperature. Finally, by deploying environmental sensors and solar height sensors, the image acquisition node is activated when the environmental interference is less than the specified value and the acquisition is completed. The results showed that the accuracy of this multiple sensors system was 86.9%, which is 30% higher than the traditional model and 4.28% higher than the latest advanced model. It makes it possible to quickly and accurately assess the health status of plants by a single factor without in-person manual intervention, and provides an important indication of the early, undetectable state of strawberry disease, based on remote operation. Full article
(This article belongs to the Section Artificial Intelligence and Digital Agriculture)
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23 pages, 5064 KiB  
Article
Study on Reasonable Well Spacing for Geothermal Development of Sandstone Geothermal Reservoir—A Case Study of Dezhou, Shandong Province, China
by Shuai Liu, Yan Yan, Lanxin Zhang, Weihua Song, Ying Feng, Guanhong Feng and Jingpeng Chen
Energies 2025, 18(15), 4149; https://doi.org/10.3390/en18154149 - 5 Aug 2025
Abstract
Shandong Province is rich in geothermal resources, mainly stored in sandstone reservoirs. The setting of reasonable well spacing in the early stage of large-scale recharge has not attracted enough attention. The problem of small well spacing in geothermal engineering is particularly prominent in [...] Read more.
Shandong Province is rich in geothermal resources, mainly stored in sandstone reservoirs. The setting of reasonable well spacing in the early stage of large-scale recharge has not attracted enough attention. The problem of small well spacing in geothermal engineering is particularly prominent in the sandstone thermal reservoir production area represented by Dezhou. Based on the measured data of temperature, flow, and water level, this paper constructs a typical engineering numerical model by using TOUGH2 software. It is found that when the distance between production and recharge wells is 180 m, the amount of production and recharge is 60 m3/h, and the temperature of reinjection is 30 °C, the temperature of the production well will decrease rapidly after 10 years of production and recharge. In order to solve the problem of thermal breakthrough, three optimization schemes are assumed: reducing the reinjection temperature to reduce the amount of re-injection when the amount of heat is the same, reducing the amount of production and injection when the temperature of production and injection is constant, and stopping production after the temperature of the production well decreases. However, the results show that the three schemes cannot solve the problem of thermal breakthrough or meet production demand. Therefore, it is necessary to set reasonable well spacing. Therefore, based on the strata near the Hydrological Homeland in Decheng District, the reasonable spacing of production and recharge wells is achieved by numerical simulation. Under a volumetric flux scenario ranging from 60 to 80 m3/h, the well spacing should exceed 400 m. For a volumetric flux between 80 and 140 m3/h, it is recommended that the well spacing be greater than 600 m. Full article
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17 pages, 415 KiB  
Review
Advanced Wood Composites with Recyclable or Biodegradable Polymers Embedded—A Review of Current Trends
by Paschalina Terzopoulou, Dimitris S. Achilias and Evangelia C. Vouvoudi
J. Compos. Sci. 2025, 9(8), 415; https://doi.org/10.3390/jcs9080415 - 4 Aug 2025
Abstract
Wood polymer composites (WPCs) represent a rapidly growing class of sustainable materials, formed by combining lignocellulosic fibers with thermoplastic or thermoset polymeric matrices. This review summarizes the state of the art in WPC development, emphasizing the use of recyclable (or recycled) and biodegradable [...] Read more.
Wood polymer composites (WPCs) represent a rapidly growing class of sustainable materials, formed by combining lignocellulosic fibers with thermoplastic or thermoset polymeric matrices. This review summarizes the state of the art in WPC development, emphasizing the use of recyclable (or recycled) and biodegradable polymers as matrix materials. The integration of waste wood particles into the production of WPCs addresses global environmental challenges, including plastic pollution and deforestation, by offering an alternative to conventional wood-based and petroleum-based products. Key topics covered in the review include raw material sources, fiber pre-treatments, compatibilizers, mechanical performance, water absorption behavior, thermal stability and end-use applications. Full article
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17 pages, 2479 KiB  
Article
Spectroscopic, Thermally Induced, and Theoretical Features of Neonicotinoids’ Competition for Adsorption Sites on Y Zeolite
by Bojana Nedić Vasiljević, Maja Milojević-Rakić, Maja Ranković, Anka Jevremović, Ljubiša Ignjatović, Nemanja Gavrilov, Snežana Uskoković-Marković, Aleksandra Janošević Ležaić, Hong Wang and Danica Bajuk-Bogdanović
Molecules 2025, 30(15), 3267; https://doi.org/10.3390/molecules30153267 - 4 Aug 2025
Abstract
The competitive retention of pollutants in water tables determines their environmental fate and guides routes for their removal. To distinguish the fine differences in competitive binding at zeolite adsorption centers, a group of neonicotinoid pesticides is compared, relying on theoretical (energy of adsorption, [...] Read more.
The competitive retention of pollutants in water tables determines their environmental fate and guides routes for their removal. To distinguish the fine differences in competitive binding at zeolite adsorption centers, a group of neonicotinoid pesticides is compared, relying on theoretical (energy of adsorption, orientation, charge distribution) and experimental (spectroscopic and thermogravimetric) analyses for quick, inexpensive, and reliable screening. The MOPAC/QuantumEspresso platform was used for theoretical calculation, indicating close adsorption energy values for acetamiprid and imidacloprid (−2.2 eV), with thiamethoxam having a lower binding energy of −1.7 eV. FTIR analysis confirmed hydrogen bonding, among different dipole-dipole interactions, as the dominant adsorption mechanism. Due to their comparable binding energies, when the mixture of all three pesticides is examined, comparative adsorption capacities are evident at low concentrations, owing to the excellent adsorption performance of the FAU zeotype. At higher concentrations, competition for adsorption centers occurs, with the expected thiamethoxam binding being diminished due to the lower bonding energy. The catalytic impact of zeolite on the thermal degradation of pesticides is evidenced through TG analysis, confirming the adsorption capacities found by UV/VIS and HPLC/UV measurements. Detailed analysis of spectroscopic results in conjunction with theoretical calculation, thermal profiles, and UV detection offers a comprehensive understanding of neonicotinoids’ adsorption and can help with the design of future adsorbents. Full article
(This article belongs to the Special Issue Design, Synthesis, and Application of Zeolite Materials)
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30 pages, 11385 KiB  
Article
Experimental Evaluation of Thermal and Moisture Behavior of Stearic Acid-Coated Expanded Perlite for Sustainable Insulation Mortars
by Betül Tülin Asan, Lütfullah Gündüz and Gülay Yakar
Buildings 2025, 15(15), 2749; https://doi.org/10.3390/buildings15152749 - 4 Aug 2025
Abstract
In this study, the water-repellent performance of Expanded Perlite (EP) coated with stearic acid (SA) at different coating/EP ratios (0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 1%, 2%, 3%, 4% and 5%) and the capillary water absorption and thermal conductivity behaviors of the modified insulation [...] Read more.
In this study, the water-repellent performance of Expanded Perlite (EP) coated with stearic acid (SA) at different coating/EP ratios (0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 1%, 2%, 3%, 4% and 5%) and the capillary water absorption and thermal conductivity behaviors of the modified insulation mortars prepared at these different coating/EP ratios were investigated experimentally. In contrast to the existing literature, experimental studies were carried out for both coated and uncoated EP particles used in mortars to which water-repellent polymers were not added, and the minimum and maximum coating amounts showing the lowest capillary water absorption and slump were determined. In addition, the sustainability of modified insulation mortars consisting of EP-coated SA was determined by sustainable thermal performance (STP). In other words, this study is the first in the literature to determine how the thermal conductivity values of these mortars may change during their use in buildings. According to the experimental results, water absorption, which is an undesirable property, decreased significantly when coated with SA, and even SA-coated expanded coarse perlite (SCP) showed almost no water-absorption behavior at coating levels above 2%. The water-repellent performance of SCP was determined to be 83.2% between 0.1% and 0.4%. In addition, for coarse mortars (MCs), the best water-repellent performance was achieved at a 5% coating/EP ratio, with a 37% reduction in the capillary water-absorption coefficient. In addition, it was found that STP values increased as the coating/EP ratio increased. In other words, modified insulation mortars became more sustainable with an increasing SA coating/EP ratio. The highest STP values were observed in Groups 2 and 4 at a 5% coating/EP ratio, with MC-5 reaching 39.27% in Group 2 and MF-5 reaching 30.30% in Group 4. The results are important from a practical/industrial point of view and from a scientific point of view. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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14 pages, 2310 KiB  
Article
A High-Fidelity Model of the Peach Bottom 2 Turbine-Trip Benchmark Using VERA
by Nicholas Herring, Robert Salko and Mehdi Asgari
J. Nucl. Eng. 2025, 6(3), 28; https://doi.org/10.3390/jne6030028 - 4 Aug 2025
Abstract
This work presents a high-fidelity simulation of the Peach Bottom turbine trip (PBTT) benchmark using the Virtual Environment for Reactor Applications (VERA), a multiphysics reactor modeling tool developed by the U.S. Department of Energy’s Consortium for Advanced Simulation of Light Water Reactors energy [...] Read more.
This work presents a high-fidelity simulation of the Peach Bottom turbine trip (PBTT) benchmark using the Virtual Environment for Reactor Applications (VERA), a multiphysics reactor modeling tool developed by the U.S. Department of Energy’s Consortium for Advanced Simulation of Light Water Reactors energy innovation hub. The PBTT benchmark, based on a 1977 transient event at the end of cycle 2 in a General Electric Type-4 boiling water reactor (BWR), is a critical test case for validating core physics models with thermal feedback during rapid reactivity events. VERA was employed to perform end-to-end, pin-resolved simulations from conditions at the beginning of cycle 1 through the turbine-trip transient, incorporating detailed neutron transport, fuel depletion, and subchannel thermal hydraulics. The simulation reproduced key benchmark observables with high accuracy: the peak power excursion occurred at 0.75 s, matching the scram time and closely aligning with the benchmark average of 0.742 s; the simulated maximum power spike was approximately 7600 MW, which is within 3% of the benchmark average of 7400 MW; and void-collapse dynamics were consistent with benchmark expectations. Reactivity predictions during cycles 1 and 2 remained within 1500 pcm and 400 pcm of criticality, respectively. These results confirm VERA’s ability to model complex coupled neutronic and thermal hydraulic behavior in a BWR turbine-trip transient, which will support its use in future studies of modeling dryout, fuel performance, and uncertainty quantification for transients of this type. Full article
(This article belongs to the Special Issue Validation of Code Packages for Light Water Reactor Physics Analysis)
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