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Keywords = thermal emissive bands

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11 pages, 2887 KiB  
Article
INTEGRAL/ISGRI Post 2024-Periastron View of PSR B1259-63
by Aleksei Kuzin, Denys Malyshev, Maria Chernyakova, Brian van Soelen and Andrea Santangelo
Universe 2025, 11(8), 254; https://doi.org/10.3390/universe11080254 - 31 Jul 2025
Viewed by 118
Abstract
PSR B1259-63/LS 2883 is a well-studied gamma-ray binary hosting a pulsar in a 3.4-year eccentric orbit around a Be-type star. Its non-thermal emission spans from radio to TeV energies, exhibiting a significant increase near the periastron passage. This paper is dedicated to the [...] Read more.
PSR B1259-63/LS 2883 is a well-studied gamma-ray binary hosting a pulsar in a 3.4-year eccentric orbit around a Be-type star. Its non-thermal emission spans from radio to TeV energies, exhibiting a significant increase near the periastron passage. This paper is dedicated to the analysis of INTEGRAL observations of the system following its last periastron passage in June 2024. We aim to study the spectral evolution of this gamma-ray binary in the soft (0.3–10 keV) and hard (30–300 keV) X-ray energy bands. We performed a joint analysis of the data taken by INTEGRAL/ISGRI in July–August 2024 and quasi-simultaneous Swift/XRT observations. The spectrum of the system in the 0.3–300 keV band is well described by an absorbed power law with a photon index of Γ=1.42±0.03. We place constraints on potential spectral curvature, limiting the break energy Eb>30 keV for ΔΓ>0.3 and cutoff energy Ecutoff>150 keV at a 95% confidence level. For one-zone leptonic emission models, these values correspond to electron distribution spectral parameters of Eb,e>0.8 TeV and Ecutoff,e>1.7 TeV, consistent with previous constraints derived by H.E.S.S. Full article
(This article belongs to the Section Compact Objects)
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31 pages, 11019 KiB  
Review
A Review of Tunnel Field-Effect Transistors: Materials, Structures, and Applications
by Shupeng Chen, Yourui An, Shulong Wang and Hongxia Liu
Micromachines 2025, 16(8), 881; https://doi.org/10.3390/mi16080881 - 29 Jul 2025
Viewed by 396
Abstract
The development of an integrated circuit faces the challenge of the physical limit of Moore’s Law. One of the most important “Beyond Moore” challenges is the scaling down of Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs) versus their increasing static power consumption. This is because, at [...] Read more.
The development of an integrated circuit faces the challenge of the physical limit of Moore’s Law. One of the most important “Beyond Moore” challenges is the scaling down of Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs) versus their increasing static power consumption. This is because, at room temperature, the thermal emission transportation mechanism will cause a physical limitation on subthreshold swing (SS), which is fundamentally limited to a minimum value of 60 mV/decade for MOSFETs, and accompanied by an increase in off-state leakage current with the process of scaling down. Moreover, the impacts of short-channel effects on device performance also become an increasingly severe problem with channel length scaling down. Due to the band-to-band tunneling mechanism, Tunnel Field-Effect Transistors (TFETs) can reach a far lower SS than MOSFETs. Recent research works indicated that TFETs are already becoming some of the promising candidates of conventional MOSFETs for ultra-low-power applications. This paper provides a review of some advances in materials and structures along the evolutionary process of TFETs. An in-depth discussion of both experimental works and simulation works is conducted. Furthermore, the performance of TFETs with different structures and materials is explored in detail as well, covering Si, Ge, III-V compounds and 2D materials, alongside different innovative device structures. Additionally, this work provides an outlook on the prospects of TFETs in future ultra-low-power electronics and biosensor applications. Full article
(This article belongs to the Special Issue MEMS/NEMS Devices and Applications, 3rd Edition)
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35 pages, 2895 KiB  
Review
Ventilated Facades for Low-Carbon Buildings: A Review
by Pinar Mert Cuce and Erdem Cuce
Processes 2025, 13(7), 2275; https://doi.org/10.3390/pr13072275 - 17 Jul 2025
Viewed by 643
Abstract
The construction sector presently consumes about 40% of global energy and generates 36% of CO2 emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding [...] Read more.
The construction sector presently consumes about 40% of global energy and generates 36% of CO2 emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding and the insulated structure, address that challenge. First, the paper categorises VFs by structural configuration, ventilation strategy and functional control into four principal families: double-skin, rainscreen, hybrid/adaptive and active–passive systems, with further extensions such as BIPV, PCM and green-wall integrations that couple energy generation or storage with envelope performance. Heat-transfer analysis shows that the cavity interrupts conductive paths, promotes buoyancy- or wind-driven convection, and curtails radiative exchange. Key design parameters, including cavity depth, vent-area ratio, airflow velocity and surface emissivity, govern this balance, while hybrid ventilation offers the most excellent peak-load mitigation with modest energy input. A synthesis of simulation and field studies indicates that properly detailed VFs reduce envelope cooling loads by 20–55% across diverse climates and cut winter heating demand by 10–20% when vents are seasonally managed or coupled with heat-recovery devices. These thermal benefits translate into steadier interior surface temperatures, lower radiant asymmetry and fewer drafts, thereby expanding the hours occupants remain within comfort bands without mechanical conditioning. Climate-responsive guidance emerges in tropical and arid regions, favouring highly ventilated, low-absorptance cladding; temperate and continental zones gain from adaptive vents, movable insulation or PCM layers; multi-skin adaptive facades promise balanced year-round savings by re-configuring in real time. Overall, the review demonstrates that VFs constitute a versatile, passive-plus platform for low-carbon buildings, simultaneously enhancing energy efficiency, durability and indoor comfort. Future advances in smart controls, bio-based materials and integrated energy-recovery systems are poised to unlock further performance gains and accelerate the sector’s transition to net-zero. Emerging multifunctional materials such as phase-change composites, nanostructured coatings, and perovskite-integrated systems also show promise in enhancing facade adaptability and energy responsiveness. Full article
(This article belongs to the Special Issue Sustainable Development of Energy and Environment in Buildings)
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27 pages, 7955 KiB  
Article
Land Surface Condition-Driven Emissivity Variation and Its Impact on Diurnal Land Surface Temperature Retrieval Uncertainty
by Lijuan Wang, Ping Yue, Yang Yang, Sha Sha, Die Hu, Xueyuan Ren, Xiaoping Wang, Hui Han and Xiaoyu Jiang
Remote Sens. 2025, 17(14), 2353; https://doi.org/10.3390/rs17142353 - 9 Jul 2025
Viewed by 223
Abstract
Land surface emissivity (LSE) is the most critical factor affecting land surface temperature (LST) retrieval. Understanding its variation characteristics is essential, as this knowledge provides fundamental prior constraints for the LST retrieval process. This study utilizes thermal infrared emissivity and hyperspectral data collected [...] Read more.
Land surface emissivity (LSE) is the most critical factor affecting land surface temperature (LST) retrieval. Understanding its variation characteristics is essential, as this knowledge provides fundamental prior constraints for the LST retrieval process. This study utilizes thermal infrared emissivity and hyperspectral data collected from diverse underlying surfaces from 2017 to 2024 to analyze LSE variation characteristics across different surface types, spectral bands, and temporal scales. Key influencing factors are quantified to establish empirical relationships between LSE dynamics and environmental variables. Furthermore, the impact of LSE models on diurnal LST retrieval accuracy is systematically evaluated through comparative experiments, emphasizing the necessity of integrating time-dependent LSE corrections into radiative transfer equations. The results indicate that LSE in the 8–11 µm band is highly sensitive to surface composition, with distinct dual-valley absorption features observed between 8 and 9.5 µm across different soil types, highlighting spectral variability. The 9.6 µm LSE exhibits strong sensitivity to crop growth dynamics, characterized by pronounced absorption valleys linked to vegetation biochemical properties. Beyond soil composition, LSE is significantly influenced by soil moisture, temperature, and vegetation coverage, emphasizing the need for multi-factor parameterization. LSE demonstrates typical diurnal variations, with an amplitude reaching an order of magnitude of 0.01, driven by thermal inertia and environmental interactions. A diurnal LSE retrieval model, integrating time-averaged LSE and diurnal perturbations, was developed based on underlying surface characteristics. This model reduced the root mean square error (RMSE) of LST retrieved from geostationary satellites from 6.02 °C to 2.97 °C, significantly enhancing retrieval accuracy. These findings deepen the understanding of LSE characteristics and provide a scientific basis for refining LST/LSE separation algorithms in thermal infrared remote sensing and for optimizing LSE parameterization schemes in land surface process models for climate and hydrological simulations. Full article
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15 pages, 1991 KiB  
Article
ALMA Observations of G333.6-0.2: Molecular and Ionized Gas Environment
by Aruzhan Omar, Aidana Abdirakhman, Nazgul Alimgazinova, Meiramgul Kyzgarina, Aisha Naurzbayeva, Zhomartkali Islyam, Kunduz Turekhanova, Aizat Demessinova and Arailym Manapbayeva
Galaxies 2025, 13(4), 73; https://doi.org/10.3390/galaxies13040073 - 27 Jun 2025
Viewed by 510
Abstract
We present high-angular resolution observations, conducted with the Atacama Large Millimeter/Submillimeter Array (ALMA) in Band 6, of high-excitation molecular lines of CH3CN, CH3OH, and the H29α radio recombination line, towards the G333.6-0.2 ultracompact (UC) H ii region. [...] Read more.
We present high-angular resolution observations, conducted with the Atacama Large Millimeter/Submillimeter Array (ALMA) in Band 6, of high-excitation molecular lines of CH3CN, CH3OH, and the H29α radio recombination line, towards the G333.6-0.2 ultracompact (UC) H ii region. Our observations reveal three hot molecular cores: A, B, and C, where emission is detected in ten components of the J=1413 rotational ladder of CH3CN and in the CH3OH J=51,441,3 transition. Rotational diagram analysis of CH3CN reveals excitation temperatures ranging from 380 to 430 K. First-order moment maps of CH3CN and CH3OH reveal distinct velocity gradients in all cores, suggesting rotating structures, with core A also showing evidence of expansion motions. The H29α recombination line shows a linewidth of 30.2±0.12 km s−1, dominated by dynamical and thermal broadening, indicative of large-scale motions in ionized gas. Analysis of the ionized gas properties yields an electron density of (4.8±0.4)×105 cm−3, an emission measure of (1.23±0.06)×109 pc cm−6, and a Lyman continuum photon flux consistent with an O5–O6 V (Zero-Age Main Sequence; ZAMS) star. Our results suggest that G333.6-0.2 is in an intermediate evolutionary stage between hypercompact (HC) and ultracompact (UC) H ii regions, hosting active high-mass star formation with rotating hot cores and ionized gas dynamics. Full article
(This article belongs to the Special Issue Circumstellar Matter in Hot Star Systems)
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30 pages, 10022 KiB  
Article
A Camera Calibration Method for Temperature Measurements of Incandescent Objects Based on Quantum Efficiency Estimation
by Vittorio Sala, Ambra Vandone, Michele Banfi, Federico Mazzucato, Stefano Baraldo and Anna Valente
Sensors 2025, 25(10), 3094; https://doi.org/10.3390/s25103094 - 14 May 2025
Viewed by 626
Abstract
High-temperature thermal images enable monitoring and controlling processes in metal, semiconductors, and ceramic manufacturing but also monitor activities of volcanoes or contrasting wildfires. Infrared thermal cameras require knowledge of the emissivity coefficient, while multispectral pyrometers provide fast and accurate temperature measurements with limited [...] Read more.
High-temperature thermal images enable monitoring and controlling processes in metal, semiconductors, and ceramic manufacturing but also monitor activities of volcanoes or contrasting wildfires. Infrared thermal cameras require knowledge of the emissivity coefficient, while multispectral pyrometers provide fast and accurate temperature measurements with limited spatial resolution. Bayer-pattern cameras offer a compromise by capturing multiple spectral bands with high spatial resolution. However, temperature estimation from color remains challenging due to spectral overlaps among the color filters in the Bayer pattern, and a widely accepted calibration method is still missing. In this paper, the quantum efficiency of an imaging system including the camera sensor, lens, and filters is inferred from a sequence of images acquired by looking at a black body source between 700 °C and 1100 °C. The physical model of the camera, based on the Planck law and the optimized quantum efficiency, allows the calculation of the Planckian locus in the color space of the camera. A regression neural network, trained on a synthetic dataset representing the Planckian locus, predicts temperature pixel by pixel in the 700 °C to 3500 °C range from live images. Experiments done with a color camera, a multispectral camera, and a furnace for heat treatment of metals as ground truth show that our calibration procedure leads to temperature prediction with accuracy and precision of a few tens of Celsius degrees in the calibration temperature range. Tests on a temperature-calibrated halogen bulb prove good generalization capability to a wider temperature range while being robust to noise. Full article
(This article belongs to the Section Sensing and Imaging)
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12 pages, 7173 KiB  
Article
Sb3+-Doped Rb2HfCl6 Perovskites as High-Performance Thermally Stable Single-Component Phosphors for White Light-Emitting Diodes
by Yanbiao Li and Yuefeng Gao
Materials 2025, 18(9), 1896; https://doi.org/10.3390/ma18091896 - 22 Apr 2025
Viewed by 536
Abstract
Stable and efficient inorganic lead-free double perovskites are crucial for high-reliability optoelectronic devices. However, dual-doped perovskite phosphors often suffer from poor color stability due to differences in thermal activation energies and electron–phonon interactions between the doped ions. To address this, single-doped Sb3+ [...] Read more.
Stable and efficient inorganic lead-free double perovskites are crucial for high-reliability optoelectronic devices. However, dual-doped perovskite phosphors often suffer from poor color stability due to differences in thermal activation energies and electron–phonon interactions between the doped ions. To address this, single-doped Sb3+-incorporated Rb2HfCl6 perovskite crystals were synthesized via a co-precipitation method. Under UV excitation, Rb2HfCl6:Sb exhibits broad dual emission bands, attributed to singlet and triplet self-trapped exciton radiative transitions induced by Jahn–Teller distortion in [SbCl6]3− octahedra. This dual emission endows the material with high sensitivity to excitation wavelengths, enabling tunable luminescence from cyan to orange-red across 400–800 nm. Utilizing this dual emission, a white LED was fabricated, showcasing a high color rendering index and excellent long-term stability. Remarkably, the material exhibits breakthrough thermal stability, maintaining more than 90% of its emission intensity at 100 °C, while also exhibiting remarkable resistance to humidity and oxygen exposure. Compared to co-doped phosphors, Rb2HfCl6:Sb offers advantages such as environmental friendliness, simple fabrication, and stable performance, making it an ideal candidate for WLEDs. This study demonstrates notable progress in developing thermally stable and reliable optoelectronic devices. Full article
(This article belongs to the Section Energy Materials)
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17 pages, 9262 KiB  
Article
Infrared Absorption of Laser Patterned Sapphire Al2O3 for Radiative Cooling
by Nan Zheng, Daniel Smith, Soon Hock Ng, Hsin-Hui Huang, Dominyka Stonytė, Dominique Appadoo, Jitraporn Vongsvivut, Tomas Katkus, Nguyen Hoai An Le, Haoran Mu, Yoshiaki Nishijima, Lina Grineviciute and Saulius Juodkazis
Micromachines 2025, 16(4), 476; https://doi.org/10.3390/mi16040476 - 16 Apr 2025
Cited by 1 | Viewed by 879
Abstract
The reflectance (R) of linear and circular micro-gratings on c-plane sapphire Al2O3 ablated by a femtosecond (fs) laser were spectrally characterised for thermal emission (1R) in the mid-to-far infrared (IR) spectral range. An [...] Read more.
The reflectance (R) of linear and circular micro-gratings on c-plane sapphire Al2O3 ablated by a femtosecond (fs) laser were spectrally characterised for thermal emission (1R) in the mid-to-far infrared (IR) spectral range. An IR camera was used to determine the blackbody radiation temperature from laser-patterned regions, which showed (3–6)% larger emissivity dependent on the grating pattern. The azimuthal emission curve closely followed the Lambertian angular profile cosθa at the 7.5–13 μm emission band. The back-side ablation method on transparent substrates was employed to prevent debris formation during energy deposition as it applies a forward pressure of >0.3 GPa to the debris and molten skin layer. The back-side ablation maximises energy deposition at the exit interface where the transition occurs from the high-to-low refractive index. Phononic absorption in the Reststrahlen region 20–30 μm can be tailored with the fs laser inscription of sensor structures/gratings. Full article
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10 pages, 2124 KiB  
Article
Multifunctional Hierarchical Metamaterials: Synergizing Visible-Laser-Infrared Camouflage with Thermal Management
by Shenglan Wu, Hao Huang, Zhenyong Huang, Chunhui Tian, Lina Guo, Yong Liu and Shuang Liu
Photonics 2025, 12(4), 387; https://doi.org/10.3390/photonics12040387 - 16 Apr 2025
Viewed by 658
Abstract
With the rapid development of multispectral detection technology, realizing the synergistic camouflage and thermal management of materials in multi-band has become a major challenge. In this paper, a multifunctional radiation-selective hierarchical metamaterial (RSHM) is designed to realize the modulation of optical properties in [...] Read more.
With the rapid development of multispectral detection technology, realizing the synergistic camouflage and thermal management of materials in multi-band has become a major challenge. In this paper, a multifunctional radiation-selective hierarchical metamaterial (RSHM) is designed to realize the modulation of optical properties in a wide spectral range through the delicate design of microstructures and nanostructures. In the atmospheric windows of 3–5 μm and 8–14 μm, the emissivity of the material is as low as 0.14 and 0.25, which can effectively suppress the radiation characteristics of the target in the infrared band, thus realizing efficient infrared stealth. Simultaneously, it exhibits high emissivity in the 2.5–3 μm (up to 0.80) and 5–8 μm (up to 0.98) bands, significantly improving thermal radiation efficiency and enabling active thermal management. Notably, RSHM achieves low reflectivity at 1.06 μm (0.13) and 1.55 μm (0.005) laser wavelengths, as well as in the 8–14 μm (0.06) band, substantially improving laser stealth performances. Additionally, it maintains high transmittance in the visible light range, ensuring excellent visual camouflage effects. Furthermore, the RSHM demonstrates exceptional incident angle and polarization stability, maintaining robust performances even under complex detection conditions. This design is easy to expand relative to other frequency bands of the electromagnetic spectrum and holds significant potential for applications in military camouflage, energy-efficient buildings, and optical devices. Full article
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10 pages, 1391 KiB  
Article
Luminescence and Scintillation Properties of YAl3(BO3)4 Single Crystal for Thermal Neutron Detection
by Yutaka Fujimoto, Masanori Koshimizu, Hiroki Kawamoto, Kenichi Watanabe, Akio Miyamoto and Keisuke Asai
Crystals 2025, 15(4), 357; https://doi.org/10.3390/cryst15040357 - 12 Apr 2025
Viewed by 463
Abstract
A single crystal of YAl3(BO3)4 was grown using the top-seeded solution growth method. The vacuum ultraviolet (VUV) excitation spectrum, monitored at the emission wavelength of 312 and 372 nm, showed a narrow excitation band at around 162 nm, [...] Read more.
A single crystal of YAl3(BO3)4 was grown using the top-seeded solution growth method. The vacuum ultraviolet (VUV) excitation spectrum, monitored at the emission wavelength of 312 and 372 nm, showed a narrow excitation band at around 162 nm, which is located near the absorption edge of the YAl3(BO3)4 host. Upon VUV excitation at 162 nm, the characteristic self-trapped exciton (STE) emission bands were observed at 312 and 372 nm. The X-ray excited scintillation spectrum shows a broad emission band peaking at 310 nm with a weak shoulder band at around 375 nm, which is consistent with photoluminescence, and can thus be assigned to the STE emission. The scintillation light yield under irradiation at a 252Cf-thermal neutron reached 2700 photons/thermal neutron. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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23 pages, 5226 KiB  
Article
Object-Based Downscaling Method for Land Surface Temperature with High-Spatial-Resolution Multispectral Data
by Siyao Wu, Shengmao Zhang and Fei Wang
Appl. Sci. 2025, 15(8), 4211; https://doi.org/10.3390/app15084211 - 11 Apr 2025
Viewed by 422
Abstract
Land surface temperature (LST) is an important environmental parameter in many fields. However, many studies require high-spatial- and high-temporal-resolution LST products to improve the coarse spatial resolution of moderate-resolution imaging spectroradiometer (MODIS) LSTs. Numerous approaches have downscaled MODIS LST images to a finer [...] Read more.
Land surface temperature (LST) is an important environmental parameter in many fields. However, many studies require high-spatial- and high-temporal-resolution LST products to improve the coarse spatial resolution of moderate-resolution imaging spectroradiometer (MODIS) LSTs. Numerous approaches have downscaled MODIS LST images to a finer spatial resolution using pixel-based image analysis (PBA). Meanwhile, object-based image analysis (OBIA) methods, which have developed rapidly in the analysis of high-spatial-resolution visible and near-infrared (VNIR) band data, have received little attention in the LST downscaling field. In this paper, we propose an object-based downscaling (OBD) method for MODIS LST using high-spatial-resolution multispectral images (e.g., Landsat Thematic Mapper (TM), Enhanced Thematic Mapper Plus (ETM+), and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER)) as auxiliary data. The fundamental principle of this method is to preserve the thermal radiance of the “object”, which is composed of several MODIS LST pixels (partly or entirely) and is unchanged after disaggregation into subpixels in the resulting LST image. The decomposition process consists of two key parts: the thermal radiance (TR) estimation of the object from MODIS LST products and the weight calculation of sub-objects or subpixels. Objects were generated from VNIR data and remote sensing indices (e.g., the normalized difference vegetation index (NDVI), the normalized difference built-up index (NDBI), and fractions of different endmembers) using a multiscale segmentation method. The radiance of subpixels or sub-objects was calculated based on the weights of their parent objects, which were estimated by the relationships between the remote sensing indices and the LST. The accuracy and the efficiency of the OBD method were validated using a pair of ASTER and MODIS datapoints that were acquired at the same time. The decomposed LST results showed that the spatial distribution of the downscaled LST image closely resembled the true LST of the ASTER, with an RMSE of 2.5 K for the entire image. A comparison with PBA methods for pixel downscaling also indicated that the OBD method achieves the lowest root mean square error (RMSE) across different landcovers, including urban areas, water bodies, and natural terrain. Therefore, the proposed OBD method significantly enhances the capability of increasing the spatial resolution of coarse MODIS LST, providing an alternative for improving the spatial resolution of MODIS LST images and expanding their applicability to studies that require high-temporal- and high-spatial-resolution LST products. Full article
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19 pages, 3285 KiB  
Article
Diurnal Variations of Infrared Land Surface Emissivity in the Taklimakan Desert: An Observational Analysis
by Yufen Ma, Kang Zeng, Ailiyaer Aihaiti, Junjian Liu, Zonghui Liu and Ali Mamtimin
Remote Sens. 2025, 17(7), 1276; https://doi.org/10.3390/rs17071276 - 3 Apr 2025
Viewed by 570
Abstract
This study’s field observations of Light Source Efficiency (LSE) in the Taklamakan Desert have unveiled significant daily average variations across different wavelengths, with LSE values ranging from 0.827 at 9.1 μm to a peak of 0.969 at 12.1 μm, and notably, a substantial [...] Read more.
This study’s field observations of Light Source Efficiency (LSE) in the Taklamakan Desert have unveiled significant daily average variations across different wavelengths, with LSE values ranging from 0.827 at 9.1 μm to a peak of 0.969 at 12.1 μm, and notably, a substantial daily variation (DV) of Δε = 0.080 in the 14.3 μm band. These findings underscore the necessity for wavelength-specific analysis in LSE research, which is crucial for enhancing the precision of remote sensing applications and climate models. This study’s high-temporal-resolution FTIR field observations systematically reveal the diurnal dynamics of infrared surface emissivity in the desert for the first time, challenging existing satellite-based inversion products and highlighting the limitations of traditional temperature–emissivity separation algorithms in arid regions. The diurnal fluctuations are governed by three primary mechanisms: the amplification of lattice vibrations in quartz minerals under high daytime temperatures, changes in the surface topography due to thermal expansion and contraction, and nocturnal radiative cooling effects. The lack of a significant correlation between environmental parameters and the emissivity change rate suggests that microclimate factors play a dominant indirect regulatory role. Model comparisons indicate that sinusoidal functions outperform polynomial fits across most wavelengths, especially at 12.1 μm, confirming the significant influence of diurnal forcing. The high sensitivity of the 14.3 μm band makes it an ideal indicator for monitoring desert surface–atmosphere interactions. This study provides three key insights for remote sensing applications: the development of dynamic emissivity correction schemes, the prioritization of the long-wave infrared band for surface temperature inversion in arid regions, and the integration of ground-based observations with geostationary high-spectral data to construct spatiotemporally continuous emissivity models. Future research should focus on multi-angle observation experiments and the exploration of machine learning’s potential in cross-scale emissivity modeling. Full article
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15 pages, 10576 KiB  
Article
Dy3+ and Mn4+ Ions Co-Doped Stannate Phosphors for Applications in Dual-Mode Optical Thermometry
by Zaifa Yang, Zhide Wang, Yi Su, Wenyue Zhang and Yu Zheng
Molecules 2025, 30(7), 1569; https://doi.org/10.3390/molecules30071569 - 31 Mar 2025
Cited by 1 | Viewed by 377
Abstract
In order to break through the limitations of the application of traditional temperature measurement technology, non-contact optical temperature sensing material with good sensitivity is one of the current research hotspots. Herein, a series of Dy3+ and Mn4+ co-doping Mg3Ga [...] Read more.
In order to break through the limitations of the application of traditional temperature measurement technology, non-contact optical temperature sensing material with good sensitivity is one of the current research hotspots. Herein, a series of Dy3+ and Mn4+ co-doping Mg3Ga2SnO8 fluorescent materials were prepared successfully, and the crystal structure, phase purity, and morphology of the synthesized phosphors were comprehensively investigated, as well as their photoluminescence properties, energy transfer, and high-temperature thermal stability. The two pairs of independent thermally coupled energy levels of Dy3+ ions and Mn4+ ions in Mg3Ga2SnO8 are utilized to realize the dual-mode optical temperature detection with excellent performance. On the one hand, based on the different ionic energy level transitions of 4F9/26H13/2 and 2Eg4A2g responding differently to temperature, two emission bands of 577 nm and 668 nm were chosen to construct the fluorescence intensity ratio thermometry, and the maximum sensitivity of 1.82 %K−1 was achieved at 473 K. On the other hand, based on the strong temperature dependence of the lifetime of Mn4+ in Mg3Ga2SnO8:0.06Dy3+,0.009Mn4+, fluorescence lifetime thermometry was constructed and a maximum sensitivity of 2.75 %K−1 was achieved at 473 K. Finally, the Mg3Ga2SnO8: 0.06Dy3+,0.009Mn4+ sample realizes dual-mode optical temperature measurement with high sensitivity and a wide temperature detection range, indicating that the sample has promising applications in optical temperature measurement. Full article
(This article belongs to the Special Issue Organic and Inorganic Luminescent Materials, 2nd Edition)
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14 pages, 3240 KiB  
Article
Phase, Chemical, Thermal, and Morphological Analyses of Thermoplastic Polyurethane (TPU) Nanocomposites Reinforced with Jute Cellulose Nanofibers (CNFs)
by Siti Syazwani Nordi, Ervina Efzan Mhd Noor, Chee Kuang Kok, Nurhidayatullaili Muhd Julkapli and Mirza Farrukh Baig
Polymers 2025, 17(7), 899; https://doi.org/10.3390/polym17070899 - 27 Mar 2025
Cited by 2 | Viewed by 958
Abstract
In response to the growing demand for high-performance materials in industries such as automotive, aerospace, and construction, this study investigates the impact of jute cellulose nanofibers (CNFs) on the chemical, thermal, and morphological properties of thermoplastic polyurethane (TPU) nanocomposites. Jute CNFs were extracted [...] Read more.
In response to the growing demand for high-performance materials in industries such as automotive, aerospace, and construction, this study investigates the impact of jute cellulose nanofibers (CNFs) on the chemical, thermal, and morphological properties of thermoplastic polyurethane (TPU) nanocomposites. Jute CNFs were extracted using a chemo-mechanical method and incorporated into TPU through melt blending. Fourier transform infrared (FTIR) spectroscopy revealed notable changes in the chemical structure of the nanocomposites, including intensified O-H stretching vibrations and reduced C-H stretching vibrations upon the addition of 2 wt% and 4 wt% jute CNFs. Strong interfacial interactions between the jute CNFs and the TPU matrix were observed, particularly influencing the absorbance bands related to the -NH, C=O, and N-H groups. X-ray diffraction (XRD) analysis demonstrated enhanced crystallinity in the TPU nanocomposites, with new diffraction peaks and increased crystallite size correlating with higher jute CNF content. Field emission scanning electron microscopy (FESEM) revealed a uniform dispersion of the jute CNFs within the TPU matrix, contributing to improved interfacial adhesion and enhanced structural integrity. Thermal analysis using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) showed an increase in the thermal stability, with the onset of degradation occurring at higher temperatures in the TPU/jute CNF nanocomposites. The glass transition temperature (Tg) and melting temperature (Tm) exhibited minor shifts, reflecting improved thermal performance. These findings suggest that the incorporation of jute CNFs significantly enhances the crystallinity, thermal stability, and structural organization of TPU, offering a sustainable approach for developing robust materials with potential applications in structural, corrosion-resistant, and high-performance fields. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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17 pages, 3949 KiB  
Article
Enhanced Long-Term In-Sensing Memory in ZnO Nanoparticle-Based Optoelectronic Synaptic Devices Through Thermal Treatment
by Dabin Jeon, Seung Hun Lee and Sung-Nam Lee
Materials 2025, 18(6), 1321; https://doi.org/10.3390/ma18061321 - 17 Mar 2025
Cited by 2 | Viewed by 663
Abstract
Two-terminal optoelectronic synaptic devices based on ZnO nanoparticles (NPs) were fabricated to investigate the effects of thermal annealing control (200 °C–500 °C) in nitrogen and oxygen atmospheres on surface morphology, optical response, and synaptic functionality. Atomic force microscopy (AFM) analysis revealed improved grain [...] Read more.
Two-terminal optoelectronic synaptic devices based on ZnO nanoparticles (NPs) were fabricated to investigate the effects of thermal annealing control (200 °C–500 °C) in nitrogen and oxygen atmospheres on surface morphology, optical response, and synaptic functionality. Atomic force microscopy (AFM) analysis revealed improved grain growth and reduced surface roughness. At the same time, UV–visible spectroscopy and photoluminescence confirmed a blue shift in the absorption edge and enhanced near-band-edge emission, particularly in nitrogen-annealed devices due to increased oxygen vacancies. X-ray photoelectron spectroscopy (XPS) analysis of the O 1s spectra confirmed that oxygen vacancies were more pronounced in nitrogen-annealed devices than in oxygen-annealed ones at 500 °C. Optical resistive switching was observed, where 365 nm ultraviolet (UV) irradiation induced a transition from a high-resistance state (HRS) to a low-resistance state (LRS), attributed to electron–hole pair generation and oxygen desorption. The electrical reset process, achieved by applying −1.0 V to −5.0 V, restored the initial HRS, demonstrating stable switching behavior. Nitrogen-annealed devices with higher oxygen vacancies exhibited superior synaptic performance, including higher excitatory postsynaptic currents, stronger paired-pulse facilitation, and extended persistent photoconductivity (PPC) duration, enabling long-term memory retention. By systematically varying UV exposure time, intensity, pulse number, and frequency, ZnO NPs-based devices demonstrated the transition from short-term to long-term memory, mimicking biological synaptic behavior. Learning and forgetting simulations showed faster learning and slower decay in nitrogen-annealed devices, emphasizing their potential for next-generation neuromorphic computing and energy-efficient artificial synapses. Full article
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