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Search Results (894)

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Keywords = thermal cleaning

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37 pages, 1909 KiB  
Review
Research Progress on Risk Prevention and Control Technology for Lithium-Ion Battery Energy Storage Power Stations: A Review
by Weihang Pan
Batteries 2025, 11(8), 301; https://doi.org/10.3390/batteries11080301 - 6 Aug 2025
Abstract
Amidst the background of accelerated global energy transition, the safety risk of lithium-ion battery energy storage systems, especially the fire hazard, has become a key bottleneck hindering their large-scale application, and there is an urgent need to build a systematic prevention and control [...] Read more.
Amidst the background of accelerated global energy transition, the safety risk of lithium-ion battery energy storage systems, especially the fire hazard, has become a key bottleneck hindering their large-scale application, and there is an urgent need to build a systematic prevention and control program. This paper focuses on the fire characteristics and thermal runaway mechanism of lithium-ion battery energy storage power stations, analyzing the current situation of their risk prevention and control technology across the dimensions of monitoring and early warning technology, thermal management technology, and fire protection technology, and comparing and analyzing the characteristics of each technology from multiple angles. Building on this analysis, this paper summarizes the limitations of the existing technologies and puts forward prospective development paths, including the development of multi-parameter coupled monitoring and warning technology, integrated and intelligent thermal management technology, clean and efficient extinguishing agents, and dynamic fire suppression strategies, aiming to provide solid theoretical support and technical guidance for the precise risk prevention and control of lithium-ion battery storage power stations. Full article
(This article belongs to the Special Issue Advanced Battery Safety Technologies: From Materials to Systems)
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17 pages, 2538 KiB  
Article
Influence of Abrasive Flow Rate and Feed Rate on Jet Lag During Abrasive Water Jet Cutting of Beech Plywood
by Monika Sarvašová Kvietková, Ondrej Dvořák, Chia-Feng Lin, Dennis Jones, Petr Ptáček and Roman Fojtík
Appl. Sci. 2025, 15(15), 8687; https://doi.org/10.3390/app15158687 (registering DOI) - 6 Aug 2025
Abstract
Cutting beech plywood using abrasive water jet (AWJ) technology represents a significant area of research due to increasing demands for precision, quality, and environmental sustainability in manufacturing processes within the woodworking industry. AWJ technology enables non-contact cutting of materials without causing thermal deformation [...] Read more.
Cutting beech plywood using abrasive water jet (AWJ) technology represents a significant area of research due to increasing demands for precision, quality, and environmental sustainability in manufacturing processes within the woodworking industry. AWJ technology enables non-contact cutting of materials without causing thermal deformation or mechanical damage, which is crucial for preserving the structural integrity and mechanical properties of the plywood. This article investigates cutting beech plywood using technical methods using an abrasive water jet (AWJ) at 400 MPa pressure, with Australian garnet (80 MESH) as the abrasive material. It examines how abrasive mass flow rate, traverse speed, and material thickness affect AWJ lag, which in turn influences both cutting quality and accuracy. Measurements were conducted with power abrasive mass flow rates of 250, 350, and 450 g/min and traverse speeds of 0.2, 0.4, and 0.6 m/min. Results show that increasing the abrasive mass flow rate from 250 g/min to 350 g/min slightly decreased the AWJ cut width by 0.05 mm, while further increasing to 450 g/min caused a slight increase of 0.1 mm. Changes in traverse speed significantly influenced cut width; increasing the traverse speed from 0.2 m/min to 0.4 m/min widened the AWJ by 0.21 mm, while increasing it to 0.6 m/min caused a slight increase of 0.18 mm. For practical applications, it is recommended to use an abrasive mass flow rate of around 350 g/min combined with a traverse speed between 0.2 and 0.4 m/min when cutting beech plywood with AWJ. This balance minimizes jet lag and maintains high surface quality comparable to conventional milling. For thicker plywood, reducing the traverse speed closer to 0.2 m/min and slightly increasing the abrasive flow should ensure clean cuts without compromising surface integrity. Full article
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14 pages, 5840 KiB  
Article
Paint Removal Performance and Sub-Surface Microstructural Evolution of Ti6Al4V Alloy Using Different Process Parameters of Continuous Laser Cleaning
by Haoye Zeng, Biwen Li, Liangbin Hu, Yun Zhang, Ruiqing Li, Chaochao Zhou and Pinghu Chen
Coatings 2025, 15(8), 916; https://doi.org/10.3390/coatings15080916 (registering DOI) - 6 Aug 2025
Abstract
Laser cleaning technology has been increasingly applied in the removal of damaged protective coatings from aircraft components due to its environmental friendliness and high efficiency. Appropriate laser cleaning process parameters improve cleaning efficiency while preventing substrate damage. In this study, a Gaussian continuous-wave [...] Read more.
Laser cleaning technology has been increasingly applied in the removal of damaged protective coatings from aircraft components due to its environmental friendliness and high efficiency. Appropriate laser cleaning process parameters improve cleaning efficiency while preventing substrate damage. In this study, a Gaussian continuous-wave laser was used to remove the 120 μm coating on the surface of Ti6Al4V alloy. The influence of laser power (100 W to 200 W) and scanning speed (520 mm/min to 610 mm/min) on the paint removal effect was explored based on paint removal rate, surface roughness, microstructural evolution, and the hardness’ change in the direction of heat transfer. The results reveal that optimal paint removal parameters are achieved at a laser power of 100 W with a scanning speed of 550 mm/min. The surface roughness of the sample after paint removal (55 nm) is similar to that of the original substrate (56 nm). Through EBSD analysis, the influence of laser thermal accumulation on the microstructure of the substrate is relatively small. The average hardness of the cross-section after cleaning was 347 HV, which was only 3.41% higher than that of the original substrate. This confirms that parameter-controlled laser cleaning can effectively remove ~120 μm thick paint layers without inflicting damage on the substrate. Full article
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13 pages, 4131 KiB  
Article
MBE Growth of High-Quality HgCdSe for Infrared Detector Applications
by Zekai Zhang, Wenwu Pan, Gilberto A. Umana Membreno, Shuo Ma, Lorenzo Faraone and Wen Lei
Materials 2025, 18(15), 3676; https://doi.org/10.3390/ma18153676 - 5 Aug 2025
Abstract
HgCdSe has recently been proposed as a potential alternative material to HgCdTe for fabricating high-performance infrared detectors. This work presents a study on the growth of high-crystalline-quality HgCdSe materials on GaSb (211)B substrates via molecular beam epitaxy and demonstration of the first prototype [...] Read more.
HgCdSe has recently been proposed as a potential alternative material to HgCdTe for fabricating high-performance infrared detectors. This work presents a study on the growth of high-crystalline-quality HgCdSe materials on GaSb (211)B substrates via molecular beam epitaxy and demonstration of the first prototype HgCdSe-based mid-wave infrared detectors. By optimizing the MBE growth parameters, and especially the thermal cleaning process of the GaSb substrate surface prior to epitaxial growth, high-quality HgCdSe material was achieved with a record XRD full width at half maximum of ~65 arcsec. At a temperature of 77 K, the mid-wave infrared HgCdSe n-type material demonstrated a minority carrier lifetime of ~1.19 µs, background electron concentration of ~2.2 × 1017 cm−3, and electron mobility of ~1.6 × 104 cm2/Vs. The fabricated mid-wave infrared HgCdSe photoconductor presented a cut-off wavelength of 4.2 µm, a peak responsivity of ~40 V/W, and a peak detectivity of ~1.2 × 109 cmHz1/2/W at 77 K. Due to the relatively high background electron concentration, the detector performance is lower than that of state-of-the-art low-doped HgCdTe counterparts. However, these preliminary results indicate the great potential of HgCdSe materials for achieving next-generation IR detectors on large-area substrates with features of lower cost and larger array format size. Full article
(This article belongs to the Section Optical and Photonic Materials)
40 pages, 18923 KiB  
Article
Twin-AI: Intelligent Barrier Eddy Current Separator with Digital Twin and AI Integration
by Shohreh Kia, Johannes B. Mayer, Erik Westphal and Benjamin Leiding
Sensors 2025, 25(15), 4731; https://doi.org/10.3390/s25154731 - 31 Jul 2025
Viewed by 119
Abstract
The current paper presents a comprehensive intelligent system designed to optimize the performance of a barrier eddy current separator (BECS), comprising a conveyor belt, a vibration feeder, and a magnetic drum. This system was trained and validated on real-world industrial data gathered directly [...] Read more.
The current paper presents a comprehensive intelligent system designed to optimize the performance of a barrier eddy current separator (BECS), comprising a conveyor belt, a vibration feeder, and a magnetic drum. This system was trained and validated on real-world industrial data gathered directly from the working separator under 81 different operational scenarios. The intelligent models were used to recommend optimal settings for drum speed, belt speed, vibration intensity, and drum angle, thereby maximizing separation quality and minimizing energy consumption. the smart separation module utilizes YOLOv11n-seg and achieves a mean average precision (mAP) of 0.838 across 7163 industrial instances from aluminum, copper, and plastic materials. For shape classification (sharp vs. smooth), the model reached 91.8% accuracy across 1105 annotated samples. Furthermore, the thermal monitoring unit can detect iron contamination by analyzing temperature anomalies. Scenarios with iron showed a maximum temperature increase of over 20 °C compared to clean materials, with a detection response time of under 2.5 s. The architecture integrates a Digital Twin using Azure Digital Twins to virtually mirror the system, enabling real-time tracking, behavior simulation, and remote updates. A full connection with the PLC has been implemented, allowing the AI-driven system to adjust physical parameters autonomously. This combination of AI, IoT, and digital twin technologies delivers a reliable and scalable solution for enhanced separation quality, improved operational safety, and predictive maintenance in industrial recycling environments. Full article
(This article belongs to the Special Issue Sensors and IoT Technologies for the Smart Industry)
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20 pages, 2093 KiB  
Review
A Practical Guide Paper on Bulk and PLD Thin-Film Metals Commonly Used as Photocathodes in RF and SRF Guns
by Alessio Perrone, Muhammad Rizwan Aziz, Francisco Gontad, Nikolaos A. Vainos and Anna Paola Caricato
Chemistry 2025, 7(4), 123; https://doi.org/10.3390/chemistry7040123 - 30 Jul 2025
Viewed by 303
Abstract
This paper serves as a comprehensive and practical resource to guide researchers in selecting suitable metals for use as photocathodes in radio-frequency (RF) and superconducting radio-frequency (SRF) electron guns. It offers an in-depth review of bulk and thin-film metals commonly employed in many [...] Read more.
This paper serves as a comprehensive and practical resource to guide researchers in selecting suitable metals for use as photocathodes in radio-frequency (RF) and superconducting radio-frequency (SRF) electron guns. It offers an in-depth review of bulk and thin-film metals commonly employed in many applications. The investigation includes the photoemission, optical, chemical, mechanical, and physical properties of metallic materials used in photocathodes, with a particular focus on key performance parameters such as quantum efficiency, operational lifetime, chemical inertness, thermal emittance, response time, dark current, and work function. In addition to these primary attributes, this study examines essential parameters such as surface roughness, morphology, injector compatibility, manufacturing techniques, and the impact of chemical environmental factors on overall performance. The aim is to provide researchers with detailed insights to make well-informed decisions on materials and device selection. The holistic approach of this work associates, in tabular format, all photo-emissive, optical, mechanical, physical, and chemical properties of bulk and thin-film metallic photocathodes with experimental data, aspiring to provide unique tools for maximizing the effectiveness of laser cleaning treatment. Full article
(This article belongs to the Section Electrochemistry and Photoredox Processes)
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40 pages, 910 KiB  
Review
Impact of Indoor Air Quality, Including Thermal Conditions, in Educational Buildings on Health, Wellbeing, and Performance: A Scoping Review
by Duncan Grassie, Kaja Milczewska, Stijn Renneboog, Francesco Scuderi and Sani Dimitroulopoulou
Environments 2025, 12(8), 261; https://doi.org/10.3390/environments12080261 - 30 Jul 2025
Viewed by 503
Abstract
Educational buildings, including schools, nurseries and universities, face stricter regulation and design control on indoor air quality (IAQ) and thermal conditions than other built environments, as these may affect children’s health and wellbeing. In this scoping review, wide-ranging health, performance, and absenteeism consequences [...] Read more.
Educational buildings, including schools, nurseries and universities, face stricter regulation and design control on indoor air quality (IAQ) and thermal conditions than other built environments, as these may affect children’s health and wellbeing. In this scoping review, wide-ranging health, performance, and absenteeism consequences of poor—and benefits of good—IAQ and thermal conditions are evaluated, focusing on source control, ventilation and air purification interventions. Economic impacts of interventions in educational buildings have been evaluated to enable the assessment of tangible building-related costs and savings, alongside less easily quantifiable improvements in educational attainment and reduced healthcare. Key recommendations are provided to assist decision makers in pathways to provide clean air, at an optimal temperature for students’ learning and health outcomes. Although the role of educational buildings can be challenging to isolate from other socio-economic confounders, secondary short- and long-term impacts on attainment and absenteeism have been demonstrated from the health effects associated with various pollutants. Sometimes overlooked, source control and repairing existing damage can be important cost-effective methods in minimising generation and preventing ingress of pollutants. Existing ventilation standards are often not met, even when mechanical and hybrid ventilation systems are already in place, but can often be achieved with a fraction of a typical school budget through operational and maintenance improvements, and small-scale air-cleaning and ventilation technologies, where necessary. Full article
(This article belongs to the Special Issue Air Pollution in Urban and Industrial Areas III)
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12 pages, 3668 KiB  
Article
The Study on the Electrochemical Efficiency of Yttrium-Doped High-Entropy Perovskite Cathodes for Proton-Conducting Fuel Cells
by Bingxue Hou, Xintao Wang, Rui Tang, Wenqiang Zhong, Meiyu Zhu, Zanxiong Tan and Chengcheng Wang
Materials 2025, 18(15), 3569; https://doi.org/10.3390/ma18153569 - 30 Jul 2025
Viewed by 254
Abstract
The commercialization of proton-conducting fuel cells (PCFCs) is hindered by the limited electroactivity and durability of cathodes at intermediate temperatures ranging from 400 to 700 °C, a challenge exacerbated by an insufficient understanding of high-entropy perovskite (HEP) materials for oxygen reduction reaction (ORR) [...] Read more.
The commercialization of proton-conducting fuel cells (PCFCs) is hindered by the limited electroactivity and durability of cathodes at intermediate temperatures ranging from 400 to 700 °C, a challenge exacerbated by an insufficient understanding of high-entropy perovskite (HEP) materials for oxygen reduction reaction (ORR) optimization. This study introduces an yttrium-doped HEP to address these limitations. A comparative analysis of Ce0.2−xYxBa0.2Sr0.2La0.2Ca0.2CoO3−δ (x = 0, 0.2; designated as CBSLCC and YBSLCC) revealed that yttrium doping enhanced the ORR activity, reduced the thermal expansion coefficient (19.9 × 10−6 K−1, 30–900 °C), and improved the thermomechanical compatibility with the BaZr0.1Ce0.7Y0.1Yb0.1O3−δ electrolytes. Electrochemical testing demonstrated a peak power density equal to 586 mW cm−2 at 700 °C, with a polarization resistance equaling 0.3 Ω cm2. Yttrium-induced lattice distortion promotes proton adsorption while suppressing detrimental Co spin-state transitions. These findings advance the development of durable, high-efficiency PCFC cathodes, offering immediate applications in clean energy systems, particularly for distributed power generation. Full article
(This article belongs to the Section Energy Materials)
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10 pages, 1309 KiB  
Proceeding Paper
A Sustainable Approach to Cooking: Design and Evaluation of a Sun-Tracking Concentrated Solar Stove
by Hasan Ali Khan, Malik Hassan Nawaz, Main Omair Gul and Mazhar Javed
Mater. Proc. 2025, 23(1), 4; https://doi.org/10.3390/materproc2025023004 - 29 Jul 2025
Viewed by 154
Abstract
Access to clean cooking remains a major challenge in rural and off-grid areas where traditional fuels are costly, harmful, or scarce. Solar cooking offers a sustainable solution, but many existing systems suffer from fixed positioning and low efficiency. This study presents a low-cost, [...] Read more.
Access to clean cooking remains a major challenge in rural and off-grid areas where traditional fuels are costly, harmful, or scarce. Solar cooking offers a sustainable solution, but many existing systems suffer from fixed positioning and low efficiency. This study presents a low-cost, dual-axis solar tracking parabolic dish cooker designed for such regions, featuring adjustable pot holder height and portability for ease of use. The system uses an Arduino UNO, LDR sensors, and a DC gear motor to automate sun tracking, ensuring optimal alignment throughout the day. A 0.61 m parabolic dish with ≥97% reflective silver-coated mirrors concentrates sunlight to temperatures exceeding 300 °C. Performance tests in April, June, and November showed boiling times as low as 3.37 min in high-irradiance conditions (7.66 kWh/m2/day) and 6.63 min under lower-irradiance conditions (3.86 kWh/m2/day). Compared to fixed or single-axis systems, this design achieved higher thermal efficiency and reliability, even under partially cloudy skies. Built with locally available materials, the system offers an affordable, clean, and effective cooking solution that supports energy access, health, and sustainability in underserved communities. Full article
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17 pages, 2885 KiB  
Article
Silanization-Modified Lignin Nanoparticles for Paper Coating with Enhanced Liquid and Vapor Barriers, Frication Resistance, and Self-Cleaning Properties
by Wen Chen, Ren’ai Li, Yunfeng Cao, Chunjie Ye, Zhulan Liu and Huining Xiao
Polymers 2025, 17(15), 2066; https://doi.org/10.3390/polym17152066 - 29 Jul 2025
Viewed by 270
Abstract
Paper’s inherent hydrophilicity and porosity cause inadequate barrier properties, failing under high humidity/temperature. This study successfully developed a hydrophobic nanocoating agent (xLNPs-OTS) through silanization modification using D276 (lignin nanoparticles with a diameter of 276 nm) as the substrate and OTS (octadecyltrichlorosilane) as the [...] Read more.
Paper’s inherent hydrophilicity and porosity cause inadequate barrier properties, failing under high humidity/temperature. This study successfully developed a hydrophobic nanocoating agent (xLNPs-OTS) through silanization modification using D276 (lignin nanoparticles with a diameter of 276 nm) as the substrate and OTS (octadecyltrichlorosilane) as the functionalizing agent. By applying the coating to paper surfaces followed by a hot-pressing process, the paper achieved comprehensive performance enhancements, including superior water, oil, and vapor barrier properties, thermal stability, mechanical strength, frictional resistance, and self-cleaning capabilities. The Cobb 60 value of LOTSC3.5T120t30 (the coating made from the OTS silanized lignin with the coating amount of 3.5 g/m2 and a hot-pressing at 120 °C for 30 min) coated paper is as low as 3.75 g/m2, and can withstand hot water at 100 °C for 60 min. The Cobb 60 value of the LOTSC20T120t30 (the coating made from the OTS silanized lignin with the coating amount of 20 g/m2 and a hot-pressing at 120 °C for 30 min) coated paper is reduced to 0.9 g/m2, the Kit grade is 6, and all coated papers are endowed with self-cleaning features. This study advances lignin’s high-value utilization, driving sustainable packaging and supporting eco-friendly paper material development. Full article
(This article belongs to the Special Issue Advances in Lignocellulose Research and Applications)
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14 pages, 5364 KiB  
Article
Study on the Microbial Inactivation and Quality Assurance of Ultrasonic-Assisted Slightly Acidic Electrolyzed Water for Mirror Carp (Cyprinus carpio L.) Fillets During Refrigerated Storage
by Qiang Zhong, Xiufang Xia and Fangfei Li
Foods 2025, 14(15), 2652; https://doi.org/10.3390/foods14152652 - 29 Jul 2025
Viewed by 229
Abstract
The advancement of non-thermal disinfection technologies represents a critical pathway for ensuring food safety, meeting environmental sustainability requirements, and meeting consumer preferences for clean-label products. This study systematically evaluated the combined preservation effect of ultrasonic-assisted slightly acidic electrolyzed water (US+SAEW) on mirror carp [...] Read more.
The advancement of non-thermal disinfection technologies represents a critical pathway for ensuring food safety, meeting environmental sustainability requirements, and meeting consumer preferences for clean-label products. This study systematically evaluated the combined preservation effect of ultrasonic-assisted slightly acidic electrolyzed water (US+SAEW) on mirror carp fillets during refrigeration. Results demonstrated that US+SAEW exhibited superior antimicrobial efficacy compared to individual US or SAEW, achieving reductions of 0.73, 0.74, and 0.79 log CFU/g in total viable counts (TVC), Aeromonas bacteria, and lactic acid bacteria counts compared to the control, respectively. Furthermore, the combined intervention significantly suppressed microbial proliferation throughout the refrigeration period while simultaneously delaying protein and lipid degradation/oxidation induced by spoilage bacteria, thereby inhibiting the formation of alkaline nitrogenous compounds. Consequently, lower levels of pH, total volatile basic nitrogen (TVB-N), protein carbonyl, and thiobarbituric acid reactive substances (TBARS) were observed in US+SAEW compared to the other treatments. Multimodal characterization through low-field nuclear magnetic resonance (LF-NMR), texture, and color analysis confirmed that US+SAEW effectively preserved quality characteristics, extending the shelf life of mirror carp fillets by four days. This study provides a novel non-thermal preservation strategy that combines microbial safety maintenance with quality retention, offering particular advantages for thermolabile food. Full article
(This article belongs to the Special Issue Innovative Muscle Foods Preservation and Packaging Technologies)
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24 pages, 42622 KiB  
Article
Seasonal Comparative Monitoring of Plastic and Microplastic Pollution in Lake Garda (Italy) Using Seabin During Summer–Autumn 2024
by Marco Papparotto, Claudia Gavazza, Paolo Matteotti and Luca Fambri
Microplastics 2025, 4(3), 44; https://doi.org/10.3390/microplastics4030044 - 28 Jul 2025
Viewed by 344
Abstract
Plastic (P) and microplastic (MP) pollution in marine and freshwater environments is an increasingly urgent issue that needs to be addressed at many levels. The Seabin (an easily operated and cost-effective floating debris collection device) can help clean up buoyant plastic debris in [...] Read more.
Plastic (P) and microplastic (MP) pollution in marine and freshwater environments is an increasingly urgent issue that needs to be addressed at many levels. The Seabin (an easily operated and cost-effective floating debris collection device) can help clean up buoyant plastic debris in calm waters while monitoring water pollution. A Seabin was used to conduct a comparative analysis of plastic and microplastic concentrations in northern Lake Garda (Italy) during peak and low tourist seasons. The composition of the litter was further investigated using Fourier-Transform Infrared (FTIR) spectroscopy. The analysis showed a decreased mean amount of plastic from summer (32.5 mg/m3) to autumn (17.6 mg/m3), with an average number of collected microplastics per day of 45 ± 15 and 15 ± 3, respectively. Packaging and foam accounted for 92.2% of the recognized plastic waste products. The material composition of the plastic mass (442 pieces, 103.0 g) was mainly identified as polypropylene (PP, 47.1%) and polyethylene (PE, 21.8%). Moreover, 313 microplastics (approximately 2.0 g) were counted with average weight in the range of 1–16 mg. A case study of selected plastic debris was also conducted. Spectroscopic, microscopic, and thermal analysis of specimens provided insights into how aging affects plastics in this specific environment. The purpose of this study was to establish a baseline for further research on the topic, to provide guidelines for similar analyses from a multidisciplinary perspective, to monitor plastic pollution in Lake Garda, and to inform policy makers, scientists, and the public. Full article
(This article belongs to the Collection Feature Paper in Microplastics)
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16 pages, 4597 KiB  
Article
Synthesis and Property Analysis of a High-Temperature-Resistant Polymeric Surfactant and Its Promoting Effect on Kerogen Pyrolysis Evaluated via Molecular Dynamics Simulation
by Jie Zhang, Zhen Zhao, Jinsheng Sun, Shengwei Dong, Dongyang Li, Yuanzhi Qu, Zhiliang Zhao and Tianxiang Zhang
Polymers 2025, 17(15), 2005; https://doi.org/10.3390/polym17152005 - 22 Jul 2025
Viewed by 218
Abstract
Surfactants can be utilized to improve oil recovery by changing the performance of reservoirs in rock pores. Kerogen is the primary organic matter in shale; however, high temperatures will affect the overall performance of this surfactant, resulting in a decrease in its activity [...] Read more.
Surfactants can be utilized to improve oil recovery by changing the performance of reservoirs in rock pores. Kerogen is the primary organic matter in shale; however, high temperatures will affect the overall performance of this surfactant, resulting in a decrease in its activity or even failure. The effect of surfactants on kerogen pyrolysis has rarely been researched. Therefore, this study synthesized a polymeric surfactant (PS) with high temperature resistance and investigated its effect on kerogen pyrolysis under the friction of drill bits or pipes via molecular dynamics. The infrared spectra and thermogravimetric and molecular weight curves of the PS were researched, along with its surface tension, contact angle, and oil saturation measurements. The results showed that PS had a low molecular weight, with an MW value of 124,634, and good thermal stability, with a main degradation temperature of more than 300 °C. It could drop the surface tension of water to less than 25 mN·m−1 at 25–150 °C, and the use of slats enhanced its surface activity. The PS also changed the contact angles from 127.96° to 57.59° on the surface of shale cores and reversed to a water-wet state. Additionally, PS reduced the saturated oil content of the shale core by half and promoted oil desorption, indicating a good cleaning effect on the shale oil reservoir. The kerogen molecules gradually broke down into smaller molecules and produced the final products, including methane and shale oil. The main reaction area in the system was the interface between kerogen and the surfactant, and the small molecules produced on the interface diffused to both ends. The kinetics of the reaction were controlled by two processes, namely, the step-by-step cleavage process of macromolecules and the side chain cleavage to produce smaller molecules in advance. PS could not only desorb oil in the core but also promote the pyrolysis of kerogen, suggesting that it has good potential for application in shale oil exploration and development. Full article
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22 pages, 2139 KiB  
Article
Nutritional and Technological Benefits of Pine Nut Oil Emulsion Gel in Processed Meat Products
by Berik Idyryshev, Almagul Nurgazezova, Zhanna Assirzhanova, Assiya Utegenova, Shyngys Amirkhanov, Madina Jumazhanova, Assemgul Baikadamova, Assel Dautova, Assem Spanova and Assel Serikova
Foods 2025, 14(15), 2553; https://doi.org/10.3390/foods14152553 - 22 Jul 2025
Viewed by 334
Abstract
A high intake of saturated fats and cholesterol from processed meats is associated with increased cardiovascular disease risk. This study aimed to develop a nutritionally enhanced Bologna-type sausage by partially replacing the beef content with a structured emulsion gel (EG) formulated from pine [...] Read more.
A high intake of saturated fats and cholesterol from processed meats is associated with increased cardiovascular disease risk. This study aimed to develop a nutritionally enhanced Bologna-type sausage by partially replacing the beef content with a structured emulsion gel (EG) formulated from pine nut oil, inulin, carrageenan, and whey protein concentrate. The objective was to improve its lipid quality and functional performance while maintaining product integrity and consumer acceptability. Three sausage formulations were prepared: a control and two variants with 7% and 10% EG, which substituted for the beef content. The emulsion gel was characterized regarding its physical and thermal stability. Sausages were evaluated for their proximate composition, fatty acid profile, cholesterol content, pH, cooking yield, water-holding capacity, emulsion stability, instrumental texture, microstructure (via SEM), oxidative stability (TBARSs), and sensory attributes. Data were analyzed using a one-way and two-way ANOVA with Duncan’s test (p < 0.05). The EG’s inclusion significantly reduced the total and saturated fat and cholesterol, while increasing protein and unsaturated fatty acids. The 10% EG sample achieved a PUFA/SFA ratio of 1.00 and an over 80% reduction in atherogenic and thrombogenic indices. Functional improvements were observed in emulsion stability, cooking yield, and water retention. Textural and visual characteristics remained within acceptable sensory thresholds. SEM images showed more homogenous matrix structures in the EG samples. TBARS values increased slightly over 18 days of refrigeration but remained below rancidity thresholds. This period was considered a pilot-scale evaluation of oxidative trends. Sensory testing confirmed that product acceptability was not negatively affected. The partial substitution of beef content with pine nut oil-based emulsion gel offers a clean-label strategy to enhance the nutritional quality of Bologna-type sausages while preserving functional and sensory performance. This approach may support the development of health-conscious processed meat products aligned with consumer and regulatory demands. Full article
(This article belongs to the Section Meat)
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17 pages, 1390 KiB  
Article
Microbial Valorization of Sunflower Husk for Sustainable Biohydrogen and Biomass Production
by Liana Vanyan, Akerke Toleugazykyzy, Kaisar Yegizbay, Ayaulym Daniyarova, Lyudmila Zuloyan, Gayane Mikoyan, Anait Vassilian, Anna Poladyan, Kairat Bekbayev and Karen Trchounian
Energies 2025, 18(14), 3885; https://doi.org/10.3390/en18143885 - 21 Jul 2025
Viewed by 299
Abstract
Various pretreatment methods for the valorization of sunflower husks (SHs) for H2 gas generation through fermentation by Escherichia coli were investigated. We analyzed thermal treatment (TT), acid hydrolysis (AH), and alkaline hydrolysis (AlkH) at different substrate concentrations (50 g L−1, [...] Read more.
Various pretreatment methods for the valorization of sunflower husks (SHs) for H2 gas generation through fermentation by Escherichia coli were investigated. We analyzed thermal treatment (TT), acid hydrolysis (AH), and alkaline hydrolysis (AlkH) at different substrate concentrations (50 g L−1, 75 g L−1, 100 g L−1, and 150 g L−1) and dilution levels (undiluted, 2× diluted, and 5× diluted). A concentration of 75 g L−1 SH that was acid-hydrolyzed and dissolved twice in the medium yielded optimal microbial growth, reaching 0.3 ± 0.1 g cell dry weight (CDW) L−1 biomass. The highest substrate level enabling effective fermentation was 100 g L−1, producing 0.37 ± 0.13 (g CDW) × L−1 biomass after complete fermentation, while 150 g L−1 exhibited pronounced inhibitory effects. It is worth mentioning that the sole alkaline treatment was not optimal for growth and H2 production. Co-fermentation with glycerol significantly enhanced both biomass formation (up to 0.42 ± 0.15 (g CDW) × L−1)) and H2 production. The highest H2 yield was observed during batch growth at 50 g L−1 SH hydrolysate with 5× dilution, reaching up to 5.7 mmol H2 (g sugar)−1 with glycerol supplementation. This study introduces a dual-waste valorization strategy that combines agricultural and biodiesel industry residues to enhance clean energy generation. The novelty lies in optimizing pretreatment and co-substrate fermentation conditions to maximize both biohydrogen yield and microbial biomass using E. coli, a widely studied and scalable host. Full article
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