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26 pages, 7009 KB  
Article
Design, Implementation, and Verification of High-Accuracy Trapezoidal Dual-Axis Sun Sensors for LEO Satellite Attitude Determination
by Mang Ou-Yang, Ching-I Tai, Guan-Yu Huang, Tse-Yu Cheng, Chang-Hsun Liu, Yu-Siou Liu, Jin-Chern Chiou, Chen-Yu Chan, Tung-Yun Hsieh, Chen-Tsung Lin, Ying-Wen Jan, Chih-Hsun Lin and Yung-Jhe Yan
Sensors 2026, 26(11), 3317; https://doi.org/10.3390/s26113317 (registering DOI) - 23 May 2026
Abstract
This paper presents a dual-axis sun sensor employing a cross-slit aperture in conjunction with a four-quadrant trapezoidal photodiode layout. The cross-slit configuration enhances angular sensitivity and resolution, while the trapezoidal photodiode geometry preserves a high signal-to-noise ratio at both near-normal incidence and large [...] Read more.
This paper presents a dual-axis sun sensor employing a cross-slit aperture in conjunction with a four-quadrant trapezoidal photodiode layout. The cross-slit configuration enhances angular sensitivity and resolution, while the trapezoidal photodiode geometry preserves a high signal-to-noise ratio at both near-normal incidence and large Sun angles, maintaining reliable directional discriminability around normal incidence. Compared with conventional quad-triangle photodiode layouts, the proposed trapezoidal geometry avoids the rapid collapse of the illuminated area near the triangular apex at large incidence angles, thereby preserving signal margin near the field-of-view boundary. System-level optical verification demonstrates that, after calibration, the proposed sensor achieves an angular accuracy of ±0.3 (3σ). To mitigate performance variations induced by temperature drift, an embedded shielded dummy photodiode is incorporated to provide a dark-current reference for compensation. Unlike compensation approaches that mainly rely on pre-characterization or offline calibration, the embedded shielded dummy photodiode provides an in situ, real-time dark-current reference for compensating for temperature-induced signal drift in the actual operating environment. Experimental results under dark conditions indicate that the embedded dummy photodiode served as a dark-current reference for compensating the temperature-dependent dark-current variation in the active photodiodes, reducing the peak-to-peak dark-signal variation by 96% over a temperature range from 20C–120C. Furthermore, a pyramid-type sun-sensor architecture is proposed by integrating the dual-axis fine sun sensor with four wide-field coarse sun sensors. This system-level configuration extends the effective Sun field of view from the conventional 120– 180 range to approximately 280, enabling near-hemispherical Sun-angle observability for enhanced attitude determination robustness. Full article
18 pages, 5986 KB  
Article
A Backside-Electrode-Free Lateral 4H-SiC JFET with Three-Terminal Dual-Gate Design for Stable DC Operation at 500 °C
by Yuting Tang, Qian Luo, Jiang Zhu, Hezhi Zhang, Yuchun Chang and Hongwei Liang
Micromachines 2026, 17(6), 642; https://doi.org/10.3390/mi17060642 - 22 May 2026
Abstract
To address the urgent need for electronics operable in extremely high-temperature environments, this paper presents a novel three-terminal, dual-gate, lateral 4H-SiC n-channel depletion-mode junction field effect transistor (JFET) without a backside electrode. Featuring a fully planar electrode layout, the device eliminates the back-gate [...] Read more.
To address the urgent need for electronics operable in extremely high-temperature environments, this paper presents a novel three-terminal, dual-gate, lateral 4H-SiC n-channel depletion-mode junction field effect transistor (JFET) without a backside electrode. Featuring a fully planar electrode layout, the device eliminates the back-gate effect and significantly improves integration compatibility. Experimental results demonstrate stable DC operation up to 500 °C, with an intrinsic gain of 9.79 at room temperature and 6.01 at 500 °C. Comparison with TCAD simulations confirms excellent agreement in the key physical trends of threshold voltage drift and mobility degradation, though quantitative discrepancies are observed and attributed to process-induced parasitic effects such as non-ideal ohmic contacts and interface states. Analysis shows that the new structure broadens the channel depletion layer by optimizing the depletion profile, thereby suppressing channel-length modulation and improving both output resistance and gate control. This work not only provides an effective device platform for high-temperature 4H-SiC analog integrated circuits (ICs) but also deepens the understanding of process-performance correlations, offering clear guidance for process-oriented device optimization. The proposed structure serves as a foundation for developing fully planar, high-temperature 4H-SiC analog ICs with promising potential in aerospace, automotive, and energy exploration systems. Full article
(This article belongs to the Section D1: Semiconductor Devices)
27 pages, 6872 KB  
Article
Capacitive Insect Sensing Under a Single Dual-Arc Geometry: A Laboratory Benchmark of Four CDC Architectures
by Sen-Miao Chen, Yu-Bing Huang, Jen-Cheng Wang and Joe-Air Jiang
Sensors 2026, 26(11), 3306; https://doi.org/10.3390/s26113306 - 22 May 2026
Abstract
Capacitive sensing offers a low-power, non-optical route for automated insect monitoring, but architecture-level benchmarking under shared geometry remains limited. Rather than presenting a general framework, this study proposed a configuration-specific laboratory benchmark comparing four sigma-delta and charge-transfers in a 6 mm dual-arc conduit [...] Read more.
Capacitive sensing offers a low-power, non-optical route for automated insect monitoring, but architecture-level benchmarking under shared geometry remains limited. Rather than presenting a general framework, this study proposed a configuration-specific laboratory benchmark comparing four sigma-delta and charge-transfers in a 6 mm dual-arc conduit at 25 °C, targeting six adult terrestrial arthropod species spanning a 25-fold range of the body cross-sectional area. Static measurements showed a strong linear relationship between ΔC_static and body cross-sectional area (17.96 fF/mm2, r = 0.995), supporting first-pass conduit sizing and detectability screening. In contrast, transit amplitudes were not monotonic with body size because posture, motion, and gap occupancy affected waveform shape. Under chamber conditions, static sensitivity degraded by less than 3.2% across all architectures from RH 40% to 80%. However, under the deployment-oriented noise model, SNR_FR degradation was substantially higher for charge-transfer devices (64.8–66.8%) than for Σ–Δ devices (≤35.5%), because the composite noise floor amplifies the effect of humidity-induced baseline drift. These results generated a conduit-specific reference dataset for preliminary capacitance-to-digital converter (CDC) selection within the tested 6 mm dual-arc geometry. In addition, the experimental validation focused on laboratory baseline noise characterization, long-term drift, and trap-integrated testing in temperature-controlled environments and natural-locomotion trials, providing critical information on configuration-specific architectures and body-size-scaling reference. This study serves as an initial step toward real-world capacitive insect sensing. Future studies will investigate additional conduit geometries and insect species to improve the robustness of the proposed framework. Full article
(This article belongs to the Section Smart Agriculture)
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23 pages, 2611 KB  
Article
Influence of 3D Printing Parameters on Apparent Resistivity, Repeatability and Time-Dependent Drift of Conductive PLA
by Diana Popescu, Ștefan Cula and Lidia Florentina Parpală
Polymers 2026, 18(11), 1274; https://doi.org/10.3390/polym18111274 - 22 May 2026
Abstract
Conductive filaments for Material Extrusion Additive Manufacturing (MEX) can enable low-cost fabrication of functional parts with embedded electrical features. However, systematic studies on process-dependent electrical properties like apparent resistivity and repeatability are limited, and the post-printing stability of the electrical response is not [...] Read more.
Conductive filaments for Material Extrusion Additive Manufacturing (MEX) can enable low-cost fabrication of functional parts with embedded electrical features. However, systematic studies on process-dependent electrical properties like apparent resistivity and repeatability are limited, and the post-printing stability of the electrical response is not commonly addressed. This study evaluates the influence of printing temperature, printing speed and layer height on the apparent resistivity, specimen-to-specimen repeatability and time-dependent drift of a commercial carbon black-filled conductive PLA filament (ProtoPasta). The novelty of the study consists of evaluating not only the initial apparent resistivity, but also the repeatability between specimens and the post-print drift of apparent resistivity over a 0–50 h interval. The filament was investigated using three printing temperatures (210–230 °C), two printing speeds (60–80 mm/s) and three layer heights (0.2–0.4 mm), with three replicates per configuration. Apparent resistivity ranged between 0.156 and 0.205 kΩ·mm at t0 and between 0.162 and 0.222 kΩ·mm at t50. Multifactorial ANOVA and main-effects analyses showed that the printing temperature was the main factor affecting mean apparent resistivity at both t0 and t50. Higher temperature reduced apparent resistivity, most likely due to improved polymer flow, inter-bead/inter-layer bonding and conductive-network continuity. Printing speed had no significant main effect on the mean apparent resistivity or drift within the tested range. Repeatability depended on the parameter configuration and measurement time, with variability increasing after 24 h and then becoming mainly dependent on layer height. Drift analysis showed a significant main effect of layer height and a significant layer height × temperature interaction, with the largest increase at 0.3 mm. These results show that parameter selection for conductive MEX parts should consider both the initial resistivity level and post-print stability over time. Full article
(This article belongs to the Section Polymer Processing and Engineering)
11 pages, 5631 KB  
Article
Temperature-Dependent Performance Optimization of a Filtered ASE Source Employing Low-Concentration Erbium-Doped Fiber
by Wei Liu, Jianming Liu, Wei Xu and Jia Guo
Quantum Beam Sci. 2026, 10(2), 12; https://doi.org/10.3390/qubs10020012 - 22 May 2026
Abstract
Research on the thermal stability of amplified spontaneous emission (ASE) has mostly focused on broadband spectra. High-precision fiber optic gyroscopes (FOGs), however, require spectrally filtered sources. The impact of erbium-ion doping concentration on the temperature performance of such filtered sources remains relatively explored. [...] Read more.
Research on the thermal stability of amplified spontaneous emission (ASE) has mostly focused on broadband spectra. High-precision fiber optic gyroscopes (FOGs), however, require spectrally filtered sources. The impact of erbium-ion doping concentration on the temperature performance of such filtered sources remains relatively explored. This work systematically compares low-concentration and high-concentration erbium-doped fibers (EDFs). The fibers are used in a bidirectional forward-pumped ASE configuration. This configuration integrates a 1530 nm Gaussian filter isolator. The optimized low-concentration EDF fully absorbs pump power over a longer length. Its gain-profile temperature shift partly compensates the filter passband shift. At the optimum fiber length of 10 m, this source shows a mean wavelength temperature drift of only 0.107 ppm/°C. In contrast, the commercial high-concentration EDF gives a drift of 0.136 ppm/°C. The power conversion efficiency of this source reaches 26.9%. The commercial EDF attains 24.5%. The results demonstrate that reducing the Er3+ doping concentration simultaneously improves the wavelength thermal stability and efficiency of filtered ASE sources. This finding offers important guidance for high-accuracy FOG design. Full article
(This article belongs to the Section Spectroscopy Technique)
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35 pages, 31193 KB  
Review
Machine-Learning-Enabled Hydrogel Biosensors for Wearable Health Monitoring
by Zhizhou Zhang
Gels 2026, 12(5), 449; https://doi.org/10.3390/gels12050449 - 20 May 2026
Viewed by 262
Abstract
Machine learning (ML) is reshaping the design and deployment of conductive hydrogel biosensors for wearable health monitoring by coupling material chemistry with scalable manufacturing and robust signal analytics. Persistent bottlenecks include hydration stability (dehydration and freezing), data scarcity, device variability, and model transfer [...] Read more.
Machine learning (ML) is reshaping the design and deployment of conductive hydrogel biosensors for wearable health monitoring by coupling material chemistry with scalable manufacturing and robust signal analytics. Persistent bottlenecks include hydration stability (dehydration and freezing), data scarcity, device variability, and model transfer across users and environments. Recent advances demonstrate ML-enabled gains across electrochemical, mechanical, optical, and multimodal transduction, improving feature extraction, drift compensation, and generalization in applications spanning electrophysiology, sweat chemistry, and soft tactile sensing. On the material side, polymer informatics and graph-based representations are emerging to predict gel properties and guide composition/structure selection. In analytics, physics-informed models are enhancing impedance and voltammetry interpretation and reliability. Building on these trends, this review outlines standards for dataset curation (metadata on ionic milieu, temperature, humidity history, and mechanical loading) and strategies for cross-user and domain generalization. This review closes with actionable design guidelines for standardization, real-time analytics, and the clinical translation of hydrogel wearables. Full article
(This article belongs to the Special Issue Machine Learning in Hydrogel Design and Development)
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21 pages, 2774 KB  
Article
Combined Dielectric Spectroscopy and Operando DRIFTS Analysis of Ba-Based NOx Storage Materials for Radio-Frequency-Based NOx Dosimeters
by Daniela Schönauer-Kamin, Fabian Fütterer, Johanna Baumgärtner, Thomas Wöhrl, Gunter Hagen and Ralf Moos
Sensors 2026, 26(10), 3203; https://doi.org/10.3390/s26103203 - 19 May 2026
Viewed by 207
Abstract
This study investigates the dielectric behavior and NOx storage properties of Pt/Ba–Al2O3 NOx storage materials using microwave cavity perturbation, operando DRIFTS, and impedance spectroscopy with respect to their applicability in a radio-frequency-based NOx dosimeter-type sensor. Dielectric losses [...] Read more.
This study investigates the dielectric behavior and NOx storage properties of Pt/Ba–Al2O3 NOx storage materials using microwave cavity perturbation, operando DRIFTS, and impedance spectroscopy with respect to their applicability in a radio-frequency-based NOx dosimeter-type sensor. Dielectric losses (ε″) are identified as the most sensitive indicator of NOx storage, exhibiting a clear linear correlation with both the accumulated NOx dose and the utilization of Ba storage sites. Approximately 35% of the available Ba sites participate in nitrite and nitrate formation, and the absolute dielectric loss response increases proportionally with the Ba content of the NOx storage catalyst. In contrast, the permittivity (ε′) shows only minor changes, which are mainly influenced by temperature. Temperature-dependent experiments reveal stable NOx storage with negligible desorption up to 350 °C, whereas pronounced desorption processes at 400 °C significantly limit the linear dosimeter behavior. Operando DRIFTS measurements on Pt/Ba–Al2O3 functional films confirm temperature-dependent formation of nitrites and nitrates, with nitrates dominating the NOx storage at elevated temperatures. Capacitance measurements show a slight increase during NOx storage, indicating a moderate increase in permittivity. Overall, Pt/Ba–Al2O3 NOx storage materials exhibit a robust, quantitatively interpretable dielectric response that is well suited for radio-frequency-based, dosimeter-type NOx sensing. Full article
(This article belongs to the Special Issue Advanced Sensing Technologies for Environmental Applications)
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29 pages, 1927 KB  
Review
Fiber Bragg Grating-Based Deformation Monitoring in Space Infrastructure: A Comprehensive Review
by Nurzhigit Smailov, Sauletbek Koshkinbayev, Kydyrali Yssyraiyl, Ainur Kuttybayeva, Gulbahar Yussupova, Askhat Batyrgaliyev and Akezhan Sabibolda
J. Sens. Actuator Netw. 2026, 15(3), 38; https://doi.org/10.3390/jsan15030038 - 15 May 2026
Viewed by 252
Abstract
The increasing complexity and extended operational lifetimes of modern space infrastructure have significantly intensified the demand for reliable structural health monitoring (SHM) systems. However, the extreme space environment, characterized by radiation exposure, microgravity, ultra-high vacuum, and severe thermal cycling, imposes critical limitations on [...] Read more.
The increasing complexity and extended operational lifetimes of modern space infrastructure have significantly intensified the demand for reliable structural health monitoring (SHM) systems. However, the extreme space environment, characterized by radiation exposure, microgravity, ultra-high vacuum, and severe thermal cycling, imposes critical limitations on conventional electrical sensing technologies, leading to reduced measurement accuracy, instability, and long-term degradation. This review presents a comprehensive analysis of fiber Bragg grating (FBG)-based sensing technologies as a promising solution for deformation monitoring in space infrastructure. The study investigates the fundamental operating principles of FBG sensors under space conditions and systematically classifies existing FBG-based SHM architectures, including point-based, multiplexed, long-distance, and hybrid sensing systems. Furthermore, the advantages of FBG sensors—such as immunity to electromagnetic interference, passive operation, and high-resolution multipoint sensing—are critically evaluated in comparison with traditional electrical sensors. In addition, key challenges affecting the performance of FBG systems in space environments are analyzed, including radiation-induced wavelength drift, temperature–strain cross-sensitivity, signal attenuation, and long-term stability issues. The paper also highlights recent advances in interrogation techniques and network architectures that enable reliable in situ and real-time deformation monitoring of space structures. The results demonstrate that FBG-based sensing systems provide a scalable and robust framework for SHM in extreme environments while also revealing existing limitations and open research challenges. This work establishes a structured foundation for the development of next-generation intelligent monitoring systems for space infrastructure. Full article
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17 pages, 5918 KB  
Article
Thermoresistive Characterization of Carbon Nanotube Yarn Monofilament Composites for Temperature Sensing
by Majed Alowaid, Tannaz Tayyarian, Iriana García Guerra, Maria Alexandra Erquiaga, Nader Alhabradi, Pythagore L. Kyabutwa, Abdulrahman S. Binfaris, Shouzhong Zou, Omar Rodríguez Uicab and Jandro L. Abot
J. Compos. Sci. 2026, 10(5), 268; https://doi.org/10.3390/jcs10050268 - 14 May 2026
Viewed by 329
Abstract
Carbon nanotube yarn (CNTY) monofilament composites were investigated for integrated temperature sensing by embedding a single CNTY in a vinyl ester resin (VER) and measuring the electrical resistance change by tapping into the thermoresistive response of the CNTY. The effect of curing condition [...] Read more.
Carbon nanotube yarn (CNTY) monofilament composites were investigated for integrated temperature sensing by embedding a single CNTY in a vinyl ester resin (VER) and measuring the electrical resistance change by tapping into the thermoresistive response of the CNTY. The effect of curing condition on the thermoresistive response was evaluated using dwell tests and repeated heating–cooling cycles, comparing specimens cured at room temperature (RT) with those post-cured at 140 °C for 1 h. RT-cured CNTY/VER monofilament composites exhibited electrical resistance drift, with the resistance failing to return to its initial value after each thermal cycle, resulting in a residual resistance change of ~8.85%. In contrast, post-cured (PC) specimens showed a much smaller residual change (−0.08%) after cycle completion. Thermal cycling from RT (~25 °C) to 100 °C produced a nearly linear negative thermoresistive response. The average heating and cooling TCR values were −7.98 × 10−4 °C−1 and −8.32 × 10−4 °C−1 for CNTY/VER, and −7.93 × 10−4 °C−1 and −7.13 × 10−4 °C−1 for CNTY/VER-PC, respectively. The hysteresis decreased from 21.65% for RT-cured specimens to 12.49% after post-curing, accompanied by improved linearity. The influence of heating rate on TCR was also examined for both freestanding CNTYs and CNTY/VER monofilament composites. The observed response is attributed to coupled matrix–yarn effects (wetting, resin infiltration, and shrinkage) together with temperature-dependent electron transport across CNT junctions. Finally, CNTY/VER monofilament composites demonstrated the ability to estimate internal temperatures under various thermal programs. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2026)
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19 pages, 32444 KB  
Article
Regulating Oxygen Vacancies in Ultrasonic-Assisted Green-Synthesized Copper-Doped δ-MnO2 Catalysts for Boosting Formaldehyde Oxidation
by Xiudan Tao, Xiaohan Yang, Fufen Li, Yuqing He, Chenhui Liu, Zhengjun Li and Nianhua Dan
Catalysts 2026, 16(5), 454; https://doi.org/10.3390/catal16050454 - 13 May 2026
Viewed by 142
Abstract
Oxygen vacancies play a crucial role in modulating the chemical and catalytic properties of metal oxide catalysts. Herein, quercetin was used as a green reducing agent to prepare Cu-doped MnO2 (Cu-MnO2) composite catalysts with varying Cu doping levels via an [...] Read more.
Oxygen vacancies play a crucial role in modulating the chemical and catalytic properties of metal oxide catalysts. Herein, quercetin was used as a green reducing agent to prepare Cu-doped MnO2 (Cu-MnO2) composite catalysts with varying Cu doping levels via an ultrasonically assisted strategy. The structure-activity relationships were systematically investigated using XRD, Raman, XPS, H2-TPR, and O2-TPD. Benefiting from optimized surface lattice defects induced by an appropriate Cu doping level, the Cu-MnO2-2 sample, which exhibited the highest oxygen vacancy concentration, achieved a HCHO removal efficiency of 99.2% for 1 ppm HCHO at room temperature (25 °C) and 50% relative humidity within 30 min. The enrichment of Mn3+, Cu+, and surface-adsorbed oxygen species (Oads) further corroborated the increased oxygen vacancy density, indicating that moderate Cu doping effectively promotes electron transfer and oxygen activation. After five consecutive cycles, the HCHO conversion remained above 96%. Post-cycling characterizations (XRD, FTIR, EDS, and XPS) confirmed the excellent structural and chemical stability of the catalyst, with the Mn3+ proportion and Cu+/Cu2+ ratio well preserved. In situ DRIFTS analysis revealed that surface-adsorbed oxygen and oxygen-vacancy-activated reactive oxygen species (ROS) are key factors in the efficient HCHO oxidation over the green Cu-MnO2-2 catalyst, promoting rapid conversion of intermediates and ultimately generating CO2 and H2O. This study provides a facile, low-cost, and green synthesis strategy for Cu-MnO2 composite catalysts for indoor, room-temperature HCHO abatement, offering new insights into the design of other composite catalyst materials. Full article
(This article belongs to the Special Issue Metal and Non-Metal Doping Modification of Catalysts)
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27 pages, 7901 KB  
Article
A Multi-Gradient-Descent-Integrated Physics-Informed Autoencoder for Sensor Fault Detection in Data Center Chillers
by Xinyue Shen, Pan Li, Chen Xu and Chengliang Xu
Sensors 2026, 26(10), 3025; https://doi.org/10.3390/s26103025 - 11 May 2026
Viewed by 600
Abstract
The operating status of chillers in data centers critically affects temperature stability and energy efficiency, imposing stringent requirements on the accuracy, robustness, and adaptability of sensor fault detection systems. Existing Physics-Informed Autoencoders (PIAE) for chiller fault detection face challenges such as gradient conflicts [...] Read more.
The operating status of chillers in data centers critically affects temperature stability and energy efficiency, imposing stringent requirements on the accuracy, robustness, and adaptability of sensor fault detection systems. Existing Physics-Informed Autoencoders (PIAE) for chiller fault detection face challenges such as gradient conflicts and limited generalization, especially under complex fault scenarios like sensor drift, stuck faults, and precision attenuation. To address these limitations, we propose a Multi-Gradient Descent Algorithm-integrated PIAE (MGDA-PIAE), which embeds the chiller thermal balance equation as a hard constraint and dynamically determines Pareto-optimal weights between data reconstruction and physical consistency. By unifying feature learning with physical law constraints, the model achieves improved generalization and stable performance across diverse operational conditions. Validation using operational data from a data center in Guangzhou demonstrates that MGDA-PIAE significantly outperforms conventional AE and PIAE models: the average recall increases by approximately 20% and the F1-score by 10%, while for flow sensor faults, the F1-score improves by over 80% compared with AE and 20% compared with PIAE. Further tests on multiple sensor types confirm that the model maintains high-precision detection with low false negatives under varying operating modes. By adjusting a single physical threshold, MGDA-PIAE can flexibly meet different fault detection requirements, providing a practical and reliable solution for maintaining the efficient, stable, and safe operation of data center refrigeration systems. Full article
(This article belongs to the Section Fault Diagnosis & Sensors)
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15 pages, 3356 KB  
Article
Spatiotemporal Variation Characteristics and Drivers of Winter Arctic Sea Ice Thickness Under the New Arctic Regime
by Yaowei Yin and Xiaoyu Wang
J. Mar. Sci. Eng. 2026, 14(10), 888; https://doi.org/10.3390/jmse14100888 (registering DOI) - 11 May 2026
Viewed by 218
Abstract
The “New Arctic” regime represents a prominent climatic feature of the Arctic Ocean under global warming, characterized by persistently low summer sea ice extent, a marked reduction in sea ice thickness, and an expansion of open water areas at high latitudes. As a [...] Read more.
The “New Arctic” regime represents a prominent climatic feature of the Arctic Ocean under global warming, characterized by persistently low summer sea ice extent, a marked reduction in sea ice thickness, and an expansion of open water areas at high latitudes. As a key indicator of the Arctic sea ice system, the spatiotemporal evolution of sea ice thickness and its underlying driving mechanisms remain incompletely understood. Using reanalysis datasets and remote sensing observations, this study identifies major abrupt shifts in Arctic sea ice thickness under the New Arctic regime, reveals the spatiotemporal distribution characteristics of winter sea ice thickness, and examines the driving factors from both thermodynamic and dynamic perspectives. The results show that the evolution of Arctic sea ice thickness can be divided into three phases: a high-level period during the “Traditional Arctic” (1979–1992), a rapid thinning period during the New Arctic transition (1993–2012), and a low-level stabilization period in the New Arctic regime (2013–2023). The first EOF mode of winter sea ice thickness depicts a spatially consistent thinning pattern across the entire Arctic, with the most significant reduction occurring in the multi-year ice regions north of the Canadian Arctic Archipelago and Greenland. The second EOF mode exhibits an out-of-phase variation between the Atlantic and Pacific sectors of the Arctic, accompanied by a shrinking amplitude and weakened regional oscillations. The coupling between surface air temperature and sea ice thickness displays distinct phase dependence: their negative correlation is strongest during the transition period (r = −0.78, p < 0.001) but becomes statistically insignificant in the New Arctic regime. Sea ice motion speed exhibits an overall accelerating trend, which extends from the marginal seasonal ice zones toward the high-latitude multi-year ice regions, accompanied by a notably enhanced sensitivity of sea ice motion to wind forcing. Sea ice volume flux through the Fram Strait is primarily controlled by ice motion speed, whose contribution to the flux is approximately 2.6 times that of ice thickness. The recovery of ice drift speed offsets the thinning of sea ice cover, leading to a partial rebound in volume flux during the New Arctic steady state. This study identifies the evolutionary patterns and drivers of Arctic sea ice thickness under the New Arctic regime, providing a scientific basis for further understanding the changes in the Arctic climate system and associated air–sea ice interactions. Full article
(This article belongs to the Section Physical Oceanography)
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31 pages, 9310 KB  
Article
Methanol Steam Reforming on Ru/m-ZrO2: Sodium Promotion of the CO2-Forming Pathway
by Nadia ALHirbawi, Amélie Enciso Juarez, Michela Martinelli, Savana R. Alt, A. Jeremy Kropf, Donald C. Cronauer and Gary Jacobs
Catalysts 2026, 16(5), 446; https://doi.org/10.3390/catal16050446 - 11 May 2026
Viewed by 227
Abstract
Sodium (Na) promotion of Ru/m-ZrO2 was investigated to elucidate how an alkali modification tunes selectivity in methanol steam reforming (MSR). H2-TPR/XANES/EXAFS show that Na increases surface basicity and strengthens Ru–O interactions, shifting RuOx reduction and H2 spillover to [...] Read more.
Sodium (Na) promotion of Ru/m-ZrO2 was investigated to elucidate how an alkali modification tunes selectivity in methanol steam reforming (MSR). H2-TPR/XANES/EXAFS show that Na increases surface basicity and strengthens Ru–O interactions, shifting RuOx reduction and H2 spillover to a higher temperature. DRIFTS reveals Na-induced red shifts of the formate ν(CH) band and changes in OCO vibrational splitting, consistent with weakening of the formate C–H bond and an altered binding geometry. CO2-TPD confirms a monotonic shift toward stronger basic sites with increasing Na concentrations. Under MSR conditions, Na selectively increases CO2 concentration at the expense of CO. At ~80% conversion and 325 °C, CO2 selectivity increases from 12.0% (unpromoted) to 16.2, 21.0, and 26.5% for 0.5, 1.0, and 1.8% Na, respectively; at ~300 °C and ~66–69% conversion, CO2 selectivity increases from 8.6% to 23.7% at 1.8% Na. Transient MSR experiments further show earlier and larger H2 evolution upon Na addition, corroborating the promotion of the dehydrogenation/decarbonylation route to CO2 + H2. We propose that Na increases basicity and modifies the Ru–support interface to favor formate dehydrogenation/decarboxylation, thereby increasing the H2 yield and lowering CO formation. Ru’s higher-energy, less occupied d-band stabilizes CO and oxygenated intermediates more strongly in the reforming environment, making the CO-forming pathway more resistant to suppression than on Pt. Full article
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31 pages, 416 KB  
Review
Towards Medium-Temperature Hydrogen Fuel Cells with Glassy Proton-Conductive Membranes—Part I: Fundamentals and Single-Anion Matrices
by Maciej Stanisław Siekierski, Jacek Kowalczyk, Karolina Majewska, Maja Mroczkowska-Szerszeń, Mariusz Kłos, Aleksander Piasecki, Aleksander Pizoń, Wiktor Piekarski and Karol Kiryk
Energies 2026, 19(10), 2253; https://doi.org/10.3390/en19102253 - 7 May 2026
Viewed by 484
Abstract
The accelerated deployment of hydrogen technologies is widely discussed as a pathway to mitigate climate change and reduce environmental pollution associated with fossil fuel use. In this context, intermediate-temperature proton-exchange membranes that operate in the 120–200 °C window, similar to the one characterizing [...] Read more.
The accelerated deployment of hydrogen technologies is widely discussed as a pathway to mitigate climate change and reduce environmental pollution associated with fossil fuel use. In this context, intermediate-temperature proton-exchange membranes that operate in the 120–200 °C window, similar to the one characterizing liquid-acid PAFC systems (much larger in their power range), are sought as a bridge between low-temperature PFSA-based PEMFCs and low-temperature PCFs, thus combining reduced sensitivity to external humidification with solid-electrolyte handling. This Part I review surveys phosphate- and silicate-based glassy proton conductors as single-anion baseline matrices and organizes the literature around a mechanistic screening framework that links processing fingerprints—particularly sol–gel hydrolysis/condensation conditions, aging, drying, and thermal treatment—to pore architecture, hydration state, and the dominant proton-transport regime. Across both families, conductivity is governed by coupled variables: network chemistry (acidic site density and connectivity), water activity (RH), and microstructure-controlled percolation and retention. Reported σ values can arise from fundamentally different regimes, ranging from hopping-dominated transport supported by dense hydrogen-bond networks and proton-bearing groups to carrier-assisted, water-mediated transport in connected porosity, with distinct humidity dependence and stability implications. Accordingly, the review treats σ(T,RH) and activation energy together with hydration/porosity indicators as primary screening metrics, and it records missing durability and device-level information—chemical stability (hydrolysis and leaching/acid migration), mechanical robustness and cycling response, and current/power density where available—as explicit knowledge gaps. While substantial progress has been achieved within single-anion phosphate and silicate glasses, particularly through engineered acidity and microstructural control, most systems remain limited by hydration drift under gradients, thermal/humidity cycling stability, and electrode/electrolyte interfacial constraints when evaluated against intermediate-temperature membrane requirements. These conclusions establish a quantitative baseline and comparison rules for Part II, which will assess mixed-network, composite, and hybrid strategies designed to decouple conductivity from water-retention and durability trade-offs. Full article
23 pages, 6399 KB  
Review
Comparison of Kinetic and Fluid Simulation Models for RF Capacitively Coupled Plasmas in Semiconductor Processing
by Hwanho Kim, Min Uk Lee and Hae June Lee
Materials 2026, 19(9), 1900; https://doi.org/10.3390/ma19091900 - 5 May 2026
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Abstract
As low-temperature plasmas (LTPs) have gained significant attention in materials processing for the microelectronics industry, challenges in spatiotemporal analysis of plasma parameters in a radio frequency capacitively coupled plasma (RF-CCP) system necessitate multidimensional numerical simulations. This study investigated the conditions under which a [...] Read more.
As low-temperature plasmas (LTPs) have gained significant attention in materials processing for the microelectronics industry, challenges in spatiotemporal analysis of plasma parameters in a radio frequency capacitively coupled plasma (RF-CCP) system necessitate multidimensional numerical simulations. This study investigated the conditions under which a kinetic simulation or a fluid model is effective for low-pressure CCPs, focusing on the critical role of energy-dependent electron kinetics in LTPs by comparing symmetric and asymmetric electrode structures. We provide a comprehensive investigation of particle energy distributions, elucidating the kinetic effects of non-Maxwellian distributions. The validity of standard fluid approximations, such as the drift–diffusion approximation and isotropic pressure assumptions, is assessed by comparing results from a two-dimensional fluid model with those from a particle-in-cell simulation. The dominance of the ion pressure tensor over isotropic approximations in the sheath has been observed, especially in an asymmetric electrode structure, which is more representative of realistic process chambers. Full article
(This article belongs to the Special Issue Advances in Plasma Treatment of Materials)
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