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Search Results (280)

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Keywords = sustainable lubricant

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17 pages, 909 KiB  
Review
Potential of Natural Esters as Immersion Coolant in Electric Vehicles
by Raj Shah, Cindy Huang, Gobinda Karmakar, Sevim Z. Erhan, Majher I. Sarker and Brajendra K. Sharma
Energies 2025, 18(15), 4145; https://doi.org/10.3390/en18154145 - 5 Aug 2025
Abstract
As the popularity of electric vehicles (EVs) continues to increase, the need for effective and efficient driveline lubricants and dielectric coolants has become crucial. Commercially used mineral oils or synthetic ester-based coolants, despite performing satisfactorily, are not environmentally friendly. The fatty esters of [...] Read more.
As the popularity of electric vehicles (EVs) continues to increase, the need for effective and efficient driveline lubricants and dielectric coolants has become crucial. Commercially used mineral oils or synthetic ester-based coolants, despite performing satisfactorily, are not environmentally friendly. The fatty esters of vegetable oils, after overcoming their shortcomings (like poor oxidative stability, higher viscosity, and pour point) through chemical modification, have recently been used as potential dielectric coolants in transformers. The benefits of natural esters, including a higher flash point, breakdown voltage, dielectric character, thermal conductivity, and most importantly, readily biodegradable nature, have made them a suitable and sustainable substitute for traditional coolants in electric transformers. Based on their excellent performance in transformers, research on their application as dielectric immersion coolants in modern EVs has been emerging in recent years. This review primarily highlights the beneficial aspects of natural esters performing dual functions—cooling as well as lubricating, which is necessary for “wet” e-motors in EVs—through a comparative study with the commercially used mineral and synthetic coolants. The adoption of natural fatty esters of vegetable oils as an immersion cooling fluid is a significant sustainable step for the battery thermal management system (BTMS) of modern EVs considering environmental safety protocols. Continued research and development are necessary to overcome the ongoing challenges and optimize esters for widespread use in the rapidly expanding electric vehicle market. Full article
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14 pages, 4747 KiB  
Article
Biodegradable Polyalphaolefins for Gear Lubrication in Electrical Drives: Aging and Wetting
by Kevin Holderied, Joachim Albrecht, Elisabeth Distler, Katharina Weber and Nahed El Mahallawy
Lubricants 2025, 13(8), 347; https://doi.org/10.3390/lubricants13080347 - 4 Aug 2025
Abstract
Electric propulsion requires engines and transmission systems that run at higher speeds compared to combustion engines. For improving sustainability and environmental protection, biodegradable oils are suggested for the lubrication of high-speed gears that require particularly quick wetting of the steel surfaces. Newly developed [...] Read more.
Electric propulsion requires engines and transmission systems that run at higher speeds compared to combustion engines. For improving sustainability and environmental protection, biodegradable oils are suggested for the lubrication of high-speed gears that require particularly quick wetting of the steel surfaces. Newly developed promising candidates include short-chained polyalphaolefins. In the present work, a study on the applicability of such oil is presented and discussed with respect to different aging levels based on biodegradable properties. It focuses on the wettability of metallic surfaces investigated through time-resolved contact angle measurements. Carbon steels with different carbon contents and microstructures are selected as the most commonly used materials for gears. Effects of steel composition, surface roughness and oil oxidation are studied. The results show that in most cases, the application of biodegradable polyalphaolefins is not critical; however, a combination of steels with inhomogeneous microstructure, high surface roughness and aged oil can be critical because of limited wetting. Full article
(This article belongs to the Special Issue Tribology of Electric Vehicles)
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32 pages, 1403 KiB  
Review
Advancements in Environmentally Friendly Lubricant Technologies: Towards Sustainable Performance and Efficiency
by Iwona Wilińska and Sabina Wilkanowicz
Energies 2025, 18(15), 4006; https://doi.org/10.3390/en18154006 - 28 Jul 2025
Viewed by 336
Abstract
The advancement of next-generation lubricants is pivotal for enhancing energy efficiency and mitigating environmental impacts across diverse industrial applications. This review systematically examines recent developments in lubricant technologies, with a particular focus on sustainable strategies incorporating bio-based feedstocks, nanostructured additives, and hybrid formulations. [...] Read more.
The advancement of next-generation lubricants is pivotal for enhancing energy efficiency and mitigating environmental impacts across diverse industrial applications. This review systematically examines recent developments in lubricant technologies, with a particular focus on sustainable strategies incorporating bio-based feedstocks, nanostructured additives, and hybrid formulations. These innovations are designed to reduce friction and wear, decrease energy consumption, and prolong the operational lifespan of mechanical systems. A critical assessment of tribological behavior, environmental compatibility, and functional performance is presented. Furthermore, the integration of artificial intelligence (AI) into lubricant formulation and performance prediction is explored, highlighting its potential to accelerate development cycles and enable application-specific optimization through data-driven approaches. The findings emphasize the strategic role of eco-innovative lubricants in supporting low-carbon technologies and facilitating the transition toward sustainable energy systems. Full article
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43 pages, 1282 KiB  
Review
Process Intensification Strategies for Esterification: Kinetic Modeling, Reactor Design, and Sustainable Applications
by Kim Leonie Hoff and Matthias Eisenacher
Int. J. Mol. Sci. 2025, 26(15), 7214; https://doi.org/10.3390/ijms26157214 - 25 Jul 2025
Viewed by 680
Abstract
Esterification is a key transformation in the production of lubricants, pharmaceuticals, and fine chemicals. Conventional processes employing homogeneous acid catalysts suffer from limitations such as corrosive byproducts, energy-intensive separation, and poor catalyst reusability. This review provides a comprehensive overview of heterogeneous catalytic systems, [...] Read more.
Esterification is a key transformation in the production of lubricants, pharmaceuticals, and fine chemicals. Conventional processes employing homogeneous acid catalysts suffer from limitations such as corrosive byproducts, energy-intensive separation, and poor catalyst reusability. This review provides a comprehensive overview of heterogeneous catalytic systems, including ion exchange resins, zeolites, metal oxides, mesoporous materials, and others, for improved ester synthesis. Recent advances in membrane-integrated reactors, such as pervaporation and nanofiltration, which enable continuous water removal, shifting equilibrium and increasing conversion under milder conditions, are reviewed. Dual-functional membranes that combine catalytic activity with selective separation further enhance process efficiency and reduce energy consumption. Enzymatic systems using immobilized lipases present additional opportunities for mild and selective reactions. Future directions emphasize the integration of pervaporation membranes, hybrid catalyst systems combining biocatalysts and metals, and real-time optimization through artificial intelligence. Modular plug-and-play reactor designs are identified as a promising approach to flexible, scalable, and sustainable esterification. Overall, the interaction of catalyst development, membrane technology, and digital process control offers a transformative platform for next-generation ester synthesis aligned with green chemistry and industrial scalability. Full article
(This article belongs to the Section Biochemistry)
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20 pages, 7139 KiB  
Article
Synergistic Effects of CuO and ZnO Nanoadditives on Friction and Wear in Automotive Base Oil
by Ádám István Szabó and Rafiul Hasan
Appl. Sci. 2025, 15(15), 8258; https://doi.org/10.3390/app15158258 - 24 Jul 2025
Viewed by 364
Abstract
Efficient lubrication lowers friction, wear, and energy losses in automotive drivetrain components. Advanced lubricants are key to sustainable transportation performance, durability, and efficiency. This study analyzes the tribological performance of Group III base oil with CuO and ZnO nanoadditive mixtures. These additives enhance [...] Read more.
Efficient lubrication lowers friction, wear, and energy losses in automotive drivetrain components. Advanced lubricants are key to sustainable transportation performance, durability, and efficiency. This study analyzes the tribological performance of Group III base oil with CuO and ZnO nanoadditive mixtures. These additives enhance the performance of Group III base oils, making them highly relevant for automotive lubricant applications. An Optimol SRV5 tribometer performed ball-on-disk sliding contact tests with 100Cr6 steel specimens subjected to a 50 N force and a temperature of 100 °C. The test settings are designed to mimic the boundary and mixed lubrication regimes commonly seen in the automobile industry. During the tests, the effect of nanoparticles on friction was measured. Microscopic wear analysis was performed on the worn specimens. The results demonstrate that adding 0.3 wt% CuO nanoparticles to Group III base oil achieves a 19% reduction in dynamic friction and a 47% decrease in disk wear volume compared to additive-free oil. Notably, a 2:1 CuO-to-ZnO mixture produced synergy, delivering up to a 27% friction reduction and a 54% decrease in disk wear. The results show the synergistic effect of CuO and ZnO in reducing friction and wear on specimens. This study highlights the potential of nanoparticles for lubricant development and automotive applications. Full article
(This article belongs to the Special Issue Sustainable Mobility and Transportation (SMTS 2025))
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41 pages, 16361 KiB  
Review
Progress on Sustainable Cryogenic Machining of Hard-to-Cut Material and Greener Processing Techniques: A Combined Machinability and Sustainability Perspective
by Shafahat Ali, Said Abdallah, Salman Pervaiz and Ibrahim Deiab
Lubricants 2025, 13(8), 322; https://doi.org/10.3390/lubricants13080322 - 23 Jul 2025
Viewed by 318
Abstract
The current research trends of production engineering are based on optimizing the machining process concerning human and environmental factors. High-performance materials, such as hardened steels, nickel-based alloys, fiber-reinforced polymer (FRP) composites, and titanium alloys, are classified as hard-to-cut due to their ability to [...] Read more.
The current research trends of production engineering are based on optimizing the machining process concerning human and environmental factors. High-performance materials, such as hardened steels, nickel-based alloys, fiber-reinforced polymer (FRP) composites, and titanium alloys, are classified as hard-to-cut due to their ability to maintain strength at high operating temperatures. Due to these characteristics, such materials are employed in applications such as aerospace, marine, energy generation, and structural. The purpose of this article is to investigate the machinability of these alloys under various cutting conditions. The purpose of this article is to compare cryogenic cooling and cryogenic processing from the perspective of machinability and sustainability in the manufacturing process. Compared to conventional machining, hybrid techniques, which mix cryogenic and minimal quantity lubricant, led to significantly reduced cutting forces of 40–50%, cutting temperatures and surface finishes by approximately 20–30% and more than 40%, respectively. A carbon footprint is determined by several factors including power consumption, energy requirements, and carbon dioxide emissions. As a result of the cryogenic technology, the energy consumption, power consumption, and CO2 emissions were reduced by 40%, 28%, and 35%. Full article
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25 pages, 3515 KiB  
Article
Optimizing Sustainable Machining Conditions for Incoloy 800HT Using Twin-Nozzle MQL with Bio-Based Groundnut Oil Lubrication
by Ramai Ranjan Panigrahi, Ramanuj Kumar, Ashok Kumar Sahoo and Amlana Panda
Lubricants 2025, 13(8), 320; https://doi.org/10.3390/lubricants13080320 - 23 Jul 2025
Viewed by 849
Abstract
This study explores the machinability of Incoloy 800HT (high temperature) under a sustainable lubrication approach, employing a twin-nozzle minimum quantity lubrication (MQL) system with groundnut oil as a green cutting fluid. The evaluation focuses on key performance indicators, including surface roughness, tool flank [...] Read more.
This study explores the machinability of Incoloy 800HT (high temperature) under a sustainable lubrication approach, employing a twin-nozzle minimum quantity lubrication (MQL) system with groundnut oil as a green cutting fluid. The evaluation focuses on key performance indicators, including surface roughness, tool flank wear, power consumption, carbon emissions, and chip morphology. Groundnut oil, a biodegradable and nontoxic lubricant, was chosen to enhance environmental compatibility while maintaining effective cutting performance. The Taguchi L16 orthogonal array (three factors and four levels) was utilized to conduct experimental trials to analyze machining characteristics. The best surface quality (surface roughness, Ra = 0.514 µm) was obtained at the lowest depth of cut (0.2 mm), modest feed (0.1 mm/rev), and moderate cutting speed (160 m/min). The higher ranges of flank wear are found under higher cutting speed conditions (320 and 240 m/min), while lower wear values (<0.09 mm) were observed under lower speed conditions (80 and 160 m/min). An entropy-integrated multi-response optimization using the MOORA (multi-objective optimization based on ratio analysis) method was employed to identify optimal machining parameters, considering the trade-offs among multiple conflicting objectives. The entropy method was used to assign weights to each response. The obtained optimal conditions are as follows: cutting speed = 160 m/min, feed = 0.1 mm/rev, and depth of cut = 0.2 mm. Optimized outcomes suggest that this green machining strategy offers a viable alternative for sustainable manufacturing of difficult-to-machine alloys like Incoloy 800 HT. Full article
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23 pages, 9638 KiB  
Article
A Study on the Influence Mechanism of the Oil Injection Distance on the Oil Film Distribution Characteristics of the Gear Meshing Zone
by Wentao Zhao, Lin Li and Gaoan Zheng
Machines 2025, 13(7), 606; https://doi.org/10.3390/machines13070606 - 14 Jul 2025
Viewed by 305
Abstract
Under the trend of lightweight and high-efficiency development in industrial equipment, precise regulation of lubrication in gear reducers is a key breakthrough for enhancing transmission system efficiency and reliability. This study establishes a three-dimensional numerical model for high-speed gear jet lubrication using computational [...] Read more.
Under the trend of lightweight and high-efficiency development in industrial equipment, precise regulation of lubrication in gear reducers is a key breakthrough for enhancing transmission system efficiency and reliability. This study establishes a three-dimensional numerical model for high-speed gear jet lubrication using computational fluid dynamics (CFD) and dynamic mesh technology. By implementing the volume of fluid (VOF) multiphase flow model and the standard k-ω turbulence model, the study simulates the dynamic distribution of lubricant in gear meshing zones and analyzes critical parameters such as the oil volume fraction, eddy viscosity, and turbulent kinetic energy. The results show that reducing the oil injection distance significantly enhances lubricant coverage and continuity: as the injection distance increases from 4.8 mm to 24 mm, the lubricant shifts from discrete droplets to a dense wedge-shaped film, mitigating lubrication failure risks from secondary atomization and energy loss. The optimized injection distance also improves the spatial stability of eddy viscosity and suppresses excessive dissipation of turbulent kinetic energy, enhancing both the shear-load capacity and thermal management. Dynamic data from monitoring point P show that reducing the injection distance stabilizes lubricant velocity and promotes more consistent oil film formation and heat transfer. Through multiphysics simulations and parametric analysis, this study elucidates the interaction between geometric parameters and hydrodynamic behaviors in jet lubrication systems. The findings provide quantitative evaluation methods for structural optimization and energy control in gear lubrication systems, offering theoretical insights for thermal management and reliability enhancement in high-speed transmission. These results contribute to the lightweight design and sustainable development of industrial equipment. Full article
(This article belongs to the Section Friction and Tribology)
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20 pages, 8257 KiB  
Article
Tribological Performance of Bronze Engineering Materials with Environmentally Friendly Lubricants Under Starved Lubrication Conditions
by Marcin Kowalski, Kasper Górny, Szymon Bernat, Arkadiusz Stachowiak, Jacek Wernik and Wiesław Zwierzycki
Materials 2025, 18(14), 3283; https://doi.org/10.3390/ma18143283 - 11 Jul 2025
Viewed by 255
Abstract
This article demonstrated that environmentally friendly lubricants—glycerol–water-based oil (GWB) and rapeseed oil-based oil (RSB)—would provide comparable conditions (wear of node components, friction resistance) in a friction node as a commercial semi-synthetic gear oil (REF). Wear tests were performed on a block-on-ring model friction [...] Read more.
This article demonstrated that environmentally friendly lubricants—glycerol–water-based oil (GWB) and rapeseed oil-based oil (RSB)—would provide comparable conditions (wear of node components, friction resistance) in a friction node as a commercial semi-synthetic gear oil (REF). Wear tests were performed on a block-on-ring model friction node stand using GBZ12 (CuSn12), BA1032 (CuAl10Fe3Mn2), and BA1054 (CuAl10Ni5Fe4) bronze samples. Glycerol–water-based oil (GWB) significantly reduced the wear of the samples by several times, compared to semi-synthetic oil (REF) and rapeseed oil-based oil (RSB). The (GWB) oil also provided a stable friction coefficient value at the lowest level of 0.05–0.06. The main disadvantage of the (RSB) oil was the temporary fluctuation of the friction coefficient value (increase above 0.1), which indicated the lack of stability of the boundary layer. The results highlight the potential of (GWB) oil in reducing wear and stabilizing friction under extreme conditions, supporting the shift toward sustainable lubricants in industrial applications. Full article
(This article belongs to the Special Issue Engineering Materials: Friction, Wear and Damage)
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21 pages, 7240 KiB  
Article
Sustainable Combined Process for Improving Surface Integrity and Fatigue Strength of Heat-Treated 42CrMo4 Steel Shafts and Axles
by Jordan Maximov, Galya Duncheva, Angel Anchev, Vladimir Dunchev, Kalin Anastasov and Mariana Ichkova
Metals 2025, 15(7), 755; https://doi.org/10.3390/met15070755 - 4 Jul 2025
Viewed by 216
Abstract
The main goal of this study is to develop an optimized sustainable combined process, including sequential dry hard turning and dry smoothing diamond burnishing (DB), to improve the surface integrity (SI) and fatigue limit of heat-treated 42CrMo4 steel shafts and axles. A holistic [...] Read more.
The main goal of this study is to develop an optimized sustainable combined process, including sequential dry hard turning and dry smoothing diamond burnishing (DB), to improve the surface integrity (SI) and fatigue limit of heat-treated 42CrMo4 steel shafts and axles. A holistic approach was used based on a two-stage study: (1) optimization of dry hard turning under an average roughness Ra criterion and (2) selection of a suitable dry DB from three alternative DB processes, implemented with burnishing forces of 50, 100, and 150 N. With increasing burnishing force, the average roughness of Ra decreases, the microhardness increases, and the surface axial residual stresses increase in absolute value. However, the fatigue limit decreases, and at burnishing forces of 100 and 150 N, the fatigue limit is smaller than that obtained via the previous turning. The sustainable combined process achieves greater SI than consecutively applied conventional turning and DB under flood lubrication conditions. Dry DB at a force of 50 N increases the rotating bending fatigue limit by 20 MPa and the fatigue life by a factor of more than 70 compared to the previous dry turning. Full article
(This article belongs to the Special Issue Advanced High-Performance Steels: From Fundamental to Applications)
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20 pages, 2974 KiB  
Article
The Application of a New Microbial Biosurfactant to Remove Residual Oil from Electric Power Plant and to Inhibit Metal Corrosion in a Salty Environment
by Alexandre Augusto P. Selva Filho, Yslla Emanuelly S. Faccioli, Attilio Converti, Alessandro Alberto Casazza, Rita de Cássia F. Soares da Silva and Leonie A. Sarubbo
Energies 2025, 18(13), 3359; https://doi.org/10.3390/en18133359 - 26 Jun 2025
Viewed by 435
Abstract
Human development has led to increased production of oil and gas, mainly as energy sources, which, however, are responsible for contamination and metal corrosion in industrial, marine, and terrestrial environments. Lubricating oil, in particular, is widely used in generators and industrial machines in [...] Read more.
Human development has led to increased production of oil and gas, mainly as energy sources, which, however, are responsible for contamination and metal corrosion in industrial, marine, and terrestrial environments. Lubricating oil, in particular, is widely used in generators and industrial machines in the electric sector and is responsible for contamination not only in industrial environments but also in many terrestrial and aquatic ecosystems. In this context, this study aimed to apply the Starmerella bombicola ATCC 222214 biosurfactant to inhibit metal corrosion in seawater and in an Accelerated Corrosion Chamber (ACC). For this purpose, its toxicity against the microcrustacean Artemia salina, its dispersion capacity, and its ability to promote oil biodegradation in a saline environment were investigated. The biosurfactant, when applied at twice its Critical Micellar Concentration (CMC), caused low mortality (30.0%) of microcrustaceans in a saline environment, and, in its crude form, the biosurfactant ensured the dispersion of no less than 77.56% of residual engine oil in seawater. Oil biodegradation by autochthonous microorganisms reached 94.39% in the presence of the biosurfactant in seawater. Furthermore, the biosurfactant, when used at twice its CMC, acted satisfactorily as a corrosion inhibitor by reducing the mass loss of galvanized iron specimens (plates) in seawater in a static system to only 0.36%. On the other hand, when the biosurfactant was added at the CMC as an atmospheric corrosion inhibitor, the reduction in mass loss of carbon steel plates treated in the ACC was 17.38% compared to the control containing only a biodegradable matrix based on vegetable resin. When the biosurfactant was incorporated into different paints applied to galvanized iron plates placed in contact with the salt spray produced in the ACC, the best result was obtained using the biomolecule at a concentration of 3% in the satin paint, ensuring a plate mass loss (29.236 g/m2) that was almost half that obtained without surfactant (52.967 g/m2). The study indicated the use of yeast biosurfactant as a sustainable alternative in combating the contamination of marine environments and metal corrosion, with the aim of preserving the environment and improving the quality of life in aquatic and terrestrial ecosystems. Full article
(This article belongs to the Section B: Energy and Environment)
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17 pages, 2694 KiB  
Article
Evaluation of Vibratory Ball Mill Mixing as an Alternative to Wet Granulation in the Manufacturing of Sodium Naproxen Tablets with Dolomite-Based Formulations
by Mateusz Przywara, Klaudia Jękot and Wiktoria Jednacz
Appl. Sci. 2025, 15(13), 6966; https://doi.org/10.3390/app15136966 - 20 Jun 2025
Viewed by 251
Abstract
The development of robust and scalable tablet manufacturing methods remains a key objective in pharmaceutical technology, especially when dealing with active pharmaceutical ingredients (APIs) and excipients that exhibit suboptimal processing properties. This study evaluated two alternative manufacturing strategies for tablets containing sodium naproxen [...] Read more.
The development of robust and scalable tablet manufacturing methods remains a key objective in pharmaceutical technology, especially when dealing with active pharmaceutical ingredients (APIs) and excipients that exhibit suboptimal processing properties. This study evaluated two alternative manufacturing strategies for tablets containing sodium naproxen (20%, API), dolomite (65%, sustainable mineral filler), cellulose (7%), polyvinylpyrrolidone (5%, binder), and magnesium stearate (3%, lubricant). The direct compression method used a vibrating ball mill (SPEX SamplePrep 8000M), while the indirect method employed wet granulation using a pan granulator at different inclination angles. Physical properties of raw materials and granules were assessed, and final tablets were evaluated for mass, thickness, mechanical resistance, abrasiveness, and API content uniformity. Direct compression using vibratory mixing for 5–10 min (DT2, DT3) resulted in average tablet masses close to the target (0.260 g) and improved reproducibility compared to a reference V-type blender. Wet granulation produced tablets with the lowest abrasiveness (<1.0%) and minimal variability in dimensions and API content. The best uniformity (SD < 0.5%) was observed in batch IT2. Overall, vibratory mixing proved capable of achieving tablet quality comparable to that of wet granulation, while requiring fewer processing steps. This highlights its potential as an efficient and scalable alternative in solid dosage manufacturing. Full article
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23 pages, 6546 KiB  
Article
Bidirectionally Coupled FE-CFD Simulation Study on MQL Machining Process of Ti-6Al-4V Alloy
by Xiaorong Zhou, Lin He, Sen Yuan, Hongwan Jiang, Jing Deng, Feilong Du, Jingdou Yang and Zebin Su
Lubricants 2025, 13(6), 274; https://doi.org/10.3390/lubricants13060274 - 19 Jun 2025
Viewed by 764
Abstract
In the context of sustainable manufacturing practices, minimum quantity lubrication (MQL) has been extensively employed in machining operations involving hard-to-cut materials. While substantial experimental and numerical investigations on MQL-assisted machining have been conducted, existing simulation approaches remain inadequate for modeling the dynamic flow [...] Read more.
In the context of sustainable manufacturing practices, minimum quantity lubrication (MQL) has been extensively employed in machining operations involving hard-to-cut materials. While substantial experimental and numerical investigations on MQL-assisted machining have been conducted, existing simulation approaches remain inadequate for modeling the dynamic flow field variations inherent to MQL processes, significantly compromising the predictive reliability of current models. This study introduced an innovative bidirectional iterative coupling framework integrating finite element (FE) analysis and computational fluid dynamics (CFD) to enhance simulation accuracy. Since fluid flow characteristics critically influence tribological and thermal management at the tool–workpiece interface during machining, CFD simulations were initially performed to evaluate how MQL parameters govern fluid flow behavior. Subsequently, an integrated FE-CFD modeling approach was developed to simulate Ti-6Al-4V alloy turning under MQL conditions with varying feed rates. The novel methodology involved transferring thermal flux data from FE simulations to CFD’s heat source domain, followed by incorporating CFD-derived convective heat transfer coefficients back into FE computations. This repetitive feedback process continued until the thermal exchange parameters reached convergence. Validation experiments demonstrated that the proposed method achieved improved alignment between the simulated and experimental results for both cutting temperature profiles and principal force components across different feed conditions, confirming the enhanced predictive capability of this coupled simulation strategy. Full article
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13 pages, 3330 KiB  
Article
Super Hydrophobic UHMWPE/PTFE/PVA Composites with Low Friction: Preparation and Wear Mechanism
by Hai Wang, Zhiwei Shao, Kuiyuan Shen, Buhe Bateer, Fushen Ren and Xiaowen Qi
Polymers 2025, 17(12), 1664; https://doi.org/10.3390/polym17121664 - 16 Jun 2025
Viewed by 433
Abstract
This study develops novel superhydrophobic UHMWPE/PTFE/PVA composites via hot-pressing sintering to achieve ultra-low friction and enhanced wear resistance. The ternary system synergistically combines UHMWPE’s mechanical stability, PTFE’s lubricity, and PVA’s dispersion/binding capability. Results show PTFE disrupts UHMWPE crystallization, reducing melting temperature by 2.77 [...] Read more.
This study develops novel superhydrophobic UHMWPE/PTFE/PVA composites via hot-pressing sintering to achieve ultra-low friction and enhanced wear resistance. The ternary system synergistically combines UHMWPE’s mechanical stability, PTFE’s lubricity, and PVA’s dispersion/binding capability. Results show PTFE disrupts UHMWPE crystallization, reducing melting temperature by 2.77 °C and enabling energy dissipation. All composites exhibit hydrophobicity, with optimal formulations (UPP3/UPP4) reaching superhydrophobicity. Tribological testing under varied loads and frequencies reveals low friction, where UPP1 achieves a COF of 0.043 and wear rate below 1.5 × 10−5 mm3/(N·m) under low-load conditions. UHMWPE oxidative degradation forming carboxylic acids at the interface (C=O at 289 eV, C–O at 286 eV). Formation of tungsten oxides (WO3/WO2), carbides (WC), and transfer films on steel counterparts. A four-step tribochemical reaction pathway is established. PVA promotes uniform transfer films, while PTFE lamellar peeling and UHMWPE chain stability enable sustained lubrication. Carbon-rich stratified accumulations under high-load/speed increase COF via abrasive effects. The composites demonstrate exceptional biocompatibility and provide a scalable solution for biomedical and industrial tribological applications. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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27 pages, 5180 KiB  
Article
Nano-Enhanced Cactus Oil as an MQL Cutting Fluid: Physicochemical, Rheological, Tribological, and Machinability Insights into Machining H13 Steel
by Nada K. ElBadawy, Mohamed G. A. Nassef, Ibrahem Maher, Belal G. Nassef, Mohamed A. Daha, Florian Pape and Galal A. Nassef
Lubricants 2025, 13(6), 267; https://doi.org/10.3390/lubricants13060267 - 15 Jun 2025
Viewed by 838
Abstract
The widespread use of mineral cutting fluids in metalworking poses challenges due to their poor wettability, toxicity, and non-biodegradability. This study explores cactus oil-based nanofluids as sustainable alternatives for metal cutting applications. Samples of cactus oil are prepared in plain form and with [...] Read more.
The widespread use of mineral cutting fluids in metalworking poses challenges due to their poor wettability, toxicity, and non-biodegradability. This study explores cactus oil-based nanofluids as sustainable alternatives for metal cutting applications. Samples of cactus oil are prepared in plain form and with 0.025 wt.%, 0.05 wt.%, and 0.1 wt.% activated carbon nanoparticles (ACNPs) from recycled plastic waste. Plain cactus oil exhibited a 34% improvement in wettability over commercial soluble oil, further enhanced by 60% with 0.05 wt.% ACNPs. Cactus oil displayed consistent Newtonian behavior with a high viscosity index (283), outperforming mineral-based cutting fluid in thermal stability. The addition of ACNPs enhanced the dynamic viscosity by 108–130% across the temperature range of 40–100 °C. The presence of nano-additives reduced the friction coefficient in the boundary lubrication zone by a maximum reduction of 32% for CO2 compared to plain cactus oil. The physical and rheological results translated directly to the observed improvements in surface finish and tool wear during machining operations on H13 steel. Cactus oil with 0.05 wt.% ACNP outperformed conventional fluids, reducing surface roughness by 35% and flank wear by 57% compared to dry. This work establishes cactus oil-based nanofluids as a sustainable alternative, combining recycled waste-derived additives and non-edible feedstock for greener manufacturing. Full article
(This article belongs to the Special Issue Tribology of 2D Nanomaterials and Active Control of Friction Behavior)
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