Search Results (63)

Supercritical carbon dioxide (s-CO₂) Brayton cycles have emerged as a promising technology for high-efficiency power generation, owing to their compact architecture and favorable thermophysical properties. However, their performance degrades significantly under cold-climate conditions—such as those encountered in Greenland, Russia, Canada, Scandinavia, and Alaska—due to the proximity to the fluid’s critical point. This study investigates the behavior of the recompression Brayton cycle (RBC) under subzero ambient temperatures through the incorporation of low-critical-temperature additives to create CO₂-based binary mixtures. The working fluids examined include methane (CH₄), tetrafluoromethane (CF₄), nitrogen trifluoride (NF₃), and krypton (Kr). Simulation results show that CH₄- and CF₄-rich mixtures can achieve thermal efficiency improvements of up to 10 percentage points over pure CO₂. NF₃-containing blends yield solid performance in moderately cold environments, while Kr-based mixtures provide modest but consistent efficiency gains. At low compressor inlet temperatures, the high-temperature recuperator (HTR) becomes the dominant performance-limiting component. Optimal distribution of recuperator conductance (UA) favors increased HTR sizing when mixtures are employed, ensuring effective heat recovery across larger temperature differentials. The study concludes with a comparative exergy analysis between pure CO₂ and mixture-based cycles in RBC architecture. The findings highlight the potential of custom-tailored working fluids to enhance thermodynamic performance and operational stability of s-CO₂ power systems under cold-climate conditions. Full article

To address the thermal protection challenges of multiple high-temperature components and the electrical power deficiency in hypersonic vehicles, this study proposes twelve multi-heat-source thermoelectric conversion schemes based on the sCO₂ Brayton cycle. A three-dimensional evaluation system for thermal management is established, incorporating thermal efficiency, coolant mass flow rate, and system mass as key metrics. A comprehensive parameter sensitivity analysis was conducted on the twelve dual-heat-source cycle configurations. For systematic performance comparison, the Non-dominated Sorting Genetic Algorithm II (NSGA-II) was employed for multi-objective optimization, with Pareto fronts analyzed to determine optimal configurations. The results demonstrate that appropriately increasing the minimum cycle temperature can significantly reduce coolant flow requirements. Multi-objective optimization reveals the following: (1) The pre-compressed aero-comb configuration achieves optimal performance in the efficiency-mass flow rate optimization scenario; (2) Both pre-compressed aero-comb and re-compressed comb-aero configurations show superiority in the efficiency-mass optimization scenario; (3) The pre-compressed aero-comb configuration exhibits lower system mass in low coolant flow regions for the mass flow rate-mass optimization scenario. Overall, the performance of the precompression aero-comb configuration is relatively superior. This work provides an important reference for the design of thermal management systems for hypersonic vehicles. Full article

Since the beginning of the 21st century, the supercritical carbon dioxide (sCO₂) Brayton cycle has emerged as a hot topic of research in the energy field. Among its key components, the sCO₂ compressor has received significant attention. In particular, axial-flow sCO₂ compressors are increasingly being investigated as power systems advance toward high power scaling. This paper reviews global research progress in this field. As for performance characteristics, currently, sCO₂ axial-flow compressors are mostly designed with large mass flow rates (>100 kg/s), near-critical inlet conditions, multistage configurations with relatively low stage pressure ratios (1.1–1.2), and high isentropic efficiencies (87–93%). As for internal flow characteristics, although similarity laws remain applicable to sCO₂ turbomachinery, the flow dynamics are strongly influenced by abrupt variations in thermophysical properties (e.g., viscosities, sound speeds, and isentropic exponents). High Reynolds numbers reduce frictional losses and enhance flow stability against separation but increase sensitivity to wall roughness. The locally reduced sound speed may induce shock waves and choke, while drastic variation in the isentropic exponent makes the multistage matching difficult and disperses normalized performance curves. Additionally, the quantitative impact of a near-critical phase change remains insufficiently understood. As for the experimental investigation, so far, it has been publicly shown that only the University of Notre Dame has conducted an axial-flow compressor experimental test, for the first stage of a 10 MW sCO₂ multistage axial-flow compressor. Although the measured efficiency is higher than that of all known sCO₂ centrifugal compressors, the inlet conditions evidently deviate from the critical point, limiting the applicability of the results to sCO₂ power cycles. As for design and optimization, conventional design methodologies for axial-flow compressors require adaptations to incorporate real-gas property correction models, re-evaluations of maximum diffusion (e.g., the DF parameter) for sCO₂ applications, and the intensification of structural constraints due to the high pressure and density of sCO₂. In conclusion, further research should focus on two aspects. The first is to carry out more fundamental cascade experiments and numerical simulations to reveal the complex mechanisms for the near-critical, transonic, and two-phase flow within the sCO₂ axial-flow compressor. The second is to develop loss models and design a space suitable for sCO₂ multistage axial-flow compressors, thus improving the design tools for high-efficiency and wide-margin sCO₂ axial-flow compressors. Full article

To investigate the operational characteristics of the supercritical carbon dioxide (S-CO₂) Brayton cycle and enhance its applicability in practical operating conditions for micro-scale reactors, an experimental platform for a recuperative S-CO₂ Brayton cycle is constructed and investigated. Several controllable operational parameters, including compressor pump frequency, expansion valve opening, and electric heating power, each intrinsically linked to the thermal characteristics of its corresponding equipment, as well as the cooling water flow rate, are systematically adjusted and analyzed. Experimental results demonstrate that the cooling water flow rate has a significantly greater impact on the temperature and pressure of the cycle system compared to other operational parameters. Based on these findings, steady-state experiments are conducted within a pressure range of 8 MPa to 15 MPa and a temperature range of 70 °C to 150 °C. It is observed that the heat exchange capacity of the recuperator decreases as the cooling water flow rate is reduced, suggesting that sufficient cooling efficiency is required to maximize the recuperative function. Under the condition of a maximum system temperature of 150 °C, the isentropic efficiency of the expansion valve decreases with an increase in the inlet pressure of the valve. However, the overall thermal efficiency of the cycle system requires further calculation and assessment following the optimization of the experimental platform. The result of validation of experimental results is less than 20%. The findings presented in this study offer essential data that encompass the potential operational conditions of the CO₂ Brayton cycle section applicable to small-scale reactors, thereby providing a valuable reference for the design and operation of practical cycle systems. Full article

The supercritical carbon dioxide Brayton cycle has been identified as being applicable in a wide variety of applications, and printed circuit heat exchangers (PCHEs) are widely used in these applications due to their good compactness and high thermal efficiency. A PCHE with hybrid-size unit channels has been proposed and found capable of improving the heat transfer performance, but most results were obtained at non-consistent total volume and mass flow rate. Therefore, given the space constraints of heat exchangers in supercritical CO₂ Brayton cycles, this study investigates the application of standard-size and hybrid-size unit channel configurations under different hot-to-cold fluid thermal resistance ratios while maintaining a fixed total volume and consistent total mass flow rate. The results demonstrate that the hybrid-size unit channel configuration fails to enhance heat transfer. The heat transfer rate per volume exhibits a marginal 5.2% reduction at smaller thermal resistance ratios and a drastic 28.9% degradation at larger thermal resistance ratios. The hybrid-size channel configuration significantly improves the pressure drop per unit length on the hot side, achieving maximum reductions of 80.3% and 79.7% under the two thermal resistance ratios, respectively. The enhancement magnitude on the hot side outweighs the increased pressure drop on the cold side. Simultaneously, the ratio of average heat transfer rate to total pumping power exhibits significant differences between the two channel configurations under varying thermal resistance ratios. Under scenarios with substantial thermal resistance disparities, the hybrid-size unit channel configuration achieves a maximum 356.2% improvement in the ratio compared to the identical-size unit channel configuration, whereas balanced thermal resistance ratios lead to a degradation in overall performance. Full article

In the context of central solar receiver systems, the utilisation of S-CO₂ Brayton cycles as opposed to Rankine cycles confers a number of advantages, including enhanced efficiency, the requirement for less sophisticated turbomachinery, and a reduction in water consumption. A pivotal consideration in the design of such systems pertains to the thermal storage system. This work undertakes a comparative analysis of the performance of an S-CO₂ Brayton cycle utilising two distinct types of molten salts, namely solar salts and chloride salts (MgCl₂–KCl), as the heat transfer fluid on the thermal energy storage medium. The present study adopts an energetic and exergetic perspective with the objective of identifying areas of high irreversibility and proposing mechanisms to reduce them. The work is concluded with an analysis of the size of the different components. The overall energy efficiency is determined as 22.29 % and 23.76 % for solar and chloride salts, respectively. In the case of chloride salts, this efficiency is penalized by the higher losses in the solar receiver due to the higher operating temperature. The exergy analysis shows that using MgCl₂–KCl salts increases exergy destruction in the recuperators, lowering irreversibilities in other components. While the sizes of all components decrease when using chloride salts, the volume of the storage system increases. These results demonstrate that the incorporation of MgCl₂–KCl salts enhances the performance of S-CO₂ recompression cycles operating in conjunction with a central solar receiver. Full article

Improvement of energy efficiency in technological processes at industrial enterprises is one of the key areas of energy saving. Reduction of energy costs required for the production of energy-intensive products can be achieved through the utilization of waste heat produced by high-temperature thermal furnace units. Generation of electric power based on the waste heat using power cycles with working fluids that are not conventional for large power engineering, may become a promising energy saving trend. In this paper, thermodynamic analysis and optimization of power cycles for the purposes of waste heat recovery are performed. The efficiency of combining several power cycles was also evaluated. It has been established that the combination of the Brayton recompression cycle on supercritical carbon dioxide with the organic Rankine cycle using R124 allows for greater electrical power than steam-power cycles with three pressure circuits under conditions where the gas temperature is in the range of 300–550 °C and the cooling temperature of is up to 80 °C. Additionally, when cooling gases with a high sulfur and moisture content to 150 °C, the combined cycle has greater electrical power at gas temperatures of 330 °C and above. At enterprises where the coolant has a high content of sulfur compounds or moisture and deep cooling of gases will lead to condensation, for example, at petrochemical and non-ferrous metallurgy enterprises, the use of combined cycles can ensure a utilization efficiency of up to 45%. Full article

This study proposes a supercritical carbon dioxide Brayton cycle incorporating multi-stage main compressor intermediate cooling (MMCIC sCO₂ Brayton cycle), and conducts an in-depth investigation and discussion on the enhancement of its thermodynamic performance. With the aim of achieving the maximum power cycle thermal efficiency and the maximum specific net work, this study examines the variation of the Pareto frontier with respect to the number of intermediate cooling stages and critical operational parameters. The results indicate that the MMCIC sCO₂ Brayton cycle offers significant advantages in improving power cycle thermal efficiency, reducing energy consumption, and mitigating the adverse effects associated with main compressor inlet temperature increasing. Under the investigated operational conditions, the optimal cycle performance is achieved with four intermediate cooling stages, yielding a maximum power cycle thermal efficiency of 67.85% and a maximum specific net work of 0.177 MW·kg⁻¹. Cycles with two or three intermediate cooling stages also deliver competitive cycle performance, and can be regarded as alternative options. Additionally, increasing the turbine inlet temperature proves more effective for enhancing power cycle thermal efficiency, whereas increasing the turbine inlet pressure can substantially improve the specific net work. This study provides a feasible structural layout approach and research framework to improve the thermodynamic performance of the sCO₂ Brayton cycle, offering a robust theoretical foundation and technical guidance for its implementation in power engineering. Full article

The Supercritical Carbon Dioxide Brayton Cycle (sCO₂-BC) is a highly efficient and eco-friendly alternative for marine propulsion. The adoption of sCO₂-BC aligns with the industry’s focus on sustainability and can help meet emission regulations. In this context, the current study introduces a cascade system that harnesses the exhaust gases from a marine Gas Turbine Propulsion System to serve as a heat source for a bottoming Supercritical Carbon Dioxide Brayton Cycle (sCO₂-BC), which facilitates an onboard heat recovery system. The investigation primarily focuses on the recompression cycle layouts of the sCO₂-BC. To assess the performance of the bottoming cycle layouts and the overall cascade system, various parameters of the recompression sCO₂-BC are analyzed. These parameters include the mass flow rate of CO₂ in the bottoming cycle and the effectiveness of both the low-temperature recuperator (LTR) and the high-temperature recuperator (HTR). For conducting the cycle simulations, two codes are built and integrated; this first code models the thermodynamic cycle, while the second code models the recuperators. The research shows that incorporating the sCO₂ Brayton Cycle as a bottoming cycle has the potential to greatly improve the efficiency of the entire system, increasing it from 54% to 59%. Therefore, it provides a useful framework for advancing energy-efficient gas turbine systems and future research. Full article

The corrosion of structural materials is a crucial issue of the application of supercritical carbon dioxide in the Brayton power cycle system. The oxidation and carburization behaviors of typical alloy materials in high-temperature CO₂ environments are studied based on thermodynamic analysis technology, including the analysis of the oxidation and carburization performance of the CO₂ atmosphere as well as the corrosion behaviors of alloy elements under 500 °C, 600 °C, and 650 °C. In addition, the oxide film characteristics of T91 and 800H alloys, including phase composition and morphology structure, are studied at 500 °C and 650 °C. Research has found that for the T91, FeCr₂O₄ and Fe₃O₄ can form a continuous oxide film layer with coverage and SiO₂, VO, and MnCr₂O₄ oxides are mainly in the inner layer of the oxide film. For the 800H, Cr₂O₃ and MnCr₂O₄ can form flakes of oxide film layers, while Al₂O₃, TiO₂, and SiO₂ are distributed as scattered grains near the interface between the oxide film and the matrix material. Both T91 and 800H will produce chromium carbides, which will reduce the toughness of the material. Full article

Small nuclear power plants are a promising direction of research for the development of carbon-free energy in isolated power systems and in remote regions with undeveloped infrastructure. Improving the efficiency of power units integrated with small modular reactors will improve the prospects for the commercialization of such projects. Power cycles based on supercritical carbon dioxide are an effective solution for nuclear power plants that use reactor facilities with an initial coolant temperature above 550 °C. However, the presence of low temperature rejected heat sources in closed Bryton cycles indicates a potential for energy saving. This paper presents a comprehensive thermodynamic analysis of the integration of an additional low-temperature organic Rankine cycle for heat recovery to supercritical carbon dioxide cycles. A scheme for sequential heat recovery from several sources in S-CO₂ cycles is proposed. It was found that the use of R134a improved the power of the low-temperature circuit. It was revealed that in the S-CO₂ Brayton cycle with a recuperator, the ORC add-on increased the net efficiency by an average of 2.98%, and in the recompression cycle by 1.7–2.2%. With sequential heat recovery in the recuperative cycle from the intercooling of the compressor and the main cooler, the increase in efficiency from the ORC superstructure will be 1.8%. Full article

The gas turbine is a crucial piece of equipment in the energy and power industry. The exhaust gas has a sufficiently high temperature to be recovered for energy cascade use. The supercritical carbon dioxide (S-CO₂) Brayton cycle is an advanced power system that offers benefits in terms of efficiency, volume, and flexibility. It may be utilized for waste heat recovery (WHR) in gas turbines. This study involved the design of a 5 MW S-CO₂ recompression cycle specifically for the purpose of operational control. The dynamic models for the printed circuit heat exchangers, compressors, and turbines were developed. The stability and dynamic behavior of the components were validated. The suggested control strategies entail utilizing the cooling water controller to maintain the compressor inlet temperature above the critical temperature of CO₂ (304.13 K). Additionally, the circulating mass flow rate is regulated to modify the output power, while the exhaust gas flow rate is controlled to ensure that the turbine inlet temperature remains within safe limits. The simulations compare the performance of PI controllers tuned using the SIMC rule and ADRC controllers tuned using the bandwidth method. The findings demonstrated that both controllers are capable of adjusting operating conditions and effectively suppressing fluctuations in the exhaust gas. The ADRC controllers exhibit a superior control performance, resulting in a 55% reduction in settling time under the load-tracking scenario. Full article

The supercritical carbon dioxide (S-CO₂) Brayton cycle efficiency increases as the compressor inlet condition approaches the critical point. However, the thermodynamic properties of CO₂ vary dramatically near the critical point, and phase change is most likely to happen. Both cavitation and condensation bring about significant adverse effects on the performance of compressors. In this paper, the quantitative effects of nonequilibrium condensation and cavitation on the performance of an S-CO₂ centrifugal compressor with different inlet-relative entropy values are investigated. The properties of CO₂ were provided by the real-gas property table, and the nonequilibrium phase-change model was adopted. The numerical simulation method with the nonequilibrium phase-change model was validated in the Lettieri nozzle and Sandia compressor. Furthermore, simulations were carried out in a two-stage centrifugal compressor under conditions of various inlet-relative entropy values. The type of nonequilibrium phase change can be distinguished by inlet-relative entropy. Cavitation makes the choke mass flow rate decrease due to the drop in the speed of sound. Condensation mainly occurs on the leading edge of the main blade at a large mass flow rate, but cavitation occurs on the splitter. The condensation is more evenly distributed on the main blade, but the cavitation is mainly centered on the leading edge. Full article

Printed circuit heat exchangers (PCHEs) are widely used as recuperators in the supercritical carbon dioxide (S-CO₂) Brayton cycle design. The variation of heat sources will have a great impact on the heat transfer effect of the recuperator. It is of interest to study the fast calculation of flow and heat transfer performance of PCHEs under different operating conditions to obtain the optimal comprehensive performance and provide guidance for the operation control strategy analysis. Herein, a fast calculation method is established through a one-dimensional model of a PCHE based on Modelica. The effects of working medium mass flow rate and inlet temperature on the flow and heat transfer process are analyzed from the three aspects of heat transfer rate, flow pressure drop, and comprehensive performance, and the mass flow rate matching optimization is realized. The results show that increased mass flow rate increases heat transfer rate and flow pressure drop. The efficiency evaluation coefficient (EEC) has a maximum value at which the mass flow rate values of the cold and hot channels are best matched, and the comprehensive performance is optimal. When the mass flow rate of the heat channel is 4.8 g/s, the maximum EEC is 1.42, corresponding to the mass flow rate of the cold channel, 4.2 g/s. Compared with the design condition, the heat transfer rate increases by 62.1%, and the total pump power increases by 14.2%. When the cold channel inlet temperature increases, EEC decreases rapidly, whereas EEC increases when the hot channel inlet temperature increases. The conclusions can provide theoretical support for the design and operation of PCHEs. Full article

Super-critical Carbon dioxide (s-CO₂) power plants are considered to be efficient and environmentally friendly compared to the traditional Rankine cycle-based steam power plants and Brayton cycle-based gas turbine power plants. In this work, the system design of a coal-fired 100 MWe double reheat s-CO₂ power plant is presented. The system is also optimized for efficiency with turbine inlet pressures and the recompression ratio as the variables. The components needed, mass flow rates of various streams and their pressures at various locations in the system have been established. The plant has been studied based on 1st and 2nd laws at full load and at part loads of 80%, 60% and 40%. Operating parameters such as mass flow rate, pressure and temperature have considerably changed in comparison to full load operation. It was also observed that the 1st law efficiency is 53.96%, 53.93%, 52.63% and 50% while the 2nd law efficiency is 51.88%, 51.86%, 50.61% and 48.1% at 100%, 80%, 60% and 40% loads, respectively. The power plant demonstrated good performance even at part loads, especially at 80% load, while the performance deteriorated at lower loads. At full load, the highest amount of exergy destruction is found in the main heater (36.6%) and re-heaters (23.2% and 19.6%) followed by the high-temperature recuperator (5.7%) and cooler (4.1%). Similar trends were observed for the part load operation. It has been found that the recompression ratio should be kept high (>0.5) at lower loads in order to match the performance at higher loads. Combustion and heat exchange due to finite temperature differences are the main causes of exergy destruction, followed by pressure drop. Full article