Search Results (28)

Biomass fluidized bed gasification technology has attracted significant attention due to its high efficiency and clean energy conversion capabilities. However, its industrial application has been limited by insufficient technological maturity. This paper systematically reviews the research progress on biomass fluidized bed gasification characteristics; compares the applicability of bubbling fluidized beds (BFBs), circulating fluidized beds (CFBs), and dual fluidized beds (DFBs); and highlights the comprehensive advantages of CFBs in large-scale production and tar control. The gas–solid flow characteristics within CFB reactors are highly complex, with factors such as fluidization velocity, gas–solid mixing homogeneity, gas residence time, and particle size distribution directly affecting syngas composition. However, experimental studies have predominantly focused on small-scale setups, failing to characterize the impact of flow dynamics on gasification reactions. Therefore, numerical simulation has become essential for in-depth exploration. Additionally, this study analyzes the influence of different gasification agents (air, oxygen-enriched, oxygen–steam, etc.) on syngas quality. The results demonstrate that oxygen–steam gasification eliminates nitrogen dilution, optimizes reaction kinetics, and significantly enhances syngas quality and hydrogen yield, providing favorable conditions for downstream processes such as green methanol synthesis. Based on the current research landscape, this paper employs numerical simulation to investigate oxygen–steam CFB gasification at a pilot scale (500 kg/h biomass throughput). The results reveal that under conditions of O₂/H₂O = 0.25 and 800 °C, the syngas H₂ volume fraction reaches 43.7%, with a carbon conversion rate exceeding 90%. These findings provide theoretical support for the industrial application of oxygen–steam CFB gasification technology. Full article

An Integrated Process Intensification (IPI) technology-based roadmap is proposed for the utilization of renewables (water, air and biomass/unavoidable waste) in the small-scale distributed production of the following primary products: electricity, H₂, NH₃, HNO₃ and symbiotic advanced (SX) fertilizers with CO₂ mineralization capacity to achieve negative CO₂ emission. Such a production platform is an integrated intensified biorefinery (IIBR), used as an alternative to large-scale centralized production which relies on green electricity and CCUS. Hence, the capacity and availability of the renewable biomass and unavoidable waste were examined. The critical elements of the IIBR include gasification/syngas production; syngas cleaning; electricity generation; and the conversion of clean syngas (which contains H₂, CO, CH₄, CO₂ and N₂) to the primary products using nonthermal plasma catalytic reactors with in situ NH₃ sequestration for SA fertilizers. The status of these critical elements is critically reviewed with regard to their techno-economics and suitability for industrial applications. Using novel gasifiers powered by a combination of CO₂, H₂O and O₂-enhanced air as the oxidant, it is possible to obtain syngas with high H₂ concentration suitable for NH₃ synthesis. Gasifier performances for syngas generation and cleaning, electricity production and emissions are evaluated and compared with gasifiers at 50 kWe and 1–2 MWe scales. The catalyst and plasma catalytic reactor systems for NH₃ production with or without in situ reactive sequestration are considered in detail. The performance of the catalysts in different plasma reactions is widely different. The high intensity power (HIP) processing of perovskite (barium titanate) and unary/binary spinel oxide catalysts (or their combination) performs best in several syntheses, including NH₃ production, NO_x from air and fertigation fertilizers from plasma-activated water. These catalysts can be represented as BaTi_1−vO_3−x{#}_yN_z (black, piezoelectric barium titanate, bp-{BTO}) and M⁽¹⁾_3−jM⁽²⁾_kO_4−m{#}_nN_r/SiO₂ (unary (k = 0) or a binary (k > 0) silane-coated SiO₂-supported spinel oxide catalyst, denoted as M/Si = X) where {#} infers oxygen vacancy. HIP processing in air causes oxygen vacancies, nitrogen substitution, the acquisition of piezoelectric state and porosity and chemical/morphological heterogeneity, all of which make the catalysts highly active. Their morphological evaluation indicates the generation of dust particles (leading to porogenesis), 2D-nano/micro plates and structured ribbons, leading to quantum effects under plasma catalytic synthesis, including the acquisition of high-energy particles from the plasma space to prevent product dissociation as a result of electron impact. M/Si = X (X > 1/2) and bp-{BTO} catalysts generate plasma under microwave irradiation (including pulsed microwave) and hence can be used in a packed bed mode in microwave plasma reactors with plasma on and within the pores of the catalyst. Such reactors are suitable for electric-powered small-scale industrial operations. When combined with the in situ reactive separation of NH₃ in the so-called Multi-Reaction Zone Reactor using NH₃ sequestration agents to create SA fertilizers, the techno-economics of the plasma catalytic synthesis of fertilizers become favorable due to the elimination of product separation costs and the quality of the SA fertilizers which act as an artificial root system. The SA fertilizers provide soil fertility, biodiversity, high yield, efficient water and nutrient use and carbon sequestration through mineralization. They can prevent environmental damage and help plants and crops to adapt to the emerging harsh environmental and climate conditions through the formation of artificial rhizosphere and rhizosheath. The functions of the SA fertilizers should be taken into account when comparing the techno-economics of SA fertilizers with current fertilizers. Full article

This research study explores the technology of biomass syngas production by using an experimental downdraft fixed-bed gasifier coupled to a two-cylinder engine, designed and implemented at the Polytechnic University of Valencia, Spain. Furthermore, it deals with the study of the experimental and analytical relations between the driving thermodynamic parameters that control the gasification process, in order to contribute to the development of a theoretical model for the design of a small-scale gasification facility. Different experiments have been performed to investigate the variations in parameters such as low heating values, the air–syngas ratio, the reduction and combustion temperature, efficiency, and electrical power generation during the continuous functioning of the gasification power production facility. The results obtained show that the low heating value is directly related to the inlet air flow rate, so that it increases when the air flow increases, while the increase in the inlet air flow of the gasifier makes both the reduction and the combustion temperature increase. Moreover, the efficiency of the motor–generator reaches a maximum value of 0.204 at the maximum power (around 5 kW), being characterized by an excellent operating range for the air–fuel ratio of a gasification facility. Full article

Despite being resource-richly endowed with various energy sources, and despite the connection of 89.8% of the households to the grid in South Africa, the Eastern Cape province, as compared to other provinces, has the lowest level of grid connection of about 64.5%. Some of the rural poor households in the Eastern Cape province supplement their free basic electricity with unclean energy alternatives. Using unclean energy alternatives is not only detrimental to the environment and health of the people, but it is a sign of energy poverty and among the contributing factors to depesantization, deagrarianization, and deindustrialization which prolongs the underdevelopment in rural areas. Innovation in energy technologies is a key ingredient in meaningful rural development. The utilization of small-scale biomass gasification technologies can be a solution to the South African energy crisis in rural areas, and it is in line with sustainable development goal number 7, which is about ensuring access to affordable, reliable, sustainable, and modern energy for all. Alternative renewable energy sources cannot be ignored when dealing with the energy crises in South Africa. Renewable energy sources in the country include biomass, solar, wind, and hydropower. Despite its low utilization in the Eastern Cape province, small-scale biomass gasification technology remains pivotal in reducing energy crisis by producing electricity. However, the affordability of biomass gasification technology also plays a role in whether people will accept small-scale biomass gasification technology. The purpose of this paper is to determine the possibilities of using small-scale biomass gasification technology. This paper gives a comprehensive review of small-scale biomass gasification technology potential in the Eastern Cape province and the link between acceptance of small-scale gasification technology and affordability by evaluating the availability of biomass sources in the province and achievements with regards to small-scale biomass gasification. This paper also covers the impact of biomass gasification technology integration in the energy grid, what needs to be taken into consideration before its installation, its benefits and the barriers to its development in Eastern Cape province. Full article

Biomass gasification, a promising sustainable technology for decentralized electricity production, has the potential to displace fossil fuels while valorizing locally produced waste. Previous studies indicate that its technical and financial viabilities vary among projects, and few projects have been successfully developed, despite the sustainability benefits. This study identified and characterized the factors that influence the economic and environmental performances of such projects using a novel, hybrid method, with qualitative analysis using the Business Model Canvas and quantitative life-cycle costs (LCCs) considering the financial and external costs. The financial LCCs and external electricity generation costs were evaluated for business models in agro-industrial factories using proprietary residual biomasses and for those in isolated grids using local agricultural waste. The business models used for biomass gasification projects affect their LCCs and externalities more than factors such as their investment costs and energy efficiencies. The relationship between the business models, the financial performances of the projects, and their impacts on society are highlighted, showing that although projects using proprietary biomass waste have lower financial costs, off-grid projects generate more positive externalities, resulting in lower costs for society. These results indicate that policy support focused on appropriate business models may contribute to optimizing the use of financial incentives to foster investment in new sustainable technologies, contributing to the energy transition. Full article

The fermentation of syngas is an attractive technology that can be integrated with gasification of lignocellulosic biomass. The coupling of these two technologies allows for treating a great variety of raw materials. Lignin usually hinders microbial fermentations; thus, the thermal decomposition of the whole material into small molecules allows for the production of fuels and other types of molecules using syngas as substrate, a process performed at mild conditions. Syngas contains mainly hydrogen, carbon monoxide, and carbon dioxide in varying proportions. These gases have a low volumetric energy density, resulting in a more interesting conversion into higher energy density molecules. Syngas can be transformed by microorganisms, thus avoiding the use of expensive catalysts, which may be subject to poisoning. However, the fermentation is not free of suffering from inhibitory problems. The presence of trace components in syngas may cause a decrease in fermentation yields or cause a complete cessation of bacteria growth. The presence of tar and hydrogen cyanide are just examples of this fermentation’s challenges. Syngas cleaning impairs significant restrictions in technology deployment. The technology may seem promising, but it is still far from large-scale application due to several aspects that still need to find a practical solution. Full article

This multi-disciplinary paper aims to provide a roadmap for the development of an integrated, process-intensified technology for the production of H₂, NH₃ and NH₃-based symbiotic/smart fertilizers (referred to as target products) from renewable feedstock with CO₂ sequestration and utilization while addressing environmental issues relating to the emerging Food, Energy and Water shortages as a result of global warming. The paper also discloses several novel processes, reactors and catalysts. In addition to the process intensification character of the processes used and reactors designed in this study, they also deliver novel or superior products so as to lower both capital and processing costs. The critical elements of the proposed technology in the sustainable production of the target products are examined under three-sections: (1) Materials: They include natural or synthetic porous water absorbents for NH₃ sequestration and symbiotic and smart fertilizers (S-fertilizers), synthesis of plasma interactive supported catalysts including supported piezoelectric catalysts, supported high-entropy catalysts, plasma generating-chemical looping and natural catalysts and catalysts based on quantum effects in plasma. Their performance in NH₃ synthesis and CO₂ conversion to CO as well as the direct conversion of syngas to NH₃ and NH₃—fertilizers are evaluated, and their mechanisms investigated. The plasma-generating chemical-looping catalysts (Catalysts, 2020, 10, 152; and 2016, 6, 80) were further modified to obtain a highly active piezoelectric catalyst with high levels of chemical and morphological heterogeneity. In particular, the mechanism of structure formation in the catalysts BaTi_1−rM_rO_3−x−y{#}_xN_z and M₃O_4−x−y{#}_xN_z/Si = X was studied. Here, z = 2y/3, {#} represents an oxygen vacancy and M is a transition metal catalyst. (2) Intensified processes: They include, multi-oxidant (air, oxygen, CO₂ and water) fueled catalytic biomass/waste gasification for the generation of hydrogen-enriched syngas (H₂, CO, CO₂, CH₄, N₂); plasma enhanced syngas cleaning with ca. 99% tar removal; direct syngas-to-NH₃ based fertilizer conversion using catalytic plasma with CO₂ sequestration and microwave energized packed bed flow reactors with in situ reactive separation; CO₂ conversion to CO with BaTiO_3−x{#}_x or biochar to achieve in situ O₂ sequestration leading to higher CO₂ conversion, biochar upgrading for agricultural applications; NH₃ sequestration with CO₂ and urea synthesis. (3) Reactors: Several patented process-intensified novel reactors were described and utilized. They are all based on the Multi-Reaction Zone Reactor (M-RZR) concept and include, a multi-oxidant gasifier, syngas cleaning reactor, NH₃ and fertilizer production reactors with in situ NH₃ sequestration with mineral acids or CO₂. The approach adopted for the design of the critical reactors is to use the critical materials (including natural catalysts and soil additives) in order to enhance intensified H₂ and NH₃ production. Ultimately, they become an essential part of the S-fertilizer system, providing efficient fertilizer use and enhanced crop yield, especially under water and nutrient stress. These critical processes and reactors are based on a process intensification philosophy where critical materials are utilized in the acceleration of the reactions including NH₃ production and carbon dioxide reduction. When compared with the current NH₃ production technology (Haber–Bosch process), the proposed technology achieves higher ammonia conversion at much lower temperatures and atmospheric pressure while eliminating the costly NH₃ separation process through in situ reactive separation, which results in the production of S-fertilizers or H₂ or urea precursor (ammonium carbamate). As such, the cost of NH₃-based S-fertilizers can become competitive with small-scale distributed production platforms compared with the Haber–Bosch fertilizers. Full article

Among decentralized small-scale biomass energy sources with the potential to revitalize local communities, combined heat and power (CHP) from gasification is promising in terms of its high power generation efficiency. Still, it has yet to achieve operational stability, in part due to the variation in the moisture content of the woodchips used as fuel. In this study, a technical and economic evaluation was performed to establish a center for the efficient production of high-quality dry woodchips within a sawmill and to determine the technical characteristics and economic viability of a system using gasification CHP, wood waste-fired boilers or an organic Rankine cycle (ORC) as heat sources. The results showed that the net present values (NPVs) of gasified CHP, wood waste-fired boilers and ORC were −186 million, −402 million, and −103 million JPY, respectively. None of them were deemed profitable. Therefore, a sensitivity analysis was performed to determine the impact of low-quality wood prices, dry woodchips, heavy oil A, and the grid electricity charge on the NPV. The improvement of the low-quality wood price and dry woodchips sales price was effective for heat supply by gasification CHP and ORC turbines, and their combination was effective for woodchip-fired boilers. Full article

The combustion of solid biomass in industrial boilers involves a sequence of processes that include heating, drying, devolatilization, and char conversion. To maintain a repeatable and fully controlled environment, and to monitor all the dynamics involved in the phenomena at a real scale, field-scale experiments become necessary to perform investigations. In this way, to evaluate different thermochemical conversion conditions of biomass particles under an oxidative atmosphere, and to quantify the emission of the main gas compounds continuously, a small-scale reactor was developed and presented in this paper. Hence, in this work, larger particles of eucalyptus are burned at 400 and 800 °C under different stoichiometric conditions to understand the differences between different biomass conversion regimes (gasification and combustion). The analysis of the mass loss at the different temperatures was characterized by only two different and consecutive stages for both thermochemical conditions. The first region does not present the influence on the air flow rate; however, there is a significant difference in the second region. This fact highlighted the importance of the diffusion of oxygen during the char conversion. Regarding the quantification of the gas compounds, an increase of around 3 times in the CO and CO₂ emissions when gasification occurs was observed at 400 °C. However, at 800 °C, the same trend was verified, also verifying a considerable amount of CH₄. Full article

The utilization of new and renewable energy sources explicitly based on biomass needs to be increased to reduce dependence on fossil fuels. One of the potential biomasses of plantation waste in Indonesia that can be utilized is oil palm plantation waste in the form of fronds and trunks that are converted with multi-stage downdraft gasification technology. This study aimed to conduct a technical analysis, economic analysis, investment risk analysis, social analysis, and an environmental impact assessment of power plants fueled by oil palm plantation waste. The method used was the upscaling of a prototype of a 10 kW power plant to 100 kW. The results showed that it was technically and economically feasible to apply. The economic indicators were a positive NPV of USD 48.846 with an IRR of 9.72% and a B/C ratio of 1.16. The risk analysis predicted a probability of an NPV 49.94% above the base case. The study of the social aspects suggested that the construction of power plants has a positive impact in the form of increased community income and the growth of new economic sectors that utilize electricity as a primary source. An analysis of the environmental effects is critical so that the impacts can be minimized. Overall, the construction of small-scale power plants in oil palm plantations is worth considering as long as it is carried out following the applicable regulations. Full article

Literature and manuals refer to biomass gasification as one of the most efficient processes for power generation, highlighting features, such as residual biomass use, distributed generation and carbon sequestration, that perfectly incorporate gasification into circular economies and sustainable development goals. Despite these features, small scale applications struggle to succeed as a leading solution for sustainable development. The aim of this review is to investigate the existing technological barriers that limit the spreading of biomass gasification from a socio-technical point of view. The review outlines how existing technologies originated from under feed-in-tariff regimes and highlights where the current design goals strongly differ from what will be needed in the near future. Relevant market-ready small-scale gasification systems are analyzed under this lens, leading to an analysis of the reactor and filtration design. To help understand the economical sustainability of these plants, an analysis of the influence of capital expenditures and operating expenditures on the return of investment is included in the discussion. Finally, a literature review on prototypes and pre-market reactors is used as a basis for spotting the characteristics of the system that will likely resolve issues around fuel flexibility, cost efficiency and load variability. Full article

The accumulation of biomass fuels resulting from the growth of heliophilous shrubs and small tree species at the edge of forests and on scrub and pasture lands contributes to the increased risk of rural fires in Mediterranean climate regions. This situation has been managed with a set of legislative measures launched with the objective of promoting cleaning and the control of these species. Areas of scrub and pasture already constitute the largest part of the annually burnt area in Portugal, resulting in high-intensity fires. In the present study, shrubs and small tree species were characterized in the laboratory. Thermogravimetric, chemical and calorimetric analyses for the evaluation of the potential for the energy recovery of the selected species were carried out. It was observed that energetic valorization (i.e., to enhance the value by planned actions) of these species is difficult because they present high levels of ash and metals, becoming prone to the occurrence of fouling and slagging phenomena. Thus, the creation of value chains that justify the incorporation of these materials becomes very difficult, except if used in non-certified, small-scale and locally based processes. The possibility of recovery through thermochemical conversion processes, such as torrefaction, pyrolysis or gasification, must be studied so that more efficient and feasible recovery alternatives can be found, allowing for the creation of value chains for these residual materials to promote their sustainable management and, thus, mitigate the risk of rural fires occurring. Full article

Its relatively low cost and high surface area makes activated carbon an ideal adsorbent candidate for H₂S removal. However, physical adsorption of H₂S is not very effective; therefore, methods to facilitate reactive H₂S oxidation on carbons are of interest. The performance of H₂S removal of non-impregnated, impregnated, and doped activated carbon in low-temperature syngas was evaluated in fixed-bed breakthrough tests. The importance of oxygen content and relative humidity was established for reactive H₂S removal. Impregnates especially improved the adsorption rate compared to non-impregnated carbons. Non-impregnated carbons could however retain a high capture capacity with sufficient contact time. In a relative performance test, the best performance was achieved by doped activated carbon, 320 mg g⁻¹. Ammonia in syngas was found to significantly improve the adsorption rate of non-impregnated activated carbon. A small quantity of ammonia was consumed by the carbon bed, suggesting that ammonia is a reactant. Finally, to validate ammonia-enhanced desulfurization, bench-scale experiments were performed in biomass-based gasification syngas. The results show that when the ammonia concentration in syngas was in the tens of ppm range, 40–160 ppm H₂S oxidation proceeded rapidly. Ammonia-enhanced oxidation allows utilization of cheaper non-impregnated activated carbons by in situ improvement of the adsorption kinetics. Ammonia enhancement is therefore established as a viable method for achieving high-capacity H₂S removal with unmodified activated carbons. Full article

Tanzania has a high rural population, of which many rely on off-grid diesel generators to produce electricity. The focus of this paper is to assess if the waste biomass residues in Tanzania have sufficient energy potential to produce renewable electrical energy for small-scale electricity generation using off-grid diesel generators coupled with anaerobic digestion (AD) and/or gasification. The gaseous fuel produced can then be used to substitute diesel fuel used in small-scale dual fuel diesel gen-sets; thus, providing more affordable electricity whilst reducing dependency on fossil fuels. The biomass waste streams estimated are those arising from agriculture, forestry, livestock, and urban human waste. To answer this question, the energy potentials of each of these biomass waste streams are quantified, followed by further calculations to determine the electricity generation capacity per stream based on overall efficiencies of 10 and 25%. The results show that combined these waste streams have an energy potential of 385 PJ (for the base year of 2018) generated from 26,924 kilotonnes (kt). Collectively, these residues can produce at least 1.2 times the electricity generated nationally in 2018 using AD and gasification coupled with a diesel gen-set engine. Full article

Torrefaction used in combination with pelletization is a promising technology to upgrade solid biofuels and has been demonstrated worldwide. In comparison with normal biomass pellets, which disintegrate under wet conditions, one of the advantages of torrefied biomass pellets is better water resistance. An understanding of the differences in water proof properties for torrefied biomass pellets by different production schemes can promote their further application. In the communication, various torrefied pellets were exposed to indoor and outdoor conditions, and changes in moisture content and diameter were examined. Two production schemes for the torrefied pellets were used for comparison: the torrefaction of wood chips followed by pelletization (pre-torrefaction) and the pelletization of wood chips followed by torrefaction (post-torrefaction). It was found that the post-torrefied pellets had much lower moisture levels than the pre-torrefied pellets in both indoor and outdoor tests. In the outdoor test with no-roof condition, the rate of increase in moisture content for the pre-torrefied pellets was more than double that for the post-torrefied pellets, and the post-torrefied pellets exhibited almost no diameter change. The results on the superior water resistance of post-torrefied pellets were nearly consistent with those reported in previous literature. Torrefied pellets have been considered for industrial use, such as in co-combustion and gasification on a large scale. Taking advantage of the different water resistances, torrefied pellets could also be used by personal and community consumers on a small scale for long-term indoor and outdoor storages as advanced solid biofuels with high waterproof performance, energy density, and lower biodegradation. Full article