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Keywords = situative learning

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26 pages, 15315 KB  
Article
Machine and Deep Learning Framework for Sargassum Detection and Fractional Cover Estimation Using Multi-Sensor Satellite Imagery
by José Manuel Echevarría-Rubio, Guillermo Martínez-Flores and Rubén Antelmo Morales-Pérez
Data 2025, 10(11), 177; https://doi.org/10.3390/data10110177 (registering DOI) - 1 Nov 2025
Abstract
Over the past decade, recurring influxes of pelagic Sargassum have posed significant environmental and economic challenges in the Caribbean Sea. Effective monitoring is crucial for understanding bloom dynamics and mitigating their impacts. This study presents a comprehensive machine learning (ML) and deep learning [...] Read more.
Over the past decade, recurring influxes of pelagic Sargassum have posed significant environmental and economic challenges in the Caribbean Sea. Effective monitoring is crucial for understanding bloom dynamics and mitigating their impacts. This study presents a comprehensive machine learning (ML) and deep learning (DL) framework for detecting Sargassum and estimating its fractional cover using imagery from key satellite sensors: the Operational Land Imager (OLI) on Landsat-8 and the Multispectral Instrument (MSI) on Sentinel-2. A spectral library was constructed from five core spectral bands (Blue, Green, Red, Near-Infrared, and Short-Wave Infrared). It was used to train an ensemble of five diverse classifiers: Random Forest (RF), K-Nearest Neighbors (KNN), XGBoost (XGB), a Multi-Layer Perceptron (MLP), and a 1D Convolutional Neural Network (1D-CNN). All models achieved high classification performance on a held-out test set, with weighted F1-scores exceeding 0.976. The probabilistic outputs from these classifiers were then leveraged as a direct proxy for the sub-pixel fractional cover of Sargassum. Critically, an inter-algorithm agreement analysis revealed that detections on real-world imagery are typically either of very high (unanimous) or very low (contentious) confidence, highlighting the diagnostic power of the ensemble approach. The resulting framework provides a robust and quantitative pathway for generating confidence-aware estimates of Sargassum distribution. This work supports efforts to manage these harmful algal blooms by providing vital information on detection certainty, while underscoring the critical need to empirically validate fractional cover proxies against in situ or UAV measurements. Full article
(This article belongs to the Section Spatial Data Science and Digital Earth)
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57 pages, 9699 KB  
Review
Detection of Protein and Metabolites in Cancer Analyses by MALDI 2000–2025
by Dorota Bartusik-Aebisher, Daniel Roshan Justin Raj and David Aebisher
Cancers 2025, 17(21), 3524; https://doi.org/10.3390/cancers17213524 (registering DOI) - 31 Oct 2025
Abstract
Cancer metabolomics has become a powerful way of understanding tumor biology, identifying biomarkers and metabolites, and helping precision oncology. Matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS), among many other analytical platforms, has gained popularity over the past two and a half decades due to [...] Read more.
Cancer metabolomics has become a powerful way of understanding tumor biology, identifying biomarkers and metabolites, and helping precision oncology. Matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS), among many other analytical platforms, has gained popularity over the past two and a half decades due to its unique ability of directly analyzing metabolites in tissue with spatial resolution. This review will study 2000–2025 MALDI-based strategies for cancer metabolite detection, spanning from early proof-of-concept protein profiling to the development of high-resolution MALDI-MS imaging (MALDI-MSI), which is capable of mapping thousands of metabolites at near single-cell resolution. Its applications include the differentiation of tumor versus normal tissue, discovery of stage and subtype specific biomarkers, mapping of metabolic heterogeneity, and the visualization of drug metabolism in situ. Breakthrough technological milestones, such as the advanced matrices, on-tissue derivatization, MALDI-2 post-ionization, and the integration with Orbitrap or Fourier-transform ion cyclotron resonance (FT-ICR) platforms, have significantly improved the overall sensitivity, metabolite coverage, and spatial fidelity. Clinically, MALDI-MS has shown its purpose in breast, prostate, colorectal, lung, and liver cancers by providing metabolic fingerprints that are linked to tumor microenvironments, hypoxia, and therapeutic response. However, challenges such as the inclusion of matrix interface with low-mass metabolites, limited quantitation, ion suppression, and the lack of standardized procedures do not yet allow for the transition from translation to routine diagnostics. Even with these hurdles, the future of MALDI-MS in oncology remains in a good position with major advancements in multimodal imaging, machine learning-based data integration, portable sampling devices, and clinical validation studies that are pushing the field towards precision treatment. Full article
(This article belongs to the Special Issue New Biomarkers in Cancers 2nd Edition)
29 pages, 10037 KB  
Article
Assessing the Feasibility of Satellite-Based Machine Learning for Turbidity Estimation in the Dynamic Mersey Estuary (Case Study: River Mersey, UK)
by Deelaram Nangir, Manolia Andredaki and Iacopo Carnacina
Remote Sens. 2025, 17(21), 3617; https://doi.org/10.3390/rs17213617 (registering DOI) - 31 Oct 2025
Abstract
The monitoring of turbidity in estuarine environments is a challenging essential task for managing water quality and ecosystem health. This study focuses on the lower reaches of the River Mersey, Liverpool. Harmonized Sentinel-2 MSI Level-2A imagery was integrated with in situ measurements from [...] Read more.
The monitoring of turbidity in estuarine environments is a challenging essential task for managing water quality and ecosystem health. This study focuses on the lower reaches of the River Mersey, Liverpool. Harmonized Sentinel-2 MSI Level-2A imagery was integrated with in situ measurements from seven Environment Agency monitoring stations for two consecutive years (January 2023–January 2025). The workflow included image preprocessing, spectral index calculation, and the application of four machine learning algorithms: Gradient Boosting Regressor, XGBoost, Support Vector Regressor, and K-Nearest Neighbors. Among these, Gradient Boosting Regressor achieved the highest predictive accuracy (R2 = 0.84; RMSE = 15.0 FTU), demonstrating the suitability of ensemble tree-based methods for capturing non-linear interactions between spectral indices and water quality parameters. Residual analysis revealed systematic errors linked to tidal cycles, depth variation, and salinity-driven stratification, underscoring the limitations of purely data-driven approaches. The novelty of this study lies in demonstrating the feasibility and proof-of-concept of using machine learning to derive spatially explicit turbidity estimates under data-limited estuarine conditions. These results open opportunities for future integration with Computational Fluid Dynamics models to enhance temporal forecasting and physical realism in estuarine monitoring systems. The proposed methodology contributes to sustainable coastal management, pollution monitoring, and climate resilience, while offering a transferable framework for other estuaries worldwide. Full article
24 pages, 6272 KB  
Article
A New Methodology for Medium-Term Wind Speed Forecasting Using Wave, Oceanographic and Meteorological Predictor Variables
by Diego Sánchez-Pérez, Juan José Cartelle Barros and José A. Orosa
Appl. Sci. 2025, 15(21), 11639; https://doi.org/10.3390/app152111639 (registering DOI) - 31 Oct 2025
Viewed by 18
Abstract
Onshore and offshore wind energy are two of the best options from an environmental point of view. Nevertheless, the volatile and intermittent nature of the wind resource hampers its integration into the power system. Accurate wind speed forecasting facilitates the operation of the [...] Read more.
Onshore and offshore wind energy are two of the best options from an environmental point of view. Nevertheless, the volatile and intermittent nature of the wind resource hampers its integration into the power system. Accurate wind speed forecasting facilitates the operation of the electric grid, guaranteeing its stability and safety. However, most existing studies focus on very-short- and short-term time horizons, typically ranging from a few minutes to six hours, and rely exclusively on data measured at the prediction site. In contrast, only a few works address medium-term horizons or incorporate offshore data. Therefore, the main objective of this study is to predict medium-term (24 h ahead) onshore wind speed using the most influential offshore predictors, which are water surface temperature, atmospheric pressure, air temperature, wave direction, and spectral significant height. A new methodology based on twenty-seven machine learning regression models was developed and compared using the root mean squared error (RMSE) as the main evaluation metric. Unlike most existing studies that focus on very-short- or short-term horizons (typically below 6 h), this work addresses the medium-term (24 h ahead) forecast. After hyperparameter tuning, the CatBoost regressor achieved the best performance, with a root mean squared error of 2.06 m/s and a mean absolute error of 1.62 m/s—an improvement of around 40% compared to the simplest regression models. This approach opens new possibilities for wind speed estimation in regions where in situ measurements are not available. This will potentially reduce the cost, time, and environmental impacts derived from onshore wind resource characterisation campaigns. It also serves as a basis for future applications using combined offshore data from several locations. Full article
(This article belongs to the Special Issue Advances in AI and Multiphysics Modelling)
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26 pages, 3341 KB  
Review
A Comprehensive Review of Rubber Contact Mechanics and Friction Theories
by Raffaele Stefanelli, Gabriele Fichera, Andrea Genovese, Guido Napolitano Dell’Annunziata, Aleksandr Sakhnevych, Francesco Timpone and Flavio Farroni
Appl. Sci. 2025, 15(21), 11558; https://doi.org/10.3390/app152111558 - 29 Oct 2025
Viewed by 160
Abstract
This review surveys theoretical frameworks developed to describe rubber contact and friction on rough surfaces, with a particular focus on tire–road interaction. It begins with classical continuum approaches, which provide valuable foundations but show limitations when applied to viscoelastic materials and multiscale roughness. [...] Read more.
This review surveys theoretical frameworks developed to describe rubber contact and friction on rough surfaces, with a particular focus on tire–road interaction. It begins with classical continuum approaches, which provide valuable foundations but show limitations when applied to viscoelastic materials and multiscale roughness. More recent formulations are then examined, including the Klüppel–Heinrich model, which couples fractal surface descriptions with viscoelastic dissipation, and Persson’s theory, which applies a statistical mechanics perspective and later integrates flash temperature effects. Grosch’s pioneering experimental work is also revisited as a key empirical reference linking friction, velocity, and temperature. A comparative discussion highlights the ability of these models to capture scale-dependent contact and energy dissipation while also noting practical challenges such as calibration requirements, parameter sensitivity, and computational costs. Persistent issues include the definition of cutoff criteria for roughness spectra, the treatment of adhesion under realistic operating conditions, and the translation of detailed power spectral density (PSD) data into usable inputs for predictive models. The review emphasizes progress in connecting material rheology, surface characterization, and operating conditions but also underscores the gap between theoretical predictions and real tire–road performance. Bridging this gap will require hybrid approaches that combine physics-based and data-driven methods, supported by advances in surface metrology, in situ friction measurements, and machine learning. Overall, the paper provides a critical synthesis of current models and outlines future directions toward more predictive and application-oriented tire–road friction modeling. Full article
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27 pages, 4440 KB  
Review
MoS2-Based Composites for Electrochemical Detection of Heavy Metal Ions: A Review
by Baizun Cheng, Hongdan Wang, Shouqin Xiang, Shun Lu and Bingzhi Ren
Nanomaterials 2025, 15(21), 1639; https://doi.org/10.3390/nano15211639 - 27 Oct 2025
Viewed by 387
Abstract
Heavy metal ions (HMIs) threaten ecosystems and human health due to their carcinogenicity, bioaccumulativity, and persistence, demanding highly sensitive, low-cost real-time detection. Electrochemical sensing technology has gained significant attention owing to its rapid response, high sensitivity, and low cost. Molybdenum disulfide (MoS2 [...] Read more.
Heavy metal ions (HMIs) threaten ecosystems and human health due to their carcinogenicity, bioaccumulativity, and persistence, demanding highly sensitive, low-cost real-time detection. Electrochemical sensing technology has gained significant attention owing to its rapid response, high sensitivity, and low cost. Molybdenum disulfide (MoS2), with its layered structure, tunable bandgap, and abundant edge active sites, demonstrates significant potential in the electrochemical detection of heavy metals. This review systematically summarizes the crystal structure characteristics of MoS2, various preparation strategies, and their mechanisms for regulating electrochemical sensing performance. It particularly explores the cooperative effects of MoS2 composites with other materials, which effectively enhance the sensitivity, selectivity, and detection limits of electrochemical sensors. Although MoS2-based materials have made significant progress in theoretical and applied research, practical challenges remain, including fabrication process optimization, interference from complex-matrix ions, slow trace-metal enrichment kinetics, and stability issues in flexible devices. Future work should focus on developing efficient, low-cost synthesis methods, enhancing interference resistance through microfluidic and biomimetic recognition technologies, optimizing composite designs, resolving interfacial reaction dynamics via in situ characterization, and establishing structure–property relationship models using machine learning, ultimately promoting practical applications in environmental monitoring, food safety, and biomedical fields. Full article
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23 pages, 4351 KB  
Article
Upscaling of Soil Moisture over Highly Heterogeneous Surfaces and Validation of SMAP Product
by Jiakai Qin, Zhongli Zhu, Qingxia Wu, Julong Ma, Shaomin Liu, Linna Chai and Ziwei Xu
Land 2025, 14(10), 2098; https://doi.org/10.3390/land14102098 - 21 Oct 2025
Viewed by 290
Abstract
Soil moisture (SM) is a critical component of the global water cycle, profoundly influencing carbon fluxes and energy exchanges between the land surface and the atmosphere. NASA’s Soil Moisture Active/Passive (SMAP) mission provides soil moisture products at the global scale; however, validation of [...] Read more.
Soil moisture (SM) is a critical component of the global water cycle, profoundly influencing carbon fluxes and energy exchanges between the land surface and the atmosphere. NASA’s Soil Moisture Active/Passive (SMAP) mission provides soil moisture products at the global scale; however, validation of SMAP faces significant challenges due to scale mismatches between in situ measurements and satellite pixels, particularly in highly heterogeneous regions such as the Qinghai–Tibet Plateau. This study leverages high-spatiotemporal-resolution Harmonized Landsat–Sentinel-2 (HLS v2.0) data and the QLB-NET observation network, employing multiple machine learning models to generate pixel-scale ground-truth soil moisture from in situ measurements. The results indicate that XGBoost performs best (R = 0.941, RMSE = 0.047 m3/m3), and SHAP analysis identifies elevation and DOY as the primary drivers of the spatial patterns and dynamics of soil moisture. The XGBoost-upscaled soil moisture was employed as a validation benchmark to assess the accuracy of the SMAP 9 km and 36 km products, with the following key findings: (1) the proposed upscaling method effectively bridges the scale gap, yielding a correlation of 0.858 between the 36 km SMAP product and the pixel-scale soil moisture reference derived from XGBoost, surpassing the 0.818 correlation obtained using the traditional in situ averaging approach; (2) descending-orbit data generally outperform ascending-orbit data. In the 9 km SMAP product, 15 descending-orbit grids meet the scientific standard, compared to 10 ascending-orbit grids. For the 36 km product, only descending orbits satisfy the scientific standard. Full article
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18 pages, 1181 KB  
Article
Application of Remote Sensing for the Detection and Monitoring of Microplastics in the Coastal Zone of the Colombian Caribbean
by Ana Carolina Torregroza-Espinosa, Iván Portnoy, Rodney Correa-Solano, David Alejandro Blanco-Álvarez, Ana María Echeverría-González and Luis Carlos González-Márquez
Microplastics 2025, 4(4), 77; https://doi.org/10.3390/microplastics4040077 - 21 Oct 2025
Viewed by 386
Abstract
Microplastic pollution in marine environments represents a significant ecological threat due to its persistence and harmful effects on biodiversity and human health. In Colombia, coastal ecosystems (particularly in La Guajira) have exhibited increasing microplastic concentrations, but systematic monitoring remains limited. This study explored [...] Read more.
Microplastic pollution in marine environments represents a significant ecological threat due to its persistence and harmful effects on biodiversity and human health. In Colombia, coastal ecosystems (particularly in La Guajira) have exhibited increasing microplastic concentrations, but systematic monitoring remains limited. This study explored the application of remote sensing, including multispectral satellite imagery (Sentinel-2) and machine learning algorithms, to detect and monitor microplastics in the coastal zone of Riohacha, La Guajira. To inform the model selection and ensure methodological relevance, a focused systematic literature review was conducted, serving as a foundational step in identifying effective remote sensing strategies and machine learning algorithms previously applied to microplastic detection in aquatic environments. Moreover, microplastic samples were collected from four coastal sites on Riohacha’s coast and analyzed via Fourier transform infrared spectroscopy (FTIR), while environmental parameters were recorded in situ. The remote sensing data were processed and integrated with field observations to train linear regression, random forest, and artificial neural network (ANN) models. The ANN model achieved the highest accuracy (MAE = 0.040; RMSE = 0.071), outperforming the other models in estimating the microplastic concentrations. Based on these results, environmental risk maps were generated, identifying critical zones of pollution. The findings support the integration of remote sensing tools and field data for scalable, cost-efficient microplastic monitoring, offering a methodological framework for marine pollution assessment in Colombia and other developing coastal regions. Full article
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47 pages, 2233 KB  
Review
Synergistic Approaches for Navigating and Mitigating Agricultural Pollutants
by Swati Srivastava, Dheeraj Raya, Rajni Sharma, Shiv Kumar Giri, Kanu Priya, Anil Kumar, Gulab Singh and Saurabh Sudha Dhiman
Pollutants 2025, 5(4), 37; https://doi.org/10.3390/pollutants5040037 - 20 Oct 2025
Viewed by 309
Abstract
The alarming increase in the use of chemically driven pesticides for enhanced crop productivity has severely affected soil fertility, ecosystem balance, and consumer health. Inadequate handling protocols and ineffective remediation strategies have led to elevated pesticide concentrations, contributing to human respiratory and metabolic [...] Read more.
The alarming increase in the use of chemically driven pesticides for enhanced crop productivity has severely affected soil fertility, ecosystem balance, and consumer health. Inadequate handling protocols and ineffective remediation strategies have led to elevated pesticide concentrations, contributing to human respiratory and metabolic disorders in humans. In the current context, where agricultural activities and pesticide applications are intertwined, strong and sustainable remediation strategies are essential for environmental protection without sacrificing crop productivity. Various bio-inspired methods have been reported, such as phytoremediation, bioremediation, and in situ remediation; however, limited success has been observed with either single or combined approaches. Consequently, biopolymer biomanufacturing, nanoparticle-based bioengineering, and computational biology for improved understanding of mechanisms have been revisited to incorporate updated methodologies that detail the fate and action of harmful chemical pesticides in agriculture. An in silico mechanistic approach has been emphasized to understand the molecular mechanisms involved in agricultural pesticides’ degradation using nanomaterials. A roadmap has been created by integrating cutting-edge machine learning techniques to develop nature-inspired sustainable agricultural practices and contaminant disposal methods. This review represents a pioneering effort to explore the roles of wet-lab chemistry and in silico methods in mitigating the effects of agricultural pesticides, providing a comprehensive strategy for balancing environmental sustainability and agricultural practices. Full article
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18 pages, 3666 KB  
Article
Reinforcement Learning Enabled Intelligent Process Monitoring and Control of Wire Arc Additive Manufacturing
by Allen Love, Saeed Behseresht and Young Ho Park
J. Manuf. Mater. Process. 2025, 9(10), 340; https://doi.org/10.3390/jmmp9100340 - 18 Oct 2025
Viewed by 469
Abstract
Wire Arc Additive Manufacturing (WAAM) has been recognized as an efficient and cost-effective metal additive manufacturing technique due to its high deposition rate and scalability for large components. However, the quality and repeatability of WAAM parts are highly sensitive to process parameters such [...] Read more.
Wire Arc Additive Manufacturing (WAAM) has been recognized as an efficient and cost-effective metal additive manufacturing technique due to its high deposition rate and scalability for large components. However, the quality and repeatability of WAAM parts are highly sensitive to process parameters such as arc voltage, current, wire feed rate, and torch travel speed, requiring advanced monitoring and adaptive control strategies. In this study, a vision-based monitoring system integrated with a reinforcement learning framework was developed to enable intelligent in situ control of WAAM. A custom optical assembly employing mirrors and a bandpass filter allowed simultaneous top and side views of the melt pool, enabling real-time measurement of layer height and width. These geometric features provide feedback to a tabular Q-learning algorithm, which adaptively adjusts voltage and wire feed rate through direct hardware-level control of stepper motors. Experimental validation across multiple builds with varying initial conditions demonstrated that the RL controller stabilized layer geometry, autonomously recovered from process disturbances, and maintained bounded oscillations around target values. While systematic offsets between digital measurements and physical dimensions highlight calibration challenges inherent to vision-based systems, the controller consistently prevented uncontrolled drift and corrected large deviations in deposition quality. The computational efficiency of tabular Q-learning enabled real-time operation on standard hardware without specialized equipment, demonstrating an accessible approach to intelligent process control. These results establish the feasibility of reinforcement learning as a robust, data-efficient control technique for WAAM, capable of real-time adaptation with minimal prior process knowledge. With improved calibration methods and expanded multi-physics sensing, this framework can advance toward precise geometric accuracy and support broader adoption of machine learning-based process monitoring and control in metal additive manufacturing. Full article
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21 pages, 9067 KB  
Article
Research on Intelligent Early Warning System and Cloud Platform for Rockburst Monitoring
by Tianhui Ma, Yongle Duan, Wenshuo Duan, Hongqi Wang, Chun’an Tang, Kaikai Wang and Guanwen Cheng
Appl. Sci. 2025, 15(20), 11098; https://doi.org/10.3390/app152011098 - 16 Oct 2025
Viewed by 279
Abstract
Rockburst disasters in deep underground engineering present significant safety hazards due to complex geological conditions and high in situ stresses. To address the limitations of traditional microseismic (MS) monitoring methods—namely, vulnerability to noise interference, low recognition accuracy, and limited computational efficiency—this study proposes [...] Read more.
Rockburst disasters in deep underground engineering present significant safety hazards due to complex geological conditions and high in situ stresses. To address the limitations of traditional microseismic (MS) monitoring methods—namely, vulnerability to noise interference, low recognition accuracy, and limited computational efficiency—this study proposes an intelligent real-time monitoring and early warning framework that integrates deep learning, MS monitoring, and Internet of Things (IoT) technologies. The methodology includes db4 wavelet-based signal denoising for preprocessing, an improved Gaussian Mixture Model for automated waveform recognition, a U-Net-based neural network for P-wave arrival picking, and a particle swarm optimization algorithm with Lagrange multipliers for event localization. Furthermore, a cloud-based platform is developed to support automated data processing, three-dimensional visualization, real-time warning dissemination, and multi-user access. Field application in a deep-buried railway tunnel in Southwest China demonstrates the system’s effectiveness, achieving an early warning accuracy of 87.56% during 767 days of continuous monitoring. Comparative verification further indicates that the fine-tuned neural network outperforms manual approaches in waveform picking and event identification. Overall, the proposed system provides a robust, scalable, and intelligent solution for rockburst hazard mitigation in deep underground construction. Full article
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25 pages, 3078 KB  
Review
Sensing While Drilling and Intelligent Monitoring Technology: Research Progress and Application Prospects
by Xiaoyu Li, Zongwei Yao, Tao Zhang and Zhiyong Chang
Sensors 2025, 25(20), 6368; https://doi.org/10.3390/s25206368 - 15 Oct 2025
Viewed by 451
Abstract
Obtaining accurate information on stratigraphic conditions and drilling status is necessary to ensure the safety of the drilling process and to guarantee the production of oil and gas. Sensing while drilling and intelligent monitoring technology, which employ multiple sensors and involve the use [...] Read more.
Obtaining accurate information on stratigraphic conditions and drilling status is necessary to ensure the safety of the drilling process and to guarantee the production of oil and gas. Sensing while drilling and intelligent monitoring technology, which employ multiple sensors and involve the use of intelligent algorithms, can be used to collect downhole information in situ to ensure safe, reliable, and efficient drilling and mining operations. These approaches are characterized by effective sensing and comprehensive utilization of drilling information through the integration of multi-sensor signals and intelligent algorithms, a core component of machine learning. The article summarizes the current research status of domestic and international sensing while drilling and intelligent monitoring technology using systematically collected relevant information. Specifically, first, the drilling-sensing methods used for in situ acquisition of downhole information, including fiber-optic sensing, electronic-nose sensing, drilling engineering-parameter sensing, drilling mud-parameter sensing, drilling acoustic logging, drilling electromagnetic wave logging, and drilling seismic logging, are described. Next, the basic composition and development direction of each sensing technology are analyzed. Subsequently, the application of intelligent monitoring technology based on machine learning in various aspects of drilling- and mining-status identification, including bit wear monitoring, stuck drill real-time monitoring, well surge real-time monitoring, and real-time monitoring of oil and gas output, is introduced. Finally, the potential applications of sensing while drilling and intelligent monitoring technology in deep-earth, deep-sea, and deep-space contexts are discussed, and the challenges, constraints, and development trends are summarized. Full article
(This article belongs to the Topic Advances in Oil and Gas Wellbore Integrity, 2nd Edition)
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64 pages, 10522 KB  
Review
Spectroscopic and Microscopic Characterization of Inorganic and Polymer Thermoelectric Materials: A Review
by Temesgen Atnafu Yemata, Tessera Alemneh Wubieneh, Yun Zheng, Wee Shong Chin, Messele Kassaw Tadsual and Tadisso Gesessee Beyene
Spectrosc. J. 2025, 3(4), 24; https://doi.org/10.3390/spectroscj3040024 - 14 Oct 2025
Viewed by 475
Abstract
Thermoelectric (TE) materials represent a critical frontier in sustainable energy conversion technologies, providing direct thermal-to-electrical energy conversion with solid-state reliability. The optimizations of TE performance demand a nuanced comprehension of structure–property relationships across diverse length scales. This review summarizes established and emerging spectroscopic [...] Read more.
Thermoelectric (TE) materials represent a critical frontier in sustainable energy conversion technologies, providing direct thermal-to-electrical energy conversion with solid-state reliability. The optimizations of TE performance demand a nuanced comprehension of structure–property relationships across diverse length scales. This review summarizes established and emerging spectroscopic and microscopic techniques used to characterize inorganic and polymer TE materials, specifically poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS). For inorganic TE, ultraviolet–visible (UV–Vis) spectroscopy, energy-dispersive X-ray (EDX) spectroscopy, and X-ray photoelectron spectroscopy (XPS) are widely applied for electronic structure characterization. For phase analysis of inorganic TE materials, Raman spectroscopy (RS), electron energy loss spectroscopy (EELS), and nuclear magnetic resonance (NMR) spectroscopy are utilized. For analyzing the surface morphology and crystalline structure, chemical scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD) are commonly used. For polymer TE materials, ultraviolet−visible–near-infrared (UV−Vis−NIR) spectroscopy and ultraviolet photoelectron spectroscopy (UPS) are generally employed for determining electronic structure. For functional group analysis of polymer TE, attenuated total reflectance–Fourier-transform infrared (ATR−FTIR) spectroscopy and RS are broadly utilized. XPS is used for elemental composition analysis of polymer TE. For the surface morphology of polymer TE, atomic force microscopic (AFM) and SEM are applied. Grazing incidence wide-angle X-ray scattering (GIWAXS) and XRD are employed for analyzing the crystalline structures of polymer TE materials. These techniques elucidate electronic, structural, morphological, and chemical properties, aiding in optimizing TE properties like conductivity, thermal stability, and mechanical strength. This review also suggests future research directions, including in situ methods and machine learning-assisted multi-dimensional spectroscopy to enhance TE performance for applications in electronic devices, energy storage, and solar cells. Full article
(This article belongs to the Special Issue Advances in Spectroscopy Research)
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56 pages, 3273 KB  
Systematic Review
Artificial Intelligence and Machine Learning in Cold Spray Additive Manufacturing: A Systematic Literature Review
by Habib Afsharnia and Javaid Butt
J. Manuf. Mater. Process. 2025, 9(10), 334; https://doi.org/10.3390/jmmp9100334 - 13 Oct 2025
Viewed by 663
Abstract
Due to its unique benefits over conventional subtractive manufacturing, additive manufacturing methods continue to attract interest in both academia and industry. One such method is called Cold Spray Additive Manufacturing (CSAM), a solid-state coating deposition technology to manufacture repair metallic components using a [...] Read more.
Due to its unique benefits over conventional subtractive manufacturing, additive manufacturing methods continue to attract interest in both academia and industry. One such method is called Cold Spray Additive Manufacturing (CSAM), a solid-state coating deposition technology to manufacture repair metallic components using a gas jet and powder particles. CSAM offers low heat input, stable phases, suitability for heat-sensitive substrates, and high deposition rates. However, persistent challenges include porosity control, geometric accuracy near edges and concavities, anisotropy, and cost sensitivities linked to gas selection and nozzle wear. Interdisciplinary research across manufacturing science, materials characterisation, robotics, control, artificial intelligence (AI), and machine learning (ML) is deployed to overcome these issues. ML supports quality prediction, inverse parameter design, in situ monitoring, and surrogate models that couple process physics with data. To demonstrate the impact of AI and ML on CSAM, this study presents a systematic literature review to identify, evaluate, and analyse published studies in this domain. The most relevant studies in the literature are analysed using keyword co-occurrence and clustering. Four themes were identified: design for CSAM, material analytics, real-time monitoring and defect analytics, and deposition and AI-enabled optimisation. Based on this synthesis, core challenges are identified as small and varied datasets, transfer and identifiability limits, and fragmented sensing. Main opportunities are outlined as physics-based surrogates, active learning, uncertainty-aware inversion, and cloud-edge control for reliable and adaptable ML use in CSAM. By systematically mapping the current landscape, this work provides a critical roadmap for researchers to target the most significant challenges and opportunities in applying AI/ML to industrialise CSAM. Full article
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23 pages, 4523 KB  
Article
Lung Nodule Malignancy Classification Integrating Deep and Radiomic Features in a Three-Way Attention-Based Fusion Module
by Sadaf Khademi, Shahin Heidarian, Parnian Afshar, Arash Mohammadi, Abdul Sidiqi, Elsie T. Nguyen, Balaji Ganeshan and Anastasia Oikonomou
J. Imaging 2025, 11(10), 360; https://doi.org/10.3390/jimaging11100360 - 13 Oct 2025
Viewed by 396
Abstract
In this study, we propose a novel hybrid framework for assessing the invasiveness of an in-house dataset of 114 pathologically proven lung adenocarcinomas presenting as subsolid nodules on Computed Tomography (CT). Nodules were classified into group 1 (G1), which included atypical adenomatous hyperplasia, [...] Read more.
In this study, we propose a novel hybrid framework for assessing the invasiveness of an in-house dataset of 114 pathologically proven lung adenocarcinomas presenting as subsolid nodules on Computed Tomography (CT). Nodules were classified into group 1 (G1), which included atypical adenomatous hyperplasia, adenocarcinoma in situ, and minimally invasive adenocarcinomas, and group 2 (G2), which included invasive adenocarcinomas. Our approach includes a three-way Integration of Visual, Spatial, and Temporal features with Attention, referred to as I-VISTA, obtained from three processing algorithms designed based on Deep Learning (DL) and radiomic models, leading to a more comprehensive analysis of nodule variations. The aforementioned processing algorithms are arranged in the following three parallel paths: (i) The Shifted Window (SWin) Transformer path, which is a hierarchical vision Transformer that extracts nodules’ related spatial features; (ii) The Convolutional Auto-Encoder (CAE) Transformer path, which captures informative features related to inter-slice relations via a modified Transformer encoder architecture; and (iii) a 3D Radiomic-based path that collects quantitative features based on texture analysis of each nodule. Extracted feature sets are then passed through the Criss-Cross attention fusion module to discover the most informative feature patterns and classify nodules type. The experiments were evaluated based on a ten-fold cross-validation scheme. I-VISTA framework achieved the best performance of overall accuracy, sensitivity, and specificity (mean ± std) of 93.93 ± 6.80%, 92.66 ± 9.04%, and 94.99 ± 7.63% with an Area under the ROC Curve (AUC) of 0.93 ± 0.08 for lung nodule classification among ten folds. The hybrid framework integrating DL and hand-crafted 3D Radiomic model outperformed the standalone DL and hand-crafted 3D Radiomic model in differentiating G1 from G2 subsolid nodules identified on CT. Full article
(This article belongs to the Special Issue Progress and Challenges in Biomedical Image Analysis—2nd Edition)
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