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Keywords = semiconductor screens

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13 pages, 2352 KiB  
Article
Research on Improving the Avalanche Current Limit of Parallel SiC MOSFETs
by Hua Mao, Binbing Wu, Xinsheng Lan, Yalong Xia, Junjie Chen and Lei Tang
Electronics 2025, 14(13), 2502; https://doi.org/10.3390/electronics14132502 - 20 Jun 2025
Viewed by 451
Abstract
The transient overvoltage caused by coupling of loop inductance during rapid turn off of a silicon carbide metal-oxide-semiconductor field-effect transistor (SiC MOSFET) can easily induce avalanche breakdown. Meanwhile, the instantaneous high-density heat flux generated by energy dissipation can create significant electrothermal coupling stress, [...] Read more.
The transient overvoltage caused by coupling of loop inductance during rapid turn off of a silicon carbide metal-oxide-semiconductor field-effect transistor (SiC MOSFET) can easily induce avalanche breakdown. Meanwhile, the instantaneous high-density heat flux generated by energy dissipation can create significant electrothermal coupling stress, potentially leading to device failure under severe conditions. To address the issue that the multi-chip parallel structure of power modules cannot linearly enhance avalanche withstand capability, an innovative device screening method based on parameter matching is proposed in this paper. The effectiveness of the proposed solution is verified through experiments, with the total current limit of dual-tube parallel devices and three-tube parallel devices achieving 1.9 times and 2.4 times that of single-tube devices, respectively. This research is of great significance for improving safe and reliable operation of the system. Full article
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13 pages, 10049 KiB  
Article
Rapid and Sensitive Detection of Thrombospondin-2 Using Nanoparticle Sensors for Cancer Screening and Prognosis
by Maziyar Kalateh Mohammadi, Seyedsina Mirjalili, Md Ashif Ikbal, Hao Xie and Chao Wang
Micromachines 2025, 16(3), 354; https://doi.org/10.3390/mi16030354 - 20 Mar 2025
Viewed by 1316
Abstract
Thrombospondin-2 (THBS2) is a prevailing prognostic biomarker implicated in different cancer types, such as deadly colorectal, pancreas, and triple-negative breast cancers. While the current methods for cancer-relevant protein detection, such as enzyme-linked immunosorbent assay (ELISA), mass spectrometry, and immunohistochemistry, are feasible at advanced [...] Read more.
Thrombospondin-2 (THBS2) is a prevailing prognostic biomarker implicated in different cancer types, such as deadly colorectal, pancreas, and triple-negative breast cancers. While the current methods for cancer-relevant protein detection, such as enzyme-linked immunosorbent assay (ELISA), mass spectrometry, and immunohistochemistry, are feasible at advanced stages, they have shortcomings in sensitivity, specificity, and accessibility, particularly at low concentrations in complex biological fluids for early detection. Here, we propose and demonstrate a modular, in-solution assay design concept, Nanoparticle-Supported Rapid Electronic Detection (NasRED), as a versatile cancer screening and diagnostic platform. NasRED utilizes antibody-functionalized gold nanoparticles (AuNPs) to capture target proteins from a minute amount of sample (<10 µL) and achieve optimal performance with a short assay time by introducing active fluidic forces that act to promote biochemical reaction and accelerate signal transduction. This rapid (15 min) process serves to form AuNP clusters upon THBS2 binding and subsequently precipitate such clusters, resulting in color modulation of the test tubes that is dependent on the THBS2 concentration. Finally, a semiconductor-based, portable electronic device is used to digitize the optical signals for the sensitive detection of THBS2. High sensitivity (femtomolar level) and a large dynamic range (five orders of magnitude) are obtained to analyze THBS2 spiked in PBS, serum, whole blood, saliva, cerebrospinal fluids, and synovial fluids. High specificity is also preserved in differentiating THBS2 from other markers such as cancer antigen (CA) 19-9 and bovine serum albumin (BSA). This study highlights NasRED’s potential to enhance cancer prognosis and screening by offering a cost-effective, accessible, and minimally invasive solution. Full article
(This article belongs to the Special Issue Immunoassay Platforms for Biomedical Detection)
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35 pages, 11367 KiB  
Article
A Novel Field-Programmable Gate Array-Based Self-Sustaining Current Balancing Approach for Silicon Carbide MOSFETs
by Nektarios Giannopoulos, Georgios Ioannidis, Georgios Vokas and Constantinos S. Psomopoulos
Electronics 2025, 14(2), 268; https://doi.org/10.3390/electronics14020268 - 10 Jan 2025
Viewed by 1054
Abstract
In medium- and high-power-density applications, silicon carbide (SiC) metal-oxide semiconductor field effect transistors (MOSFETs) are often connected in parallel increasing the current capability. However, the current sharing of paralleled SiC MOSFETs is affected by the mismatched technical parameters of devices and the deviated [...] Read more.
In medium- and high-power-density applications, silicon carbide (SiC) metal-oxide semiconductor field effect transistors (MOSFETs) are often connected in parallel increasing the current capability. However, the current sharing of paralleled SiC MOSFETs is affected by the mismatched technical parameters of devices and the deviated power circuit parasitic inductances, even if power devices are controlled by a single gate driver. This leads to unevenly distributed power losses causing different stress between SiC MOSFETs. As a result, unbalanced current sharing increases the probability of severe power switch(es) and system failures. For over a decade, the current imbalance issue between parallel-connected SiC MOSFETs has concerned the scientific community, and many methods and techniques have been proposed. However, most of these solutions are impossible to realize without the necessity of screening power devices to measure their technical parameters. Consequently, system costs significantly increase due to the expensive equipment for screening SiC MOSFETs. Also, transient current imbalance is the main concern of most papers, without addressing static imbalance. In this paper, an innovative approach is proposed, capable of suppressing both static and transient current imbalance between paralleled SiC MOSFETs, under both symmetrical and asymmetrical layouts, through an improved active gate driver and without the requirement for any power device screening process. Additionally, the proposed solution employs a self-sustaining algorithmic approach utilizing current sensors and a field-programmable gate array (FPGA). The functionality of the proposed solution is verified through experimental tests, achieving current imbalance suppression between two paralleled SiC MOSFETs, actively and autonomously. Full article
(This article belongs to the Special Issue Innovative Technologies in Power Converters, 2nd Edition)
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8 pages, 810 KiB  
Article
Getting to the Heart of the Matter: Control over the Photolysis of PbI2 Through Partial Lead Substitution
by Marina I. Ustinova, Gennadii V. Shilov, Pavel A. Troshin, Sergey M. Aldoshin and Lyubov A. Frolova
Inorganics 2025, 13(1), 13; https://doi.org/10.3390/inorganics13010013 - 6 Jan 2025
Viewed by 904
Abstract
A crucial problem of the photoinduced degradation of perovskite semiconductors based on complex lead halides has been addressed here by suppressing PbI2 photolysis to metallic lead. The systematic screening of >30 modifying cations introduced as substituents for 5% of Pb2+ in [...] Read more.
A crucial problem of the photoinduced degradation of perovskite semiconductors based on complex lead halides has been addressed here by suppressing PbI2 photolysis to metallic lead. The systematic screening of >30 modifying cations introduced as substituents for 5% of Pb2+ in the PbI2 composition has revealed their tremendous effects on the rate of material degradation under light exposure. Thus, the most successful stabilizing cations could maintain a high absorbance of the Pb0.95M0.1/nI2 films and block Pb0 formation after 400 h of continuous illumination, when the non-modified PbI2 films completely decomposed to Pb0 and I2. The obtained results present a promising solution for the problem of metallic lead formation in the active layer of perovskite solar cells during their operation, which can pave the way for the development of a new generation of highly efficient and stable perovskite photovoltaics. Full article
(This article belongs to the Special Issue New Semiconductor Materials for Energy Conversion)
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24 pages, 7104 KiB  
Review
Recent Advances in Metal Oxide Semiconductor Heterojunctions for the Detection of Volatile Organic Compounds
by Shengming Zhang, Heng Zhang, Haiyu Yao, Peijie Wang, Min Zhu, Xuerong Shi and Shusheng Xu
Chemosensors 2024, 12(12), 244; https://doi.org/10.3390/chemosensors12120244 - 22 Nov 2024
Cited by 5 | Viewed by 4006
Abstract
The efficient detection of volatile organic compounds (VOCs) is critically important in the domains of environmental protection, healthcare, and industrial safety. The development of metal oxide semiconductor (MOS) heterojunction gas-sensing materials is considered one of the most effective strategies to enhance sensor performance. [...] Read more.
The efficient detection of volatile organic compounds (VOCs) is critically important in the domains of environmental protection, healthcare, and industrial safety. The development of metal oxide semiconductor (MOS) heterojunction gas-sensing materials is considered one of the most effective strategies to enhance sensor performance. This review summarizes and discusses the types of heterojunctions and their working principles, enhancement strategies, preparation methodologies, and applications in acetone and ethanol detection. To address the constraints pertaining to low sensitivity, sluggish response/recovery times, and elevated operating temperatures that are inherent in VOC sensors, several improvement methods are proposed, including doping with metals like Ag and Pd, incorporating additives such as MXene and polyoxometalates, optimizing morphologies through a fine design, and self-doping via oxygen vacancies. Furthermore, this work provides insights into the challenges faced by MOSs heterojunction-based gas sensors and outlines future research directions in this field. This review will contribute to foundational theories to overcome existing bottlenecks in MOS heterojunction technology while promoting its large-scale application in disease screening or agricultural food quality assessments. Full article
(This article belongs to the Special Issue Functional Nanomaterial-Based Gas Sensors and Humidity Sensors)
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13 pages, 5425 KiB  
Article
Highly Sensitive SnS2/rGO-Based Gas Sensor for Detecting Chemical Warfare Agents at Room Temperature: A Theoretical Study Based on First-Principles Calculations
by Ting Liang, Huaizhang Wang, Huaning Jiang, Yelin Qi, Rui Yan, Jiangcun Li and Yanlei Shangguan
Crystals 2024, 14(12), 1008; https://doi.org/10.3390/cryst14121008 - 21 Nov 2024
Cited by 2 | Viewed by 2908
Abstract
Chemical warfare agents (CWAs) are known as poor man’s bombs because of their small lethal dose, cheapness, and ease of production. Therefore, the highly sensitive and rapid detection of CWAs at room temperature (RT = 25 °C) is essential. In this paper, we [...] Read more.
Chemical warfare agents (CWAs) are known as poor man’s bombs because of their small lethal dose, cheapness, and ease of production. Therefore, the highly sensitive and rapid detection of CWAs at room temperature (RT = 25 °C) is essential. In this paper, we have developed a resistive semiconductor sensor for the highly sensitive detection of CWAs at RT. The gas-sensing material is SnS2/rGO nanosheets (NSs) prepared by hydrothermal synthesis. The lower detection limits of the SnS2/rGO NSs-based gas sensor were 0.05 mg/m3 and 0.1 mg/m3 for the typical chemical weapons sarin (GB) and sulfur mustard (HD), respectively. The responsivity can reach −3.54% and −10.2% in 95 s for 1.0 mg/m3 GB, and in 47 s for 1.0 mg/m3 HD. They are 1.17 and 2.71 times higher than the previously reported Nb-MoS2 NSs-based gas sensors, respectively. In addition, it has better repeatability (RSD = 6.77%) and stability for up to 10 weeks (RSD = 20.99%). Furthermore, to simplify the work of later researchers based on the detection of CWAs by two-dimensional transition metal sulfur compounds (2D-TMDCs), we carried out calculations of the SnS2 NSs-based and SnS2/rGO NSs-based gas sensor-adsorbing CWAs. Detailed comparisons are made in conjunction with experimental results. For different materials, it was found that the SnS2/rGO NSs-based gas sensor performed better in all aspects of adsorbing CWAs in the experimental results. Adsorbed CWAs at a distance smaller than that of the SnS2 NSs-based gas sensor in the theoretical calculations, as well as its adsorption energy and transferred charge, were larger than those of the SnS2 NSs-based gas sensor. For different CWAs, the experimental results show that the sensitivity of the SnS2/rGO NSs-based gas sensor for the adsorption of GB is higher than that of HD, and accordingly, the theoretical calculations show that the adsorption distance of the SnS2/rGO NSs-based gas sensor for the adsorption of GB is smaller than that of HD, and the adsorption energy and the amount of transferred charge are larger than that of HD. This regularity conclusion proves the feasibility of adsorption of CWAs by gas sensors based on SnS2 NSs, as well as the feasibility and reliability of theoretical prediction experiments. This work lays a good theoretical foundation for subsequent rapid screenings of gas sensors with gas-sensitive materials for detecting CWAs. Full article
(This article belongs to the Special Issue Organic Photonics: Organic Optical Functional Materials and Devices)
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11 pages, 1735 KiB  
Article
Coulomb Contribution to Shockley–Read–Hall Recombination
by Konrad Sakowski, Pawel Strak, Pawel Kempisty, Jacek Piechota, Izabella Grzegory, Piotr Perlin, Eva Monroy, Agata Kaminska and Stanislaw Krukowski
Materials 2024, 17(18), 4581; https://doi.org/10.3390/ma17184581 - 18 Sep 2024
Cited by 2 | Viewed by 1080
Abstract
A nonradiative recombination channel is proposed, which does not vanish at low temperatures. Defect-mediated nonradiative recombination, known as Shockley–Read–Hall (SRH) recombination, is reformulated to accommodate Coulomb attraction between the charged deep defect and the approaching free carrier. It is demonstrated that this effect [...] Read more.
A nonradiative recombination channel is proposed, which does not vanish at low temperatures. Defect-mediated nonradiative recombination, known as Shockley–Read–Hall (SRH) recombination, is reformulated to accommodate Coulomb attraction between the charged deep defect and the approaching free carrier. It is demonstrated that this effect may cause a considerable increase in the carrier velocity approaching the recombination center. The effect considerably increases the carrier capture rates. It is demonstrated that, in a typical semiconductor device or semiconductor medium, the SRH recombination rate at low temperatures is much higher and cannot be neglected. This effect renders invalid the standard procedure of estimating the radiative recombination rate by measuring the light output in cryogenic temperatures, as a significant nonradiative recombination channel is still present. We also show that SRH is more effective in the case of low-doped semiconductors, as effective screening by mobile carrier density could reduce the effect. Full article
(This article belongs to the Section Optical and Photonic Materials)
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11 pages, 4034 KiB  
Article
Fresnel Diffraction Model for Laser Dazzling Spots of Complementary Metal Oxide Semiconductor Cameras
by Xinyu Wang, Zhongjie Xu, Hairong Zhong, Xiang’ai Cheng, Zhongyang Xing and Jiangbin Zhang
Sensors 2024, 24(17), 5781; https://doi.org/10.3390/s24175781 - 5 Sep 2024
Cited by 1 | Viewed by 1469
Abstract
Laser dazzling on complementary metal oxide semiconductor (CMOS) image sensors is an effective method in optoelectronic countermeasures. However, previous research mainly focused on the laser dazzling under far fields, with limited studies on situations that the far-field conditions were not satisfied. In this [...] Read more.
Laser dazzling on complementary metal oxide semiconductor (CMOS) image sensors is an effective method in optoelectronic countermeasures. However, previous research mainly focused on the laser dazzling under far fields, with limited studies on situations that the far-field conditions were not satisfied. In this paper, we established a Fresnel diffraction model of laser dazzling on a CMOS by combining experiments and simulations. We calculated that the laser power density and the area of saturated pixels on the detector exhibit a linear relationship with a slope of 0.64 in a log-log plot. In the experiment, we found that the back side illumination (BSI-CMOS) matched the simulations, with an error margin of 3%, while the front side illumination (FSI-CMOS) slightly mismatched the simulations, with an error margin of 14%. We also found that the full-screen saturation threshold for the BSI-CMOS was 25% higher than the FSI-CMOS. Our work demonstrates the applicability of the Fresnel diffraction model for BSI-CMOS, which provides a valuable reference for studying laser dazzling. Full article
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13 pages, 2553 KiB  
Article
Carbon-Based FET-Type Gas Sensor for the Detection of ppb-Level Benzene at Room Temperature
by Risheng Cao, Zhengyu Lu, Jinyong Hu and Yong Zhang
Chemosensors 2024, 12(9), 179; https://doi.org/10.3390/chemosensors12090179 - 4 Sep 2024
Cited by 4 | Viewed by 1972
Abstract
Benzene, as a typical toxic gas and carcinogen, is an important detection object in the field of environmental monitoring. However, it remains challenging for the conventional resistance-type gas sensor to effectively detect low-concentration (ppb-level) benzene gas molecules, owing to their insufficient reaction activation [...] Read more.
Benzene, as a typical toxic gas and carcinogen, is an important detection object in the field of environmental monitoring. However, it remains challenging for the conventional resistance-type gas sensor to effectively detect low-concentration (ppb-level) benzene gas molecules, owing to their insufficient reaction activation energy, especially when operating at room temperature. Herein, a field-effect transistor (FET)-type gas sensor using carbon nanotubes as a channel material is proposed for the efficient detection of trace benzene, where carbon nanotubes (CNTs) with high semiconductor purity act as the main channel material, and ZnO/WS2 nanocomposites serve as the gate sensitive material. On the basis of the remarkable amplification effect in CNTs-based FET, the proposed gas sensor manifests desirable sensitive ability with the detection limit as low as 500 ppb for benzene even working at room temperature, and the sensor also exhibits fast response speed (90 s), high consistency with a response deviation of less than 5%, and long-term stability of up to 30 days. Furthermore, utilizing Tenax TA as the screening unit, the as-proposed gas sensor can achieve the feasible selective detection of benzene. These experimental results demonstrate that the strategy proposed here can provide significant guidance for the development of high-performance gas sensors to detect trace benzene gas at room temperature. Full article
(This article belongs to the Special Issue Functional Nanomaterial-Based Gas Sensors and Humidity Sensors)
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20 pages, 6461 KiB  
Article
Textile-Integrated Conductive Layers for Flexible Semiconductor-Based Photovoltaic Structures
by Przemysław Czarnecki, Bartosz Szudziel, Daniel Janczak, Łukasz Ruta, Maciej Sibiński and Katarzyna Znajdek
Energies 2024, 17(15), 3839; https://doi.org/10.3390/en17153839 - 3 Aug 2024
Viewed by 1740
Abstract
This paper presents the results of research on conductive layers dedicated to flexible photovoltaic cells based on semiconductors integrated with a textile substrate. The presented work is part of a broader project aimed at producing flexible solar cells based on the CdTe semiconductor [...] Read more.
This paper presents the results of research on conductive layers dedicated to flexible photovoltaic cells based on semiconductors integrated with a textile substrate. The presented work is part of a broader project aimed at producing flexible solar cells based on the CdTe semiconductor component and manufactured directly on textiles. The research focuses on the selection of textile substrates and contact materials, as well as the methods of their application. This study compares three types of fabrics (basalt, glass, and silicone fibers) and three metals (copper, molybdenum, and silver), evaluating their mechanical and electrical properties. During the experiments, flexible metallic layers with a thickness ranging from 160 to 415 nm were obtained. Preliminary experiments indicated that metallic layers deposited directly on textiles do not provide adequate conductivity, reaching the levels of several hundred Ω/sq and necessitating the introduction of intermediate layers, such as screen-printed graphite. The results show that molybdenum layers on basalt fabrics exhibit the lowest increase in resistance after dynamic bending tests. The obtained relative resistance changes in Mo layers varied from 50% to as low as 5% after a complete set of 200 bending cycles. This article also discusses current challenges and future research directions in the field of textile-integrated photovoltaics, emphasizing the importance of further technological development to improve the energy efficiency and durability of such solutions. Full article
(This article belongs to the Special Issue Advances on Solar Energy Materials and Solar Cells)
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12 pages, 3735 KiB  
Article
Detection of α-Galactosidase A Reaction in Samples Extracted from Dried Blood Spots Using Ion-Sensitive Field Effect Transistors
by Alexander Kuznetsov, Andrey Sheshil, Eugene Smolin, Vitaliy Grudtsov, Dmitriy Ryazantsev, Mark Shustinskiy, Tatiana Tikhonova, Irakli Kitiashvili, Valerii Vechorko and Natalia Komarova
Sensors 2024, 24(11), 3681; https://doi.org/10.3390/s24113681 - 6 Jun 2024
Cited by 3 | Viewed by 1533
Abstract
Fabry disease is a lysosomal storage disorder caused by a significant decrease in the activity or absence of the enzyme α-galactosidase A. The diagnostics of Fabry disease during newborn screening are reasonable, due to the availability of enzyme replacement therapy. This paper presents [...] Read more.
Fabry disease is a lysosomal storage disorder caused by a significant decrease in the activity or absence of the enzyme α-galactosidase A. The diagnostics of Fabry disease during newborn screening are reasonable, due to the availability of enzyme replacement therapy. This paper presents an electrochemical method using complementary metal-oxide semiconductor (CMOS)-compatible ion-sensitive field effect transistors (ISFETs) with hafnium oxide-sensitive surfaces for the detection of α-galactosidase A activity in dried blood spot extracts. The capability of ISFETs to detect the reaction catalyzed by α-galactosidase A was demonstrated. The buffer composition was optimized to provide suitable conditions for both enzyme and ISFET performance. The use of ISFET structures as sensor elements allowed for the label-free detection of enzymatic reactions with melibiose, a natural substrate of α-galactosidase A, instead of a synthetic fluorogenic one. ISFET chips were packaged with printed circuit boards and microfluidic reaction chambers to enable long-term signal measurement using a custom device. The packaged sensors were demonstrated to discriminate between normal and inhibited GLA activity in dried blood spots extracts. The described method offers a promising solution for increasing the widespread distribution of newborn screening of Fabry disease. Full article
(This article belongs to the Special Issue Advances in Electrochemical Sensors for Bioanalysis)
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18 pages, 28128 KiB  
Article
All Screen Printed and Flexible Silicon Carbide NTC Thermistors for Temperature Sensing Applications
by Arjun Wadhwa, Jaime Benavides-Guerrero, Mathieu Gratuze, Martin Bolduc and Sylvain G. Cloutier
Materials 2024, 17(11), 2489; https://doi.org/10.3390/ma17112489 - 22 May 2024
Cited by 4 | Viewed by 2850
Abstract
In this study, Silicon Carbide (SiC) nanoparticle-based serigraphic printing inks were formulated to fabricate highly sensitive and wide temperature range printed thermistors. Inter-digitated electrodes (IDEs) were screen printed onto Kapton® substrate using commercially avaiable silver ink. Thermistor inks with different weight ratios [...] Read more.
In this study, Silicon Carbide (SiC) nanoparticle-based serigraphic printing inks were formulated to fabricate highly sensitive and wide temperature range printed thermistors. Inter-digitated electrodes (IDEs) were screen printed onto Kapton® substrate using commercially avaiable silver ink. Thermistor inks with different weight ratios of SiC nanoparticles were printed atop the IDE structures to form fully printed thermistors. The thermistors were tested over a wide temperature range form 25 °C to 170 °C, exhibiting excellent repeatability and stability over 15 h of continuous operation. Optimal device performance was achieved with 30 wt.% SiC-polyimide ink. We report highly sensitive devices with a TCR of −0.556%/°C, a thermal coefficient of 502 K (β-index) and an activation energy of 0.08 eV. Further, the thermistor demonstrates an accuracy of ±1.35 °C, which is well within the range offered by commercially available high sensitivity thermistors. SiC thermistors exhibit a small 6.5% drift due to changes in relative humidity between 10 and 90%RH and a 4.2% drift in baseline resistance after 100 cycles of aggressive bend testing at a 40° angle. The use of commercially available low-cost materials, simplicity of design and fabrication techniques coupled with the chemical inertness of the Kapton® substrate and SiC nanoparticles paves the way to use all-printed SiC thermistors towards a wide range of applications where temperature monitoring is vital for optimal system performance. Full article
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16 pages, 3421 KiB  
Article
Non-Invasive Alcohol Concentration Measurement Using a Spectroscopic Module: Outlook for the Development of a Drunk Driving Prevention System
by Yechan Cho, Wonjune Lee, Heock Sin, Suseong Oh, Kyo Chang Choi and Jae-Hoon Jun
Sensors 2024, 24(7), 2252; https://doi.org/10.3390/s24072252 - 1 Apr 2024
Cited by 4 | Viewed by 3948
Abstract
Alcohol acts as a central nervous system depressant and falls under the category of psychoactive drugs. It has the potential to impair vital bodily functions, including cognitive alertness, muscle coordination, and induce fatigue. Taking the wheel after consuming alcohol can lead to delayed [...] Read more.
Alcohol acts as a central nervous system depressant and falls under the category of psychoactive drugs. It has the potential to impair vital bodily functions, including cognitive alertness, muscle coordination, and induce fatigue. Taking the wheel after consuming alcohol can lead to delayed responses in emergency situations and increases the likelihood of collisions with obstacles or suddenly appearing objects. Statistically, drivers under the influence of alcohol are seven times more likely to cause accidents compared to sober individuals. Various techniques and methods for alcohol measurement have been developed. The widely used breathalyzer, which requires direct contact with the mouth, raises concerns about hygiene. Methods like chromatography require skilled examiners, while semiconductor sensors exhibit instability in sensitivity over measurement time and has a short lifespan, posing structural challenges. Non-dispersive infrared analyzers face structural limitations, and in-vehicle air detection methods are susceptible to external influences, necessitating periodic calibration. Despite existing research and technologies, there remain several limitations, including sensitivity to external factors such as temperature, humidity, hygiene consideration, and the requirement for periodic calibration. Hence, there is a demand for a novel technology that can address these shortcomings. This study delved into the near-infrared wavelength range to investigate optimal wavelengths for non-invasively measuring blood alcohol concentration. Furthermore, we conducted an analysis of the optical characteristics of biological substances, integrated these data into a mathematical model, and demonstrated that alcohol concentration can be accurately sensed using the first-order modeling equation at the optimal wavelength. The goal is to minimize user infection and hygiene issues through a non-destructive and non-invasive method, while applying a compact spectrometer sensor suitable for button-type ignition devices in vehicles. Anticipated applications of this study encompass diverse industrial sectors, including the development of non-invasive ignition button-based alcohol prevention systems, surgeon’s alcohol consumption status in the operating room, screening heavy equipment operators for alcohol use, and detecting alcohol use in close proximity to hazardous machinery within factories. Full article
(This article belongs to the Section Biosensors)
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10 pages, 1781 KiB  
Article
Feature-Assisted Machine Learning for Predicting Band Gaps of Binary Semiconductors
by Sitong Huo, Shuqing Zhang, Qilin Wu and Xinping Zhang
Nanomaterials 2024, 14(5), 445; https://doi.org/10.3390/nano14050445 - 28 Feb 2024
Cited by 5 | Viewed by 3894
Abstract
The band gap is a key parameter in semiconductor materials that is essential for advancing optoelectronic device development. Accurately predicting band gaps of materials at low cost is a significant challenge in materials science. Although many machine learning (ML) models for band gap [...] Read more.
The band gap is a key parameter in semiconductor materials that is essential for advancing optoelectronic device development. Accurately predicting band gaps of materials at low cost is a significant challenge in materials science. Although many machine learning (ML) models for band gap prediction already exist, they often suffer from low interpretability and lack theoretical support from a physical perspective. In this study, we address these challenges by using a combination of traditional ML algorithms and the ‘white-box’ sure independence screening and sparsifying operator (SISSO) approach. Specifically, we enhance the interpretability and accuracy of band gap predictions for binary semiconductors by integrating the importance rankings of support vector regression (SVR), random forests (RF), and gradient boosting decision trees (GBDT) with SISSO models. Our model uses only the intrinsic features of the constituent elements and their band gaps calculated using the Perdew–Burke–Ernzerhof method, significantly reducing computational demands. We have applied our model to predict the band gaps of 1208 theoretically stable binary compounds. Importantly, the model highlights the critical role of electronegativity in determining material band gaps. This insight not only enriches our understanding of the physical principles underlying band gap prediction but also underscores the potential of our approach in guiding the synthesis of new and valuable semiconductor materials. Full article
(This article belongs to the Special Issue Theoretical Chemistry and Computational Simulations in Nanomaterials)
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15 pages, 3640 KiB  
Review
Optical Biosensing of Polarized Light
by Aleksey Kudreyko and Vladimir Chigrinov
Crystals 2023, 13(12), 1680; https://doi.org/10.3390/cryst13121680 - 14 Dec 2023
Cited by 3 | Viewed by 2188
Abstract
Interactions between liquid crystal molecules and target analytes open up various biosensing applications for quick screening and point-of-care applications. In this review, we categorized biosensors by type, depending on the liquid crystal mesophase, and considered several applications for the detection of biomolecules, point-of-care [...] Read more.
Interactions between liquid crystal molecules and target analytes open up various biosensing applications for quick screening and point-of-care applications. In this review, we categorized biosensors by type, depending on the liquid crystal mesophase, and considered several applications for the detection of biomolecules, point-of-care diagnostics and environmental monitoring. We also discuss interactions between polarized light and target pathogens dispersed in biological fluids, which result in the change of the polarization state. An array of the Stokes parameters can be compared with the pattern, and a proper pathogen can be manifested. We suggest that a combination of a micropolarizer array and a complementary metal oxide semiconductor sensor is an optimal setup for the detection of pathogens. Herein, we discuss the working principles of liquid crystal biosensors and their fabrication principles. In addition, relevant theoretical and practical issues related to liquid crystal biosensors are outlined. In general, this review gives an in-depth survey of the research on liquid crystal-based sensors, making it easier for researchers to locate their niche and make contributions to this subject from multiple viewpoints. Full article
(This article belongs to the Section Liquid Crystals)
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