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Keywords = saturated asphalt pavement

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16 pages, 11748 KiB  
Article
Research on the Correlation Between the Chemical Components and the Macroscopic Properties of Asphalt Binder
by Zhihao Li, Xuejuan Cao, Jue Li and Xiaoyu Yang
Materials 2025, 18(3), 610; https://doi.org/10.3390/ma18030610 - 29 Jan 2025
Cited by 3 | Viewed by 933
Abstract
The chemical composition of asphalt binder is closely related to its macroscopic properties, and as an important road building material, its performance directly affects the service performance of asphalt binder pavement. Saturate, aromatic, resin, and asphaltene are the four most common chemical components [...] Read more.
The chemical composition of asphalt binder is closely related to its macroscopic properties, and as an important road building material, its performance directly affects the service performance of asphalt binder pavement. Saturate, aromatic, resin, and asphaltene are the four most common chemical components of asphalt binders, collectively known as the SARA components. The SARA components are used to establish the corresponding relationship between the chemical composition and the macroscopic properties of asphalt binder, which is of great significance for further research on and development of high-performance asphalt pavement materials. This study used eight types of virgin asphalt binders as raw materials, labeled A–H. Firstly, the thin-layer chromatography–flame ionization detection (TLC-FID) method was used to test the SARA contents of the different asphalt binders. Then, the conventional, rheological, and low-temperature properties of the different binders were tested. Finally, gray relational analysis (GRA) and Pearson correlation analysis (PCA) were used to study the correlation between the asphalt binder’s SARA content and its macroscopic properties. The results indicate that the contents of asphaltenes and resins are crucial in determining the high-temperature performance of asphalt binder. By adjusting the ratio of these components, the high-temperature performance of asphalt binder can be optimized. An increase in the content of heavy components, particularly asphaltenes, negatively affects the low-temperature performance of asphalt binder. In contrast, a higher aromatic content enhances its low-temperature performance. Full article
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21 pages, 6032 KiB  
Article
Study on the Properties of Graphene Oxide–Wood Tar-Based Composite Rejuvenated Asphalt
by Ling Feng, Fuyan Zhou, Yongwei Li, Kefei Liu, Juncai Zhu and Guoqing Gong
Coatings 2024, 14(9), 1081; https://doi.org/10.3390/coatings14091081 - 23 Aug 2024
Viewed by 1208
Abstract
This study aims at counteracting the problem of rejuvenated asphalt with poor performance and weak secondary anti-aging ability by improving the existing biomass rejuvenator. In this study, a carbon nanomaterial, graphene oxide (GO) with excellent anti-aging performance, was introduced to the wood tar-based [...] Read more.
This study aims at counteracting the problem of rejuvenated asphalt with poor performance and weak secondary anti-aging ability by improving the existing biomass rejuvenator. In this study, a carbon nanomaterial, graphene oxide (GO) with excellent anti-aging performance, was introduced to the wood tar-based rejuvenator (WR) to prepare a composite rejuvenator. Based on laboratory tests, the effects of the GO–wood tar-based composite rejuvenator (GWCR) on the performance of aged asphalt and on the secondary aging performance were investigated, and its rejuvenation mechanism was analyzed. The results indicate that the GWCR can increase the penetration, ductility, and creep rate (m) of aged asphalt while decreasing its softening point, rutting factor (G*/sinδ), and stiffness modulus (S). This indicates that the high-temperature resistance to the permanent deformation ability of aged asphalt degrades, while the low-temperature performance improves, and all values are slightly greater than those of the 70# original base asphalt. After PAV aging, the S value of the GO–wood tar-based composite rejuvenated asphalt (GWCRA) increased by 83.71%, while the m value decreased by 49.45%. The secondary aging resistance of the GWCRA is better than that of 70# original base asphalt, RA-75 rejuvenated asphalt, and wood tar-based rejuvenated asphalt. When adding the GWCR into aged asphalt, the content of saturates and aromatics in the asphalt increases by 1.08% and 11.1%, respectively. In contrast, the content of asphaltenes and resins decreases by 6.288% and 5.9%, respectively. As a result, the colloidal structure of the aged asphalt transfers from a gel to a sol–gel state. The surface roughness of the GWCRA increases by the synergistic effect of GO and wood tar, making its adhesion better than that of the 70# original base asphalt. Adding GO can improve the performance of wood tar rejuvenated asphalt (WRA) with high-temperature deformation resistance and resistance to secondary aging, and effectively make up for the defects in the performance of WRA rejuvenated asphalt, so as to extend the service life of asphalt pavements, thus increasing the value of wood tar engineering applications, which is of great practical significance. Full article
(This article belongs to the Special Issue Novel Cleaner Materials for Pavements)
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17 pages, 4852 KiB  
Article
Mechanism of Rejuvenation in Aged SBS-Modified Asphalt by Density Functional Theory
by Ping Li, Zhanghui Li and Shenyang Cao
Appl. Sci. 2024, 14(16), 7417; https://doi.org/10.3390/app14167417 - 22 Aug 2024
Viewed by 991
Abstract
As a large area of SBS-modified asphalt pavement entered the maintenance period, the aging and rejuvenation of SBS-modified asphalt have attracted attention in recent years. In order to further study the rejuvenation of aged SBS-modified asphalt, both rheological experiments and quantum mechanical simulations [...] Read more.
As a large area of SBS-modified asphalt pavement entered the maintenance period, the aging and rejuvenation of SBS-modified asphalt have attracted attention in recent years. In order to further study the rejuvenation of aged SBS-modified asphalt, both rheological experiments and quantum mechanical simulations were used. Complex shear modulus (G*) and phase angle (δ) were used to analyze the rejuvenation effect of aged SBS-modified asphalt. Electron density, binding energy (Ebinding), and charge transfer number (Qtransfer) were used to observe the process of rejuvenation in aged SBS-modified asphalt. The results show that compared to asphalt components, SBS polymer was the least stable and most susceptible to breaking. After oxidative aging, SBS polymer with its aging products could impair the rejuvenation in aged asphalt. The interaction between aromatic components in rejuvenator and asphaltenes in aged asphalt was unstable and could be influenced by asphalt aging level. The interaction between heavy component molecules in aged asphalt with saturate component molecules in rejuvenator are closer than those with aromatic components molecules. The binding energies between saturate components in rejuvenator and asphaltenes in aged asphalt could be served as an evaluation indicator of rejuvenation. Full article
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15 pages, 1407 KiB  
Article
A Deep Neural Network Approach towards Performance Prediction of Bituminous Mixtures Produced Using Secondary Raw Materials
by Fabio Rondinella, Cristina Oreto, Francesco Abbondati and Nicola Baldo
Coatings 2024, 14(8), 922; https://doi.org/10.3390/coatings14080922 - 23 Jul 2024
Cited by 2 | Viewed by 1211
Abstract
With the progressive reduction in virgin material availability and the growing global concern for sustainability, civil engineering researchers worldwide are shifting their attention toward exploring alternative and mechanically sound technological solutions. The feasibility of preparing both cold and hot asphalt mixtures (AMs) for [...] Read more.
With the progressive reduction in virgin material availability and the growing global concern for sustainability, civil engineering researchers worldwide are shifting their attention toward exploring alternative and mechanically sound technological solutions. The feasibility of preparing both cold and hot asphalt mixtures (AMs) for road pavement binder layers with construction and demolition wastes (C&DWs) and reclaimed asphalt pavement (RAP) partially replacing virgin materials like limestone aggregates and filler has already been proven. The technical suitability and compliance with technical specifications for road paving materials involved the evaluation of mechanical and volumetric aspects by means of indirect tensile strength tests and saturated surface dry voids, respectively. Thus, the main goal of the present study is to train, validate, and test selected machine learning algorithms based on data obtained from the previous experimental campaign with the aim of predicting the volumetric properties and the mechanical performance of the investigated mixtures. A comparison between the predictions made by ridge and lasso regression techniques and both shallow (SNN) and deep neural network (DNN) models showed that the latter achieved better predictive capabilities, highlighted by fully satisfactory performance metrics. DNN performance can be summarized by R2 values equal to 0.8990 in terms of saturated surface dry void predictions, as well as 0.9954 in terms of indirect tensile strength predictions. Predicted observations can be thus implemented within the traditional mix design software. This would reduce the need to carry out additional expensive and time-consuming experimental campaigns. Full article
(This article belongs to the Section Environmental Aspects in Colloid and Interface Science)
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20 pages, 7546 KiB  
Article
Effect of SARA Fractions on Fatigue Properties of Hard Asphalt
by Jinyi Jiang, Fei Lu, Xiaogang Guo, Peiwen Hao, Wei Wang and Jincheng Yu
Materials 2024, 17(11), 2713; https://doi.org/10.3390/ma17112713 - 3 Jun 2024
Cited by 5 | Viewed by 1328
Abstract
The fatigue performance of hard asphalt is an important factor that affects the service life of asphalt pavement. In order to comprehensively explore the influence of chemical components on the fatigue performance of hard asphalt, and to eliminate the chemical instability between the [...] Read more.
The fatigue performance of hard asphalt is an important factor that affects the service life of asphalt pavement. In order to comprehensively explore the influence of chemical components on the fatigue performance of hard asphalt, and to eliminate the chemical instability between the microstructure of asphalt from different oil sources, seven kinds of hard asphalt were designed and prepared with saturates, aromatics, resins, and asphaltenes (SARA) extracted from the same hard asphalt. Rheological, time sweep and linear amplitude sweep (LAS) tests were carried out to evaluate the fatigue properties. The results show that the complex modulus of asphalt binds increased rapidly with an increase of asphaltene and resins and that the colloidal structure was strengthened, which would increase the fatigue factor. In the time sweep test, the strength of the colloidal structure significantly affected the fatigue life, and the fatigue life was different under different test stresses. In the viscoelastic continuum damage (VECD) model, the cumulative damage was related to the modulus, while with the increase of asphaltene and resins, the fatigue life showed a trend of first increasing and then decreasing. The linear regression analysis showed that the fatigue life of hard asphalt had a good correlation with strain sensitivity. This study investigated the applicability of different fatigue evaluation methods and revealed the influence of four components on the fatigue properties of hard asphalt. The results provide significant insights in the improvement of the fatigue performance of both hard asphalt and corresponding mixtures. Full article
(This article belongs to the Special Issue Sustainable Materials and Structures Used in Pavement Engineering)
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17 pages, 6136 KiB  
Article
Calculation of and Key Influencing Factors Analysis on Equivalent Resilient Modulus of a Submerged Subgrade
by Junyao Tang, Siyu Chen, Tao Ma, Binshuang Zheng and Xiaoming Huang
Materials 2024, 17(4), 949; https://doi.org/10.3390/ma17040949 - 18 Feb 2024
Viewed by 1355
Abstract
To calculate and analyze the equivalent resilient modulus of a submerged subgrade, a constitutive model considering the effect of saturation and matrix suction was introduced using ABAQUS’s user-defined material (UMAT)subroutine. The pavement response under falling weight deflectometer (FWD) load was simulated at various [...] Read more.
To calculate and analyze the equivalent resilient modulus of a submerged subgrade, a constitutive model considering the effect of saturation and matrix suction was introduced using ABAQUS’s user-defined material (UMAT)subroutine. The pavement response under falling weight deflectometer (FWD) load was simulated at various water levels based on the derived distribution of the resilient modulus within the subgrade. The equivalent resilient modulus of the subgrade was then calculated using the equivalent iteration and weighted average methods. Based on this, the influence of the material and structural parameters of the subgrade was analyzed. The results indicate that the effect of water level rise on the tensile strain at the bottom of the asphalt layer and the compressive strain at the top of the subgrade is obvious, and its trend is similar to an exponential change. The equivalent resilient modulus of the subgrade basically decreases linearly with the rise in the water level, and there is high consistency between the equivalent iteration and weighted average methods. The saturated permeability coefficient and subgrade height have the most significant effect on the resilient modulus of the subgrade, which should be emphasized in the design of submerged subgrades, and the suggested values of the resilient modulus of the subgrade should be proposed according to the relevant construction conditions. Full article
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15 pages, 2788 KiB  
Article
Laboratory Investigation and Machine Learning Modeling of Road Pavement Asphalt Mixtures Prepared with Construction and Demolition Waste and RAP
by Fabio Rondinella, Cristina Oreto, Francesco Abbondati and Nicola Baldo
Sustainability 2023, 15(23), 16337; https://doi.org/10.3390/su152316337 - 27 Nov 2023
Cited by 12 | Viewed by 2022
Abstract
Due to the decreasing availability of virgin materials coupled with an increased awareness of environmental sustainability issues, many researchers have focused their efforts on investigating innovative technological solutions in the civil engineering domain. This paper aims to evaluate the suitability of construction and [...] Read more.
Due to the decreasing availability of virgin materials coupled with an increased awareness of environmental sustainability issues, many researchers have focused their efforts on investigating innovative technological solutions in the civil engineering domain. This paper aims to evaluate the suitability of construction and demolition waste (C and DW) and reclaimed asphalt pavement (RAP) reused within asphalt mixtures (AMs) prepared for the binder layer of road pavements. Both hot and cold mixing methodologies were investigated. The technical assessment was based on the volumetric and mechanical suitability, according to saturated surface dry voids (SSDV) and indirect tensile strength (ITS) tests carried out at 10 °C, respectively. Laboratory findings showed that all the hot AMs matched the desired target SSDV at the design gyrations number at different optimum bitumen content levels, alternatively showing a non-significant variation or a significant increase in ITS compared to conventional hot mix asphalt. Conversely, the cold AMs with cement and emulsion bitumen showed a greater volume of voids and moisture sensitivity, and lower temperature susceptibility compared to hot AMs, reaching, on average, 11% lower ITS when using coarse C and DW aggregates and 43% lower ITS when using filler from C and DW. These volumetric and mechanical properties were modeled by means of support vector machines and categorical boosting (CatBoost) machine learning algorithms. The results proved to be satisfactory, with CatBoost determination coefficients R2 referring to SSDV and ITS equal to 0.8678 and 0.9916, respectively. This allowed for the mechanical performance of these sustainable mixtures to be predicted with high accuracy and implemented within conventional mix design procedures. Full article
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16 pages, 30040 KiB  
Article
Influence of Deicer on Water Stability of Asphalt Mixture under Freeze–Thaw Cycle
by Mingjun Guo, Viktor Pavlovich Kovalskiy, Tengfei Nian and Ping Li
Sustainability 2023, 15(18), 13707; https://doi.org/10.3390/su151813707 - 14 Sep 2023
Cited by 9 | Viewed by 1881
Abstract
In seasonal frozen soil areas, the repeated freeze–thaw cycle of internal moisture in asphalt mixture in winter and spring will accelerate the peeling of asphalt film and aggravate the water damage of asphalt pavement. It is of great significance to carry out the [...] Read more.
In seasonal frozen soil areas, the repeated freeze–thaw cycle of internal moisture in asphalt mixture in winter and spring will accelerate the peeling of asphalt film and aggravate the water damage of asphalt pavement. It is of great significance to carry out the attenuation law of mechanical properties of asphalt mixture under freeze–thaw cycles to prevent and reduce the economic losses caused by water damage to asphalt pavement. This study will investigate the impact of deicer application on the water stability of asphalt mixtures within the climatic conditions prevalent in Northwest China. Specifically, freeze–thaw cycle tests were administered to two types of dense-graded asphalt mixtures under three distinct deicer solutions and three disparate low-temperature environments. The Marshall water immersion test and freeze–thaw splitting test were employed to evaluate the water stability of asphalt mixtures subject to multiple factors, and the relative importance of each factor was statistically analyzed using the acquired data. Results demonstrated that AC-13 and AC-16 asphalt mixtures (AC is asphalt-concrete, which is asphalt concrete, and 13 or 16 represents the maximum particle size of aggregate (13 mm or 16 mm)), saturated in 15% CH4N2O, 20% NaCl, and 20% CH2CH3OH solutions, underwent a varying number of freezing–thawing cycles (0, 5, 10, 15, 20, 25, and 30) at temperatures of −5 °C, −15 °C, and −25 °C, respectively, displayed a discernible decline in their residual stability MS0 and freeze–thaw splitting tensile strength ratio TSR. This decline was particularly marked when temperatures dropped below the solution’s freezing point. Disregarding the fixed factors of weather variation (different low-temperature environments) and road service duration (number of freezing–thawing cycles), the aggregate grading imposed a more pronounced influence on asphalt mixture water stability than the presence of deicers. Full article
(This article belongs to the Section Sustainable Materials)
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21 pages, 5077 KiB  
Review
A Methodological Review on Development of Crack Healing Technologies of Asphalt Pavement
by Lei Zhang, Inge Hoff, Xuemei Zhang, Jianan Liu, Chao Yang and Fusong Wang
Sustainability 2023, 15(12), 9659; https://doi.org/10.3390/su15129659 - 16 Jun 2023
Cited by 18 | Viewed by 3729
Abstract
Crack healing has been a key area of asphalt pavement research. In this review, different crack-healing theories and crack-healing evaluation methods in bitumen and asphalt mixtures are summarized and presented. Then different crack healing technologies have highlighted the problems and solutions associated with [...] Read more.
Crack healing has been a key area of asphalt pavement research. In this review, different crack-healing theories and crack-healing evaluation methods in bitumen and asphalt mixtures are summarized and presented. Then different crack healing technologies have highlighted the problems and solutions associated with their implementation. Detailly, traditional technologies (hot pouring and fog seal) are introduced. They mainly fill cracks from the outside, which can effectively prevent further damage to the asphalt pavement, when the cracks have generally developed to the middle and late stages of practical engineering. Their extension of the life of the asphalt pavement is relatively limited. Energy supply technologies (induction and microwave heating) have demonstrated significant efficacy in enhancing the crack healing capability of asphalt pavement, particularly in microcracks. Now, Extensive laboratory testing and some field test sections have been conducted and they are waiting for the promotion from the industry. The agents encapsulated technologies (Saturated porous aggregates encapsulate rejuvenators, Core-shell polymeric microcapsules, Ca-alginate capsule, Hollow fibers and Compartment fibers) not only heal cracks but rejuvenate the aged asphalt pavement. In order to promote industrial application, more field test sections and large industrial mixing and compaction equipment applications need to be implemented. Finally, some other potential crack healing techniques (coupling application, electrical conductivity, 3D printing, and modifications) are also mentioned. Full article
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22 pages, 5761 KiB  
Article
Moisture Sensitivity Evaluation of the Asphalt Mortar-Aggregate Filler Interface Using Pull-Out Testing and 3-D Structural Imaging
by Feng Xu, Xin Nie, Wenxia Gan, Hongzhi E, Peiyao Xu, Hongqiao Cao, Ruifang Gong and Yuxiang Zhang
Coatings 2023, 13(5), 868; https://doi.org/10.3390/coatings13050868 - 4 May 2023
Cited by 7 | Viewed by 2247
Abstract
Moisture damage is one of the undesired distresses occurring in flexible asphalt pavements, mostly through water intrusion that weakens and ultimately degrades the asphalt mortar-aggregate interfacial bond. One method to mitigate this distress is using anti-stripping or anti-spalling filler materials that, however, require [...] Read more.
Moisture damage is one of the undesired distresses occurring in flexible asphalt pavements, mostly through water intrusion that weakens and ultimately degrades the asphalt mortar-aggregate interfacial bond. One method to mitigate this distress is using anti-stripping or anti-spalling filler materials that, however, require a systematic quantification of their interfacial bonding potential and moisture tolerance properties prior to wide-scale field use. With this background, this study was conducted to comparatively evaluate and quantitatively characterize the moisture sensitivity and water damage resistance of the interfacial bonding between the asphalt mortar and aggregate fillers. Using an in-house custom developed water-temperature coupling setup, numerous laboratory pull-out tests were carried out on the asphalt mortar with four different filler materials, namely limestone mineral powder, cement, slaked (hydrated) lime, and waste brake pad powder, respectively. In the study, the effects of moisture wet-curing conditions, temperature, and filler types were comparatively evaluated to quantify the water damage resistance of the asphalt mortar-aggregate filler interface. For interfacial microscopic characterization, the Image-Pro Plus software, 3-D digital imaging, and scanning electron microscope (SEM) were jointly used to measure the spalling rate and the surface micromorphology of the asphalt mortar and aggregate filler before and after water saturation, respectively. In general, the pull-out tensile force exhibited a decreasing response trend with more water damage and interfacial bonding decay as the moisture wet-curing temperature and time were increased. Overall, the results indicated superiority for slaked (hydrated) lime over the other filler materials with respect to enhancing and optimizing the asphalt mortar-aggregate interfacial bonding strength, moisture tolerance, and water damage resistance, respectively—with limestone mineral powder being the poorest performer. Full article
(This article belongs to the Special Issue Novel Green Pavement Materials and Coatings)
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22 pages, 2895 KiB  
Review
Review of Geotechnical Properties of Reclaimed Asphalt Pavement for Reuse in Infrastructure
by Catherine H. Dager, Robert H. Morro, Jonathan F. Hubler and Kristin M. Sample-Lord
Geotechnics 2023, 3(1), 21-42; https://doi.org/10.3390/geotechnics3010003 - 15 Feb 2023
Cited by 4 | Viewed by 4426
Abstract
Reclaimed Asphalt Pavement (RAP) has been extensively studied for potential use as a recycled material in infrastructure construction. There is consensus that utilization of RAP provides environmental and economic benefits for most projects. However, impacts to engineering performance are less known, owing to [...] Read more.
Reclaimed Asphalt Pavement (RAP) has been extensively studied for potential use as a recycled material in infrastructure construction. There is consensus that utilization of RAP provides environmental and economic benefits for most projects. However, impacts to engineering performance are less known, owing to the highly variable nature of RAP sources with different asphalt pavement mixtures and milling processes, which has limited the adoption of RAP as fill material in geotechnical infrastructure. This study conducted a comprehensive review of geotechnical properties reported for RAP in the experimental literature. The gradation, specific gravity, density, moisture content, hydraulic conductivity, leaching, shear strength, and creep properties of different RAP sources are summarized and compared. These geotechnical properties, as well as recent investigations into the effects of temperature and aggregate mixing, were used to identify the potential reuse of RAP in highway transportation applications beyond just asphalt mixture design, such as embankments. Additionally, correlations between gradation properties (Cu, D10, D85), asphalt content, and the geotechnical properties of maximum dry density, saturated hydraulic conductivity, and shear strength were identified. Full article
(This article belongs to the Special Issue Recent Advances in Geotechnical Engineering)
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19 pages, 6766 KiB  
Article
Numerical Simulation and Experimental Measurements of Dynamic Responses of Asphalt Pavement in Dry and Saturated Conditions under Full-Scale Accelerated Loading
by Wentao Wang, Guannan Yan, Kang Zhao and Linbing Wang
Appl. Sci. 2022, 12(23), 12291; https://doi.org/10.3390/app122312291 - 1 Dec 2022
Cited by 6 | Viewed by 1703
Abstract
Asphalt pavement presents diverse dynamic responses to vehicle loading in dry and saturated conditions, which can be systematically explored by numerical simulation. Building a numerical model based on the actual conditions of asphalt pavement is necessary, and relevant field tests should be subsequently [...] Read more.
Asphalt pavement presents diverse dynamic responses to vehicle loading in dry and saturated conditions, which can be systematically explored by numerical simulation. Building a numerical model based on the actual conditions of asphalt pavement is necessary, and relevant field tests should be subsequently conducted to monitor dynamic responses to calibrate and validate the numerical model. On the basis of strictly controlling the paths of vehicle wheels during field tests, this study numerically analyzed the dynamic responses of asphalt pavement in dry and saturated conditions under full-scale accelerated loading. The trends of the modeling results were consistent with those of field measurements. The increase in vehicle load significantly increased the magnitudes of stress, strain, and pore water pressure, while vehicle speed showed an obvious impact on pore water pressure. The dynamic responses decreased with pavement depths. Water made the dynamic responses more complex, and pore water pressure significantly decreased with depth within the upper layer of saturated asphalt pavement. Transverse distributions of indicators presented obvious compressive states in the regions in direct contact with vehicle wheels, while tensile states were found in the range of the middle vehicle axle. The numerical results provided a basis for field measurements in future studies, especially for the exploration of factors of temperature and layer depth. Full article
(This article belongs to the Special Issue Advances in Asphalt Pavement Technologies and Practices)
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12 pages, 1421 KiB  
Article
Performance Evaluation of Aged Asphalt Pavement Binder through Rejuvenators
by Ghulam Yaseen, Arshad Jamal, Meshal Almoshageh, Fawaz Alharbi and Hammad Hussain Awan
Sustainability 2022, 14(21), 14557; https://doi.org/10.3390/su142114557 - 5 Nov 2022
Cited by 4 | Viewed by 2712
Abstract
Natural resources are declining due to rising infrastructure, renovation, demolition, and recycling of existing structures that necessitate sustainable development. It urges the researchers to modify the aged asphalt binder in the recycling to enhance the performance life of asphaltic pavements. The aim of [...] Read more.
Natural resources are declining due to rising infrastructure, renovation, demolition, and recycling of existing structures that necessitate sustainable development. It urges the researchers to modify the aged asphalt binder in the recycling to enhance the performance life of asphaltic pavements. The aim of this research study is to reutilize recycled materials through rejuvenation. This study utilizes the Cereclor to rejuvenate the aged binder collected from recycling and explore its transformation by comparing it with parent binder of similar grade. Different types of tests, such as basic physical properties, saturates, aromatics, resins, and asphaltenes (SARA) analysis for the fractional composition, bending beam rheometer (BBR), and dynamic shear rheometer (DSR) for rheological properties are applied to investigate these properties and effect on the performance. The results show that rejuvenator improved the fractional composition of the aged asphalt binder. It significantly improved the physical properties of the binder. The asphaltene contents are reduced up to 18% in the fractional composition through the addition of the optimum dosage (7.5%) of the rejuvenator. The colloidal instability index was decreased from 0.74 to 0.43 value by changing its unstable to stable colloidal structure. In addition, rejuvenator improved the rheological properties at a wide range of temperatures. The rejuvenator has the potential to soften the aged binder through optimum dosage (7.5%), as indicated in the results of fractional composition, colloidal structure, and rheological properties. Furthermore, it has been concluded that it can be utilized as a rejuvenator in the recycling industry to resolve the recycled materials disposal issues and lead to promote sustainable development. Full article
(This article belongs to the Special Issue Application of Waste Materials in Pavement Structures)
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20 pages, 11547 KiB  
Article
A Coarse-Grained Molecular Model for Simulating Self-Healing of Bitumen
by Liang He, Zhiguang Zhou, Fei Ling, Alessio Alexiadis, Wim Van den Bergh, Augusto Cannone Falchetto, Romain Balieu, Jiqing Zhu, Jan Valentin, Karol J. Kowalski and Lei Zhang
Appl. Sci. 2022, 12(20), 10360; https://doi.org/10.3390/app122010360 - 14 Oct 2022
Cited by 7 | Viewed by 3371
Abstract
The longevity of asphalt pavements is a key focus of road engineering, which closely relates to the self-healing ability of bitumen. Our work aims to establish a CGMD model and matched force field for bitumen and break through the limitations of the research [...] Read more.
The longevity of asphalt pavements is a key focus of road engineering, which closely relates to the self-healing ability of bitumen. Our work aims to establish a CGMD model and matched force field for bitumen and break through the limitations of the research scale to further explore the microscopic mechanism of bitumen self-healing. In this study, a CGMD mapping scheme containing 16 kinds of beads is proposed, and the non-bond potential energy function and bond potential energy function are calculated based on all-atom simulation to construct and validate a coarse-grained model for bitumen. On this basis, a micro-crack model with a width of 36.6nm is simulated, and the variation laws of potential energy, density, diffusion coefficient, relative concentration and temperature in the process of bitumen self-healing are analyzed with the cracking rate parameter proposed to characterize the degree of bitumen crack healing. The results show that the computational size of the coarse-grained simulation is much larger than that of the all-atom, which can explain the self-healing mechanism at the molecular level. In the self-healing process, non-bonded interactions dominate the molecular movement, and differences in the decreased rate of diffusion among the components indicate that saturates and aromatics play a major role in self-healing. Meanwhile, the variations in crack rates reveal that healing time is inversely proportional to temperature. The impact of increasing temperature on reducing healing time is most obvious when the temperature approaches the glass transition temperature (300 K). Full article
(This article belongs to the Special Issue Advances in Asphalt Pavement Technologies and Practices)
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18 pages, 5276 KiB  
Article
Self-Healing Properties of Asphalt Concrete with Calcium Alginate Capsules Containing Different Healing Agents
by Huoming Wang, Miao Yuan, Jie Wu, Pei Wan and Quantao Liu
Materials 2022, 15(16), 5555; https://doi.org/10.3390/ma15165555 - 12 Aug 2022
Cited by 11 | Viewed by 2509
Abstract
Calcium alginate capsules encapsulating rejuvenator are a promising self-healing technology for asphalt pavement, but the effects of different healing agents on the self-healing performance of asphalt concrete has not been considered. In view of this, this paper aimed at exploring the effects of [...] Read more.
Calcium alginate capsules encapsulating rejuvenator are a promising self-healing technology for asphalt pavement, but the effects of different healing agents on the self-healing performance of asphalt concrete has not been considered. In view of this, this paper aimed at exploring the effects of calcium alginate capsules containing different healing agents on the self-healing properties of asphalt concrete. Three types of capsules with sunflower oil, waste cooking oil and commercial rejuvenator were fabricated via the orifice-coagulation bath method and the interior structure, mechanical strength, thermal stability and oil content of the prepared capsules were characterized. The healing levels of asphalt mixtures with different capsules under different loading cycles and stress levels were evaluated. Furthermore, the saturates, aromatics, resins and asphaltenes (SARA) fractions and rheological property of extracted asphalt binder within test beams with different capsules after different loading conditions were assessed. The results indicated that all the three types of capsules meet the mechanical and thermal requirement of mixing and compaction of asphalt mixtures. The healing levels of test beams containing vegetable oil capsules were higher than that of waste cooking oil capsules and industrial rejuvenator capsules. The strength recovery ratio and fracture energy recovery ratio of test beams with vegetable oil capsules reached 82.8% and 96.6%, respectively, after 20,000 cycles of compressive loading at 1.4 MPa. The fracture energy recovery ratio of the waste cooking oil capsules also reached as high as 90%, indicating that waste cooking oil can be used as the healing agent of calcium alginate capsules to improve the self-healing property of asphalt mixture. This work provides a significant guide for the selection of healing agent for self-healing capsules in the future. Full article
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