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Search Results (327)

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20 pages, 8745 KB  
Article
Design Optimization of Sensor-Embedded Bearing Rings in Heavy-Duty Electric Shovel Applications via Multi-Physics Coupling Analysis and Experimental Validation
by Longkai Wang, Fengyuan Liu, Can Hu and Hongbin Tang
Machines 2025, 13(11), 1008; https://doi.org/10.3390/machines13111008 (registering DOI) - 1 Nov 2025
Abstract
To enhance the thermo-mechanical coupling performance of heavy-duty bearings with smart sensing capability in electric shovel applications, this study proposes a multi-objective optimization methodology for sensor-embedded bearing rings incorporating smart sensor-embedded grooves. Driven by multi-physics coupling analysis and experimental validation, a coupled thermal–mechanical [...] Read more.
To enhance the thermo-mechanical coupling performance of heavy-duty bearings with smart sensing capability in electric shovel applications, this study proposes a multi-objective optimization methodology for sensor-embedded bearing rings incorporating smart sensor-embedded grooves. Driven by multi-physics coupling analysis and experimental validation, a coupled thermal–mechanical model integrating frictional heat generation, heat transfer, and stress response was established. Parametric finite element simulations were conducted, with varying groove depths and axial positions. A comprehensive performance index combining three metrics—maximum temperature, equivalent stress, and principal strain—was formulated to evaluate design efficacy. Experimental tests on thermal and strain responses were employed to validate the simulation model confirming its predictive ability. Among the 21 parameter combinations, the configuration featuring an 8 mm groove depth located 20 mm from the large end face exhibited relatively optimal synergy across thermal dissipation, structural strength, and strain sensitivity. The proposed framework provides a certain theoretical and practical guidance for the design and optimization of the sensor-embedded groove structure in intelligent heavy-duty bearings. Full article
(This article belongs to the Section Machine Design and Theory)
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17 pages, 4669 KB  
Article
Compact Bio-Inspired Terahertz Ultrawideband Antenna: A Viburnum tinus-Based Approach for 6G and Beyond Applications
by Jeremiah O. Abolade, Dominic B. O. Konditi, Pradeep Kumar and Grace Olaleru
J. Sens. Actuator Netw. 2025, 14(6), 107; https://doi.org/10.3390/jsan14060107 - 30 Oct 2025
Abstract
A compact bio-inspired terahertz wideband antenna is presented in this work. The proposed antenna is based on Viburnum tinus leaf shape, a defective ground plane, a folded-ring slot, and parasitic elements. The footprint of the proposed antenna is [...] Read more.
A compact bio-inspired terahertz wideband antenna is presented in this work. The proposed antenna is based on Viburnum tinus leaf shape, a defective ground plane, a folded-ring slot, and parasitic elements. The footprint of the proposed antenna is 0.46 × 0.18 λg2 at 0.18 THz. A bandwidth of 0.536 THz (0.18–0.72 THz) is achieved with a band notch at 0.35 THz (0.3–0.36 THz). The proposed antenna has a peak gain of 5 dBi and the stable radiation patterns. The proposed antenna is validated through a finite difference time domain simulator and the equivalent circuit analysis. The results from show a good correlation. Also, an extensive parametric analysis is performed, and the comparative analysis of the proposed antenna with the existing antennas shows that the proposed antenna is compact with competitive performance metrics such as gain, efficiency, and notch-band characteristics. Therefore, the proposed antenna (hereafter referred to as VTB-A) is a promising candidate for future terahertz wireless communications (5G, 6G, and beyond) and terahertz imaging. Full article
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16 pages, 3146 KB  
Article
Predictive Control and Manufacturing of Rotation Accuracy of Angular Contact Ball Bearings (ACBBs)
by Chaojun Wang, Dongfeng Wang, Xiaofei Li, Huqiang Wang, Dengke Li, Gang Chen and Lai Hu
J. Manuf. Mater. Process. 2025, 9(10), 333; https://doi.org/10.3390/jmmp9100333 - 13 Oct 2025
Viewed by 342
Abstract
High-precision angular contact ball bearings (ACBBs) are critical components in advanced manufacturing equipment, where rotation accuracy directly determines system performance and stability. Considering error superposition and equipment processing capability comprehensively, this study establishes an error analysis and control model of the ACBBs, studies [...] Read more.
High-precision angular contact ball bearings (ACBBs) are critical components in advanced manufacturing equipment, where rotation accuracy directly determines system performance and stability. Considering error superposition and equipment processing capability comprehensively, this study establishes an error analysis and control model of the ACBBs, studies the error transmission law, and puts forward a rotation accuracy control strategy for batch manufacturing of precision ACBBs. The ACBBs 7020C/P4, 7020AC/P4, 7020A/P4, and 7020B/P4 (four conventional contact angles of 15°, 25°, 30°, 40°) were taken as examples to verify the experiment. The error of the calculation compared with actual test results was not more than 7.5%, which had good accuracy and practicability. The research shows that the roundness error of bearing raceway, the thickness difference in bearing ring wall, and the parallelism error of raceway to end face were the main influencing factors of bearing rotation accuracy Kia, Sia, Kea, and Sea. The influence coefficient of raceway roundness error on the axial runout of bearing (Sia, Sea) decreased rapidly with the increase in contact angle, while the influence coefficient on radial runout (Kia, Kea) remained constant. The rotation accuracy error of the outer ring was always greater than that of the inner ring, and this law was not affected by the contact angle. Moreover, with the increase in contact angle, the radial runout of the inner and outer rings of the bearing increased. During actual machining, bearings with larger contact angle place lower demands on the equipment process capability index (Cp), particularly on the parameter Cer. This reduction in required capability is equivalent to an effective Cp improvement of about 30%. Full article
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18 pages, 4365 KB  
Article
Thermo-Mechanical Coupled Characteristics for the Non-Axisymmetric Outer Ring of the High-Speed Rail Axle Box Bearing with Embedded Intelligent Sensor Slots
by Longkai Wang, Can Hu, Fengyuan Liu and Hongbin Tang
Symmetry 2025, 17(10), 1667; https://doi.org/10.3390/sym17101667 - 6 Oct 2025
Viewed by 313
Abstract
As high-speed railway systems continue to develop toward intelligent operation, axle box bearings integrated with sensors have become key components for real-time condition monitoring. However, introducing sensor-embedded slots disrupts the structural continuity and thermal conduction paths of traditional bearing rings. This results in [...] Read more.
As high-speed railway systems continue to develop toward intelligent operation, axle box bearings integrated with sensors have become key components for real-time condition monitoring. However, introducing sensor-embedded slots disrupts the structural continuity and thermal conduction paths of traditional bearing rings. This results in localized stress concentrations and thermal distortion, which compromise the bearing’s overall performance and service life. This study focuses on a double-row tapered roller bearing used in axle boxes and develops a multi-physics finite element model incorporating the effects of sensor-embedded grooves, based on Hertzian contact theory and the Palmgren frictional heat model. Both contact load verification and thermo-mechanical coupling analysis were performed to evaluate the influence of two key design parameters—groove depth and arc length—on equivalent stress, temperature distribution, and thermo-mechanical coupling deformation. The results show that the embedded slot structure significantly alters the local thermodynamic response. Especially when the slot depth reaches a certain value, both stress and deformation due to thermo-mechanical effects exhibit obvious nonlinear escalation. During the design process, the length and depth of the arc-shaped embedded slot, among other parameters, should be strictly controlled. The study of the stress and temperature characteristics under the thermos-mechanical coupling effect of the axle box bearing is of crucial importance for the design of the intelligent bearing body structure and safety assessment. Full article
(This article belongs to the Section Engineering and Materials)
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27 pages, 20230 KB  
Article
Mitigation of Switching Ringing of GaN HEMT Based on RC Snubbers
by Xi Liu, Hui Li, Jinshu Lin, Chen Song, Honglang Zhang, Yuxiang Xue and Hengbin Zhang
Aerospace 2025, 12(10), 885; https://doi.org/10.3390/aerospace12100885 - 30 Sep 2025
Viewed by 333
Abstract
Gallium nitride high electron mobility transistors (GaN HEMTs), characterized by their extremely high switching speeds and superior high-frequency performance, have demonstrated significant advantages, and gained extensive applications in fields such as aerospace and high-power-density power supplies. However, their unique internal architecture renders these [...] Read more.
Gallium nitride high electron mobility transistors (GaN HEMTs), characterized by their extremely high switching speeds and superior high-frequency performance, have demonstrated significant advantages, and gained extensive applications in fields such as aerospace and high-power-density power supplies. However, their unique internal architecture renders these devices highly sensitive to circuit parasitic parameters. Conventional circuit design methodologies often induce severe issues such as overshoot and high-frequency oscillations, which significantly constrain the realization of their high-frequency performance. To solve this problem, this paper investigates the nonlinear dynamic behavior of GaN HEMTs during switching transients by establishing an equivalent impedance model. Based on this model, a detailed analysis is implemented to elucidate the mechanism by which RC Snubber circuits influence the system’s resonance frequency and the amplitude at the resonant frequency. Through this analysis, an optimal RC Snubber circuit parameter is derived, enabling effective suppression of high-frequency oscillations during the switching transient of GaN HEMT. Experimental results demonstrate that the proposed design achieves a maximum reduction of 40% in voltage overshoot, shortens the ringing time to one-twentieth of the original value, and suppresses noise by 20 dB in the high-frequency range of 20 MHz to 30 MHz, thereby significantly enhancing the stability and reliability of circuit operation. Additionally, considering the heat dissipation requirements in high power density scenarios, this work optimizes the layout of devices, and heat sinks to maintain operational temperatures within safe limits, further mitigating the impact of parasitic parameters on overall system performance. Full article
(This article belongs to the Section Aeronautics)
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17 pages, 6335 KB  
Article
Impedance Resonant Channel Shaping for Current Ringing Suppression in Dual-Active Bridge Converters
by Yaoqiang Wang, Zhaolong Sun, Peiyuan Li, Jian Ai, Chan Wu, Zhan Shen and Fujin Deng
Electronics 2025, 14(19), 3823; https://doi.org/10.3390/electronics14193823 - 26 Sep 2025
Viewed by 241
Abstract
Current ringing in dual-active bridge (DAB) converters significantly degrades efficiency and reliability, particularly due to resonant interactions in the magnetic tank impedance network. We propose a novel impedance resonant channel shaping technique to suppress the ringing by systematically modifying the converter’s equivalent impedance [...] Read more.
Current ringing in dual-active bridge (DAB) converters significantly degrades efficiency and reliability, particularly due to resonant interactions in the magnetic tank impedance network. We propose a novel impedance resonant channel shaping technique to suppress the ringing by systematically modifying the converter’s equivalent impedance model. The method begins with establishing a high-fidelity network representation of the magnetic tank, incorporating transformer parasitics, external inductors, and distributed capacitances, where secondary-side components are referred to the primary via the turns ratio squared. Critical damping is achieved through a rank-one modification of the coupling denominator, which is analytically normalized to a second-order form with explicit expressions for resonant frequency and damping ratio. The optimal series–RC damping network parameters are derived as functions of leakage inductance and winding capacitance, enabling precise control over the effective damping factor while accounting for core loss effects. Furthermore, the integrated network with the damping network dynamically shapes the impedance response, thereby attenuating ringing currents without compromising converter dynamics. Experimental validation confirms that the proposed approach reduces peak ringing amplitude by over 60% compared to the conventional snubber-based methods, while maintaining full soft-switching capability. Full article
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16 pages, 4419 KB  
Article
Thermoplasmonic Nanorings via Sputter Deposition
by Xavier Baami González, Peter K. Petrov and Duncan S. Sutherland
Materials 2025, 18(18), 4371; https://doi.org/10.3390/ma18184371 - 18 Sep 2025
Viewed by 542
Abstract
The fabrication of plasmonic nanostructures with precise geometries and scalable production remains a critical challenge for advancing light–matter interaction technologies in applications such as sensing, photonics, and thermal management. Here, we present a versatile, self-assembly-based strategy for metallic nanoring fabrication. We extend Hole-mask [...] Read more.
The fabrication of plasmonic nanostructures with precise geometries and scalable production remains a critical challenge for advancing light–matter interaction technologies in applications such as sensing, photonics, and thermal management. Here, we present a versatile, self-assembly-based strategy for metallic nanoring fabrication. We extend Hole-mask Colloidal Lithography (HCL) by employing ring-shaped holes to produce nanorings via direct current (DC) magnetron sputtering. The process relies entirely on industry-standard thin-film techniques, enabling wafer-scale integration. Using this approach, we fabricate copper (Cu) nanorings with tunable near-infrared (NIR) resonances suitable for thermoplasmonic applications. The thermoplasmonic performance of these nanorings is evaluated under direct sunlight, revealing efficient photon-to-heat conversion. Nanorings displayed enhanced heating, outperforming nanodisks of equivalent size, with maximum surface temperatures reaching approximately 37 °C, an increase of over 13 °C above ambient, in contrast to the 6 °C increase shown by disks that reached a temperature of 30 °C. This superior performance is attributed to the nanoring geometry, which promotes stronger light absorption and localized heating. Overall, our results demonstrate that Cu nanorings represent a robust and scalable plasmonic platform with significant potential for solar-driven technologies and thermal management applications. Full article
(This article belongs to the Section Metals and Alloys)
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20 pages, 4448 KB  
Article
AFSS Wide-Frequency Reconfigurable Design and Electromagnetic Characterization Research
by Lei Gong, Xinru Tian, Ge Zhang, Xuan Liu, Shigeng Song, Jian Song, Haoyang Liu, Liguo Wang and Zhiqiang Yang
Electronics 2025, 14(18), 3628; https://doi.org/10.3390/electronics14183628 - 12 Sep 2025
Viewed by 452
Abstract
In order to solve the dynamic adaptation problem of the working frequency band of the FSS in the complex electromagnetic environment and further expand the frequency tuning range, a reconfigurable AFSS unit model based on PIN and varactor diodes are designed, which can [...] Read more.
In order to solve the dynamic adaptation problem of the working frequency band of the FSS in the complex electromagnetic environment and further expand the frequency tuning range, a reconfigurable AFSS unit model based on PIN and varactor diodes are designed, which can achieve the insertion loss below−1 dB in the wide frequency range of 10.2–15.2 GHz, meet the working-band switching, and allow for flexibly adjusting the working frequency point. In order to verify the accuracy of the design method, a square-ring aperture and notched patch-coupling structure that can exhibit broadband transmission response in the X-Ku band is first proposed based on the equivalent circuit model topology. A numerical simulation and a processing test of the structure are carried out. The measured data are in good agreement with the simulation results. After optimizing the unit structure, different capacitance values and resistance values are added to the diodes in the numerical simulation to control the equivalent PIN diode switch and the capacitance change in the varactor diodes. According to the equivalent circuit model and the electric-field intensity distribution, the AFSS regulation mechanism of the loaded diodes is explored. In this paper, through numerical simulation optimizations and experimental verification, the design method and performance optimization strategy of frequency-tunable FSS in the working range of 2–18 GHz are systematically studied, which provides theoretical support for the design of electromagnetic functional devices in the new generation of communication, radar, and electronic warfare systems. Full article
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21 pages, 5183 KB  
Article
Evaluating Ecological Contributions of Tree Assemblages in Urban Expressway Interchange Landscapes: A Case Study from Nanjing, China
by Mingxing Xu and Lu Ding
Forests 2025, 16(8), 1355; https://doi.org/10.3390/f16081355 - 20 Aug 2025
Viewed by 724
Abstract
Urban expressway interchanges, though primarily engineered for traffic efficiency, also serve as crucial ecological nodes within urban landscapes. This study evaluates the ecological functions of arborous vegetation across four typical interchange configurations—cloverleaf, single trumpet, double trumpet, and irregular—along the Nanjing Ring Expressway. Using [...] Read more.
Urban expressway interchanges, though primarily engineered for traffic efficiency, also serve as crucial ecological nodes within urban landscapes. This study evaluates the ecological functions of arborous vegetation across four typical interchange configurations—cloverleaf, single trumpet, double trumpet, and irregular—along the Nanjing Ring Expressway. Using the i-Tree Eco model, we quantified key ecosystem services, including carbon sequestration and storage, air pollutant removal, and stormwater mitigation. Field surveys documented 7985 trees from 45 species, with the 10 most abundant accounting for over two-thirds of total individuals. Results revealed that the trees sequester around 115 tons of carbon annually and store nearly 1850 tons in total, equivalent to an estimated economic benefit of ¥5.8 million. Trees also removed more than 1.5 tons of air pollutants and intercepted nearly 2400 cubic meters of stormwater each year. Species such as Sophora japonica, Phoebe zhennan, and Cinnamomum camphora emerged as key contributors to ecological performance. Among interchange types, double trumpet configurations yielded the highest overall service value, while single trumpet interchanges demonstrated superior efficiency per unit area. These findings highlight the underutilized ecological potential of transport-adjacent green spaces and underscore the importance of species selection and spatial design in maximizing multifunctional benefits. Full article
(This article belongs to the Special Issue Ecosystem Services of Urban Forest)
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27 pages, 7925 KB  
Article
Development and Verification of a Centrifugal Pump Rotor Model Based on Integrated Multibody Dynamics in the ADAMS Environment
by Madina Isametova, Rollan Nussipali, Gulbarshyn Smailova, Layla Sabirova, Arailym Tursynbayeva, Laila Sagatova, Denis Tkachenko and Nazym Saidinbayeva
Appl. Sci. 2025, 15(16), 9132; https://doi.org/10.3390/app15169132 - 19 Aug 2025
Viewed by 913
Abstract
This study proposes a novel computational method, employing the integral dynamics of multibody systems to simulate the transverse vibrations of the rotor in a cantilever-type centrifugal pump. This method was applied to the kinematic assembly of the rotor and its supports, with the [...] Read more.
This study proposes a novel computational method, employing the integral dynamics of multibody systems to simulate the transverse vibrations of the rotor in a cantilever-type centrifugal pump. This method was applied to the kinematic assembly of the rotor and its supports, with the latter modeled as springs possessing stiffness and damping properties equivalent to those of real bearings supporting the shaft in an actual design. To investigate transverse vibrations within the system, three key observation points were defined—at the locations of the left and right bearings, as well as at the rotor’s center of mass—to allow for a thorough dynamic analysis. Additionally, the influence of motor rotational speed and the impeller’s eccentricity on the transverse vibrations of the supports and the shaft was examined. The results have revealed that transverse vibrations significantly affect the system’s dynamics at lower rotational speeds, leading to the classification of the shaft as flexible. As the rotational speed increases, the system exhibits enhanced dynamic stability. Furthermore, it was found that for impellers with a diameter less than 300 mm, the unbalanced forces are negligible and can be disregarded in pump design. To reduce vibration levels, an elastic damping ring was selected and incorporated into the system. This novel method provides an effective tool for analyzing the transverse vibrations of centrifugal pump rotors and for optimizing vibration mitigation strategies. Full article
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18 pages, 4003 KB  
Article
Understanding the Paradigm of Molecular-Network Conformations in Nanostructured Se-Rich Arsenoselenides AsxSe100−x (x < 10)
by Oleh Shpotyuk, Zdenka Lukáčová Bujňáková, Yaroslav Shpotyuk and Andriy Kovalskiy
Molecules 2025, 30(16), 3380; https://doi.org/10.3390/molecules30163380 - 14 Aug 2025
Viewed by 533
Abstract
The paradigm of molecular-network conformations in Se-rich glassy arsenoselenides AsxSe100−x compositionally approaching pure Se (x < 10) is considered, employing comprehensive XRD analysis of diffuse peak-halos and nanocrystalline reflections from the known Se polymorphs in their XRD patterns. Within a [...] Read more.
The paradigm of molecular-network conformations in Se-rich glassy arsenoselenides AsxSe100−x compositionally approaching pure Se (x < 10) is considered, employing comprehensive XRD analysis of diffuse peak-halos and nanocrystalline reflections from the known Se polymorphs in their XRD patterns. Within a modified microcrystalline model, the changes with growing Se content in these alloys are interpreted in terms of suppression in intermediate range ordering due to shifting to high diffraction angles and a narrowed FSDP (first sharp diffraction peak)-related diffuse peak-halo, accompanied by enhancement in extended range ordering due to a shift to low diffraction angles and a broadened SSDP (second sharp diffraction peak)-related peak-halo. Overlapping of these peak-halos is enhanced in Se-rich alloys, tending towards unified FSDP-SSDP-related halos with characteristic doublet asymmetry due to the remnants of nanocrystalline trigonal t-Se. Drastic enhancement of the crystallization processes related to the trigonal t-Se phase is a principal feature of nanostructurization effects in Se-rich glassy arsenoselenides driven by nanomilling. The nanostructurization response in these alloys is revealed as a fragmentation impact on the correlation length of the FSDP-responsible entities, accompanied by an agglomeration impact on the correlation length of the SSDP-responsible entities. The FSDP- and SSDP-related diffuse peak-halos become more distinguishable in the XRD patterning of nanostructured arsenoselenides, being associated with other contributions from crystalline remnants, such as those expected in transition to glassy arsenoselenides with higher Se content. An irregular sequence of randomly distributed cis- and trans-configurated multiatomic Se linkages is visualized by ab initio quantum-chemical modeling of Sen chain- and ring-like conformations. The most critical point of molecular-network disproportionality analysis in the examined arsenoselenide AsxSe100−x glassy alloys obeying the chain-crossing model corresponds to x = 7 (equivalent to 93 at. % of Se in the binary As-Se system), as an equilibrium point between mixed cis-trans-configurated Se7 chains and exceptionally cis-configurated molecular Se8 rings. At the basis of developed models, the paradigm of thermodynamically stable molecular-network conformations in the nanostructured Se-rich arsenoselenides AsxSe100−x (x < 10) is surely resolved in favor of chain-like network-forming conformations composed of mixed cis-trans-configurated network-forming multiatomic Se fragments. Full article
(This article belongs to the Special Issue Exclusive Feature Papers in Physical Chemistry, 3rd Edition)
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22 pages, 7373 KB  
Article
Study of the Thermal Performance of Oil-Cooled Electric Motor with Different Oil-Jet Ring Configurations
by Hao Yang, Fan Wu, Jinhao Fu, Junxiong Zeng, Xiaojin Fu, Guangtao Zhai and Feng Zhang
Energies 2025, 18(16), 4302; https://doi.org/10.3390/en18164302 - 13 Aug 2025
Viewed by 1166
Abstract
This study investigates the thermal performance of an oil-jet-cooled permanent magnet synchronous motor (PMSM), with a particular focus on end-winding heat dissipation. A high-fidelity numerical model that preserves the full geometric complexity of the end-winding is developed and validated against experimental temperature data, [...] Read more.
This study investigates the thermal performance of an oil-jet-cooled permanent magnet synchronous motor (PMSM), with a particular focus on end-winding heat dissipation. A high-fidelity numerical model that preserves the full geometric complexity of the end-winding is developed and validated against experimental temperature data, achieving average deviations below 7%. To facilitate efficient parametric analysis, a simplified equivalent model is constructed by replacing the complex geometry with a thermally equivalent annular region characterized by calibrated radial conductivity. Based on this model, the effects of key spray ring parameters—including orifice diameter, number of nozzles, inlet oil temperature, and flow rate—are systematically evaluated. The results indicate that reducing the orifice diameter from 4 mm to 2 mm lowers the maximum winding temperature from 162 °C to 153 °C but increases the pressure drop from 205 Pa to 913 Pa. An optimal nozzle number of 12 decreases the peak winding temperature to 155 °C compared with 162 °C for 8 nozzles, while increasing the oil flow rate from 2 L/min to 6 L/min reduces the peak winding temperature from 162 °C to 142 °C. Furthermore, a non-uniform spray ring configuration decreases maximum stator, winding, spray ring, and shaft temperatures by 5.6–9.2% relative to the baseline, albeit with a pressure drop increase from 907 Pa to 1410 Pa. These findings provide quantitative guidance for optimizing oil-jet cooling designs for PMSMs under engineering constraints. Full article
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26 pages, 3805 KB  
Article
Ferrocene-Catalyzed Aromatization and Competitive Oxidative Ring Transformations of 1,2-Dihydro-1-Arylpyridazino[4,5-d]Pyridazines
by Dániel Hutai, Tibor Zs. Nagy, Veronika Emődi and Antal Csámpai
Catalysts 2025, 15(8), 742; https://doi.org/10.3390/catal15080742 - 4 Aug 2025
Viewed by 1049
Abstract
This paper presents the expected and unexpected, but typically substituent-dependent, ferrocene-catalyzed DDQ-mediated oxidative transformations of a series of 5,8-bis(methylthio)-1-aryl-1,2-dihydropyridazino[4,5-d]pyridazines and 8-(3,5-dimethyl-1H-pyrazol-1-yl)-5-(methylthio)-1-aryl-1,2-dihydropyridazino[4,5-d]pyridazines. Under noncatalytic conditions the reactions were sluggish, mainly producing a substantial amount of undefined [...] Read more.
This paper presents the expected and unexpected, but typically substituent-dependent, ferrocene-catalyzed DDQ-mediated oxidative transformations of a series of 5,8-bis(methylthio)-1-aryl-1,2-dihydropyridazino[4,5-d]pyridazines and 8-(3,5-dimethyl-1H-pyrazol-1-yl)-5-(methylthio)-1-aryl-1,2-dihydropyridazino[4,5-d]pyridazines. Under noncatalytic conditions the reactions were sluggish, mainly producing a substantial amount of undefined tarry materials; nevertheless, the ferrocene-catalyzed reactions of the 5,8-bis(methylthio)-substituted precursors gave the aromatic products the expected aromatic products in low yields. Their formation was accompanied by ring transformations proceeding via aryne-generating fragmentation/Diels–Alder (DA)/N2-releasing retro Diels–Alder (rDA) sequence to construct arene-fused phthalazines. On the other hand, neither the noncatalytic nor the catalytic reactions of the 8-pyrazolyl-5-methylthio-substituted dihydroaromatics yielded the expected aromatic products. Instead, depending on their substitution pattern, the catalytic reactions of these pyrazolyl-substituted precursors also led to the formation of dearylated arene-fused phthalazines competing with an unprecedented multistep fragmentation sequence terminated by the hydrolysis of cationic intermediates to give 4-(methylthio)pyridazino[4,5-d]pyridazin-1(2H)-one and the corresponding 3,5-dimethyl-1-aryl-1H-pyrazole. When 0.6 equivalents of DDQ were applied in freshly absolutized THF, a representative pyrazolyl-substituted model underwent an oxidative coupling to give a dimer formed by the interaction of the cationic intermediate, and a part of the N-nucleophilic precursor remained intact. A systematic computational study was conducted on these intriguing reactions to support their complex mechanisms proposed on the basis of the structures of the isolated products. Full article
(This article belongs to the Special Issue Catalysis in Heterocyclic and Organometallic Synthesis, 3rd Edition)
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25 pages, 1765 KB  
Article
Trigger-Based Systems as a Promising Foundation for the Development of Computing Architectures Based on Neuromorphic Materials
by Dina Shaltykova, Kaisarali Kadyrzhan, Jelena Caiko, Yelizaveta Vitulyova and Ibragim Suleimenov
Technologies 2025, 13(8), 326; https://doi.org/10.3390/technologies13080326 - 31 Jul 2025
Cited by 1 | Viewed by 451
Abstract
It is demonstrated that neuromorphic materials designed for computational tasks can be effectively implemented by drawing an analogy with trigger-based systems built upon classical binary elements. Among the most promising approaches in this context are systems that perform computations based on the Residue [...] Read more.
It is demonstrated that neuromorphic materials designed for computational tasks can be effectively implemented by drawing an analogy with trigger-based systems built upon classical binary elements. Among the most promising approaches in this context are systems that perform computations based on the Residue Number System (RNS). A specific implementation of a trigger-based adder employing the proposed methodology is presented and tested through simulation modeling. This adder utilizes the representation of natural numbers as elements of a subtraction ring modulo P, where P is the product of Mersenne prime numbers. This configuration enables component-wise, independent execution of arithmetic operations. It is further shown that analogous trigger-based systems can be realized using recurrent neural network analogs, particularly those implemented with neuromorphic materials. The study emphasizes that it is possible to construct a neural network, especially one based on neuromorphic substrates, that can perform logical operations equivalent to those executed by conventional binary circuitry. A key challenge in the proposed approach lies in implementing an operation analogous to the carry mechanism employed in classical binary adders. An algorithm addressing this issue is proposed, based on the transition from computations modulo P to computations modulo 2P. Full article
(This article belongs to the Section Information and Communication Technologies)
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12 pages, 5121 KB  
Article
Design of an Energy Selective Surface Employing Dual-Resonant Circuit Topology
by Honglin Zhang, Jihong Zhang, Song Zha, Huan Jiang, Tao Zhou, Chenxi Liu and Peiguo Liu
Electronics 2025, 14(15), 3029; https://doi.org/10.3390/electronics14153029 - 30 Jul 2025
Cited by 1 | Viewed by 434
Abstract
A dual-polarization energy selective surface (ESS) with low insertion loss (IL) and high shielding effectiveness (SE) based on a dual-resonant equivalent circuit topology was proposed for high-intensity radiation field (HIRF) protection in this paper. The design principle was elucidated through an equivalent circuit [...] Read more.
A dual-polarization energy selective surface (ESS) with low insertion loss (IL) and high shielding effectiveness (SE) based on a dual-resonant equivalent circuit topology was proposed for high-intensity radiation field (HIRF) protection in this paper. The design principle was elucidated through an equivalent circuit model and translated into a physical ESS implementation. It consists of two resonant rings, vertically arranged and loaded with diodes, along with two lumped capacitors. Simulation and measurement results demonstrate that the IL is less than 3 dB when in the OFF state in a working frequency band, and the SE exceeds 20 dB when in the ON state. Moreover, the ESS’s dual-polarization, low cost, and easy-to-design characteristics hold great promise for broad applications in protecting communication and radar systems in complex electromagnetic environments. Full article
(This article belongs to the Section Microelectronics)
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