Search Results (16)

The geopolitical and economic situation impacts raw materials demand. As principal ore deposits reach exhaustion, the study of new sources of raw materials becomes essential. Therefore, mining wastes emerge as alternative sources of raw materials. Their physicochemical properties, such as small particle size or concentration of some metals of interest, enhance reprocessing. A number of critical raw materials (As, Co, Cu, Sb) and base metals (Pb, Zn), as well as precious metals (Ag), were found present in an abandoned tailing deposit composed by finely grounded washed roasted pyrites within the Iberian Pyrite Belt. Copper leaching from a sample of this deposit was investigated. Two hydrometallurgical approaches were studied: acidic leaching with and without activated carbon; and alkaline leaching with glycine solutions. Leaching tests were carried out during 24 h at ambient and moderate temperatures (60 °C). In acidic medium, the maximum copper extraction varied from 88 to 92.5%, while in alkaline medium, the maximum copper extraction was in the range of 71%–76%. Using activated carbon and H₂O₂ seemed to slightly promote the copper extraction with the maximum extraction (92.5%) after 2 h of leaching at 60 °C. Complementarily, above 50% of the zinc and cobalt contained were extracted. In contrast, temperature in alkaline conditions played a key role in reaction speed, but also in precipitation of copper insoluble compounds. In addition, the glycine solution at pH 10–10.5 showed high selectivity for copper over zinc, iron, lead, arsenic, and antimony. Two extra tests at pH above 12 showed arsenic dissolution (up to 51% at pH 12.5). Full article

The growing demand for green and, therefore, sustainable technologies present new challenges for our society. The European Union (EU) identified the critical raw materials (CRMs) and strategic raw materials (SRMs) necessary for these technologies and introduced policies to reduce reliance on external suppliers, which includes investigating the recovery of CRMs from extractive waste. This study assesses the recovery potential of mine waste collected in the Traversella mine district (Piedmont, Italy), known for its polymetallic Fe-Cu-W deposit. The characterization of waste rock samples involved chemical and mineralogical analyses, revealing metallic-bearing minerals such as magnetite and scheelite. Laboratory-scale magnetic and gravity separation tests were carried out and compared. Magnetic separation resulted in a recovery of 75.4% of Fe, 72.3% of Cu, and 83.7% of W, with a weak concentration. Instead, gravity separation produced high-grade Fe (67.6%) and W (1289 ppm) concentrate with lower recovery rates. Full article

Mining operations for the extraction and processing of useful geological materials are common anthropogenic activities that generate enormous quantities of waste that can alter the natural balance. In this way, soil, water and air are contaminated with waste that contains heavy metals, acids and many other compounds that are toxic to the environment and health. Minimizing and eradicating these pollutants is an arduous but necessary task. That is why, in the present work, the physical, chemical and mineralogical characterization of metallurgical mining waste was carried out using analytical techniques. Tests and trials were also carried out to assess the degree of toxicity, corrosiveness and chemical capacity to generate acid mine drainage. In general, it was found that this waste does not contain active toxic elements or elements that could be corrosive. However, due to the residual content of sulfide minerals, it can generate acid mine drainage, which could contaminate groundwater. Likewise, it can be seen that due to the content of heavy metals and minerals such as quartz and feldspars, this waste can be reprocessed to recover metals and subsequently separate, by flotation, the associated silica and feldspar, which can be used in the glass and cement industry. Full article

The management of mine tailings presents a global challenge. Re-mining these tailings to recover remaining metals could play a crucial role in reducing the volume of stored tailings, as historical mining methods were less efficient than those used today. Consequently, mine wastes have the potential to become unconventional resources for critical minerals. To assess this potential, critical minerals and metals in the mine tailings were investigated through sampling, characterization, and 3D geostatistical modeling. The Bleïda copper mine tailings in Morocco were modeled, and residual copper resources were estimated using ordinary kriging (OK). Tailings were systematically sampled at a depth of 1.8 m using a triangular grid and tubing method. The metallic and mineralogical content of the samples was analyzed, and a numerical 3D model of the tailing’s facility was created using topographic drone surveys, geochemical data, and geostatistical modeling. The results from the 3D block model of the Bleïda tailings facility reveal that the volume of deposited tailings is 3.73 million cubic meters (mm³), equivalent to 4.85 million tonnes (Mt). Furthermore, based on the average copper grade (~0.3% by weight) in the studied part of the tailings pond, the copper resources are estimated at 2760 tonnes. Mineralogical characterization indicates that this metallic content is mainly associated with sulfide and carbonate minerals, which exhibit a low degree of liberation. This study aims to serve as a reference for assessing the reprocessing feasibility of tailings in both abandoned and active mines, thereby contributing to the sustainable management of mine tailings facilities. Geostatistical modeling has proven effective in producing tonnage estimates for tailings storage facilities and should be adopted by the industry to reduce the technical and financial uncertainties associated with re-mining. Full article

Remining has been researched for decades, but its potential to supplement virgin extraction is currently unknown. This review addresses the remining of tailings/waste rock, coal residues, and byproduct and primary production materials for renewable energy metals (e.g., Co, Ni, REEs, Mn, Li). Geochemical characterization methods for estimating pollution potential must be supplemented with mineral liberation analysis and process testing to reliably estimate remining’s economic potential. National and regional remining characterization efforts currently exist in the U.S., Europe, Australia, and China but will take years to produce viable operations at scale. Tailings hold the most promise due to their large amounts worldwide and the fact that they are already extracted and pre-processed, which reduces energy and water use. Of the processing approaches examined, bioleaching appears to offer the most benefits with the fewest potential downsides. The advantages and challenges of the processing methods and remining sources are presented. Best remining practices are urgently needed to improve resource estimates and avoid impacts such as the tailings dam failures that occurred at remining operations in Romania and South Africa. Interest in remining is booming because it can increase domestic supply. If properly conducted, remining can also improve circularity and environmental conditions in areas affected by existing and legacy mining activity. Full article

The legacy of the early days of the Atomic Age consists of many problematic sites worldwide, including radioactive waste dumps, uranium mines, spent fuel reprocessing plants, and defunct processing and enrichment plants. Although nature quickly reclaims abandoned sites, any remaining radioisotopes can pose a threat for millennia to come, long after the benefits gained from nuclear technology have faded. The field of nuclear industrial archaeology specialises in finding and characterising these sites to support local communities and site owners. Where maps and building plans have been lost, nuclear archaeologists deploy state-of-the-art analysis techniques on the ground to unravel the current state of legacy sites, and quantify the remaining radioactive inventories to the standard required by the nation the site is located within. The objectives of nuclear industrial archaeology are varied and site dependent. Whether the objective is to puzzle the forgotten history of activity back together or safeguard and recover dangerous radioactive materials, nuclear industrial archaeology adapts radioanalytical laboratory and site-surveying techniques in order to understand the site and allow scientists to communicate this information to support remediation efforts. This paper discusses current methodologies alongside a case study. Full article

An urgent technological, economic and environmental task of mining and metallurgical enterprises is to involve poor, off-balance and hard-to-beneficiate ores in the technological process, as well as accumulated and current waste from mining and metallurgical industries. As the reserves of developed deposits are depleted, technogenic objects may become a priority, and in some cases the only, source of mineral raw materials. Mining wastes represent a large reserve of raw materials for the extraction of non-ferrous and precious metals, and at the same time, they are centers of local or regional environmental pollution. Stale waste re-processing may promote territorial cultivation and reduce the environmental burden. The conventional methods of poor ore and waste treatment do not fully provide for a sufficient separation degree of high metal extraction, and lead to significant valuable ore losses, while the quality of the obtained concentrates often does not meet the requirements for subsequent technological process. In this regard, the development of novel chelating agents with specific functional groups that can selectively adsorb on the mineral surface, change the contrast of chemical surface composition and improve the flotation properties of mineral complexes, is an innovative solution for increasing their flotation selectivity. Furthermore, the synthesis and application of novel flotation reagents may help to replace toxic reagents by ecologically friendly or less-toxic ones. Full article

The Hiendelaencina district in Spain was the most important silver producer in Europe during 1844–1925. At the end of the 20th century, with mines having closed, some waste rock dumps were reprocessed, and the sludge from the flotation process was stored in two tailings ponds. When this activity ceased, the residues began to be eroded and disperse. In this study, the state of degradation of both deposits was evaluated using historical mapping and light detection and ranging (LiDAR) data, incorporated into a Geographic Information System. In the aerial images (1946–2018), mine tailings and their main erosive and sedimentary forms were mapped. Geoforms linked to hydrological (channels, gullies, alluvial cones), wind (eolian mantles), hydric–gravitational (colluvium) and anthropic (motorbike tracks) processes which move sludge into the surrounding areas were identified. A net loss of 8849 m³ of sludge, a release of 10.3 t of potentially polluting substances and a high erosion rate of 346 t/ha*year were calculated based on LiDAR data from 2009 and 2014. The ponds show a current high degree of erosion that could increase due to both human activity and the growing frequency of drought and torrential rain periods if stabilization measures are not undertaken. Full article

The main goal of this study was to identify potential chemical elements present in three types of polymetallic mine waste, stored in the old mine site of São Domingos, located in the Iberian Pyrite Belt, Alentejo, Southern Region of Portugal. This study involves the characterization of potential resources in those mine residues, bearing in mind that its reprocessing can facilitate the environmental remediation and rehabilitation activities which are underway at the site. X-ray Fluorescence (XRF) and micro (μ)-XRF 2D mapping surveys were performed. Univariate and multivariate data analysis reveal that differences in compositions are mainly related with element concentration per type of waste. Image processing and clustering analysis allowed the recognition of distinct elemental spatial distribution patterns. Some of these residues, although classified as archeological-industrial heritage materials may present toxicity to the ecological environment and to human health. This fact enhances, therefore, geoethical doubts regarding its remining and exploitability. In this context, a multi-criteria decision analysis considering two geoethical alternatives was performed. Full article

The possibility of replacing the traditional components of the filling mass with man-made waste and the need for the use of mechanical activation of the components of the filling composite in order to improve its rheological characteristics and the strength of the mass after solidification are proved. The demand for resource-reproducing technologies that allow the most complete use of the industrial mineral resource potential of the mining and processing enterprise, which will lead to a multiplicative ecological and economic effect, is confirmed. It is necessary to introduce the re-processing of man-made waste in order to further extract the useful component to a level that meets the standards of environmental safety and economic feasibility, which would create conditions for the actual sustainable development and give some perspectives for extending the operating time of mining regions. It is established that the sustainable development of the mining and processing region is impossible without a highly efficient exploitation of natural deposits and man-made georesources in combination with an integrated approach to the development of subsurface resources. Full article

Tungsten is recognized as a critical metal due to its unique properties, economic importance, and limited sources of supply. It has wide applications where hardness, high density, high wear, and high-temperature resistance are required, such as in mining, construction, energy generation, electronics, aerospace, and defense sectors. The two primary tungsten minerals, and the only minerals of economic importance, are wolframite and scheelite. Secondary tungsten minerals are rare and generated by hydrothermal or supergene alteration rather than by atmospheric weathering. There are no reported concerns for tungsten toxicity. However, tungsten tailings and other residues may represent severe risks to human health and the environment. Tungsten metal scrap is the only secondary source for this metal but reprocessing of tungsten tailings may also become important in the future. Enhanced gravity separation, wet high-intensity magnetic separation, and flotation have been reported to be successful in reprocessing tungsten tailings, while bioleaching can assist with removing some toxic elements. In 2020, the world’s tungsten mine production was estimated at 84 kt of tungsten (106 kt WO₃), with known tungsten reserves of 3400 kt. In addition, old tungsten tailings deposits may have great potential for exploration. The incomplete statistics indicate about 96 kt of tungsten content in those deposits, with an average grade of 0.1% WO₃ (versus typical grades of 0.3–1% in primary deposits). This paper aims to provide an overview of tungsten minerals, tungsten primary and secondary resources, and tungsten mine waste, including its environmental risks and potential for reprocessing. Full article

The anthropogenic pollution of lake ecosystems by human activities (e.g., mining industries) is recognized as a serious issue. The Osisko urban lake located in Rouyn-Noranda (Quebec, Canada) was used partially as a waste disposal facility for many decades, causing a heavy pollution. The main undertakings of this study are (i) assessing the mineralogical and geochemical properties of lake Osisko sediments, and (ii) studying the pollution that occurred within lake water due to the sediments’ reactivity. Water and sediments across the lake were collected in different sensitive locations. Within the sediment samples, two parts were distinguished: a small layer of black vase over grey sediments. The black vase resembled organic matter while the gray sediment seemed close to clean lake sediments. The collected samples were characterized for their physical (particle size distribution, specific gravity and specific surface area), chemical (minor and major elements as well as total sulfur and carbon) and mineralogical (X-ray diffraction and scanning electron microscope) properties. Additionally, the reactivity of sediments was studied using weathering cells to quantify chemical species leaching and their releasing rates. The results showed that the vase was the only contaminated part with high concentrations of sulfur and metals such as copper, zinc and iron. Geochemical data showed that the composite sample and the vase potentially cause contaminated acid drainage if they are exposed to atmospheric conditions. Indeed, the pH values of the leachates from both samples were between 4 and 6, while those corresponding to sediments remained around circumneutral values. Quantitatively, the contaminant release from the tested samples was variable. Indeed, the Fe cumulative concentrations were around 200, 80 and 20 mg/kg for the vase, composite and sediment samples, respectively. Similarly, the Zn cumulative concentrations were around 4500, 4200, and below the detection limit for vase, composite and sediment samples, respectively. The same tendency was observed for Cu, S, and Fe. Thus, sediments within Osisko lake present a risk for water contamination if they are resuspended or dredged out of the lake. Consequently, they should be stabilized before their disposal. The samples’ high Cu contents also offer the possibility of their reprocessing. Full article

Inorganic acids are commonly used in mining, metallurgical, metal-processing, and nuclear-fuel-reprocessing industries in various processes, such as leaching, etching, electroplating, and metal-refining. Large amounts of spent acidic liquids containing toxic metal ion complexes are produced during these operations, which pose a serious hazard to the living and non-living environment. Developing economic and eco-friendly regeneration approaches to recover acid and valuable metals from these industrial effluents has focused the interest of the research community. Diffusion dialysis (DD) using anion exchange membranes (AEMs) driven by an activity gradient is considered an effective technology with a low energy consumption and little environmental contamination. In addition, the properties of AEMs have an important effect on the DD process. Hence, this paper gives a critical review of the properties of AEMs, including their acid permeability, membrane stability, and acid selectivity during the DD process for acid recovery. Furthermore, the DD processes using AEMs integrated with various technologies, such as pressure, an electric field, or continuous operation are discussed to enhance its potential for industrial applications. Finally, some directions are provided for the further development of AEMs in DD for acid recovery from acidic waste solutions. Full article

The generation of mining waste commonly led to the use of spaces for its disposal. Challenges like mitigating the damage to surrounding communities have promoted the need to reuse, recycle and/or reduce their generation. Besides, these residues may become a source of materials, which are capable of being recovered and reused in several industries, minimizing the environmental impact. In the mining region of Pachuca, Mexico, waste from the mining industry have been generated for more than 100 years, which have a high SiO₂ content that can be recovered for various industrial applications. This work aims to recover silica from a material of the Dos Carlos dam. A columnar system composed of two-stage of cleaning was used, considering a J_LT (surface liquid rate) value of 0.45 and 0.68 cm/s, respectively; while the J_g (surface gas rate) value was 0.30 cm/s for both stages. Similar bubble sizes in the range of J_g 0.10 to 0.30 cm/s, with values between 0.14 and 0.16 cm in the first stage, and 0.05 to 0.06 cm in the second one. This provided a recovery of 75.10% for all the allotropic phases of silica (quartz, trydimite, and cristobalite) leaving a concentration of 24.90% of a feldspathic phase (orthoclase), as flotation tails. Full article