Search Results (672)

Despite widespread implementation, current waste management practices—such as landfilling and incineration—are associated with significant environmental drawbacks, including greenhouse gas emissions and resource loss. Consequently, the search for more sustainable and environmentally friendly waste valorization methods has highlighted oxidative liquefaction as a promising pathway. This study focused on two critical waste streams: personal protective equipment (PPE) and municipal solid waste (MSW). These categories were selected due to the significant increase in PPE waste generated during the recent pandemic, as well as the need to develop effective strategies to address potential future surges in such waste streams. Experiments were carried out at 200–300 °C, with waste-to-liquid ratios of 3–7% and oxidant concentrations of 30–60 wt.%. The aim was to demonstrate the potential of oxidative liquefaction as a thermochemical conversion route for resource recovery, enabling the breakdown of the organic matrix of PPE and MSW into valuable liquid products such as fine chemicals or a source of carbon in biotechnological processes. Chromatographic analyses, combined with chemometric methods, revealed how temperature, waste-to-liquid ratio, and oxidant concentration affected the yield and composition of oxygenated chemical compounds (OCCs). Using raw chromatographic data directly in optimization eliminated the need for manual gas chromatography (GC) signal processing and provided a faster approach to process evaluation. The results confirmed distinct differences in degradation behavior and OCC formation between PPE and MSW, with maximum yields of 183–212 gOCC/kg for PPE and 51–69 gOCC/kg for MSW. These findings highlight the strong influence of physicochemical waste properties on degradation and product composition. Overall, oxidative liquefaction shows significant potential as a waste-to-value strategy, supporting renewable fuels, chemical precursors, and circular economy development within the framework of biomass, biofuels, and waste valorization. Full article

The universal need for sustainable and renewable energy sources has accelerated the shift towards bioenergy as a valuable option to fossil fuels. However, a significant challenge remains in the underutilisation of biomass resources and the environmental pollution caused by improper biomass disposal methods. Biochar, a by-product of biomass pyrolysis rich with carbon, serves as a means to convert underused biomass into valuable energy and a tool for environmental remediation. Biochar can be integrated into a biorefinery for improved bioelectricity and biogas production, but there are challenges with regard to its production scalability, quality control, and standardisation. This article provides a comprehensive review of the prospective processes useful in the valorisation of biomass into biochar for bioenergy, co-firing potential with fossil fuels, and in waste biomass transformation. This article also provides insight into business development and policy-making by bioentrepreneurs, bioengineers, and the government, as it identifies grey opportunities for bioenergy production and improvement. The prospect of AI technology in improving the production, quality, and yield of biochar, by identifying the most efficient parameters and conditions, as well as optimising the application of biochar in various industries, is also highlighted. The transition to biofuels in aviation, a step towards a future in the industry that is more sustainable, is also suggested in this review. Full article

Mining activities have caused widespread land degradation and contamination, affecting millions of hectares worldwide and posing persistent ecological risks. However, reclamation substrates are constrained by limited availability and compromised quality, which restricts their ability to fully support mine ecological restoration. Among various amendment materials, biomass-based amendments have been widely applied due to their broad availability, renewability, biodegradability, and low cost. In recent years, their role has expanded beyond simple nutrient supplementation to encompass multiple functions, including structural optimization, pollutant stabilization, and microbial regulation. This review highlights the valorisation of biomass-derived solid wastes as multifunctional amendments for mine ecological restoration. By converting agricultural and industrial wastes into green materials, these amendments improve substrate structure, stabilize heavy metals and organic pollutants, enhance nutrient cycling, and stimulate microbial activity. Potential risks, including nutrient leaching, secondary pollution, and greenhouse gas emissions, are critically assessed, with emphasis on their variability under different environmental conditions. By integrating functional benefits with ecological risks, this work underscores the critical role of biomass-based amendments as waste-to-resource strategies in advancing sustainable mine reclamation, contributing to circular economy goals, and supporting environmental engineering practices. Full article

This study presents a complete and zero-waste valorization strategy for barley straw through the synthesis of bio-polyols and the concurrent utilization of its cellulose fraction as lignin-containing cellulose nanofibers (LCNF) for the development of bio-based polyurethane (PU) foams. Two types of bio-polyols were prepared: one derived from lignin isolated via biomass fractionation, named lignin bio-polyol (LBP), and another obtained directly from unfractionated barley straw, called straw bio-polyol (SBP), thereby incorporating all lignocellulosic constituents into a single reactive matrix. LCNF, produced from the same feedstock, was incorporated at different loadings to achieve full biomass utilization and reinforce the polyurethane foam structure. Foams prepared with LBP exhibited lower density and a more homogeneous structure, whereas those synthesized with SBP developed a stiffer, more crosslinked network. The incorporation of LCNF generally increased apparent density and mechanical performance, with optimal reinforcement at 3 wt.% in foams with SBP and 5 wt.% in LBP foams, corresponding to a 62.5 and 121% enhancement in compressive strength relative to their respective control foams. Moreover, the use of barley straw bio-polyol shifted some thermal degradation peaks toward higher temperatures, evidencing improved thermal resistance. Overall, this dual-route strategy provides a sustainable and versatile methodology for the comprehensive valorization of lignocellulosic biomass, enabling a systematic understanding of the role of each structural component in polyurethane foam synthesis. The resulting materials offer a renewable, low-impact pathway toward high-performance polymeric materials. Full article

This study provides the first comprehensive evaluation of the biochemical hydrogen production (BHP) potential of Acrocomia aculeata pulp waste, a residue abundantly generated during fruit processing in Latin America. The valorization of this underused biomass is essential to promote circular bioeconomy strategies and expand renewable energy sources in the region. The fermentative hydrogen potential of untreated pulp and of fractions obtained after subcritical water pretreatment was assessed under mesophilic conditions to quantify hydrogen yields and elucidate the energy distribution between solid and liquid phases. Pretreatments were performed at 150, 200, and 250 °C, and both fractions were individually tested. The untreated pulp achieved the highest BHP (125.1 NmL H₂/g VS fed), while pretreated solids showed decreasing values of 118.1, 71.6, and 41.6 NmL H₂/g VS fed at 150, 200, and 250 °C, respectively. The liquid fractions yielded 107.2, 79.4, and 76.0 NmL H₂/g COD fed, showing a similar decline with increasing severity. A mass-energy balance revealed that 1 ton of residual pulp could produce up to 104 m³ H₂, equivalent to 15 GJ/ha-year, while the combined solid plus liquid fractions from pretreatment at 150 °C recovered a comparable 14.5 GJ/ha-year, with 65% of hydrogen energy originating from the liquid phase. More severe conditions led to up to 40% lower total energy yields. These findings demonstrate that A. aculeata pulp waste inherently exhibits high fermentative hydrogen potential without requiring hydrothermal pretreatment, highlighting its direct applicability as a renewable substrate for sustainable biohydrogen production. Full article

The growing scarcity of natural renewable resources has accelerated interest in producing nanomaterials from waste streams. Nanomaterials offer exceptional reinforcement capabilities for advanced composites, driving the need for sustainable and scalable production routes. While prior reviews have broadly examined nanomaterial synthesis from biomass or industrial residues, they often overlook textile waste as a strategic feedstock. This review uniquely focuses on the upcycling of textile waste—one of the most abundant yet underutilized waste streams—into high-value nanomaterials, thereby advancing circular economy principles. Unlike earlier studies that primarily discuss energy recovery or generic recycling, this work systematically explores mechanical, chemical, and thermal conversion routes tailored for textiles, leading to the production of cellulose nanofibers, cellulose nanocrystals, and carbon nanoparticles, which represent a significant class of biodegradable nanomaterials. Furthermore, a comprehensive analysis of the physicochemical properties of the nanomaterials and their emerging applications in water purification and environmental remediation is provided. An alternative pathway for nanomaterial synthesis from waste rather than renewable sources, providing information on the effective extraction of nanomaterials from mixed fiber compositions and dye residues present in textile waste, is also highlighted. By addressing current challenges and outlining future research directions, this review establishes a roadmap for sustainable textile waste valorization, marking a critical step toward eco-friendly nanomaterial production. Full article

Anaerobic digestion (AD) produces renewable energy but releases biogenic CO₂ and generates digestate requiring management. This paper evaluates four emerging pathways for CO₂ capture and reuse in AD systems: (1) in situ CO₂ conversion to CH₄ via microbial electrolysis cells (MECs), (2) hydrogenotrophic CO₂ methanation using green hydrogen, (3) enzymatic CO₂ capture coupled with autotrophic algae cultivation, and (4) digestate pyrolysis with syngas biomethanation. Each pathway is assessed in terms of technical feasibility, biocatalyst performance, system configuration, and key implementation challenges. Integrated scenarios demonstrate up to 98% CO₂ emission reduction, substantial bioenergy yield improvements, and enhanced nutrient and biomass recovery compared to conventional AD. MEC-based and hydrogenotrophic pathways show the highest energy efficiency, while algae-based systems provide added bioproduct valorization. The remaining limitations include cost, process integration, and scale-up. The study defines development priorities to advance zero-emission AD technologies for the agri-food and waste management sectors. Full article

The increasing challenge of waste disposal and the growing demand for reliable renewable energy sources are particularly critical in developing countries. Waste-to-Energy technologies have emerged as a promising approach to harness the energy potential of waste in an economically viable and environmentally sustainable manner. This study provides a global overview of scientific developments and technological trends in Waste-to-Energy through a bibliometric analysis of 1869 documents retrieved from the Web of Science database, covering the period 2017–2021 and focusing on the field of bioenergy. Here, the term bioenergy is used in a broad sense, encompassing energy recovery from both biogenic waste (e.g., food waste, agricultural residues) and non-biogenic waste (e.g., plastics, synthetic polymers) under the Waste-to-Energy framework. The analysis revealed that developing countries prioritize specific technologies for energy recovery: anaerobic digestion for organic waste, incineration for non-biodegradable mixed waste, and pyrolysis and gasification for carbon-rich waste streams such as biomass and plastics. Landfilling is mentioned solely as a final disposal route for inert materials, not as an energy recovery pathway. Additionally, research highlights the potential benefits of synergistic combinations of raw materials in improving product quality and reducing pollution in Waste-to-Energy processes. This bibliometric and content-based review supports future research efforts by identifying key trends, influential contributions, and critical implementation challenges. The findings underscore the role of Waste-to-Energy technologies as valuable tools in sustainable waste management strategies, especially in regions where improving energy access and reducing environmental impact are pressing concerns. Full article

Aqueous phase reforming has been posed as a promising technology for renewable hydrogen production in the framework of the transition to a sustainable energy economy. Since the use of chemical compounds as process feedstock has proven to be one of the major constraints to its potential scalability, several cost-free residual biomasses have been investigated as alternative substrates. This also allows for the recovery of residues, offsetting the significant costs of waste management through conventional treatment. In recent years, different wastes from the food processing industry such as brewery, fish canning, dairy industries, fruit juice extraction, and corn production wastewaters, have taken the attention of scientific community due to their composition, favorable to this process, and its high-water content. However, few and heterogeneous results can be found within the literature, suggesting that the research into this application is now at a stage of development which will require further investigation. Therefore, this work is focused on compiling and discussing the reported studies, aiming to present a critical reflection on the potential of aqueous phase reforming as a means for the valorization of this kind of residue. Full article

This work presents a preliminary “Strengths, Weaknesses, Opportunities, and Threats” (SWOT) analysis followed by a “Correct, Adapt, Maintain, and Explore” (CAME) analysis on wood sawdust biofuel. New designs of sawdust biofuels boilers and reactors require gathering relevant information on the main characteristics of sawdust biofuels. Optimisation algorithms require not only the numerical parameters needed to find optimal solutions but also the consideration of scenarios related to the use of this type of biofuel. This work provides complementary information to create a comprehensive framework for assessing the viability and sustainability of integrating wood sawdust into diverse energy production systems. This includes an examination of the current state of sawdust utilisation, its environmental implications, and the potential of valorising this abundant biomass resource. This review further delves into the technical aspects of converting sawdust into biofuel pellets, examining various technical processes involved in its physical analysis. The intended audience of this review encompasses researchers, mechanical designers, policymakers, and industry strategists and stakeholders interested in sustainable energy solutions and waste management strategies, providing a holistic perspective on the opportunities presented by wood sawdust as a renewable energy source. Full article

The growing global demand for clean energy and sustainability has increased interest in lignocellulosic biomass as a viable alternative to conventional fossil fuels. Among the various biomass resources, sugarcane bagasse, an abundant agro-industrial by-product, has emerged as a promising feedstock to produce renewable fuels and value-added chemicals. Its high carbohydrate content offers significant potential for bioconversion. However, its complex and recalcitrant lignocellulosic matrix presents significant challenges that necessitate advanced pretreatment techniques to improve enzymatic digestibility and fermentation efficiency. This review consolidates recent developments in the valorization of sugarcane bagasse focusing on innovative pretreatment and fermentation strategies for sustainable bioethanol production. It emphasizes the synergistic benefits of integrating various pretreatment and fermentation methods to improve bioethanol yields, reduce processing costs and enhance overall process sustainability. This review further explores recent technological advancements, the impact of fermentation inhibitor, and emerging strategies to overcome these challenges through microbial strains and innovative fermentation methods. Additionally, it highlights the multi-faceted advantages of bagasse valorization, including waste minimization, renewable energy production and the promotion of sustainable agricultural practices. By evaluating the current state of research and outlining future perspectives, this paper serves as a comprehensive guide to advancing the valorization of sugarcane bagasse in the transition towards a low-carbon economy. The novelty of this review lies in its holistic integration of technological, economic, and policy perspectives, uniquely addressing the scalability of integrated pretreatment and fermentation processes for sugarcane bagasse, and outlining practical pathways for their translation from laboratory to sustainable industrial biorefineries within the circular bioeconomy framework. Full article

The growing demand for air connectivity, coupled with the forecasted increase in passengers by 2040, implies an exigency in the aviation sector to adopt sustainable approaches for net zero emission by 2050. Sustainable Aviation Fuel (SAF) is currently the most promising short-term solution; however, ensuring its overall sustainability depends on reducing the life cycle carbon footprints. A key challenge prevails in hydrogen usage as a reactant for the approved ASTM routes of SAF. The processing, conversion and refinement of feed entailing hydrodeoxygenation (HDO), decarboxylation, hydrogenation, isomerisation and hydrocracking requires substantial hydrogen input. This hydrogen is sourced either in situ or ex situ, with the supply chain encompassing renewables or non-renewables origins. Addressing this hydrogen usage and recognising the emission implications thereof has therefore become a novel research priority. Aside from the preferred adoption of renewable water electrolysis to generate hydrogen, other promising pathways encompass hydrothermal gasification, biomass gasification (with or without carbon capture) and biomethane with steam methane reforming (with or without carbon capture) owing to the lower greenhouse emissions, the convincing status of the technology readiness level and the lower acidification potential. Equally imperative are measures for reducing hydrogen demand in SAF pathways. Strategies involve identifying the appropriate catalyst (monometallic and bimetallic sulphide catalyst), increasing the catalyst life in the deoxygenation process, deploying low-cost iso-propanol (hydrogen donor), developing the aerobic fermentation of sugar to 1,4 dimethyl cyclooctane with the intermediate formation of isoprene and advancing aqueous phase reforming or single-stage hydro processing. Other supportive alternatives include implementing the catalytic and co-pyrolysis of waste oil with solid feedstocks and selecting highly saturated feedstock. Thus, future progress demands coordinated innovation and research endeavours to bolster the seamless integration of the cutting-edge hydrogen production processes with the SAF infrastructure. Rigorous techno-economic and life cycle assessments, alongside technological breakthroughs and biomass characterisation, are indispensable for ensuring scalability and sustainability. Full article

The biogas sector is undergoing development as a result of the growing demand for renewable energy. Methane fermentation allows for the acquisition of energy that is universally usable, while also facilitating the neutralization of problematic waste. Sewage sludge generated as a result of a number of technological processes occurring during wastewater treatment requires appropriate management, and its volume increases every year. In this work, the task was to determine the suitability of sewage sludge for co-digestion with agricultural biomass. The research allowed for the determination of the positive impact of using sewage sludge for fermentation with agricultural biomass. The amount of biogas produced and the methane content were higher compared to the single-component fermentation of agricultural biomass. Mixed sludge had a particularly beneficial effect on fermentation. The largest amount of biogas was obtained from maize silage input and mixed sludge, i.e., 309 Ndm³·k⁻¹ d.m. The methane content in this mixture reached a maximum level of 63%. The least productive was mixture no. 4, consisting exclusively of apple pomace. It produced the smallest amount of biogas (96 Ndm³/kg d.m.) and the process occurred with the greatest delay. The rate of the process was similar for mixtures 3 and 4 for an extended period. In the case of mixture no. 2, there was initially a slightly higher inhibition of the process, but by day 17, it had reached the biogas yield level of mixture 3. The amount of biogas produced for mixtures 2 and 3 was 119 and 133 Ndm³/kg d.m., respectively. From day 22 onwards, the process for all mixtures was coming to an end, with no significant biogas yields observed until the end of the study period. Such a high methane content increases the energy value of biogas, which in practice means a higher yield of electricity and heat from the same amount of feedstock, and thus lower unit costs of energy production. Co-digestion of maize silage, apple pomace, and beet pulp with sewage sludge can be a successful practice in biogas plants. Full article

Anaerobic digestion is a well-known technology for renewable energy generation. Its efficiency depends on the substrate composition and its biodegradability. Microalgae are considered a promising feedstock due to their rapid growth, high protein and lipid content, and potential for wastewater treatment. However, the mono-digestion is often limited by a low carbon-to-nitrogen (C/N) ratio and a recalcitrant cell wall structure. This study evaluated the potential of co-digesting microalgal biomass with bakery waste under batch conditions. Two types of bakery residues (stale wheat bread and stale wheat rolls), were tested. Each was added to the microalgal biomass at proportions of 25%, 50%, and 75% based on volatile solids (VS). The experiment was carried out in a semi-technical anaerobic digester under mesophilic conditions. During the anaerobic digestion, the biogas volume, gas composition, and the energy potential of the substrates were analysed. The highest biogas yield (494.34 L·kg⁻¹ VS) was obtained from the mixture of microalgae and 75% bread. Although mono-digestion of microalgal biomass resulted in the highest methane concentration, the differences compared to co-digested samples were not significant. The lowest hydrogen sulphide concentration (234.20 ppm) was measured in the 25% rolls variant, while the control sample (100% microalgae) showed the highest H₂S levels. From an energy perspective, the most beneficial result was obtained with the addition of 75% bread. Full article

When renewable resources such as biomass, waste, or carbon dioxide together with renewable electrical energy are used, Fischer–Tropsch (FT) synthesis is a promising option for the sustainable production of fuels and petrochemicals conventionally derived from crude oil. As such renewable resources generally do not occur in large point sources like fossil fuels, future sustainable FT facilities will likely be substantially smaller in scale than their fossil counterparts, which will have a significant impact on their design. A core topic in the reimagination of such smaller-scale facilities will be the reduction in complexity of the FT gas loop. To this end, three simple gas loop designs for the conversion of syngas from biomass gasification were conceived, simulated in DWSIM, and compared regarding their performance. Concepts only employing an internal recycle were found to be inherently limited in terms of efficiency. To achieve high efficiencies, an external recycle with a tail gas reformer and high tail gas recycling ratios (>3) were required. Thereby, the carbon dioxide content of the syngas had a considerable influence on the required syngas H₂/CO ratio, making the separation efficiency of the carbon dioxide removal unit a suitable control parameter in this respect. Full article