Search Results (14)

The mechanical properties of grouting materials and their cured grouts significantly impact the reinforcement effectiveness in deep coal mine roadways. This study employed shear rheology tests of slurry, structural tests, NMR (nuclear magnetic resonance), and uniaxial compression tests to comparatively analyze the mechanical characteristics of a composite cement-based grouting material (HGC), ordinary Portland cement (OPC), and sulfated aluminum cement (SAC) slurry and their cured grouts. The HGC (High-performance Grouting Composite) slurry is formulated with 15.75% sulfated aluminum cement (SAC), 54.25% ordinary Portland cement (OPC), 10% fly ash, and 20% mineral powder, achieving a water/cement ratio of 0.26. The results indicate that HGC slurry more closely follows power-law flow characteristics, while OPC and SAC slurries fit better with the Bingham model. The structural recovery time for HGC slurry after high-strain disturbances is 52 s, significantly lower than the 312 s for OPC and 121 s for SAC, indicating that HGC can quickly produce hydration products that re-bond the flocculated structure. NMR T2 spectra show that HGC cured grouts have the lowest porosity, predominantly featuring inter-nanopores, whereas OPC and SAC have more super-nanopores. Uniaxial compression tests show that the uniaxial compressive strength of HGC, SAC, and OPC samples at various curing ages gradually decreases. Compared to traditional cementitious materials, HGC exhibits a rapid increase in uniaxial compressive strength within the first seven days, with an increase rate of approximately 77.97%. Finally, the relationship between micropore distribution and strength is analyzed, and the micro-mechanisms underlying the strength differences of different grouting materials are discussed. This study aids in developing a comparative analysis system of mechanical properties for deep surrounding rock grouting materials, providing a reference for selecting grouting materials for various engineering fractured rock masses. Full article

Acid-etched zirconia has emerged as a high-strength alternative to traditional glass ceramics for laminate veneers in aesthetic dentistry. This randomized, double-blind controlled clinical trial aimed to evaluate the one-year clinical performance of zirconia veneers etched with a hydrofluoric-nitric acid mixture and bonded using a 10-methacryloyloxydecyl dihydrogen phosphate (MDP) containing polymeric adhesive system, compared to lithium disilicate veneers. Fifty-two patients were treated with either translucent zirconia or lithium disilicate veneers, and restorations were bonded using light-cured resin-based adhesives. Clinical parameters, including veneer survival, esthetics, marginal adaptation, postoperative sensitivity, and periodontal health, were assessed using modified United States Public Health Service (USPHS) criteria and periodontal indexes at 2 weeks, 6 months, and 12 months. Both materials showed high survival rates with no statistically significant differences in clinical outcomes. One zirconia veneer debonded early but was successfully rebonded without fracture, while one lithium disilicate veneer fractured upon debonding. The findings support the viability of acid-etched zirconia veneers bonded with polymer-based adhesives as a durable and esthetic restorative option. The study highlights the clinical relevance of polymeric bonding systems in enhancing zirconia veneer performance and reinforces their role in modern adhesive dentistry. Full article

Dynamic polymer networks combine the noteworthy (thermo)mechanical features of thermosets with the processability of thermoplastics. They rely on externally triggered bond exchange reactions, which induce topological rearrangements and, at a sufficiently high rate, a macroscopic reflow of the polymer network. Due to this controlled change in viscosity, dynamic polymers are repairable, malleable, and reprocessable. Herein, several dynamic polyurethane networks were synthetized as model compounds, which were able to undergo thermo-activated transcarbamoylation for the use in rebondable adhesives. Ethylenediamine-N,N,N′,N′-tetra-2-propanol (EDTP) was applied as a transcarbamoylation catalyst, which participates in the curing reaction across its four -OH groups and thus, is covalently attached within the polyurethane network. Both bond exchange rate and (thermo)mechanical properties of the dynamic networks were readily adjusted by the crosslink density and availability of -OH groups. In a last step, the most promising model compound was optimized to prepare an adhesive formulation more suitable for a real case application. Single-lap shear tests were carried out to evaluate the bond strength of this final formulation in adhesively bonded carbon fiber reinforced polymers (CFRP). Exploiting the dynamic nature of the adhesive layer, the debonded CFRP test specimens were rebonded at elevated temperature. The results clearly show that thermally triggered rebonding was feasible by recovering up to 79% of the original bond strength. Full article

Rebonding of orthodontic brackets to new positions during treatment with fixed orthodontic appliances is a common practice and it is important not to cause plastic deformation during bracket removal. The aim of this study was to evaluate the resistance of various brackets to compression and assess their thresholds for plastic deformation. 5 different groups of metal brackets (BioQuick, Damon Q, Experience, Mini Diamond, Mini Sprint II) were bonded to 85 extracted human central incisor teeth utilizing the same adhesive system (Transbond XT). Compressive forces were applied via Weingart forceps in order to mimic clinical setting with the Shimadzu Universal tester. Kruskall-Wallis and Mann-Whitney U tests were used for comparing groups. Damon Q group exhibited the highest yield point value (549.35 N), the highest ultimate strength value (764.50 N) and the highest failure/debonding point value (721.89 N). The lowest yield point value (211.73 N), the lowest ultimate strength value (224.07 N) and the lowest failure/debonding point value (121.71 N) were found in the Mini Diamond group. The ultimate strength point values of Damon Q and Experience brackets were higher compared to Mini Diamond, BioQuick and Mini Sprint II brackets (p < 0.05). No statistically significant difference between Damon Q and Experience brackets in terms of yield strength and ultimate strength values (p > 0.05) were observed. Adhesive Remnant Index (ARI) score was 3 for all debonded samples. It may be concluded that Damon Q brackets were more resistant to plastic deformation than Mini Diamond, BioQuick and Mini Sprint II brackets (p < 0.05). Full article

Many patients experience vertical root fractures, and clinicians often consider conservative treatment options like reattaching the fractured root segments. The study investigated the impact of different bonding agents on the fracture resistance of rebonded vertically fractured teeth with various alveolar bone defects. Human premolar teeth with a single root were sectioned and reattached using dual-cure resin cement (DCRC), resin-modified glass ionomer (RMGI), and cyanoacrylate. The reattached teeth were then restored with a resin fiber post, composite resin core, and full veneer metal copings. These teeth were embedded in acrylic blocks with angular, V-shaped, and step-shaped bone defects to simulate various alveolar bone conditions. After subjecting the samples to thermal cycling, the fracture resistance was evaluated using a universal testing machine. Teeth samples reattached with RMGI exhibited a higher average fracture resistance. The study also found that DCRC proved to be an effective bonding agent for VRF teeth. However, cyanoacrylate-rebonded teeth exhibited the lowest fracture resistance. The V-shaped defects had a significant impact on the fracture resistance of reattached VRF teeth, with largely unfavorable fractures observed in these cases. Predominantly favorable fractures were observed in the teeth treated with RMGI. The fracture loads in both RMGI and DCRC groups exceeded the expected masticatory load. Full article

Adhesion between orthodontic brackets and conditioned enamel surfaces is essential for treatment success with fixed appliances. During treatment, enamel demineralization lesions commonly appear although remineralization is possible through fluoride application. Aim: Evaluation of the surface rugosity in bracket rebonding, specifically the influence of fluoride application before the bonding protocol. In total, 30 human premolars extracted for orthodontic reasons were used and divided into three groups. The control group was not submitted to any experimental manipulation; group 1 and 2 were placed in a demineralization solution and group 2 was additionally subjected to a subsequent fluoride application. The surface rugosity was measured at different timings: T0—before bracket bonding; T1—first bracket debonding after composite removal; and T2—second bracket debonding after composite removal. For the statistical analysis, the Kruskal–Wallis test, Mann-Whitney test, and Student’s t-test were used. Regarding the comparison between groups, at T0 and T1, no statistically significant differences were observed. However, at T2, statistically significant differences were verified between the control group and group 1 for the parameters: Ra (p = 0.0043), Rq (p = 0.0043), Rqmax (p = 0.0043), Rp (p = 0.0087), and Rv (p = 0.026). Regarding the evaluation between time points, in the control group, no statistically significant differences were observed. In group 1, statistically significant results were found between T0 and T1 for the parameters: Rq (p = 0.0451), Rqmax (p = 0.0451), Rp (p = 0.0091), and Rvk (p = 0.0433) and between T1 and T2 for the parameters: Ra (p = 0.0465), Rq (p = 0.0433), Rqmax (p = 0.0433), and Rp (p = 0.0155). In group 2, statistically significant differences were found between T0 and T1 for the parameter Rvk (p = 0.0405). A decrease In surface rugosity was observed during multiple bracket rebonding procedures. Therefore, this study suggests that rebonding procedures alter the enamel surface rugosity. The need for rebonding should be avoided, opting for a more effective and correct first bonding. In the case of multiple rebonding, enamel remineralization maneuvers must be applied to recover the surface, since the results of this study suggest that the application of fluoride prior to bracket adhesion promotes lower surface roughness. Full article

The association of the V-prep and a resin-modified glass ionomer cement (RMGIC) has shown to be a suitable alternative for the orthodontic bracket bonding procedure in vitro. The aim of this study was to evaluate over eighteen months the clinical bonding failure and survival rates of the conventional bonding technique using the Transbond XT (3M Unitek, Monrovia, CA, USA) and the RMGIC Fuji Ortho LC (GC Corporation, Tokyo, Japan) prepared with the V-prep. Therefore, one operator using the straight-wire technique bonded two hundred metallic brackets to upper and lower premolars of twenty-five patients requiring an orthodontic treatment. The randomized trial was a single-blind design in a split-mouth comparison. Each patient was randomly allocated one of the two bonding systems for each premolar on each side of the mouth. The bonding and rebonding techniques were standardized throughout the trial and bond failure was recorded each month for a period of eighteen months. The survival rates of the brackets were estimated by Kaplan–Meier and log-rank test (p < 0.05). A total of 200 orthodontic brackets were included in the study with a significant lower failure rate of 9.0% for the V-prep and RMGIC compared to 25.0% for the conventional bonding technique (p < 0.05). A higher survival rate was observed for the V-prep and RMGIC (16.36 months) over the conventional bonding technique (13.95 months) (p < 0.05). Lower premolar bonding failure was higher than upper premolar for both bonding techniques. The V-prep followed by RMGIC, with enamel surface protection abilities, can be used as an alternative bonding technique in an orthodontic treatment. Full article

This study aimed to evaluate the failure rates and relevant factors of bonded orthodontic brackets with a computer-aided design and manufacturing (CAD/CAM)-based 3D-printed indirect bonding jig system (IDBS) using 2531 natural teeth selected from 99 orthodontic patients. Ceramic self-ligating brackets and metal tubes were used in this study. Proportion analysis was used to calculate the total bracket re-bonding rate and respective proportions of bonding failure and position error. Crossover frequency analysis was used to analyze the total bracket re-bonding, bonding failure, and position error rates in different tooth positions of the maxilla and mandible. Multiple linear regression analysis was used to evaluate the association between dependent variables (age, sex, treatment stage, skeletal divergence, and tooth position) and the bracket bonding failure rate. Pearson’s Chi-square test was used to test the difference between the maxilla and mandible for each variable. The total bracket re-bonding rate was 22.64%, and the bonding failure rate and position error rates accounted for 15.09% and 7.55%, respectively. The bonding failure rate was higher in the mandibular teeth than in the maxillary teeth (p < 0.05). Anterior teeth had a higher position error rate, and mandibular anterior teeth had a higher bonding failure rate. The accuracy of IDBS was higher in the premolars and molars. Sex, age, and treatment stage were affected by IDBS. Patients with hyperdivergent skeletal patterns had higher rates of bracket bonding failure. The results of this study can provide practical guidelines for placing brackets with 3D-printed IDBS on the entire dentition to ensure the precision and accuracy of their use during orthodontic treatments. Full article

Polyurethane foam (PUF) is an exceptionally adaptable product that has a variety of applications—it can be found almost everywhere. Due to such high utilization, the amount of polyurethane foam waste generated each year is growing over time. Rebonding polyurethane foam waste is a suitable way to progress towards a circular economy. In this paper, the prospect of using rebonded polyurethane foam (RPUF) in noise control applications is examined. An experimental study was carried out on RPUFs with various thicknesses and densities. The sound absorption coefficients at normal incidence and air resistivity were measured. The five-parameter Johnson-Champoux-Allard (JCA) model was adopted for the simulation of the porous layer. The remaining unknown parameters of the JCA model were estimated by inverse acoustic characterization based on fitting the transfer matrix method (TMM) model of an unbounded porous layer with rigid backing to the experimentally obtained sound absorption coefficients. Furthermore, sound absorption coefficients were calculated for a wide range of sample thicknesses, as well as for different air gap thicknesses between the wall and the porous layer. For some of the considered RPUFs, a sound absorption coefficient above 0.8 was achieved over a wide frequency range. Full article

The aim of the study is the deep understanding of the essential reactivity of the environmentally friendly mortar by which its applicability can be justified. Created in the study was the environmentally friendly mortar, which helped relieve the increasing requirements on conventional building materials that are produced from exhausted freshwater and river sand nowadays. Seawater (SW) and sea sand (SS) collected from the Eastern Seas of China were used to produce the mortar at various ages, including 10-day, 33-day, and 91-day. Both the curing and working conditions of the mortar were natural marine ones. The physicochemical-mechanical behaviors were investigated using uniaxial compression tests (UCTs), Energy Dispersive Spectrometer (EDS), X-ray Diffraction (XRD), and thermal-field emission scanning electron microscopy (SEM) analysis to understand the essential reactivity of the mortar with age accumulation. The results indicated that hydration products and favorable components were generated promisingly in the mortar: the C-S-H (xCaO·SiO₂·zH₂O) development was certainly achieved in the critical environment during the curing and working period; the extensive generation of C-A-S-H (CaO·Al₂O₃·2SiO₂·4H₂O) helped densify the C-S-H grid, which caused the promising development of the uniaxial compression strength (UCS); the framework porosity of the mortar was restrained effectively due to the development of Friedel’s salt that re-bonded the interfacial cracks between SS and the hydration products with the age accumulation in the critical environment. Consequently, UCS and the resistance against damage of the mortar showed increasing behavior even in the critical environment. The study established Friedel’s salt working models and strength and damage models to interpret the physicochemical reactivity of the mortar as: the source of the strength and toughness was the proper polymerization between the native saline components and the hydration product mixture generated throughout the production, curing, and application without the leaching phenomenon. The novel models and interpretation of the physicochemical reactivity ensured the applicability of the mortar produced with SW and SS in the critical environment. Full article

The objectives of this study were to (1) to evaluate the shear bond strength (SBS) of two ceramic brackets when new and when rebonded following various bracket base conditioning methods, and (2) to determine bond failure mode relative to bracket base morphology. 100 Symetri Clear^TM (SC) and 100 Radiance Plus^® (RP) ceramic brackets were bonded to bovine incisors and divided into five groups: one group served as controls and four had brackets rebonded following conditioning by: no surface treatment, sealant, sandblasting, and flame then steam. SBS, adhesive remnant index, and bracket base morphology were evaluated. SBS showed no statistical difference between new and rebonded with no surface treatment or sealant (SC brackets) and with sealant or flame and steam (RP brackets). When comparing SC to RP, SBS was higher with SC, no surface treatment, and sandblasted groups. All groups had varying amounts of adhesive left on the tooth, with the sandblasted group having the most. SEM analysis showed that sandblasting damaged the retention features of bracket bases. In conclusion, when rebonded, the SBS of SC brackets that had no surface treatment and both SC and RP brackets that had sealant showed no significant differences to new brackets. Sandblasting damaged the retention features of SC and RP bracket bases, resulting in low SBS. Full article

This work aims to study the healing potential properties of a reversible thermoplastic adhesive. The adhesive is activable by using induction heating systems that can induce thermal heat in the particles throughout the electromagnetic field so they can melt the adhesive for bonding or separation procedures. The healing procedure consists of damaging single lap joint (SLJ) specimens with quasi-static and fatigue tests and then using an inductor to generate an electromagnetic field able to heat the adhesive to its melting point in order to heal the damaged SLJ specimens. SLJ tests were performed on damaged and healed specimens to assess, respectively, the residual mechanical properties of the damaged specimens and the mechanical properties after healing. SLJ tests showed that the healing procedure can completely recover the joint stiffness of the damaged adhesive joints, a huge part of the maximum shear strength and the SLJ absorbed energy. This work shows also the possibility of re-bonding completely failed or separated SLJs by using the same procedure. The mechanical properties of SLJs after healing and re-bonding are compared to the SLJ compared on virgin specimens to assess the recovered mechanical properties. Full article

Debonding of orthodontic brackets is a common occurrence during orthodontic treatment. Therefore, the best option for treating debonded brackets should be indicated. This study aimed to evaluate the bond strength of rebonded brackets after different residual adhesive removal methods. This systematic review and meta-analysis was conducted according to the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) statement. PubMed, Web of Science, The Cochrane Library, SciELO, Scopus, LILACS, IBECS, and BVS databases were screened up to December 2020. Bond strength comparisons were made considering the method used for removing the residual adhesive on the bracket base. A total of 12 studies were included for the meta-analysis. Four different adhesive removal methods were identified: sandblasting, laser, mechanical grinding, and direct flame. When compared with new orthodontic metallic brackets, bond strength of debonded brackets after air abrasion (p = 0.006), mechanical grinding (p = 0.007), and direct flame (p < 0.001) was significantly lower. The use of an erbium-doped yttrium aluminum garnet (Er:YAG) laser showed similar shear bond strength (SBS) values when compared with those of new orthodontic brackets (p = 0.71). The Er:YAG laser could be considered an optimal method for promoting the bond of debonded orthodontic brackets. Direct flame, mechanical grinding, or sandblasting are also suitable, obtaining clinically acceptable bond strength values. Full article

Among various ceramic matrix composites developed, self-healing ceramics have been studied as new functional materials. Self-healing occurs in such materials by high-temperature oxidation triggered by a micro-crack initiation on the surface, and the strength of the material autonomously recovers to its robust state since the micro-crack is re-bonded. To facilitate the use of self-healing ceramics in machines and equipment, a novel numerical simulation method based on finite element analysis (FEA) needs to be applied. In this study, we applied a previously proposed constitutive model to a series of self-healing and damage processes. In the constitutive model, the damage process is formulated on the basis of fracture mechanics, while the self-healing process is formulated on the basis of empirical oxidation kinetics. The FEA model implemented the constitutive model to simulate a series of experiments of the alumina/15 vol% SiC composites. The self-healing process was targeted to a prescribed damage by Vickers indentation. Thereafter, the self-healing behavior was quantitatively compared with that observed in the experiment. The results suggest that the proposed FEA approach can be applied to the analysis of ceramic matrix composites with self-healing properties. Full article