Search Results (47)

High-purity quartz (HPQ) is a critical raw material for advanced technologies including semiconductors, photovoltaic cells, and optical fibers. This study reviews the geological occurrence, beneficiation routes, and strategic significance of HPQ within the European context. Quartz processing follows a sequential flowsheet of comminution, magnetic separation, flotation, acid leaching, and thermal treatment, designed to remove mineral impurities such as Fe, Al, Ti, and mica. The resulting ultra-high-purity quartz (UHPQ) achieves the chemical and physical specifications required for high-tech industries. Quartz, which is the most common mineral on Earth, can be found in a variety of geological locations such as granitic rocks and pegmatites in the Variscan Belt, metamorphic quartzites, hydrothermal veins, and Pleistocene periglacial and aeolian sediments. Case studies of European deposits demonstrate that geological origin directly influences processing requirements, and that tailored beneficiation strategies are essential to unlock viable resources. To our knowledge, this is the first Europe-focused synthesis that links these findings with the EU Critical Raw Materials Act, the work that emphasizes the potential for domestic HPQ development to strengthen European supply chain resilience, reduce dependence on imports, and support the transition to a green and digital economy. Full article

Underground mine surveys present unique challenges, including the logistics of deploying an energy source, placing geophones in solid rock, managing reverberation from the adit, and ensuring safety. We present the results of seismic surveying at the historic Deer Trail Mine in south-central Utah (USA). The mine is located along the eastern side of the Tushar Range. The surveys utilised a narrow, mostly horizontal adit, 120–510 m below the ground surface. The country rock consists of highly fractured and mineralised Permian to Pennsylvanian quartzites, shales, and limestones. A short test of a 96-channel common midpoint (CMP) P-wave profile was conducted using an accelerated weight-dropper source. We supplemented the P-wave survey with tests of surface-wave dispersion and horizontal-vertical spectral ratio modelling for shallow S-wave structure. These tests confirmed the capability to map shallow, small-scale structure. A conventional CMP 264-channel survey with an explosive source covered 1728 m. A static recording array was used for both surveys with 4.5-Hz vertical geophones. The conventional CMP profile imaged horizontal and dipping reflectors down to about 2000 m, interpreted as lithologic variations in the bedrock. Our study demonstrates the potential for high-resolution seismic exploration in an unconventional and challenging setting to guide the exploitation of deeply buried mineral resources. Full article

Understanding the relationship between geological and geomorphological processes is essential for reconstructing landscape evolution. This study examines how geology and geomorphology shape landscape development in central Brazil, focusing on the Natividade Group area. Sentinel-2 and SRTM data were integrated with geospatial analyses to produce two key maps: (i) a pedo-geomorphological map, classifying landforms and soil–landscape relationships, and (ii) a predictive geological–geomorphological map, based on a machine learning-based prediction of geomorphic units, which employed a Random Forest classifier trained with 15 environmental predictors from remote sensing datasets. The predictive model classified the landscape into six classes, revealing the ongoing interactions between geology, geomorphology, and surface processes. The pedo-geomorphological map identified nine pedoforms, grouped into three slope classes, each reflecting distinct lithology–relief–soil relationships. Resistant lithologies, such as quartzite-rich metasedimentary rocks, are associated with shallow, poorly developed soils, particularly in the Natividade Group. In contrast, phyllite, schist, and Paleoproterozoic basement rocks from the Almas and Aurumina Terranes support deeper, more weathered soils. These findings highlight soil formation as a critical indicator of landscape evolution in tropical climates. Although the model captured geological and geomorphological patterns, its moderate accuracy suggests that incorporating geophysical data could enhance the results. The landscape bears the imprint of several tectonic events, including the Rhyacian amalgamation (~2.2 Ga), Statherian taphrogenesis (~1.6 Ga), Neoproterozoic orogeny (~600 Ma), and the development of the Sanfranciscana Basin (~100 Ma). The results confirm that the interplay between geology and geomorphology significantly influences landscape evolution, though other factors, such as climate and vegetation, also play crucial roles in landscape development. Overall, the integration of remote sensing, geospatial analysis, and machine learning offers a robust framework for interpreting landscape evolution. These insights are valuable for applications in land-use planning, environmental management, and geohazard assessment in geologically complex regions. Full article

The Mesoproterozoic (~1470 Ma) Wolf River batholith (WRB) is exposed over 6500 km², encompassing 11 plutons that crosscut the Archean Marshfield and Proterozoic Penokean terranes. As the WRB is the classically defined anorogenic batholith, to test this hypothesis, seven igneous phases were analyzed using anisotropy of magnetic susceptibility (AMS), as a proxy for magmatic flow during intrusion, and the samples recorded a sub-horizontal emplacement in six different orientations. Paleopoles from six of eight igneous samples preserve a wide variety of sub-vertical orientations with two reversed and four normal polarities. The synorogenic Baldwin Conglomerate is the youngest rock (<1460 Ga) associated with WRB. Magnetic fabrics are horizontal, but multidomain and paleopole signatures, where interpretable, are sub-vertical. The North American APWP places middle Laurentia at low-latitude during Geon 14, and all our paleopoles are sub-vertical, not sub-horizontal, again suggesting post-intrusion deformation. Moreover, the McCauley gneiss (1886 Ma; U-Pb zircon), Rib Mountain Quartzite (1750 Ma MDA; U-Pb zircon, n = 150), Dells of the Eau Claire rhyolite (1483 Ma; U-Pb zircon, 1469 Ma; monazites-in-garnet), and Baldwin conglomerate (1460 Ma MDA; U-Pb zircons, n = 150) are sub-vertical inliers (xenoliths) in the igneous suite; the Proterozoic Wausau turbidite (1850 Ma MDA; U-Pb zircon, n = 150) was intruded by the WRB and dips 25°W. Here, we present a reinterpretation of the WRB as a deformed synorogenic rather than an anorogenic intrusion. Full article

This study analyzes the heavy metal pollution in cultivated soils developed from different parent materials in Yunnan Province and assesses their risk levels. The results show significant regional differences in soil heavy metal pollution, greatly influenced by the type of parent material. Cadmium (Cd) pollution is most severe in multiple parent material soil regions, particularly in areas with carbonate and purple rocks, exhibiting a high pollution risk. Other heavy metals such as zinc (Zn), copper (Cu), and lead (Pb) also show varying degrees of enrichment in different parent material zones, posing potential pollution risks. The soil pollution levels of heavy metals were classified using the geo-accumulation index method. It was found that soils developed from carbonate rocks and purple rocks have the most severe heavy metal pollution, while soils from quartzitic rocks, acidic crystalline rocks, and basalt exhibit relatively lower pollution levels. By analyzing the characteristics of heavy metal pollution in different parent materials, this study provides a scientific basis for regional soil pollution management and sustainable agricultural development. Full article

Laboratory-scale experiments were conducted on Carboniferous Limestone gravels from the Mendip Hills area, England; sandstones from the Pirambóia and Botucatu formations, Paraná sedimentary basin, Brazil; samples of schist and quartzite from Caldas Novas Hydrothermal Complex, Brazil; and the minerals tantalite, cassiterite, and columbite from mining areas at Rio Grande do Norte State, Brazil, with the purpose of evaluating the release of ²²²Rn to the water phase. The specific surface area of the samples corresponded to 1.69–81.36 cm²g⁻¹, which provided values of 0.001–1.68 dpm/g and 3.18 × 10⁻⁶ to 0.59 for the radon released and radon emanation coefficient, respectively. These results allowed us to calculate the radon flux with respect to the radon leakage, which corresponded to values of 0.00016–0.00158 Bq/m²/d for the denser materials and 0.018–0.43 Bq/m²/d for limestones and sandstones. They also permitted us to find an inverse, significant relationship between the radon generated by the minerals/rocks and the radon flux into the water phase, which was tested for sediments in coastal and inland Brazilian areas, demonstrating utility for evaluating the diffusive radon flux from the sediments, which is an important parameter to monitor submarine groundwater discharge (SGD) by means of radon as a natural tracer. Full article

The Iberian Pyrite Belt (IPB) represents one of the largest districts of volcanogenic massive sulfide (VMS) deposits in the world, and is a critical source of base metals (Cu, Pb, and Zn) for Europe. Confirmed resources exceed 1700 Mt of massive sulfides with grades of around 1.2% Cu, 1% Pb, and 3% Zn as well as more than 300 Mt of stockwork-type copper mineralization. Significant resources of Sn, precious metals (Au and Ag), and critical metals (Co, Bi, Sb, In, and Se) have also been evaluated. The genesis of these deposits is related to a complex geological evolution during the late Devonian and Mississippian periods. The geological record of such evolution is represented by three main lithological units: Phyllite–Quartzite Group, the volcano–sedimentary Complex (VSC), and the so-called Culm Group. The sulfide deposits are located in the VSC, associated with felsic volcanic rocks or sedimentary rocks such as black shales. The massive sulfide deposits occur as tabular bodies and replacement masses associated with both volcanic and sedimentary rocks. Their mineralogical composition is relatively simple, dominated by pyrite, chalcopyrite, sphalerite, and galena. Their origin is related to three evolutionary stages at increasing temperatures, and a subsequent stage associated with the Variscan deformation. The present paper summarizes the latest developments in the IPB and revises research areas requiring further investigation. Full article

The aim of this paper is to describe the surveys performed in order to update the interpretive conceptual circulation model of the Ladeira de Envendos hyposaline hydromineral system (Central Portugal). The geology of the Ladeira de Envendos region is strongly controlled by the Amêndoa-Carvoeiro synform, of Ordovician-Silurian age, presenting continuous and aligned quartzite ridges on the NE flank, that form the basic structure of a set of inselbergs. The physico-chemical analysis of the Ladeira de Envendos natural mineral spring and borehole waters was provided by the Super Bock Group Enterprise (Concessionaire of the Ladeira de Envendos). Furthermore, two sampling campaigns took place to increase knowledge on the isotopic composition of the studied natural mineral waters. The stable (δ²H, δ¹⁸O) isotopic data indicate that local meteoric waters infiltrate around 400 m altitude and evolve to the natural mineral waters (of Cl-Na facies) through a NW–SE underground flow path ascribed to the highly fractured and permeable quartzite rocks. From recharge to discharge, the infiltrated meteoric waters acquire silica (±9 mg/L) due to water–quartzite rock interaction. These natural mineral waters emerge at temperatures around 21 °C, being the up flow of these waters controlled by the rock fractures and local faults. The natural mineral waters mean residence time range between 25 and 40 years, as indicated by the ³H content of these waters, enhancing an active recharge of this hydromineral system. The results obtained indicate existence of three hydrogeological subsystems, ascribed to three inselbergs, with similar groundwater circulation paths. These multi and interdisciplinary studies should be seen as an important contribution to the sustainable management of this type of natural mineral water resources. Full article

The present work reports on the first evidence of a possible hypervelocity impact crater in the Sultanate of Oman. The impact origin of the structure is determined based on field observations, microscopic observations of shatter cones, planar fractures (PFs) and feather features (FFs) in quartz, calcite, and feldspar, and melt-bearing polymict breccias with various types of melts. The structure consists of an elliptical bowl-shaped ridge 750 m long and 550 m wide, oriented roughly north-northeast to south-southwest. The elliptical shape and relief asymmetry indicate an oblique collision. The precursor target lithologies include local late Proterozoic Masirah Bay siliciclastic formations, carbonate and acidic volcanic rocks of the late Precambrian Halfayn Formation, and basement rocks. The crater rim, up to 15–20 m above ground, is composed of quartzite, jasper, agate, monomict siliceous and hematite breccia, and metamorphosed shale (hornfels). An ejecta blanket composed of target rocks covers the floor, outer rim, and the area extending to the immediate northeast and east of the structure. Quaternary aeolian sand covers most of the crater surface, including the 1 to 2 m thick melt-rich polymict breccia found in the crater center. The planar fractures (PFs) and feather features (FFS) in quartz and feldspar suggest a low shock pressure between 5 and 14 GPa. Our observations are consistent with set criterions for impact crater identification, confirming the possible impact origin of the Mahout structure. Full article

This paper investigates the monazite grains from the Dibrova rare-earth-thorium-uranium (U-Th-REE) mineral deposit within the Azov Megablock of Ukrainian Shield. U-Th-REE mineralization is associated with K-feldspar-quartz metasandstones and metagritstones (hereafter quartzites) and pegmatoids. The latter possibly represent products of ultrametamorphism/granitization of initially sedimentary clastic rocks during tectono-magmatic activation during the Paleoproterozoic. Ores are composed of quartz as a principal mineral, feldspar, sillimanite, muscovite, monazite, brannerite, uraninite, zircon, rutile, and sulfides. The purpose of this work was to obtain insights into the genesis of the mineral deposit by studying the monazite grains, their chemistry, and ages. Petrographic research work was carried out that included studying/analyzing the monazites from various monazite-bearing rocks (quartzites, pegmatoid, and biotite schist samples). A variety of methods and tools were used, including optical microscopy study, X-ray fluorescence (XRF) mapping of selected samples, as well as scanning electron microscope (SEM) and electron microprobe (EPMA) characterization of monazites, including U-Th-Pb monazite chemical dating. U-Pb-Th chemical electron microprobe dating of the monazites yielded two major distinct monazite age groups at 3.0–2.8 Ga and 2.2–2.0 Ga. The first age group corresponds to the time of formation of the Archean granitoids, which served as a source of monazite for its clastic sedimentation during the Paleoproterozoic in the Dibrova suite sediments. The second age group corresponds to the reprecipitation (i.e., remobilization) of monazite during the Paleoproterozoic tectono-magmatic activation. The location of the mineral deposit within the deep mantle-crustal Devladivska shear zone is another favorable factor for the remobilization and transport of metals. New data on the age of mineralization yield a more complete understanding of the geological history and formation of the complex polyphase rare-earth-uranium-thorium Dibrova mineral deposit. Full article

The caves of Igatu, municipality of Andaraí, belonging to the region known as Chapada Diamantina represent a new hotspot of subterranean fauna. These caves are siliciclastic, which are sedimentary rocks where silica predominates, such as sandstones and (following metamorphism) quartzites, which makes them even more relevant from the point of view of subterranean diversity. For five caves, which we named Igatu Cave System (ICS), thirty-seven obligate cave species were found, of which thirty-five were troglobitic and two were stygobitic. The troglobitic taxa for ICS belong to three phyla, nine classes, 18 orders, and 32 families, representing a high phylogenetic diversity. Some taxa were, for the first time, reported as troglobitic in Brazil and even worldwide, such as Acari and scutigeromorphans (Chilopoda). We started the studies in 2009 and continue trough long-term monitoring projects. Some threats, severe in the past, such as “garimpo’’ (illegal small-scale artisanal mining) continue nowadays in an incipient way; however, the urban expansion due to the touristic appeal is also considered a threat. Our data ranked ICS as the Brazilian hotspot with the highest number of troglobitic/stygobitic species. Full article

In this paper, we outline a study conducted on altered rocks in Central Kazakhstan, in particular, focusing on secondary quartzites. The study reveals a connection between copper-porphyry deposits in Central Kazakhstan and secondary quartzites. Recent research has unveiled gold mineralization in various secondary quartzite massifs, which has spurred further investigations in the region. Over the past three decades, extensive studies have been conducted that have demonstrated similarities among the gold deposits in this area and epithermal gold-silver deposits in volcanic-plutonic arcs around the world. By identifying patterns in the distribution of gold mineralization and developing regional exploration criteria, researchers have comprehensively assessed 48 secondary quartzite massifs and have prioritized promising areas for further exploration. Valuable findings have emerged from detailed examinations of the Akgirek and Birlestik massifs, which have involved drilling exploration wells up to a depth of 250 m. These investigations have shed light on the depth distribution of metasomatites and their association with gold mineralization. Consequently, these findings strengthen our belief in the significant potential for gold mineralization in the secondary quartzites of the Jungar-Balkhash folded system. Full article

The Korean Peninsula mainly comprises the Paleoproterozoic Gwanmo, Nangnim, Gyeonggi, and Yeongnam massifs from north to south. The Paleoproterozoic basement is rarely exposed in the Paleozoic Taebaeksan basin, which is located in the northeastern part of the Okcheon belt between the Gyeonggi and Yeongnam massifs. One of the most important issues in the tectonic interpretation of the Korean Peninsula is whether Paleoproterozoic rocks in the Taebaeksan basin have an affinity with those in the Gyeonggi or Yeongnam massifs. To solve this problem, we focused on the petrogenesis of the Imgye gabbroic diorite, Jungbongsan granite, and Jangsan quartzite in the Imgye area of the Taebaeksan basin. The Imgye gabbroic diorite shows mafic to intermediate compositions with slightly enriched LREEs compared to HREEs, slightly positive Rb, K, and Pb anomalies, and negative Ta, Nb, and P anomalies. The Imgye gabbroic diorite formed in a volcanic arc tectonic setting. The geochemical compositions of the Jungbongsan granite show enriched LREEs compared to HREEs with negative Eu anomalies, and reveal strong positive Rb, Th, K, and Pb anomalies with negative Ba, Ta, Nb, Sr, P, Eu, and Ti anomalies. This Jungbongsan granite also formed in an arc tectonic setting like the Imgye gabbroic diorite. LA-ICP-MS zircon age dating of the Imgye gabbroic diorite gives an intrusion age of 1948 ± 21 Ma, whereas SHRIMP U–Pb zircon age dating on the Jungbongsan granite yields an emplacement age of 1873 ± 14 Ma. The ε_Hf(t) values of the Imgye gabbroic diorite are from 3.5 to 9.7, whereas those of the Jungbongsan granite are from −2.9 to 0.6. These data imply that the Imgye gabbroic diorite formed from a depleted mantle in the arc tectonic environment, whereas the Jungbongsan granite formed by reworking pre-existing crust material in the arc environment. The detrital zircons in the Jangsan quartzite show ages ranging from 3.06 to 1.85 Ga, with a peak concentration of ca. 2.5 Ga. Previous studies have suggested that the northern Gyeonggi and Nangnim massifs underwent collision-related magmatism and metamorphism at ca. 1.93–1.90 Ga, and then post-collisional magmatism and metamorphism at ca. 1.89–1.83 Ga, whereas the southern Gyeonggi massif underwent subduction-related magmatism and metamorphism at ca. 1.94–1.92 Ga, and then post-collision-related magmatism and metamorphism at ca. 1.84–1.78 Ga. By contrast, subduction-related events were recognized in the northern Yeongnam massif at ca 2.02–1.96 Ga and 1.90–1.85 Ga. This work, combined with the previous studies, suggests that the Paleoproterozoic basement in the Imgye area of the Taebaeksan basin can be correlated with the Paleoproterozoic basement of the northern Yeongnam massif rather than with those of the Nangnim and Gyeonggi massifs. Full article

This archaeometric study aims at characterizing the archaeological finds belonging to the lithic industry from La Calvera rock shelter (Camaleño, Cantabria) and at hypothesizing the possible provenance of each material. The site, located in the mountainous area of Picos de Europa National Park (more than 1000 m a.s.l.) close to the megalithic complex of Peña Oviedo, is characterized by the presence of hearths and charcoal remains, ancient pottery, and a rich lithic assemblage composed of siliceous rocks dating back to >8000 BP and linked to the first Holocene occupations of the Cantabrian Mountains. For the study of the rock shelter’s lithic assemblage, a multi-analytical approach was used: SEM-EDS and XRD analyses were performed to define the microtextural characteristics of samples and to identify the amorphous/crystalline phases; physical and mechanical tests were conducted to define the petrophysical properties (density, porosity, imbibition and saturation indexes, mechanical strength) of the samples. Preliminary data of chemical compositions, obtained by portable XRF, are also presented. The results show that the different siliceous materials (quartzite, cherts, hyaline quartz) can be distinguished through the basic analytical techniques used here. In addition, most of the archaeological samples have mineralogical and petrographic features similar to the natural samples coming from nearby outcrops, corroborating the hypothesis of a local material supply. The presence of local sources of useful raw materials could have favoured the site’s occupation. Finally, the diverse compositional and textural feature of the analysed materials result in different mechanical properties (porosity, density, hardness, workability), so they likely had different uses and technical functions. Full article

The Longmaxi-1 black shales in the Upper Yangtze region are a vital source rocks in southern China. This study investigates the palaeoweathering conditions, provenance, and tectonic setting of the Longmaxi-1 black shale from an elemental geochemical perspective, ultimately revealing its tectonic setting. The results showed that the Longmaxi-1 black shales in the sedimentary period have the characteristics of primary deposition. The Longmaxi-1 black shales were deposited as a primary deposition under a mainly humid climate. However, fluctuations in climatic conditions were recorded from the bottom to the upper part of the formation. The parent rock of the Longmaxi-1 black shales in the Upper Yangtze region is a mixture provenance, mainly composed of intermediate-acid volcanic lithologies (granite and granodiorite), followed by mature quartzite and basalt. Black shale deposition is related to the tectonic setting of active continental margin and island arc-continent collision. The Cathayian orogenic belts and the North Qiangling orogenic belt may have played a role in the genesis of the Longmaxi-1 black shales within the Upper Yangtze region. This study provides significant clues regarding the reconstruction of the palaeoclimatic and palaeogeographical conditions of the Upper Yangtze region during the Early Silurian period. Full article