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67 Results Found

  • Article
  • Open Access
18 Citations
3,605 Views
15 Pages

27 July 2020

The study of processing characteristic and property optimization of ultra-high-molecular-weight polyethylene (UHMWPE) pipe is increasingly performed, mainly focusing on difficulties in the melting process and poor thermal-mechanical properties after...

  • Article
  • Open Access
45 Citations
5,237 Views
14 Pages

9 August 2018

In this work, an easy way to prepare the polylactic acid (PLA)/wheat straw fiber (WSF) composite was proposed. The method involved uses either the dopamine-treated WSF or the two-step montmorillonite (MMT)-modified WSF as the filler material. In orde...

  • Article
  • Open Access
10 Citations
2,751 Views
14 Pages

31 July 2021

The current investigation presents a green mechanochemical procedure for the synthesis of a special kind of rubber-compatible organo-montmorillonite (OMMT) for use in the inner liner compound of tires. The compatibility character of the OMMT arises f...

  • Feature Paper
  • Article
  • Open Access
15 Citations
3,737 Views
25 Pages

Effect of Na- and Organo-Modified Montmorillonite/Essential Oil Nanohybrids on the Kinetics of the In Situ Radical Polymerization of Styrene

  • Ioannis S. Tsagkalias,
  • Alexandra Loukidi,
  • Stella Chatzimichailidou,
  • Constantinos E. Salmas,
  • Aris E. Giannakas and
  • Dimitris S. Achilias

13 February 2021

The great concern about the use of hazardous additives in food packaging materials has shown the way to new bio-based materials, such as nanoclays incorporating bioactive essential oils (EO). One of the still unresolved issues is the proper incorpora...

  • Article
  • Open Access
16 Citations
3,773 Views
14 Pages

Comprehensive Characterization of the Structure and Gel Property of Organo-Montmorillonite: Effect of Layer Charge Density of Montmorillonite and Carbon Chain Length of Alkyl Ammonium

  • Jun Qiu,
  • Dongliang Liu,
  • Yueting Wang,
  • Guowei Chen,
  • Shan Jiang,
  • Guoqing Li,
  • Yaqi Wang,
  • Wenxin Wang,
  • Peng Wu and
  • Xiaodong Liu
  • + 2 authors

22 April 2020

In this work, the effect of layer charge density of Na-montmorillonite (Na-MT) and carbon chain length of alkyl ammonium on the structure and gel property of organo-montmorillonite (organo-MT) was studied by using X-ray diffraction (XRD), Fourier tra...

  • Article
  • Open Access
11 Citations
3,723 Views
12 Pages

24 January 2019

In this study, poly(lactic acid) (PLA)/wood flour (WF) composites were prepared by first blending PLA with organo-montmorillonite (OMMT) at different contents (0.5, 1, 1.5, and 2 wt %). The physical and mechanical properties of the virgin and OMMT mo...

  • Article
  • Open Access
38 Citations
5,596 Views
12 Pages

Modifying Cellulose Acetate Mixed-Matrix Membranes for Improved Oil–Water Separation: Comparison between Sodium and Organo-Montmorillonite as Particle Additives

  • Micah Belle Marie Yap Ang,
  • Kiara Pauline O. Devanadera,
  • Alyssa Nicole R. Duena,
  • Zheng-Yen Luo,
  • Yu-Hsuan Chiao,
  • Jeremiah C. Millare,
  • Ruth R. Aquino,
  • Shu-Hsien Huang and
  • Kueir-Rarn Lee

22 January 2021

In this study, cellulose acetate (CA) mixed-matrix membranes were fabricated through the wet-phase inversion method. Two types of montmorillonite (MMT) nanoclay were embedded separately: sodium montmorillonite (Na-MMT) and organo-montmorillonite (O-M...

  • Article
  • Open Access
27 Citations
2,793 Views
16 Pages

17 May 2021

Polymer–clay mineral composites are an important class of materials with various applications in the industry. Despite interesting properties of polysiloxanes, such matrices were rarely used in combination with clay minerals. Thus, for the first time...

  • Article
  • Open Access
18 Citations
3,171 Views
17 Pages

Performance of Thyme Oil@Na-Montmorillonite and Thyme Oil@Organo-Modified Montmorillonite Nanostructures on the Development of Melt-Extruded Poly-L-lactic Acid Antioxidant Active Packaging Films

  • Aris E. Giannakas,
  • Constantinos E. Salmas,
  • Areti Leontiou,
  • Dimitrios Moschovas,
  • Maria Baikousi,
  • Eleni Kollia,
  • Vasiliki Tsigkou,
  • Anastasios Karakassides,
  • Apostolos Avgeropoulos and
  • Charalampos Proestos

11 February 2022

Today, the use of natural biodegradable materials in the production processes is more and more adopted by industry to achieve cyclic economy targets and to improve environmental and human health indexes. Active packaging is the latest trend for food...

  • Article
  • Open Access
2 Citations
2,104 Views
15 Pages

Optimization of the Pentachlorophenol Adsorption by Organo-Clays Based on Response Surface Methodology

  • Soufiane El Mahmoudi,
  • Abdellah Elmchaouri,
  • Assya El kaimech and
  • Antonio Gil

14 October 2022

The aim of this study is to optimize the adsorption of pentachlorophenol (PCP) using an organo-clay under the response surface methodology. The adsorbent was selected from a montmorillonite exchanged by various cations, such as Fe3+, Al3+, Zn2+, Mg2+...

  • Article
  • Open Access
6 Citations
2,753 Views
24 Pages

24 November 2021

In order to improve the thermal and mechanical properties of poly(styrene-co-butadiene) (SBR) to use it as a pervaporation membrane in the separation of the azeotropic mixture toluene/methanol, poly(styrene-co-butadiene) crosslinked Maghnia-organo-mo...

  • Article
  • Open Access
12 Citations
3,504 Views
18 Pages

12 November 2022

Polymeric anthocyanins are biologically active, pH-sensitive natural compounds and pigments with beneficial functional, pharmacological and therapeutic properties for consumer health. More recently, they have been used for the manufacture of active a...

  • Communication
  • Open Access
27 Citations
4,450 Views
8 Pages

19 August 2020

In this work, a series of comparative studies for the effect of the nine commercially available cationic, amphoteric and nonionic surfactants on the structure and wettability of the montmorillonite based organoclays were performed. The pristine and m...

  • Article
  • Open Access
4 Citations
2,078 Views
13 Pages

Improvement and Stability of Soil Organic Carbon: The Effect of Earthworm Mucus Organo-Mineral Associations with Montmorillonite and Hematite

  • Yuxuan Li,
  • Siyue Feng,
  • Lin Wang,
  • Chencen Lei,
  • Hongbo Peng,
  • Xinhua He,
  • Dandan Zhou and
  • Fangfang Li

27 June 2024

Improving soil carbon storage and stability plays an important role in the development of sustainable agricultural production and mitigating climate change. Earthworms are widely distributed in soil environments; earthworm mucus (EM) can interact wit...

  • Article
  • Open Access
25 Citations
3,605 Views
12 Pages

28 February 2021

This work aims to explore the effect of organo-modified montmorillonite nanoclay (O-MMT) on the mechanical, thermo-mechanical, and thermal properties of carbon fiber-reinforced phenolic composites (CFRP). CFRP at variable O-MMT contents (from 0 to 2....

  • Article
  • Open Access
54 Citations
10,337 Views
11 Pages

Comparison of In Situ Polymerization and Solution-Dispersion Techniques in the Preparation of Polyimide/Montmorillonite (MMT) Nanocomposites

  • Mansor Bin Ahmad,
  • Yadollah Gharayebi,
  • Mohd. Sapuan Salit,
  • Mohd. Zobir Hussein and
  • Kamyar Shameli

19 September 2011

In this paper, Polyimide/Montmorillonite Nanocomposites (PI/MMT NCs), based on aromatic diamine (4-Aminophenyl sulfone) (APS) and aromatic dianhydride (3,3',4,4'-benzophenonetetracarboxylic dianhydride) (BTDA) were prepared using in situ polymerizati...

  • Article
  • Open Access
6 Citations
2,554 Views
16 Pages

21 February 2023

The discharge of industrial phenol pollutants causes great harm to the natural environment and human health. In this study, phenol removal from water was studied via the adsorption of Na–montmorillonite (Na–Mt) modified by a series of Gem...

  • Article
  • Open Access
31 Citations
7,741 Views
17 Pages

9 February 2018

Dissolved organic matter (DOM) chemistry and the potential for organic matter (OM) to self-associate with other OM components are important aspects of understanding the mechanisms of DOM sorption to clay surfaces. To investigate this further, we sorb...

  • Article
  • Open Access
25 Citations
3,383 Views
17 Pages

11 June 2022

Polypropylene (PP), as a general thermoplastic polymer, is broadly used in different fields. However, the high flammability, melt dripping and poor mechanical properties of PP are a constraint to the expansion of its applications. In this paper, PP c...

  • Article
  • Open Access
5 Citations
2,142 Views
15 Pages

5 December 2022

The present paper aims to address the crucial concern of pollution induced by growing plastic waste and electromagnetic interference (EMI). Nanocomposites combining poly(lactic acid) (PLA) and organo-modified montmorillonite (OMMT) are synthesized an...

  • Article
  • Open Access
19 Citations
3,882 Views
21 Pages

Sorption of Molybdates and Tungstates on Functionalized Montmorillonites: Structural and Textural Features

  • Magdalena Tuchowska,
  • Barbara Muir,
  • Mariola Kowalik,
  • Robert P. Socha and
  • Tomasz Bajda

13 July 2019

Montmorillonite—the most popular mineral of the smectite group—has been recognized as a low-cost, easily available mineral sorbent of heavy metals and other organic and inorganic compounds that pollute water. The aim of this work was to d...

  • Article
  • Open Access
37 Citations
7,287 Views
12 Pages

Montmorillonite K10: An Efficient Organo-Heterogeneous Catalyst for Synthesis of Benzimidazole Derivatives

  • Sonia Bonacci,
  • Giuseppe Iriti,
  • Stefano Mancuso,
  • Paolo Novelli,
  • Rosina Paonessa,
  • Sofia Tallarico and
  • Monica Nardi

28 July 2020

The use of toxic solvents, high energy consumption, the production of waste and the application of traditional processes that do not follow the principles of green chemistry are problems for the pharmaceutical industry. The organic synthesis of chemi...

  • Article
  • Open Access
11 Citations
3,480 Views
20 Pages

2 November 2023

Mineral fillers can be added to thermoset polymers to improve thermal conductivity and deformation behavior, shrinkage, impact strength, dimensional stability and molding cycle time. This study aims to prepare various hybrid composites (MFHCs) using...

  • Article
  • Open Access
3 Citations
1,729 Views
16 Pages

22 May 2023

This study focused on the preparation, structural characterization and evaluation of some dynamic and rheological properties of a new type of mastic material, clay-mastic, which consists of bituminous binders mixed with mineral fillers. For this purp...

  • Article
  • Open Access
18 Citations
4,227 Views
16 Pages

Modified Montmorillonite as Drug Delivery Agent for Enhancing Antibiotic Therapy

  • Luciana Sciascia,
  • Ilaria Calabrese,
  • Gennara Cavallaro,
  • Marcello Merli,
  • Cinzia Scialabba and
  • Maria Liria Turco Liveri

25 November 2021

The appealing properties of surfactant-intercalated Montmorillonites (Organo-montmorillonite, OMt) were successfully investigated to propose an effective drug delivery system for metronidazole (MNE) antibiotic therapy. This represents a serious pharm...

  • Feature Paper
  • Article
  • Open Access
29 Citations
3,649 Views
16 Pages

Nowadays, active packaging is becoming significant for the extension of the shelf life of food products via the incorporation of raw nanomaterials such as nanoclays and bioactive compounds such as essential oils (EO). This study aims to study the per...

  • Article
  • Open Access
1 Citations
1,513 Views
13 Pages

New Methodology for Modifying Sodium Montmorillonite Using DMSO and Ethyl Alcohol

  • Adriana Stoski,
  • Bruno Rafael Machado,
  • Bruno Henrique Vilsinski,
  • Lee Marx Gomes de Carvalho,
  • Edvani Curti Muniz and
  • Carlos Alberto Policiano Almeida

20 June 2024

Modified clays with organic molecules have many applications, such as the adsorption of pollutants, catalysts, and drug delivery systems. Different methodologies for intercalating these structures with organic moieties can be found in the literature...

  • Article
  • Open Access
1 Citations
1,415 Views
13 Pages

Mechanochemical-Activated Organomontmorillonite for Uranium Pollution Protection

  • Iryna Kovalchuk,
  • Iryna Farbun,
  • Volodymyr Sydorchuk,
  • Andrey Lakhnik and
  • Olena Diyuk

The modification of the layered silicate with a structural type 2:1 montmorillonite by the cationic surfactant hexadecyltrimethylammonium bromide was carried out. The obtained organomontmorillonite was milled for 2–25 min in a high-energy plane...

  • Article
  • Open Access
15 Citations
3,609 Views
15 Pages

10 January 2020

Polyamide 6 (PA6)/poly(vinylidene fluoride) (PVDF) blend-based nanocomposites were successfully prepared using a twin screw extruder. Carbon nanotube (CNT) and organo-montmorillonite (30B) were used individually and simultaneously as reinforcing nano...

  • Article
  • Open Access
18 Citations
3,132 Views
15 Pages

6 August 2021

Carbon black (CB), carbon nanotubes (CNTs), and graphene nanoplatelets (GnPs) individually or doubly served as reinforcing fillers in polycarbonate (PC)/poly(vinylidene fluoride) (PVDF)-blend (designated CF)-based nanocomposites. Additionally, organo...

  • Article
  • Open Access
24 Citations
5,769 Views
17 Pages

Nanoclays for Lipase Immobilization: Biocatalyst Characterization and Activity in Polyester Synthesis

  • Hale Öztürk,
  • Eric Pollet,
  • Vincent Phalip,
  • Yüksel Güvenilir and
  • Luc Avérous

1 December 2016

The immobilization of Candida antarctica lipase B (CALB) was performed by physical adsorption on both neat and organo-modified forms of sepiolite and montmorillonite. The influence of different parameters, e.g., solvent, enzyme loading, cross-linking...

  • Article
  • Open Access
10 Citations
4,867 Views
16 Pages

Novel Montmorillonite/TiO2/MnAl-Mixed Oxide Composites Prepared from Inverse Microemulsions as Combustion Catalysts

  • Bogna D. Napruszewska,
  • Alicja Michalik-Zym,
  • Melania Rogowska,
  • Elżbieta Bielańska,
  • Wojciech Rojek,
  • Adam Gaweł,
  • Monika Wójcik-Bania,
  • Krzysztof Bahranowski and
  • Ewa M. Serwicka

19 November 2017

A novel design of combustion catalysts is proposed, in which clay/TiO2/MnAl-mixed oxide composites are formed by intermixing exfoliated organo-montmorillonite with oxide precursors (hydrotalcite-like in the case of Mn-Al oxide) obtained by an inverse...

  • Article
  • Open Access
7 Citations
4,602 Views
13 Pages

Synthesis and Characterization of a Dual-Cation Organomontmorillonite Nanocomposite

  • Guifang Wang,
  • Huizhen Xiao,
  • Shuai Zhang,
  • Jun Qiu,
  • Hengjun Li,
  • Meijin Yang,
  • Shaojian Ma and
  • Sridhar Komarneni

19 November 2018

In this study, a novel dual-cation organomontmorillonites (OMt) nanocomposite was synthesized by two kinds of modifiers cetyltrimethylammonium chloride and cysteamine hydrochloride, and the adsorption behavior of modifiers into montmorillonite (Mt) h...

  • Review
  • Open Access
65 Citations
12,193 Views
25 Pages

Flame Retardation of Natural Rubber: Strategy and Recent Progress

  • Le Wan,
  • Cong Deng,
  • Ze-Yong Zhao,
  • Hong Chen and
  • Yu-Zhong Wang

12 February 2020

Natural rubber (NR) as a kind of commercial polymer or engineering elastomer is widely used in tires, dampers, suspension elements, etc., because of its unique overall performance. For some NR products, their work environment is extremely harsh, faci...

  • Article
  • Open Access
27 Citations
3,486 Views
15 Pages

18 April 2023

The present study aims to explore the impact of pristine and surfactant-modified clays (montmorillonite, bentonite and vermiculite) on the thermomechanical properties of a poly (vinyl chloride) (PVC) polymer film. Initially, clay was modified by empl...

  • Article
  • Open Access
3 Citations
3,118 Views
20 Pages

Montmorillonite Exfoliation in LLDPE and Factors Affecting Its Orientation: From Monolayer to Multi-Nano-Layer Polymer Films

  • Noémie Rivollier,
  • René Schwiddessen,
  • Geraldine Cabrera,
  • Christelle Combeaud,
  • Susan Schorr and
  • Gilles Dennler

9 January 2024

The motivations of the present work are to investigate the exfoliation of montmorillonite within a linear low-density polyethylene matrix and to control its orientation during the cast extrusion process. The first part is focused on the exfoliation o...

  • Article
  • Open Access
4 Citations
3,531 Views
12 Pages

Role of Organo-Modifier and Metal Impurities of Commercial Nanoclays in the Photo- and Thermo-Oxidation of Polyamide 11 Nanocomposites

  • Martina Ussia,
  • Giusy Curcuruto,
  • Daniela Zampino,
  • Nadka Tzankova Dintcheva,
  • Giovanni Filippone,
  • Raniero Mendichi and
  • Sabrina Carola Carroccio

2 May 2020

The photo-oxidative degradation processes of bio-based PA11 nanocomposites containing montmorillonite (MMT) and the organo-modified Cloisite®30B were investigated to discriminate the influence of organo-modified components on the polymer durabili...

  • Article
  • Open Access
36 Citations
6,255 Views
15 Pages

Composite gel polymer electrolytes (GPEs) based on organo-modified montmorillonite clays have been prepared and investigated. The organo-clay was prepared by intercalation of CTAB molecules in the interlamellar space of sodium smectite clay (SWy) thr...

  • Article
  • Open Access
36 Citations
7,161 Views
17 Pages

12 June 2018

Polystyrene-organo-montmorillonite (PS-OMMT) nanocomposite particles were prepared via emulsion polymerization of styrene in the presence of montmorillonite modified with an anionic surfactant, sodium lauryl sulfonate (SLS), and its tribological prop...

  • Article
  • Open Access
40 Citations
5,928 Views
17 Pages

8 May 2019

In this work, the effect of doubly functionalized montmorillonite (MMT) on the structure, morphology, thermal, and tribological characteristics of the resulting polystyrene (PS) nanocomposites was investigated. The modification of the MMT was perform...

  • Article
  • Open Access
12 Citations
3,075 Views
20 Pages

Designing Antioxidant and Antimicrobial Polyethylene Films with Bioactive Compounds/Clay Nanohybrids for Potential Packaging Applications

  • Konstantinos Safakas,
  • Iro Giotopoulou,
  • Archontoula Giannakopoulou,
  • Katerina Katerinopoulou,
  • Georgia C. Lainioti,
  • Haralambos Stamatis,
  • Nektaria-Marianthi Barkoula and
  • Athanasios Ladavos

25 March 2023

In the present work, direct incorporation of bioactive compounds onto the surface and interlayer of nanoclays before their incorporation into the final polymeric film was conducted, based on a green methodology developed by our group that is compatib...

  • Article
  • Open Access
7 Citations
2,062 Views
16 Pages

In the present work, a novel methodology was developed for the fabrication of clay-based nano pigments with enhanced thermal stability and used further as a colorant to prepare polymeric membranes. Initially, the batch extraction studies were perform...

  • Article
  • Open Access
32 Citations
7,676 Views
16 Pages

13 June 2014

Multi-component nanohybrids comprising of organo-modified montmorillonite (MMT) and immiscible biopolymer blends of poly(3-hydroxybutyrate) (PHB) and epoxidized natural rubber (ENR-50) were prepared by solvent casting technique. The one and three dim...

  • Article
  • Open Access
2 Citations
2,594 Views
15 Pages

Food-Grade PE Recycling: Effect of Nanoclays on the Decontamination Efficacy

  • Yannick Laridon,
  • François Touchaleaume,
  • Nathalie Gontard and
  • Stéphane Peyron

4 April 2020

Although PE-based nanocomposites are gaining interest within the food packaging industry for their outstanding functional properties, their end-of-life has been poorly studied. The lack of identification of such materials suggests that they could end...

  • Article
  • Open Access
87 Citations
9,152 Views
21 Pages

Impact of Nanoclays on the Biodegradation of Poly(Lactic Acid) Nanocomposites

  • Edgar Castro-Aguirre,
  • Rafael Auras,
  • Susan Selke,
  • Maria Rubino and
  • Terence Marsh

17 February 2018

Poly(lactic acid) (PLA), a well-known biodegradable and compostable polymer, was used in this study as a model system to determine if the addition of nanoclays affects its biodegradation in simulated composting conditions and whether the nanoclays im...

  • Article
  • Open Access
6 Citations
2,033 Views
12 Pages

Effects of Nanofillers Based on Cetyltrimethylammonium-Modified Clays in a Polypropylene Nanocomposite

  • Hyeon-Ju Ryu,
  • Nguyen Thu Hang,
  • Sanoj Rejinold. N,
  • Byeongmoon Jeong,
  • Goeun Choi and
  • Jin-Ho Choy

30 September 2022

Nanocomposites of hydrophobic organo-clay/polypropylene (organo-clay/PP) were efficiently developed through a solution-blending technique. For this, we utilized various smectite clays as host agents; namely, Na-montmorillonite (Mt, ~1000 nm), Na-fluo...

  • Article
  • Open Access
22 Citations
7,768 Views
19 Pages

Corrosion Protection of Steel by Epoxy-Organoclay Nanocomposite Coatings

  • Domna Merachtsaki,
  • Panagiotis Xidas,
  • Panagiotis Giannakoudakis,
  • Konstantinos Triantafyllidis and
  • Panagiotis Spathis

The purpose of the present work was to study the corrosion behavior of steel coated with epoxy-(organo) clay nanocomposite films. The investigation was carried out using salt spray exposures, optical and scanning electron microscopy examination, open...

  • Article
  • Open Access
2,900 Views
23 Pages

Elastocaloric Performance of Natural Rubber: The Role of Nanoclay Addition

  • Marica Bianchi,
  • Luca Fambri,
  • Mauro Bortolotti,
  • Alessandro Pegoretti and
  • Andrea Dorigato

19 July 2025

This work investigates the effect of nanoclay addition—specifically natural montmorillonite (MMT) and organo-modified montmorillonite (O-MMT)—on the elastocaloric performance of natural rubber (NR), a promising material for solid-state co...

  • Article
  • Open Access
15 Citations
3,634 Views
22 Pages

Novel Poly(Vinylidene Fluoride)/Montmorillonite Polymer Inclusion Membrane: Application to Cr(VI) Extraction from Polluted Water

  • Ferhat Sellami,
  • Ounissa Kebiche-Senhadji,
  • Stéphane Marais,
  • Charles Lanel and
  • Kateryna Fatyeyeva

1 September 2021

Novel hybrid polymer inclusion membranes (PIMs) based on poly(vinylidene fluoride) (PVDF) (polymer matrix) and Aliquat 336 (ion carrier) and containing native sodium (Cloisite Na+ (CNa)) and organo-modified (Cloisite 30B (C30B)) Montmorillonites were...

  • Feature Paper
  • Review
  • Open Access
26 Citations
6,292 Views
41 Pages

24 December 2020

This review deals with modification of montmorillonite and other clay-minerals and clays by interacting them with organic cations, for producing slow release formulations of herbicides, and efficient removal of pollutants from water by filtration. El...

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