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190 Results Found

  • Review
  • Open Access
2 Citations
2,988 Views
31 Pages

Advancements in Non-Precious Metal Catalysts for High-Temperature Proton-Exchange Membrane Fuel Cells: A Comprehensive Review

  • Naresh Narayanan,
  • Balamurali Ravichandran,
  • Indubala Emayavaramban,
  • Huiyuan Liu and
  • Huaneng Su

14 August 2025

High-Temperature Proton-Exchange Membrane Fuel Cells (HT-PEMFCs) represent a promising clean energy technology and are valued for their fuel flexibility and simplified balance of plant. Their commercialization, however, is critically hindered by the...

  • Article
  • Open Access
3 Citations
2,743 Views
13 Pages

One-Step Synthesis of a Non-Precious-Metal Tris (Fe/N/F)-Doped Carbon Catalyst for Oxygen Reduction Reactions

  • Huitian Yang,
  • Hao Wu,
  • Lei Yao,
  • Siyan Liu,
  • Lu Yang,
  • Jieling Lu,
  • Hongliang Peng,
  • Xiangcheng Lin,
  • Ping Cai and
  • Huanzhi Zhang
  • + 3 authors

Advancements in inexpensive, efficient, and durable oxygen reduction catalysts is important for maintaining the sustainable development of fuel cells. Although doping carbon materials with transition metals or heteroatomic doping is inexpensive and e...

  • Review
  • Open Access
55 Citations
8,373 Views
23 Pages

20 January 2020

The proton exchange membrane fuel cells (PEMFCs) have been considered as promising future energy conversion devices, and have attracted immense scientific attention due to their high efficiency and environmental friendliness. Nevertheless, the practi...

  • Article
  • Open Access
7 Citations
4,106 Views
11 Pages

Cobalt-Containing Nitrogen-Doped Carbon Materials Derived from Saccharides as Efficient Electrocatalysts for Oxygen Reduction Reaction

  • Kaidi Veske,
  • Ave Sarapuu,
  • Maike Käärik,
  • Arvo Kikas,
  • Vambola Kisand,
  • Helle-Mai Piirsoo,
  • Alexey Treshchalov,
  • Jaan Leis,
  • Aile Tamm and
  • Kaido Tammeveski

20 May 2022

The development of non-precious metal electrocatalysts towards oxygen reduction reaction (ORR) is crucial for the commercialisation of polymer electrolyte fuel cells. In this work, cobalt-containing nitrogen-doped porous carbon materials were prepare...

  • Article
  • Open Access
9 Citations
5,556 Views
14 Pages

27 November 2017

Metal–organic framework (MOF) materials can be used as precursors to prepare non-precious metal catalysts (NPMCs) for oxygen reduction reaction (ORR). Herein, we prepared a novel MOF material (denoted as Co-bpdc) and then combined it with multi-walle...

  • Article
  • Open Access
10 Citations
6,606 Views
10 Pages

Positive Effect of Heat Treatment on Carbon-Supported CoS Nanocatalysts for Oxygen Reduction Reaction

  • Haihong Zhong,
  • Jingmin Xi,
  • Pinggui Tang,
  • Dianqing Li and
  • Yongjun Feng

15 July 2015

It is of increasing interest and an important challenge to develop highly efficient less-expensive cathode catalysts for anion-exchange membrane fuel cells (AEMFCs). In this work, we have directly prepared a carbon-supported CoS nanocatalyst in a so...

  • Article
  • Open Access
2 Citations
2,125 Views
12 Pages

Highly Efficient CoFeP Nanoparticle Catalysts for Superior Oxygen Evolution Reaction Performance

  • Abhishek Meena,
  • Abu Talha Aqueel Ahmed,
  • Aditya Narayan Singh,
  • Vijaya Gopalan Sree,
  • Hyunsik Im and
  • Sangeun Cho

24 August 2024

Developing effective and long-lasting electrocatalysts for oxygen evolution reaction (OER) is critical for increasing sustainable hydrogen production. This paper describes the production and characterization of CoFeP nanoparticles (CFP NPs) as high-p...

  • Article
  • Open Access
2 Citations
3,640 Views
9 Pages

Methane Conversion over C2N-Supported Fe2 Dimers

  • Haihong Meng,
  • Bing Han,
  • Fengyu Li and
  • Jingxiang Zhao

29 August 2020

Methane is a vast hydrocarbon resource around the globe that has the potential to replace petroleum as a raw material and energy source. Therefore, the catalytic conversion of methane into high value-added chemicals is significantly important for the...

  • Feature Paper
  • Article
  • Open Access
9 Citations
5,764 Views
13 Pages

13 April 2018

It is still a challenge to synthesize non-precious-metal catalysts with high activity and stability for the oxygen reduction reaction (ORR) to replace the state-of-the art Pt/C catalyst. Herein, a Fe, N, S co-doped porous carbon (Fe-NS/PC) is develop...

  • Review
  • Open Access
13 Citations
2,803 Views
26 Pages

31 October 2022

Hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) is regarded as the bridge between bio-refinery and the traditional petroleum industry. In recent years, non-precious metal-based catalysts for LA hydrogenation to GVL have attracted...

  • Article
  • Open Access
28 Citations
5,737 Views
10 Pages

6 December 2018

Electrocatalysts for the oxygen reduction (ORR) reaction play an important role in renewable energy technologies, including fuel cells and metal-air batteries. However, development of cost effective catalyst with high activity remains a great challen...

  • Article
  • Open Access
20 Citations
4,634 Views
19 Pages

Relevant Properties of Carbon Support Materials in Successful Fe-N-C Synthesis for the Oxygen Reduction Reaction: Study of Carbon Blacks and Biomass-Based Carbons

  • Julia Hülstede,
  • Dana Schonvogel,
  • Henrike Schmies,
  • Peter Wagner,
  • Frank Schröter,
  • Alexander Dyck and
  • Michael Wark

24 December 2020

Fe-N-C materials are promising non-precious metal catalysts for the oxygen reduction reaction in fuel cells and batteries. However, during the synthesis of these materials less active Fe-containing nanoparticles are formed in many cases which lead to...

  • Article
  • Open Access
18 Citations
3,380 Views
18 Pages

Iron, Cobalt, and Nickel Phthalocyanine Tri-Doped Electrospun Carbon Nanofibre-Based Catalyst for Rechargeable Zinc–Air Battery Air Electrode

  • Kaur Muuli,
  • Rohit Kumar,
  • Marek Mooste,
  • Viktoria Gudkova,
  • Alexey Treshchalov,
  • Helle-Mai Piirsoo,
  • Arvo Kikas,
  • Jaan Aruväli,
  • Vambola Kisand and
  • Aile Tamm
  • + 4 authors

27 June 2023

The goal of achieving the large-scale production of zero-emission vehicles by 2035 will create high expectations for electric vehicle (EV) development and availability. Currently, a major problem is the lack of suitable batteries and battery material...

  • Article
  • Open Access
1 Citations
1,702 Views
17 Pages

Realistic applications of zinc–air batteries are hindered by the high cost of Pt/C cathode catalysts, necessitating the search for alternative, sustainable electrocatalysts. In this work, we developed a sustainable Fe3C/Fe-Nx-C cathode catalyst...

  • Article
  • Open Access
12 Citations
2,471 Views
14 Pages

Cobalt Phthalocyanine-Doped Polymer-Based Electrocatalyst for Rechargeable Zinc-Air Batteries

  • Yogesh Kumar,
  • Srinu Akula,
  • Elo Kibena-Põldsepp,
  • Maike Käärik,
  • Jekaterina Kozlova,
  • Arvo Kikas,
  • Jaan Aruväli,
  • Vambola Kisand,
  • Jaan Leis and
  • Aile Tamm
  • + 1 author

20 July 2023

Rechargeable zinc-air batteries (RZAB) have gained significant attention as potential energy storage devices due to their high energy density, cost-effectiveness, and to the fact that they are environmentally safe. However, the practical implementati...

  • Article
  • Open Access
1,597 Views
11 Pages

25 April 2024

The development of solid-state zinc–air batteries (SZABs) has stimulated significant interest. However, the practical use of SZABs still encounters difficulties due to the complicated preparation process and low-performance air cathode. In this...

  • Article
  • Open Access
35 Citations
6,739 Views
13 Pages

28 June 2019

The possibility of wastewater treatment and electricity production using a microbial fuel cell with Cu–B alloy as the cathode catalyst is presented in this paper. Our research covered the catalyst preparation; measurements of the electroless po...

  • Article
  • Open Access
5 Citations
2,960 Views
12 Pages

1 October 2022

The oxygen reduction reaction (ORR) is of great importance for clean energy storage and conversion techniques such as fuel cells and metal–air batteries (MABs). However, the ORR is kinetically sluggish, and expensive noble metal catalysts are r...

  • Article
  • Open Access
6 Citations
3,209 Views
12 Pages

17 December 2021

Non-platinum carbon-based catalysts have attracted much more attention in recent years because of their low cost and outstanding performance, and are regarded as one of the most promising alternatives to precious metal catalysts. Activated carbon (AC...

  • Feature Paper
  • Review
  • Open Access
77 Citations
9,407 Views
53 Pages

1 February 2020

Catalysis is an indispensable part of our society, massively involved in numerous energy and environmental applications. Although, noble metals (NMs)-based catalysts are routinely employed in catalysis, their limited resources and high cost hinder th...

  • Review
  • Open Access
22 Citations
4,411 Views
39 Pages

21 April 2023

The development of efficient, stable, and economic electrocatalysts are key to the large-scale application of electrochemical energy conversion. Porous carbon-based non-precious metal electrocatalysts are considered to be the most promising materials...

  • Article
  • Open Access
8 Citations
2,360 Views
20 Pages

15 November 2023

Current study provides a novel strategy to synthesize the nano-sized MnO nanoparticles from the quick, ascendable, sol-gel synthesis strategy. The MnO nanoparticles are supported on nitrogen-doped carbon derived from the cheap sustainable source. The...

  • Review
  • Open Access
2 Citations
2,356 Views
16 Pages

2 October 2024

Green hydrogen energy from electrocatalytic hydrogen evolution reactions (HERs) has gained much attention for its advantages of low carbon, high efficiency, interconnected energy medium, safety, and controllability. Non-precious metals have emerged a...

  • Feature Paper
  • Article
  • Open Access
7 Citations
2,773 Views
16 Pages

Non-Precious Metals Catalysts for Hydrogen Generation

  • Zita Sukackienė,
  • Gitana Valeckytė,
  • Virginija Kepenienė,
  • Irena Stalnionienė,
  • Vitalija Jasulaitienė,
  • Jūratė Vaičiūnienė,
  • Loreta Tamašauskaitė-Tamašiūnaitė,
  • Giedrius Stalnionis and
  • Eugenijus Norkus

7 October 2023

In this paper, the generation of hydrogen from alkaline sodium borohydride solution by hydrolysis is studied. To obtain catalysts for efficient hydrogen generation, Ni, Mn, Mo, and Co metals were deposited on the Cu surface by the simple electroless...

  • Feature Paper
  • Review
  • Open Access
2,159 Views
21 Pages

30 July 2025

This review examines the research progress on non-noble-metal-based catalysts for formaldehyde (HCHO) oxidation at room temperature. It begins with an introduction to the hazards of HCHO as an indoor pollutant and the urgency of its removal, comparin...

  • Review
  • Open Access
13 Citations
4,921 Views
30 Pages

30 October 2022

Zinc–air batteries (ZABs) have several advantages, including high energy density, cheap price and stable performances with good application prospects in the field of power batteries. The charging and discharging reactions for the air cathode of...

  • Review
  • Open Access
2 Citations
2,660 Views
16 Pages

10 May 2024

Hydrogen, one of the most promising forms of new energy sources, due to its high energy density, low emissions, and potential to decarbonize various sectors, has attracted significant research attention. It is known that electrocatalytic hydrogen pro...

  • Article
  • Open Access
2 Citations
2,098 Views
23 Pages

This study focuses on making non-precious electrocatalysts for improving the performance of Direct Alcohol Fuel Cells (DAFCs). Specifically, it examines the oxidation of ethanol and methanol. Conventional platinum-based catalysts are expensive and su...

  • Review
  • Open Access
919 Views
31 Pages

Recent Advances in the Electrocatalytic Performance of Nanoporous Materials for Hydrogen Evolution Reaction

  • Zhangyi Li,
  • Lin Yang,
  • Yingqi Chen,
  • Wence Xu,
  • Zhonghui Gao,
  • Jiamin Zhu,
  • Yanqin Liang,
  • Hui Jiang,
  • Zhaoyang Li and
  • Zhenduo Cui
  • + 2 authors

26 November 2025

Electrocatalytic water splitting for hydrogen production is a crucial technology in achieving carbon neutrality. The development of efficient and stable hydrogen evolution reaction (HER) electrocatalysts is a core challenge in this field. This review...

  • Editorial
  • Open Access
11 Citations
2,710 Views
3 Pages

29 August 2019

The collection of articles in the Catalyst special issue entitled “Novel Non-Precious Metal Electrocatalysts for Oxygen Electrode Reactions” mirrors the relevance and strengths to address the inevitable increasing demand of energy [...]

  • Article
  • Open Access
3 Citations
3,498 Views
15 Pages

Ni5P4-NiP2-Ni2P Nanocomposites Tangled with N-Doped Carbon for Enhanced Electrochemical Hydrogen Evolution in Acidic and Alkaline Solutions

  • Miaomiao Pei,
  • Xiaowei Song,
  • Haihong Zhong,
  • Luis Alberto Estudillo-Wong,
  • Yingchun Gao,
  • Tongmengyao Jin,
  • Ju Huang,
  • Yali Wang,
  • Jun Yang and
  • Yongjun Feng

15 December 2022

Heterostructured non-precious metal phosphides have attracted increasing attention in the development of high-performance catalysts for hydrogen evolution reaction (HER), particularly in acidic media. Herein, a catalyst composed of ternary Ni5P4-NiP2...

  • Review
  • Open Access
17 Citations
5,467 Views
12 Pages

Non-Precious Metal Graphene-Based Catalysts for Hydrogen Evolution Reaction

  • Maximina Luis-Sunga,
  • Lana Regent,
  • Elena Pastor and
  • Gonzalo García

Developing sustainable and renewable energy sources is critical as higher and higher global energy and environmental challenges arise. Hydrogen has the highest mass/energy density of any fuel and is considered one of the best sources of clean energy....

  • Communication
  • Open Access
2 Citations
2,151 Views
11 Pages

27 June 2023

Energy conversion and storage systems have recently attracted significant attention owing to increasing environmental and energy problems. However, the slow kinetics of the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) rende...

  • Review
  • Open Access
7 Citations
6,180 Views
14 Pages

22 October 2021

This mini-review presents a short account of materials with exceptional activity towards oxygen reduction reaction. Two main classes of catalytic materials are described, namely platinum group metal (PGM) catalyst and Non-precious metal catalyst. The...

  • Review
  • Open Access
7 Citations
4,650 Views
19 Pages

12 March 2024

This review introduces transition metal phosphide nanoparticle catalysts as highly efficient and reusable heterogeneous catalysts for various reductive molecular transformations. These transformations include the hydrogenation of nitriles to primary...

  • Feature Paper
  • Review
  • Open Access
27 Citations
4,116 Views
19 Pages

26 October 2021

Formic acid (FA) possesses a high volumetric concentration of H2 (53 g L−1). Moreover, it can be easily prepared, stored, and transported. Therefore, FA stands out as a potential liquid organic hydrogen carrier (LOHC), which allows storage and transp...

  • Feature Paper
  • Review
  • Open Access
45 Citations
9,685 Views
67 Pages

Recent Progress of Non-Pt Catalysts for Oxygen Reduction Reaction in Fuel Cells

  • Qing Chen,
  • Zhou Zhang,
  • Ruiquan Zhang,
  • Maocong Hu,
  • Ling Shi and
  • Zhenhua Yao

23 January 2023

In recent years, non-Pt-based ORR catalysts have been developing rapidly and have achieved performance comparable to or even surpassing Pt precious metal catalysts in specific reactions, offering new possibilities for Pt-based catalyst replacement an...

  • Article
  • Open Access
7 Citations
3,227 Views
14 Pages

Precipitation of Pt, Pd, Rh, and Ru Nanoparticles with Non-Precious Metals from Model and Real Multicomponent Solutions

  • Martyna Rzelewska-Piekut,
  • Zuzanna Wolańczyk,
  • Marek Nowicki and
  • Magdalena Regel-Rosocka

This article presents studies on the precipitation of Pt, Pd, Rh, and Ru nanoparticles (NPs) from model and real multicomponent solutions using sodium borohydride, ascorbic acid, sodium formate, and formic acid as reducing agents and polyvinylpyrroli...

  • Review
  • Open Access
6 Citations
3,287 Views
31 Pages

The use of biomass-based glycerol to produce chemicals with high added value is of great significance for solving the problem of glycerol surplus and thus reducing the production cost of biodiesel. The production of 1,2-propanediol (abbreviated as 1,...

  • Review
  • Open Access
1,242 Views
18 Pages

10 October 2025

To address the greenhouse effect and environmental pollution stemming from fossil fuels, the development of new energy sources is widely regarded as a critical pathway toward achieving carbon neutrality. Microalgae, as a feedstock for third-generatio...

  • Article
  • Open Access
4 Citations
2,579 Views
12 Pages

17 June 2023

This study analyzes Diesel Oxidation Catalyst (DOC) and Carbon Diesel Particulate Filter (CDPF) after-treatment systems integrated into a WARTSILA W20DF marine dual-fuel engine. The CDPF was coated with a non-precious metal catalyst whose catalytic r...

  • Article
  • Open Access
1 Citations
1,434 Views
21 Pages

Impact of Metal Source Structure on the Electrocatalytic Properties of Polyacrylonitrile-Derived Co-N-Doped Oxygen Reduction Reaction Catalysts

  • Arseniy Kalnin,
  • Ksenia Kharisova,
  • Daniil Lukyanov,
  • Sofia Filippova,
  • Ruopeng Li,
  • Peixia Yang,
  • Oleg Levin and
  • Elena Alekseeva

29 November 2024

The oxygen reduction reaction (ORR) plays a central role in energy conversion and storage technologies. A promising alternative to precious metal catalysts are non-precious metal doped carbons. Considerable efforts have been devoted to cobalt-doped c...

  • Review
  • Open Access
1 Citations
2,101 Views
15 Pages

Recent Advances in Regulating Ceramic Monolithic Catalyst Structure for Preferential Oxidation of CO in H2

  • Qing Wang,
  • Jiancai Sui,
  • Linlin Li,
  • Yongxiao Tuo,
  • Wenfa Zhang,
  • Guoyu Zhong,
  • Huanxin Zhou and
  • Xiang Feng

25 July 2024

Preferential oxidation of CO (CO-PROX) has tremendous significance in purifying hydrogen for fuel cells to avoid catalyst poisoning by CO molecules. Traditional powder catalysts face numerous challenges, including high pressure drop, aggregation tend...

  • Review
  • Open Access
8 Citations
5,576 Views
14 Pages

8 August 2018

Nitrogen-containing aromatic polymers such as polyimide are known for their high thermal stability. While they have been widely used in industry, their relevance to catalysis is still quite limited. In recent years, nitrogen-containing polymers have...

  • Article
  • Open Access
2 Citations
2,567 Views
15 Pages

30 May 2022

The development of high-performance nonprecious metal catalysts for oxygen reduction reactions is critical for the commercialization of fuel cells. In this paper, we report a non-precious catalyst with high-performance, in which Fe and Fe3C is embedd...

  • Feature Paper
  • Article
  • Open Access
13 Citations
4,170 Views
14 Pages

Copper-Decorated Ti3C2Tx MXene Electrocatalyst for Hydrogen Evolution Reaction

  • Buxiang Wang,
  • Qing Shu,
  • Haodong Chen,
  • Xuyao Xing,
  • Qiong Wu and
  • Li Zhang

25 November 2022

It remains a formidable challenge to prepare an economical and stable electrocatalyst for hydrogen evolution reaction using non-precious metals. In this study, MXene (Ti3C2Tx) nanosheets were prepared by high-energy ultrasound treatment, and Cu nanop...

  • Article
  • Open Access
23 Citations
3,618 Views
13 Pages

2 February 2021

Through one-step pyrolysis, non-noble-metal oxygen reduction reaction (ORR) electrocatalysts were constructed from ferric trichloride, melamine, and graphene nanoribbon@carbon nanotube (GNR@CNT), in which a portion of the multiwall carbon nanotube is...

  • Editorial
  • Open Access
2,324 Views
6 Pages

24 July 2021

Catalysis is an indispensable part of our society, involved in numerous energy and environmental applications, such as the production of value-added chemicals/fuels, hydrocarbons processing, fuel cells applications, abatement of hazardous pollutants,...

  • Article
  • Open Access
1 Citations
2,402 Views
10 Pages

Rechargeable zinc–air batteries (RZABs) are basically dependent on both affordable and long-lasting bifunctional electrocatalysts. A non-precious metal catalyst, a FeNi nanoalloy catalyst (FeNi@NC) with an extremely low metal consumption (0.06...

  • Article
  • Open Access
20 Citations
3,911 Views
14 Pages

25 January 2023

The rational design of efficient Earth-abundant electrocatalysts for the ethanol oxidation reaction (EOR) is the key to developing direct ethanol fuel cells (DEFCs). Among these, the smart structure is highly demanded for highly efficient and stable...

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