Search Results (10)

This study explored the influence of hydrogen on the tensile properties and fracture behavior of high-strength API X70 and X80 linepipe steels with bainitic microstructures under varying hydrogen charging conditions. The X70 steel exhibited a ferritic microstructure with some pearlite, while the X80 steel showed a bainitic microstructure and fine pearlite due to the addition of molybdenum. Slow strain rate tests (SSRTs) were conducted using both electrochemical ex situ and in situ hydrogen charging methods subjected to different current densities. The SSRT results showed that in situ hydrogen-charged SSRT, performed at current densities above 1 A/m², led to more pronounced hydrogen embrittlement compared to ex situ hydrogen-charged SSRT. This occurred because hydrogen was continuously supplied during deformation, exceeding the critical concentration even in the center regions, leading to quasi-cleavage fractures marked by localized cleavage and tearing ridges. Thermal desorption analysis (TDA) confirmed that a greater amount of hydrogen was trapped at dislocations during in situ hydrogen-charged SSRT, intensifying hydrogen embrittlement, even with a shorter hydrogen charging duration. These findings highlight the importance of selecting appropriate hydrogen charging methods and understanding the hydrogen embrittlement behavior of linepipe steels. Full article

This study investigates the hydrogen embrittlement behavior of API X70 linepipe steel. The microstructure was primarily composed of a dislocation-rich bainitic microstructure and polygonal ferrite. Slow strain-rate tests (SSRTs) were performed under both ex situ and in situ electrochemical hydrogen charging conditions to examine the difference between hydrogen diffusion and trapping behaviors. The ex situ SSRTs showed almost the same tensile properties as air and a limited brittle fracture confined to near the surface. In contrast, the in situ SSRTs showed an abrupt failure after the maximum tensile load, leading to a brittle fracture across the entire fracture surface with stress-oriented hydrogen-induced cracking (SOHIC). The crack trace analysis results indicated that SOHIC propagation paths were influenced by localized hydrogen accumulation due to high-stress fields. As a result, the dominant hydrogen embrittlement mechanisms, such as hydrogen-enhanced localized plasticity (HELP) and hydrogen-enhanced decohesion (HEDE), changed. These findings provide critical insights into the microstructural factors affecting hydrogen embrittlement, which are essential for the design of hydrogen-resistant steels in hydrogen infrastructure applications. Full article

Toughness and the transition from ductile to brittle behavior are long-standing concerns for applications of ferritic steel such as line-pipe. Three algorithms have been developed to fit a hyperbolic tangent curve to any Charpy V-notch dataset and estimate the uncertainty for (1) the 85% shear appearance area transition temperature and (2) the upper shelf absorbed energy. To fit the hyperbolic tangent curve to the data the (I) first algorithm relied on iterative estimation of four-parameters; (II) the second algorithm on two parameters (after simplification based on physical assumptions); and (III) the third algorithm on only one parameter (after further simplification). The algorithms were written using the open-source programing language, R. The minimum input requirements for the algorithm are experimental data for shear appearance area and absorbed energy from at least four temperatures for the four-parameter algorithm, two temperatures for the two-parameter algorithm, and one temperature for the one-parameter algorithm. The test temperatures and quantity of tests at each temperature can vary. The algorithms are described in detail and demonstrated using a data set of 12 Charpy test results (shear area and absorbed energy) from one API-5L grade X52 pipe with 4.5 mm thick Charpy bars. A future paper will test and compare the algorithms using a wide variety of Charpy V-notch data sets to clarify their applicability and possible limitations. Full article

Thermo-mechanically controlled rolling is a technique used to produce steel strips and plates. One of the steels widely used in the production of heavy plates for application in oil and gas pipelines is API X80. The hot rolling process of this family of steels consists of applying deformation passes at high temperatures, mainly above Ae₃, inside the austenite phase field. It has been shown that during deformation, the phenomenon of dynamic transformation (DT) of austenite into ferrite leads to lower hot deformation resistance within the stable austenite region. In this investigation, hot torsion simulations of an industrial rolling process under continuous cooling conditions were used to monitor the formation of ferrite by DT. Stress–strain flow curves and equivalent mean flow stresses followed by sample characterization via optical and electron microscopy showed the inevitable formation of ferrite above the Ae₃. The employed 10-pass deformation schedule was divided into 5 roughing and 5 finishing passes, thereby promoting an increased volume fraction of ferrite and decreased critical strain for the onset of DT and dynamic recrystallization (DRX). A microstructural analysis confirmed the formation of ferrite from the first roughing strain until the last finishing pass. The volume fraction of DT ferrite increased due to strain accumulation, an increased number of deformation passes and as the temperature approached the Ae₃, leading to a characteristic torsion texture at the end of the simulation. Full article

The feasibility of using laser-cold metal transfer (CMT) misaligned hybrid welding to join an X80 line-pipe steel in a narrow gap configuration was investigated. The laser beam interacted with the sidewall and its bottom at a small angle, while the CMT arc acted on the backside of the laser beam. The influence of the distance parameter between the laser spot and the tip of the welding wire on the formation and defects of the filled weld were investigated. Narrow gap bevel welds were performed, and the joints were tensile and had a satisfactory Charpy impact score. The tensile fracture is located in the base metal, and the impact fracture is a ductile fracture. Under this condition, the heat input could be efficiently reduced, preventing the formation of defects such as lack of fusion and reducing the number of pores. Additionally, welds with a narrow heat affect zone (HAZ) could be obtained. The results reveal that the hybrid process, as a low-heat input method, is suitable for narrow gap welding. Full article

The purpose of this article is to compare two predictive methods of J integral assessments for center-cracked plates, single-edge cracked plates and double-edge cracked plates produced from X52 and X70 steels, and a longitudinally cracked pipe produced from X70 steel. The two methods examined are: the GSM method and the J_s procedure of the French RCC-MR construction code, designated here as the FC method. The accuracy of J integral predictions by these methods is visualized by comparing the results obtained with the “reference” values calculated by the EPRI method. The main results showed that both methods yielded similar J integral values, although in most cases, the GSM predictions were slightly more conservative than the FC predictions. In comparison with the “reference” values of the J integral, both methods provided conservative results for most crack configurations, although the estimates for cracks of a relative length smaller than 1/8 were not found to be so conservative. The prediction of burst pressures for external longitudinal semielliptical part-through cracks in X70 steel pipe showed that the magnitudes of predicted burst pressures came very close to each other, and were conservative compared to FEM (finite element method) calculations and experimentally determined burst pressures. Full article

In the 61 years that niobium has been used in commercial steels, it has proven to be beneficial via several properties, such as strength and toughness. Over this time, numerous studies have been performed and papers published showing that both the strength and toughness can be improved with higher Nb additions. Earlier studies have verified this trend for steels containing up to about 0.04 wt.% Nb. Basic studies have shown that the addition of Nb increases the recrystallization-stop temperature, T_5% or T_nr. These same studies have shown that with up to about 0.05 wt.% of Nb, the T_5% temperature increases in the range of finish rolling, which is the basis of controlled rolling. These studies also have shown that at very high Nb levels, exceeding approximately 0.06 wt.% Nb, the recrystallization-stop temperature or T_5% can increase into the temperature range of rough rolling, and this could result in insufficient grain refinement and recrystallization during rough rolling. However, the question remains as to how much Nb can be added before the detriments outweigh the benefits. While the benefits are easily observed and discussed, the detriments are not. These detriments at high Nb levels include cost, undissolved Nb particles, weldability issues, higher mill loads and roll wear and the lessening of grain refinement that might otherwise occur during plate rough rolling. This loss of grain refinement is important, since coarse grained microstructures often result in failure in the drop weight tear testing of the plate and pipe. The purpose of this paper is to discuss the practical limits of Nb microalloying in controlled rolled low carbon linepipe steels of gauges ranging from 12 to 25 mm in thickness. Full article

Isothermal treatment affects the microstructural evolution and the precipitation behavior of high-strength low alloy (HSLA) steels. In this regard, thermal simulation of different isothermal treatment temperatures was adopted by using a thermomechanical simulator. The results showed that hardness reached the maximum value at 600 °C holding temperature, which was related to a finer grain structure and granular bainite. The strengthening effect of precipitates was remarkable due to the combination of small particle size and small interparticle spacing. It is presumed that the precipitation started after 600 s at 600 °C. Precipitation strengthening continued to exist, even though coarsening of ferrite grains led to softening phenomena when the specimen was isothermally held at 750 °C, which led to relatively high hardness. The precipitates were fcc (Ti, Nb) (N, C) particles, and belonged to MX-type precipitates. Average size of precipitates increased from 3.14 to 4.83 nm when the specimens were isothermally held between 600 °C and 800 °C. Interparticle spacing of precipitates also increased with increasing isothermal treatment temperatures. These led to a reduction in precipitation strengthening. At the same time the polygonal ferrite content increased and ferrite grain size got larger, such that the hardness decreased continuously. Full article

The relationship between precipitate morphology and dissolution on grain coarsening behavior was studied in two Ti-Nb microalloyed Linepipe (LP) Steels. The developed understanding highlights the importance of the complex relationship between precipitate constitutive make-up, dissolution mechanism and grain boundary (GB) pinning force. Equilibrium-based empirical solubility products were used to calculate precipitate volume fractions and compared to experimental measurements. Scanning Electron Microscopy (SEM), Electron Backscatter Diffraction (EBSD) and Electron Probe Micro-Analysis (EPMA) were conducted on bulk samples. Transmission Electron Microscopy (TEM)-based techniques were used on C-replica extractions and thin-foils. A retardation in the grain-coarsening temperature compared to the predicted coarsening temperature based on equilibrium calculations was noticed. In addition, a consistent NbC epitaxial formation over pre-existing TiN was observed. The resulting reduction in total precipitate/matrix interface area and the low energy of the TiN/NbC interface are pointed to as responsible mechanisms for the retardation in the kinetics of precipitates’ dissolution. This dissolution retardation mechanism suggests that a lower Nb content might be effective in controlling the grain coarsening behavior of austenite. Full article

The influence of microstructure on pipe flattening response was assessed using two different commercially produced U-ing, O-ing, and expansion (UOE) pipes from API X65 steels having either a bainitic microstructure (steel B) or a ferrite/pearlite microstructure (steel FP). A four-point bending apparatus and distinctive procedure were used to minimize strain localization during flattening. The flattened specimens were sectioned at different positions through the thickness, and tensile tested in both the longitudinal (LD) and transverse directions (TD) to assess the through-thickness variation in properties. Yield strength (YS) distributions in the LD show V-shaped profiles through thickness in both steels, whereas the YS in the TD nearest the outside diameter (OD) surface is reduced. These variations in YS are due to the Bauschinger effect associated with the compressive flattening pre-strain. The uniform elongation (UE) of steel FP is almost independent of specimen position through the thickness, but for steel B there is a substantial reduction of the UE at both the inside and outside diameter positions and this reduction is greater in the LD. This work confirms that flattened pipe mechanical properties exhibit an important dependence on their microstructure type and it is postulated that the flattening procedure also influences the mechanical properties. Full article