Search Results (40)

Electrical bearing currents may disturb the performance of the bearings via electro-corrosion if they surpass a limit of ca. 0.1 to 0.3 A/mm². A continuous current flow, or, after a longer time span, an alternating current or a repeating impulse-like current, damages the raceway surface, leading in many cases to a fluting pattern on the raceway. Increased bearing vibration, audible noise, and decreased bearing lubrication as a result may demand a replacement of the bearings. Here, an electrically corroded axial ball bearing (type 51208) with fluting patterns is investigated. The bearing was lubricated with grease lubrication and was exposed to 4 A DC current flow. It is shown that the electric current flow causes higher concentrations of iron oxides and iron carbides on the bearing raceway surface together with increased surface roughness, leading to a mixed lubrication also at elevated bearing speeds up to 1500 rpm. The “electrically insulating” iron oxide layer and the “mechanically hard” iron carbide layer on the bearing steel are analysed by WLI, XPS, SEM, and EDS. White Light Interferometry (WLI) is used to provide an accurate measurement of the surface topography and roughness. X-ray Photoelectron Spectroscopy (XPS) measurements are conducted to analyze the chemical surface composition and oxidation states. Scanning Electron Microscopy (SEM) is applied for high-resolution imaging of the surface morphology, while the Focused Ion Beam (FIB) is used to cut a trench into the bearing surface to inspect the surface layers. With the Energy Dispersive X-ray spectrometry (EDS), the presence of composing elements is identified, determining their relative concentrations. The electrically-caused iron oxide and iron carbide may develop periodically along the raceway due to the perpendicular vibrations of the rolling ball on the raceway, leading gradually to the fluting pattern. Still, a simulation of this vibration-induced fluting-generation process from the start with the first surface craters—of the molten local contact spots—to the final fluting pattern is missing. Full article

A focused ion beam scanning electron microscope (FIB-SEM) is a powerful tool that is routinely used for scale imaging from the micro- to nanometer scales, micromachining, prototyping, and metrology. In spite of the significant capabilities of a FIB-SEM, there are inherent artefacts (e.g., structural defects, chemical interactions and phase changes, ion implantation, and material redeposition) that are produced due to the interaction of Ga⁺ or other types of ions (e.g., Xe⁺, Ar⁺, O⁺, etc.) with the sample. In this study, we analyzed lattice distortion and ion implantation and subsequent material redeposition in metallic micropillars which were prepared using plasma focus ion beam (PFIB) milling. We utilized non-destructive synchrotron techniques such as X-ray fluorescence (XRF) and X-ray nanodiffraction to examine the micropillars prepared using Xe⁺ ion energies of 10 keV and 30 keV. Our results demonstrate that higher Xe ion energy leads to higher density of implanted ions within the redeposited and milled material. The mixing of ions in the redeposited material significantly influences the lattice structure, causing deformation in regions with higher ion concentrations. Through an X-ray nanodiffraction analysis, we obtained numerical measurements of the strain fields induced in the regions, which revealed up to 0.2% lattice distortion in the ion bombardment direction. Full article

A jet-based direct mixing process is used to effectively mix heterogeneous materials. In this work, its application in the structuring, coating and agglomeration of cathode materials for all-solid-state battery (ASSB) production is investigated, with the aim of increasing the homogeneity and conductivity of the composites and ultimately improving battery performance. In this process, different particle systems consisting of lithium iron phosphate (LFP), carbon black (CB) and sodium chloride (NaCl) are dispersed in the gas phase and brought together in a mixing zone as particle-laden aerosol jets. The cathode material’s structure is studied through scanning electron microscopy combined with a focussed ion beam (SEM–FIB). Electrical conductivity measurements of the resulting composites assess the degree of mixing and the changes in tortuosity, while a laser light diffractor and a cascade impactor analyse the particle size distribution (PSD). The jet-based process effectively produces hetero-agglomerates with the possibility of creating different composite structures by adjusting the process parameters. The mass concentration influences not only the structure, but also the PSD in the flow and the electrical conductivity of the composite. The results serve as a basis for future experiments with solid electrolytes to comprehensively evaluate the process and the resulting battery materials. Full article

A single crystal of ytterbium-doped “mixed” yttrium–lutetium aluminum garnet with a stoichiometric composition of (Y_0.601Lu_0.233Yb_0.166)₃Al₅O₁₂ was grown by the Czochralski method and its structure, vibronic, spectroscopic, and laser properties were studied. The stimulated-emission cross-section for Yb³⁺ ions was maximized to 2.53 × 10⁻²⁰ cm² at 1031 nm. The emission bandwidth was ~8 nm, and the reabsorption-free luminescence lifetime of the ²F_5/2 state was 1.063 ms. Pumped at 941 nm, the Yb laser generated a maximum output power of 1.04 W at 1.03 and 1.05 μm with a high slope efficiency of 76.4% and a laser threshold of 76 mW. A continuous wavelength tuning over a range of 51.6 nm (1026.4–1078.0 nm) was also achieved. Power scaling was achieved using a 969 nm diode-pumped microchip cavity. A maximum output power of ~9 W was obtained at 1.05 μm with a slope efficiency of 76% and an almost circular laser beam profile. Full article

Precise measurements of nuclear beta decays provide a unique insight into the Standard Model due to their connection to the electroweak interaction. These decays help constrain the unitarity or non-unitarity of the Cabibbo–Kobayashi–Maskawa (CKM) quark mixing matrix, and can uniquely probe the existence of exotic scalar or tensor currents. Of these decays, superallowed mixed mirror transitions have been the least well-studied, in part due to the absence of data on their Fermi to Gamow-Teller mixing ratios ($\rho$). At the Nuclear Science Laboratory (NSL) at the University of Notre Dame, the Superallowed Transition Beta-Neutrino Decay Ion Coincidence Trap (St. Benedict) is being constructed to determine the $\rho$ for various mirror decays via a measurement of the beta–neutrino angular correlation parameter ($a_{\beta \nu }$) to a relative precision of 0.5%. In this work, we present an overview of the St. Benedict facility and the impact it will have on various Beyond the Standard Model studies, including an expanded sensitivity study of $\rho$ for various mirror nuclei accessible to the facility. A feasibility evaluation is also presented that indicates the measurement goals for many mirror nuclei, which are currently attainable in a week of radioactive beam delivery at the NSL. Full article

The formation and evolution of microstructures at the Ni/Fe interface in dissimilar metal weld (DMW) between ferritic steel and austenitic stainless steel were investigated. Layered martensitic structures were noted at the nickel-based weld metal/12Cr2MoWVTiB steel interface after welding and post-weld heat treatment (PWHT). The formation of the interfacial martensite layer during welding was clarified and its evolution during PWHT was discussed by means of scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), electron probe microanalysis (EPMA), focused ion beam (FIB), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), transmission kikuchi diffraction (TKD), phase diagrams, and theoretical analysis. In as-welded DMW, the Ni/Fe interface structures consisted of the BCC quenched martensite layer and the FCC partially mixed zone (PMZ), which was the result of inhomogeneous solid phase transformation due to the chemical composition gradient. During the PWHT process, the BCC interfacial microstructure further evolved to a double-layered structure of tempered martensite and quenched martensite newly formed by local re-austenitization and austenite–martensite transformation. These types of martensitic structures induced inhomogeneous hardness distribution near the Ni/Fe interface, aggravating the mismatch of interfacial mechanical properties, which was a potential factor contributing to the degradation and failure of DMW. Full article

Lead is a highly toxic heavy metal that creates a water pollutant. It can be released from industrial processes, agricultural chemistry, and community wastes, affecting creatures and human health even at a low concentration. As a result, it is advised that lead be removed before releasing wastewater into the environment. This study synthesized three chitosan bead materials from shrimp shell wastes which were chitosan powder beads (CB), chitosan powder mixed with goethite beads (CFB), and chitosan powder beads coated with goethite (CBF) for removing lead in an aqueous solution. Their surface area, pore volumes, and pore sizes were explored according to Brunauer– Emmett–Teller, and their crystalline formations were investigated using an X-ray diffractometer. Their surface structures were studied using field emission scanning electron microscopy and a focus ion beam, and their chemical compositions were determined using an energy dispersive X-ray spectrometer. Their chemical functional groups were identified via Fourier-transform infrared spectroscopy. In addition, batch experiments were conducted to investigate the effects of several factors on removing lead, and the adsorption isotherm and kinetics were also investigated for determining their adsorption pattern and mechanism. In addition, the desorption experiments were studied to confirm their possible material reusability. The CBF demonstrated the highest surface area and smallest pore size compared with the other materials. In addition, the pore sizes of the CFB and CBF were micropores, whereas those of the CB were mesopores. All materials were semicrystalline structures, and the specific goethite peaks were observed in the CFB and CBF. All materials had spherical shapes with heterogeneous surfaces. Six chemical components of O, C, Ca, N, Cl, and Na were discovered in all materials, and Fe was only found in the CFB and CBF because of the addition of goethite. Five main chemical functional groups of N–H, O–H, C–H, C–O, and –COOH were found in all materials. The optimum conditions of the CB, CFB, and CBF for removing lead were 0.5 g, 16 h, pH 5, 0.5 g, 16 h, pH 5, and 0.4 g, 14 h, pH 5, respectively. The results of the batch experiments demonstrated that the CB, CFB, and CBF were high-efficiency adsorbents for removing lead in solution by more than 95%, whereby the CBF showed the highest lead removal of 99%. The Freundlich isotherm model and pseudo-second-order kinetic model helped to well explain their adsorption pattern and mechanism. The maximum lead adsorption capacities of the CB, CFB, and CBF were 322.58, 333.33, and 344.83 mg/g, respectively. Furthermore, all chitosan materials can be reused for more than three cycles with high lead removal by more than 94%; so, they are potential materials for application in industrial applications. Full article

The unique flash heating characteristics of intense pulsed ion beams (IPIB) offer potential advantages to fabricate high-performance coatings with non-equilibrium structures. In this study, titanium-chromium (Ti-Cr) alloy coatings are prepared through magnetron sputtering and successive IPIB irradiation, and the feasibility of IPIB melt mixing (IPIBMM) for a film-substrate system is verified via finite elements analysis. The experimental results reveal that the melting depth is 1.15 μm under IPIB irradiation, which is in close agreement with the calculation value (1.18 μm). The film and substrate form a Ti-Cr alloy coating by IPIBMM. The coating has a continuous gradient composition distribution, metallurgically bonding on the Ti substrate via IPIBMM. Increasing the IPIB pulse number leads to more complete element mixing and the elimination of surface cracks and craters. Additionally, the IPIB irradiation induces the formation of supersaturated solid solutions, lattice transition, and preferred orientation change, contributing to an increase in hardness and a decrease in elastic modulus with continuous irradiation. Notably, the coating treated with 20 pulses demonstrates a remarkable hardness (4.8 GPa), more than twice that of pure Ti, and a lower elastic modulus (100.3 GPa), 20% less than that of pure Ti. The analysis of the load-displacement curves and H-E ratios indicates that the Ti-Cr alloy coated samples exhibit better plasticity and wear resistance compared to pure Ti. Specifically, the coating formed after 20 pulses exhibits exceptional wear resistance, as demonstrated by its H³/E² value being 14 times higher than that of pure Ti. This development provides an efficient and eco-friendly method for designing robust-adhesion coatings with specific structures, which can be extended to various bi- or multi-element material systems. Full article

The reaction of the Ni/X interfaces (X = Si or Cr) with O₂⁺ ions at low energy (3 keV) was studied using X-ray photoelectron spectroscopy (XPS) and factor analysis (FA). It was found that low ion doses lead to the formation of a NiO thin film on the surface that was progressively transformed into a Ni-O-X mixed oxide with increasing the ion dose. The degree of transformation of NiO into Ni-O-X depended on the covalence of the X cation, indicating that the reaction was influenced by chemical driving forces. For strong covalent cations (Si and Al), NiO was completely transformed into Ni-O-X at ion doses above 1.8 × 10¹⁷ ions/cm², whereas for ionic cations (Cr) the transformation was incomplete. The ionicity of Ni atoms in the Ni-O-X mixed oxide increased with the increase in the covalence of X cation, and the features of the Ni 2p core level, characteristic of bulk NiO which were attributed to non-local screening, disappeared. Full article

The Ethiopian magic scrolls are traditional parchment artifacts used by the Christians of Ethiopia as protection against disease and demonic possessions. On the occasion of their restoration in the Accademia delle Belle Arti di Bologna (Italy); a preliminary characterization before the treatments has been performed on four Ethiopian scrolls belonging to the Archivio storico della provincia di Cristo Re dei Frati Minori dell’Emilia Romagna of Bologna (Italy). In order to plan an effective preservative restoration procedure and; at the same time; to investigate the manufacturing techniques; the text and the decorations on the magic scrolls were studied and characterized. A combined approach by imaging and compositional techniques was used: Infrared Reflectography (IRR) for the preliminary characterization of the graphic supports and the identification of the points to sample the chemical measurements; and the spectroscopic analyses to clarify the hypothesized investigations and confirm the chemical composition of the inks. In particular; Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy has provided information relating to the molecular composition of inks and pigments; while a characterization of the constituent elements is obtained with the Ion Beam Analysis (IBA). The ink composition proved to be consistent with data generally documented in the literature and contributing to the expansion of knowledge on Ethiopian magic scrolls and their production. Full article

In this work, we present a scheme of a two-photon interaction to calculate magic wavelengths for the 6${}^2$$S_{\frac{1}{2}}$ − 5${}^2$$D_{\frac{3}{2},\frac{5}{2}}$ clock transitions of Ba${}^{+}$ ion employing the relativistic coupled-cluster method. These magic wavelengths can be essential inputs to achieve better accuracy in the future ionic clock experiments. In this paper, we further show an application of a two-photon interaction to the spin-mixing processes, $|0,0⟩$↔$|+1,-1⟩$ and $|0,0⟩$↔$|-1,+1⟩$, of an ultra-cold spin-1 mixture of ${}^{137}$Ba${}^{+}$ ions and ${}^{87}$Rb atoms. We determine the protocols for selecting these spin-mixing oscillations by changing the strength and frequencies of the externally applied magnetic field and laser beams, respectively. Full article

Based on the latest design requirements proposed by the Beijing On-Line Isotope Separation (BISOL) project, a new ${\mathrm{Sn}}^{22+}$-based, 81.25 MHz CW radio frequency quadrupole (RFQ) with external bunching has been designed. This RFQ can accelerate ${\mathrm{Sn}}^{22+}$ to 0.5 MeV/u with an output longitudinal-normalized rms emittance of 0.20 keV/u·ns over a length of 5.6 m. The tolerance and error analysis results indicate that this RFQ can handle a wide range of non-ideal beams while maintaining relatively lower longitudinal emittance growth and higher transmission efficiency. To maintain the beam intensity, the RFQ will simultaneously accelerate three kinds of high-charge-state mixed ions (${}^{132}{\mathrm{Sn}}^{21+}$, ${}^{132}{\mathrm{Sn}}^{22+}$ and ${}^{132}{\mathrm{Sn}}^{23+}$), the simulation results given by Impact-T show that the RFQ can achieve high transmission of the mixed beam. Compared with the previous ${\mathrm{Sn}}^{21+}$-based internal bunching RFQ scheme, this RFQ has a shorter length and smaller output emittance, which is beneficial to the designs of subsequent Medium-energy Beam Transport (MEBT) and Drift Tube Linac (DTL). In electromagnetic design, a four-vane structure with 48 tuners and 16 $\pi$-mode stabilizers (PSLs) were chosen. The results of the multi-physics analysis show that the maximum temperature rise and the maximum deformation of the cavity are 13.6 K and 40.3 µm, respectively. The results simulated with CST Microwave Studio (CST) and HFSS software were consistent. Full article

The midrapidity transverse momentum distributions of the charged pions, kaons, protons, and antiprotons, measured by ALICE Collaboration at ten centrality classes of Pb + Pb collisions at $\sqrt{s_{nn}}$ = 5.02 TeV in the Large Hadron Collider (LHC, CERN, Switzerland), are successfully analyzed using combined minimum χ² fits with a thermodynamically non-consistent, as well as thermodynamically consistent, Tsallis function with transverse flow. The extracted non-extensivity parameter q decreases systematically for all considered particle species with increasing Pb + Pb collision centrality, suggesting an increase in the degree of system thermalization with an increase in collision centrality. The results for q suggest quite a large degree of thermalization of quark–gluon plasma (QGP) created in central Pb + Pb collisions at $\sqrt{s_{nn} }$= 5.02 TeV with the average number of participant nucleons $⟨N_{part}⟩$ > 160. The obtained significantly different growth rates of transverse flow velocity, $⟨{\beta }_T⟩$, in regions $⟨N_{part}⟩$ < 71 ± 7 and $⟨N_{part}⟩$ > 71 ± 7 with the temperature parameter T₀ remaining constant within uncertainties in region $⟨N_{part}⟩$ > 71 ± 7 probably indicates that $⟨N_{part}⟩$ ≈ 71 ± 7 (corresponding to $⟨d{N}_{ch}/d\eta ⟩$ ≈ 251 ± 20) is a threshold border value for a crossover transition from a dense hadronic state to the QGP phase (or mixed phase of QGP and hadrons) in Pb + Pb collisions at $\sqrt{s_{nn}}$ = 5.02 TeV. The threshold border value for transverse flow velocity $⟨{\beta }_T⟩$ ≈ 0.46 ± 0.03 (corresponding to $⟨N_{part}⟩$ ≈ 71 ± 7), estimated by us in Pb + Pb collisions at $\sqrt{s_{nn}}$ = 5.02 TeV, agrees well with the corresponding border value $⟨{\beta }_T⟩$ ≈ 0.44 ± 0.02, recently obtained in Xe + Xe collisions at $\sqrt{s_{nn} }$= 5.44 TeV, and with almost constant $⟨{\beta }_T⟩$ values extracted earlier in the Beam Energy Scan (BES) program of the Relativistic Heavy-Ion Collider (RHIC, Brookhaven, GA, USA) in central Au + Au collisions in the $\sqrt{s_{nn} }$= 7.7 − 39 GeV energy range, where the threshold for QGP production is achieved. The correlations between extracted T₀ and $⟨{\beta }_T⟩$ parameters are found to be greatly different in regions $⟨{\beta }_T⟩$ < 0.46 and $⟨{\beta }_T⟩$ > 0.46, which further supports our result obtained for the threshold border value in Pb + Pb collisions at $\sqrt{s_{nn}}$= 5.02 TeV. Full article

In this study, we present the results of the effect of duplex surface modification of 304-L stainless steel substrates by an electron-beam treatment (EBT) and subsequent deposition of diamond-like carbon coatings on the surface roughness and corrosion behavior. During the EBT process, the beam power was varied from 1000 to 1500 W. The successful deposition of the DLC coatings was confirmed by FTIR and Raman spectroscopy experiments. The results showed a presence of C–O, C=N, graphite-like sp², and mixed sp²-sp³ C–C bond vibrations. The surface topography was studied by atomic force microscopy. The rise in the beam power leads to a decrease in the surface roughness of the deposited DLC coatings. The studies on the corrosion resistance of the samples have been performed using three electrochemical techniques: open circuit potential (OCP), cyclic voltammetry (polarization measurements), and non-destructive electrochemical impedance spectroscopy (EIS). The measured corrosion potentials suggest that these samples are corrosion-resistant even in a medium, containing corrosive agents such as chloride ions. It can be concluded that the most corrosion-resistant specimen is DLC coating deposited on electron-beam-treated 304-L SS substrate by a beam power of 1500 W. Full article

This research investigates the flexural and durability performances of reinforced concrete (RC) beams made with induction furnace steel slag aggregate (IFSSA) as a replacement for fired clay brick aggregate (FCBA). To achieve this, 27 RC beams (length: 750 mm, width: 125 mm, height: 200 mm) were made with FCBA replaced by IFSSA at nine replacement levels of 0%, 10%, 20%, 30%, 40%, 50%, 60%, 80%, and 100% (by volume). Flexural tests of RC beams were conducted by a four-point loading test, where the deflection behavior of the beams was monitored through three linear variable displacement transducers (LVDT). The compressive strength and durability properties (i.e., porosity, resistance to chloride ion penetration, and capillary water absorption) were assessed using the same batch of concrete mix used to cast RC beams. The experimental results have shown that the flexural load of RC beams made with IFSSA was significantly higher than the control beam (100% FCBA). The increment of the flexural load was proportional to the content of IFSSA, with an increase of 27% for the beam made with 80% IFSSA than the control beam. The compressive strength of concrete increased by 56% and 61% for the concrete made with 80% and 100% IFSSA, respectively, than the control concrete, which is in good agreement with the flexural load of RC beams. Furthermore, the porosity, resistance to chloride ion penetration, and capillary water absorption were inversely proportional to the increase in the content of IFSSA. For instance, porosity, chloride penetration, and water absorption decreased by 43%, 54%, and 68%, respectively, when IFSSA entirely replaced FCBA. This decreasing percentage of durability properties is in agreement with the flexural load of RC beams. A good linear relationship of porosity with chloride penetration resistance and capillary water absorption was observed. Full article