Search Results (4)

To accommodate the extreme thermodynamic effects and erosion damage in throttling equipment for ultra-high-pressure natural gas wells (175 MPa), a coupled multiphase flow erosion numerical model for nozzles was established. This model incorporates a real gas compressibility factor correction and is based on the renormalized k-ε RNG (Renormalization Group k-epsilon model, a turbulence model that simulates the effects of vortices and rotation in the mean flow by modifying turbulent viscosity) turbulence model and the Discrete Phase Model (DPM, a multiphase flow model based on the Eulerian–Lagrangian framework). The study revealed that the nozzle flow characteristics follow an equal-percentage nonlinear regulation pattern. Choked flow occurs at the throttling orifice throat due to supersonic velocity (Ma ≈ 3.5), resulting in a mass flow rate governed solely by the upstream total pressure. The Joule–Thomson effect induces a drastic temperature drop of 273 K. The outlet temperature drops below the critical temperature for methane hydrate phase transition, thereby presenting a substantial risk of hydrate formation and ice blockage in the downstream outlet segment. Erosion analysis indicates that particles accumulate in the 180° backside region of the cage sleeve under the influence of secondary flow. At a 30% opening, micro-jet impact causes the maximum erosion rate to surge to 3.47 kg/(m²·s), while a minimum erosion rate is observed at a 50% opening. Across all opening levels, the maximum erosion rate consistently concentrates on the oblique section of the plunger front. Results demonstrate that removing the front chamfer of the plunger effectively improves the internal erosion profile. These findings provide a theoretical basis for the reliability design and risk prevention of surface equipment in deep ultra-high-pressure gas wells. Full article

The worldwide concern regarding the harmful effects of old polluting and toxic propellants has led to increased interest in new, green propellants and higher efficiency thrusters. This fact requires that a new generation of turbopumps, fit for these propellants, is developed. This paper focuses on the design of a radial inflow turbine, which was developed to power a single-shaft turbopump system for a 30 kN upper stage expander cycle thruster engine. The objective was to create a high-efficiency, compact, cheap-to-manufacture, 3D-printable turbine suitable to simultaneously power the methane and Oxygen pumps that feed the thruster. The total power consumed by the pumps for which this turbine was designed is 152 kW. The solution proposed in this paper includes measures such as elimination of the bladed diffuser, which was carried out to reduce the weight and the overall dimensions of the turbine. Comparing it with an axial turbine with the same power output, it has lower overall dimensions because it does not require a direction change at the inlet to the turbine bladed components, it does not require a stator to work, and its casing has a conical shape and is not cylindrical like the axial construction one. The proposed design has been analysed by CFD, which revealed that it can power the pumps. Analysis performed in off-design conditions indicated that the turbine has the best efficiency if the rotation speed and mass flow are varied at the same time. A breadboard model of the turbopump for which the turbine in this paper has been designed has been built using plastic and tested at pressures up to 6 bars using compressed air. The results indicate that above 1.5 bars of inlet pressure the turbine can overcome the internal resistances of the components and the rotor starts to spin. No indication of imbalance of the rotor was observed at maximum test pressure. Two configurations of the seals between the turbine and the adjacent pump have been tested, indicating that labyrinth seals must be doubled by floating ring seals. Full article

The concentration of low-concentration coalbed methane extracted from underground coal mine fluctuates greatly, which does not meet the requirements of intake concentration of coalbed-methane utilization devices. Due to this fluctuation, the coalbed-methane-utilization device cannot maintain stable and safe operation. The gas-mixing device is mainly used in coalbed-methane-utilization systems, providing each with a stable feed gas source with qualified concentration. In order to solve the problems of unsatisfactory uniformity of gas mixing and the large resistance of the existing coalbed-methane-mixing device, the mathematical model of the internal flow of the gas-mixing device is established. The influence of the internal structure of the gas-mixing device on the change in the uniformity of gas mixing and resistance loss is studied by numerical simulation and experiment. When the flow is 7000 Nm³/h, 50,000 Nm³/h and 160,000 Nm³/h, respectively, the spiral structure combination of L-N-R, N-L-R and L-N-R is optimal (L, R, N indicate left rotation, right rotation and without setting screw, respectively). There are some defects in the processing technology of the experimental device, which make the simulation and experimental data different. The numerical simulation of the gas-mixing process inside the unit can provide technical means for reducing resistance and improving the uniformity of gas mixing, and provide a stable gas source and safety measures for the coalbed-methane-utilization unit. Full article

A halogen-bonded complex formed between methane and chlorine monofluoride has been isolated in the gas phase before the reaction between the components and has been characterised through its rotational spectrum, which is of the symmetric-top type but only exhibits K = 0 type transitions at the low effective temperature of the pulsed-jet experiment. Spectroscopic constants for two low-lying states that result from internal rotation of the CH₄ subunit were detected for each of the two isotopic varieties H₄C···³⁵ClF and H₄C···³⁷ClF and were analysed to show that ClF lies on the symmetry axis with Cl located closer than F to the C atom, at the distance r₀(C···Cl) $\cong 3.28$ Å and with an intermolecular stretching force constant k_σ $\cong$ 4 N m⁻¹. Ab initio calculations at the explicitly correlated level CCSD(T)(F12c)/cc-pVTZ-F12 show that in the equilibrium geometry, the ClF molecule lies along a C₃ axis of CH₄ and Cl is involved in a halogen bond. The Cl atom points at the nucleophilic region identified on the C₃ axis, opposite the unique C–H bond and somewhere near the C atom and the tetrahedron face centre, with r_e(C···Cl) = 3.191 Å. Atoms-in-molecules (AIM) theory shows a bond critical point between Cl and C, confirming the presence of a halogen bond. The energy that is required to dissociate the complex from the equilibrium conformation into its CH₄ and ClF components is only D_e $\cong$ 5 kJ mol⁻¹. A likely path for the internal rotation of the CH₄ subunit is identified by calculations at the same level of theory, which also provide the variation of the energy of the system as a function of the motion along that path. The barrier to the motion along the path is only $\cong$ 20 cm⁻¹. Full article