Search Results (2,160)

The increasing global demand for clean energy highlights hydrogen as a strategic energy carrier due to its high energy density and carbon-free utilization. Currently, steam methane reforming (SMR) is the most widely applied method for hydrogen production; however, its high CO₂ emissions undermine the environmental benefits of hydrogen. Blue hydrogen production integrates carbon capture and storage (CCS) technologies to overcome this drawback in the SMR process, significantly reducing greenhouse gas emissions. This study integrated a MATLAB-R2025b-based plug flow reactor (PFR) model for SMR kinetics with an Aspen HYSYS-based CCS system. The effects of reformer temperature (600–1000 °C) and steam-to-carbon (S/C) ratio (1–5) on hydrogen yield and CO₂ emission intensity were investigated. Results show that hydrogen production increases with temperature, reaching maximum conversion at 850–1000 °C, while the optimum performance is achieved at S/C ratios of 2.5–3.0, balancing high hydrogen yield and minimized methane slip. Conventional SMR generates 9–12 kgCO₂/kgH₂ emissions, whereas SMR + CCS reduces this to 2–3 kgCO₂/kgH₂, achieving more than 75% reduction. The findings demonstrate that SMR + CCS integration effectively mitigates emissions and provides a sustainable bridging technology for blue hydrogen production, supporting the transition toward low-carbon energy systems. Full article

The article examines the use of hydrogen fuel as an alternative to traditional diesel fuel for internal combustion engines (ICE) in railway applications. The main objective of the study is to analyze the operational consumption of hydrogen fuel based on the mathematical modeling of the working cycle of the EMD 12-645E3C engine installed on CIE 071 locomotives used in freight and passenger service. The article provides information on the design features of the EMD 12-645E3C engine, its technical parameters, and the results of bench tests. The indicator parameters of the engine at various controller positions are determined and analyzed, and the results of mathematical modeling of its operation on hydrogen fuel are presented. Particular attention is paid to changes in indicator parameters, including the maximum combustion pressure and the peak gas temperature in the cylinder, as well as comparing the mass consumption of diesel and hydrogen fuel. The study results demonstrate that the use of hydrogen allows the engine to maintain effective power across all operational modes while simultaneously reducing energy costs up to 8%. In this case, the pressure and temperature of the gases in the cylinder increased by 3–6% and 5–8%. Recommendations are also provided regarding technical challenges associated with transitioning to hydrogen fuel, including the modernization of the combustion chamber, fuel system, and safety system. Full article

With the growing significance of hydrogen in the global energy transition, research on its pricing mechanisms has become increasingly crucial. Focusing on hydrogen markets predominantly supplied by electrolytic production, this study proposes a nodal marginal hydrogen price decomposition algorithm that explicitly incorporates the time-delay dynamics inherent in hydrogen transmission. A four-dimensional price formation framework is established, comprising the energy component, network loss component, congestion component, and time-delay component. To address the nonconvex optimization challenges arising in the market-clearing model, an improved second-order cone programming method is introduced. This method effectively reduces computational complexity through the reconstruction of time-coupled constraints and reformulation of the Weymouth equation. On this basis, the analytical expression of the nodal marginal hydrogen price is rigorously derived, elucidating how transmission dynamics influence each price component. Empirical studies using a modified Belgian 20-node system demonstrate that the proposed pricing mechanism dynamically adapts to load variations, with hydrogen prices exhibiting a strong correlation with electricity cost fluctuations. The results validate the efficacy and superiority of the proposed approach in hydrogen energy market applications. This study provides a theoretical foundation for designing efficient and transparent pricing mechanisms in emerging hydrogen markets. Full article

Modern ports are pivotal to global trade, facing increasing pressures from operational demands, resource optimization complexities, and urgent decarbonization needs. This study highlights the critical importance of digital model adoption within the maritime industry, particularly in the port sector, while integrating sustainability principles. Despite a growing body of research on digital models, industrial simulation, and green transition, a specific gap persists regarding the intersection of port management, hydrogen energy integration, and Digital Twin (DT) applications. Specifically, a bibliometric analysis provides an overview of the current research landscape through a study of the most used keywords, while the document analysis highlights three primary areas of advancement: optimization of hydrogen storage and integrated energy systems, hydrogen use in propulsion and auxiliary engines, and DT for management and validation in maritime operations. The main outcome of this research work is that while significant individual advancements have been made across critical domains such as optimizing hydrogen systems, enhancing engine performance, and developing robust DT applications for smart ports, a major challenge persists due to the limited simultaneous and integrated exploration of them. This gap notably limits the realization of their full combined benefits for green ports. By mapping current research and proposing interdisciplinary directions, this work contributes to the scientific debate on future port development, underscoring the need for integrated approaches that simultaneously address technological, environmental, and operational dimensions. Full article

The urgent global transition toward low-carbon energy systems has highlighted the need for systematic planning of hydrogen refueling stations (HRS) to facilitate clean energy adoption. This study develops an integrated framework for regional HRS layout optimization and carbon emission assessment, considering population distribution, land area, and hydrogen demand. Using Hainan Province as a case study, the model estimates regional hydrogen demand, determines optimal HRS deployment, evaluates spatial coverage and refueling distances, and quantifies potential carbon emission reductions under various renewable energy scenarios. Model validation with Haikou demonstrates its reliability and applicability at the regional scale. Results indicate pronounced spatial disparities in hydrogen demand and infrastructure requirements, emphasizing that prioritizing station deployment in densely populated urban areas can enhance accessibility and maximize emission reduction. The framework offers a practical, data-efficient tool for policymakers and planners to guide early-stage hydrogen infrastructure development and supports strategies for regional decarbonization and sustainable energy transitions. Full article

This report evaluates the role of Hybrid Renewable Energy Systems (HRESs) in supporting South Africa’s energy transition amidst persistent power shortages, coal dependency, and growing decarbonisation imperatives. Drawing on national policy frameworks including the Integrated Resource Plan (IRP 2019), the Just Energy Transition (JET) strategy, and Net Zero 2050 targets, this study analyses five major HRES configurations: PV–Battery, PV–Diesel–Battery, PV–Wind–Battery, PV–Hydrogen, and Multi-Source EMS. Through technical modelling, lifecycle cost estimation, and trade-off analysis, the report demonstrates how hybrid systems can decentralise energy supply, improve grid resilience, and align with socio-economic development goals. Geographic application, cost-performance metrics, and policy alignment are assessed to inform region-specific deployment strategies. Despite enabling technologies and proven field performance, the scale-up of HRESs is constrained by financial, regulatory, and institutional barriers. The report concludes with targeted policy recommendations to support inclusive and regionally adaptive HRES investment in South Africa. Full article

Polymers such as PLA, PLA reinforced with carbon fiber (PLA + CF), and PETG are widely employed in utensils, structural components, and biomedical device housings where load-bearing capability and chemical resistance are desirable. This is particularly relevant for reusable applications in which sterilization with hydrogen peroxide (HP) or ethylene oxide (EO) is often required. In this study, the impact of HP and EO sterilization processes on the mechanical, thermal, and structural properties of PLA, PLA + CF, and PETG was evaluated. The mechanical properties assessed included elongation at break, elastic modulus, and tensile strength after sterilization. The thermal properties examined comprised thermal stability and the coefficient of thermal expansion (CTE). Additionally, Fourier Transform Infrared Spectroscopy (FTIR) was performed to detect potential alterations in functional groups. For PLA, sterilization with HP and EO resulted in a 22% increase in ultimate tensile strength (UTS) and a 21% increase in elastic modulus, accompanied by a noticeable reduction in ductility and the appearance of more brittle fracture surfaces. PLA + CF exhibited greater stability under both sterilization methods due to the reinforcing effect of carbon fibers. In the case of PETG, tensile strength and stiffness remained stable; however, HP sterilization led to a remarkable increase in elongation at break (294%), whereas EO sterilization reduced it. Regarding thermal properties, glass transition temperature (Tg) showed variations: PLA presented either an increase or decrease in Tg depending on the sterilization treatment, PLA + CF displayed a Tg reduction after EO sterilization, while PETG exhibited a moderate Tg increase under HP sterilization. CTE decreased at lower temperatures but increased after EO treatment. FTIR analysis revealed only minor chemical modifications induced by sterilization. Overall, HP and EO sterilization can be safely applied to additively manufactured medical components based on these polymers, provided that the structures are not subjected to high mechanical loads and do not require strict dimensional tolerances. Full article

This study investigates the development of biodegradable, scented bio-composite filaments incorporating industrial residues, specifically spent coffee grounds (SCG) and lignin (LI), into a PLA matrix for FDM 3D printing. Two fragrance additives, essential oil (EO) and microencapsulated fragrance powder (FP), were introduced (3%) to enhance sensory properties. The research investigates the effects of filler content (5%, 10%, and 15%) and fragrance additives on the surface chemistry (FTIR), thermal stability (TGA and DSC), mechanical properties (Tensile, flexural and impact), microstructure, and dimensional stability (Water absorption test and thickness swelling). Incorporating industrial residues and additives into PLA reduced the thermal stability, the degradation temperature and the glass transition temperature but increased the residual mass and the crystallinity. The effect of lignin was more pronounced than that of SCG, significantly influencing these thermal properties. Increasing the filler content of spent coffee grounds and lignin also led to a progressive decrease in tensile, flexural, and impact strength due to poor interfacial adhesion and increased void formation. However, lignin-based biocomposites exhibited enhanced stiffness at lower concentrations (≤10%), while biocomposites containing 15% SCG doubled their elongation at break compared to pure PLA. Adding fragrance reduced the mechanical strength but improved ductility due to plasticizer-like interactions. Microstructural analysis revealed heterogeneity in the biocomposites’ fracture surface characterized by the presence of pores, filler agglomeration, and delamination, indicating uneven filler dispersion and limited interfacial adhesion, particularly at high filler concentrations. The water absorption and dimensional stability of 3D-printed biocomposites increased progressively with the addition of residues. The presence of essential oil slightly improved water resistance by forming hydrogen bonds that limited moisture absorption. This article adds significant value by extending the potential applications of biocomposites beyond conventional engineering uses, making them particularly suitable for the fashion and design sectors, where multi-sensory and sustainable materials are increasingly sought after. Full article

The Co(II) complex [CoCl₂(AImd)₂] (AImd = 1-allylimidazole) was reinvestigated using a combination of experimental and theoretical methods. The previously reported crystal structure was redetermined and Hirshfeld surface analysis and enrichment ratios were added showing that intermolecular H⋯Cl and π⋯π interactions are the primary forces in the crystal structure, while H⋯H interactions dominate the surface of the molecule, making it rather hydrophobic in keeping with a low solubility in water. A Quantum Theory of Atoms in Molecules (QTAIM)/Non-Covalent Interactions (NCI)-Reduced Density Gradient (RDG) analysis on a dimeric model showed that the energies V(r) of the classical H⋯Cl hydrogen bonds range from −3.64 kcal/mol to −0.75 kcal/mol and were augmented by hydrophobic H⋯C interactions of >1 kcal/mol. T-dependent magnetization measurements reveal paramagnetic behavior with an effective magnetic moment of µ_eff = 4.66(2) µ_B. UV-vis absorption spectra in solution showed intense absorptions peaking at 240 nm, corresponding to intraligand π→π* transitions within the 1-allylimidazole moiety and a structured absorption around 600 nm, which is attributed to the spin-allowed d→d transitions of the high-spin Co(II) d⁷ ion in a distorted tetrahedral geometry. Both assignments were confirmed through TD-DFT calculations on the electronic transitions and agree with the DFT-calculated compositions of the frontier molecular orbitals. Molecular docking to hypoxia-inducible factor-1 alpha (HIF-1α) gave a docking score of −5.48 kcal/mol and showed hydrophobic⋯hydrophobic π-stacking interactions with the Ile233, Leu243, Val338, and Leu262 residues. A higher docking score of −6.11 kcal/mol and predominant hydrophobic⋯hydrophobic interactions with Trp296, His279, and Ile281 were found for HIF-1 inhibiting factor (FIH-1). Full article

This study presents a molecular dynamics (MD) investigation of water evaporation in copper nanochannels, with a focus on accurately modeling copper–water interactions through forcefield calibration. The TIP4P/2005 water model was coupled with the Modified Embedded Atom Method (MEAM) for copper, and the oxygen–copper Lennard–Jones (LJ) parameters were systematically tuned to match experimentally reported water contact angles (WCAs) on Cu (111) surfaces. Contact angles were extracted from simulation trajectories using a robust five-step protocol involving 2D kernel density estimation, adaptive thresholding, circle fitting, and mean squared error (MSE) validation. The optimized forcefield demonstrated strong agreement with experimental WCA values (50.2°–82.3°), enabling predictive control of wetting behavior by varying ε in the range 0.20–0.28 kcal/mol. Using this validated parameterization, we explored nanoscale evaporation in copper channels under varying thermal loads (300–600 K). The results reveal a clear temperature-dependent transition from interfacial-layer evaporation to bulk-phase vaporization, with evaporation onset and rate governed by the interplay between copper–water adhesion and thermal disruption of hydrogen bonding. These findings provide atomistically resolved insights into wetting and evaporation in metallic nanochannels, offering a calibrated framework for simulating phase-change heat transfer in advanced thermal management systems. Full article

Driven by the global energy transition and the dual carbon goals, developing low-carbon and zero-carbon alternative fuels has become a core issue for sustainable development in the internal combustion engine sector. Ammonia is a promising zero-carbon fuel with broad application prospects. However, its inherent combustion characteristics, including slow flame propagation, high ignition energy, and narrow flammable range, limit its use in internal combustion engines, necessitating the addition of auxiliary fuels. To address this issue, this paper proposes a composite injection technology combining “ammonia duct injection + hydrogen cylinder direct injection.” This technology utilizes highly reactive hydrogen to promote ammonia combustion, compensating for ammonia’s shortcomings and enabling efficient and smooth engine operation. This study, based on bench testing, investigated the effects of hydrogen direct injection timing (180, 170, 160, 150, 140°, 130, 120 °CA BTDC), hydrogen direct injection pressure (4, 5, 6, 7, 8 MPa) on the combustion and emissions of the ammonia–hydrogen engine. Under hydrogen direct injection timing and hydrogen direct injection pressure conditions, the hydrogen mixture ratios are 10%, 20%, 30%, 40%, and 50%, respectively. Test results indicate that hydrogen injection timing that is too early or too late prevents the formation of an optimal hydrogen layered state within the cylinder, leading to prolonged flame development period and CA10-90. The peak HRR also exhibits a trend of first increasing and then decreasing as the hydrogen direct injection timing is delayed. Increasing the hydrogen direct injection pressure to 8 MPa enhances the initial kinetic energy of the hydrogen jet, intensifies the gas flow within the cylinder, and shortens the CA0-10 and CA10-90, respectively. Under five different hydrogen direct injection ratios, the CA10-90 is shortened by 9.71%, 11.44%, 13.29%, 9.09%, and 13.42%, respectively, improving the combustion stability of the ammonia–hydrogen engine. Full article

As a pivotal clean energy carrier for achieving carbon neutrality, green hydrogen technology has attracted growing global attention. This review systematically examines four mainstream water electrolysis technologies—alkaline electrolysis, proton exchange membrane electrolysis, solid oxide electrolysis, and anion exchange membrane electrolysis—analyzing their fundamental principles, material challenges, and development trends. It further classifies and compares power electronic converter topologies, including non-isolated and isolated DC–DC converters as well as AC–DC converter architectures, and summarizes advanced control strategies such as dynamic power regulation and fault-tolerant operation aimed at enhancing system efficiency and stability. A holistic “electrolyzer–power converter–control strategy” integration framework is proposed to provide tailored technological solutions for diverse application scenarios. Finally, the challenges and future prospects of green hydrogen across the energy, transportation, and industrial sectors are discussed, underscoring its potential to accelerate the global transition toward a sustainable, low-carbon energy system. Full article

Cryogenic industries handling liquid hydrogen and helium require rigorous safety verification. However, current standards (ASTM, ASME, ISO) are optimized for LNG at −163 °C and remain inadequate for extreme cryogenic conditions such as −253 °C. As the temperature decreases, materials experience ductile-to-brittle transition, raising the risk of sudden fracture in testing equipment. This study presents a fuzzy-integrated reliability framework that combines fault tree analysis (FTA) and Failure Modes, Effects, and Criticality Analysis (FMECA). The method converts qualitative expert judgments into quantitative risk indices for use in data-scarce conditions. When applied to a cryogenic impact testing apparatus, the framework produced a total failure probability of 1.52 × 10⁻³, about 7.5% lower than the deterministic FTA result (1.64 × 10⁻³). These results confirm the framework’s robustness and its potential use in cryogenic testing and hydrogen systems. Full article

Under the dual pressures of global climate change and energy structure transition, the offshore wind–solar–current energy coupling hydrogen production (OCWPHP) system has emerged as a promising integrated energy solution. However, its complex multi-energy structure and harsh marine environment introduce systemic risks that are challenging to assess comprehensively using traditional methods. To address this, we develop a novel risk assessment framework based on hesitant fuzzy sets (HFS), establishing a multidimensional risk criteria system covering economic, technical, social, political, and environmental aspects. A hybrid weighting method integrating AHP, entropy weighting, and consensus adjustment is proposed to determine expert weights while minimizing risk information loss. Two aggregation operators—AHFOWA and AHFOWG—are applied to enhance uncertainty modeling. A case study of an OCWPHP project in the East China Sea is conducted, with the overall risk level assessed as “Medium.” Comparative analysis with the classical Cumulative Prospect Theory (CPT) method shows that our approach yields a risk value of 0.4764, closely aligning with the CPT result of 0.4745, thereby confirming the feasibility and credibility of the proposed framework. This study provides both theoretical support and practical guidance for early-stage risk assessment of OCWPHP projects. Full article

Hydrogen propulsion technologies are emerging as a key enabler for decarbonizing the aviation sector, especially for regional commercial aircraft. The evolution of aircraft propulsion technologies in recent years raises the question of the feasibility of a hydrogen propulsion system for beyond regional aircraft. This paper presents a comprehensive review of hydrogen propulsion technologies, highlighting key advancements in component-level performance metrics. It further explores the technological transitions necessary to enable hydrogen-powered aircraft beyond the regional category. The feasibility assessment is based on key performance parameters, including power density, efficiency, emissions, and integration challenges, aligned with the targets set for 2035 and 2050. The adoption of hydrogen-electric powertrains for the efficient transition from KW to MW powertrains depends on transitions in fuel cell type, thermal management systems (TMS), lightweight electric machines and power electronics, and integrated cryogenic cooling architectures. While hydrogen combustion can leverage existing gas turbine architectures with relatively fewer integration challenges, it presents its technical hurdles, especially related to combustion dynamics, NOx emissions, and contrail formation. Advanced combustor designs, such as micromix, staged, and lean premixed systems, are being explored to mitigate these challenges. Finally, the integration of waste heat recovery technologies in the hydrogen propulsion system is discussed, demonstrating the potential to improve specific fuel consumption by up to 13%. Full article