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43 Results Found

  • Article
  • Open Access
18 Citations
4,213 Views
17 Pages

21 February 2021

Remote sensing of atmospheric hydrogen fluoride (HF) is challenging because it has weak absorption signatures in the atmosphere and is surrounded by strong absorption lines from interfering gases. In this study, we first present a multi-year time ser...

  • Article
  • Open Access
2 Citations
2,978 Views
17 Pages

28 February 2024

In order to investigate the impact of environmental temperature and atmospheric humidity on the leakage and diffusion of hydrogen fluoride (HF) gas, this study focused on the real scenario of an HF chemical industrial park. Based on the actual disper...

  • Article
  • Open Access
85 Citations
27,261 Views
17 Pages

Analysis of Li-Ion Battery Gases Vented in an Inert Atmosphere Thermal Test Chamber

  • David Sturk,
  • Lars Rosell,
  • Per Blomqvist and
  • Annika Ahlberg Tidblad

4 September 2019

One way to support the development of new safety practices in testing and field failure situations of electric vehicles and their lithium-ion (Li-ion) traction batteries is to conduct studies simulating plausible incident scenarios. This paper focuse...

  • Article
  • Open Access
3,638 Views
15 Pages

25 February 2025

With the rising adoption of electric vehicles (EVs), fire-related issues have garnered significant attention, prompting extensive research efforts. This study investigates the dispersion of toxic gases generated during EV fires in confined spaces, su...

  • Erratum
  • Open Access
1 Citations
1,862 Views
2 Pages

6 May 2021

The authors would like to make the following correction of Authorship, Author Contributions and Acknowledgment [...]

  • Article
  • Open Access
4 Citations
5,150 Views
12 Pages

We have investigated the bulk and surface properties of the group II metal fluorides CaF 2 , SrF 2 and BaF 2 using periodic density functional theory (DFT) calculations and surface thermodynamics. Our bulk results show that the...

  • Article
  • Open Access
8 Citations
9,122 Views
11 Pages

Micromanufacturing in Fused Silica via Femtosecond Laser Irradiation Followed by Gas-Phase Chemical Etching

  • Francesco Venturini,
  • Maurizio Sansotera,
  • Rebeca Martinez Vazquez,
  • Roberto Osellame,
  • Giulio Cerullo and
  • Walter Navarrini

28 September 2012

Femtosecond laser irradiation followed by chemical etching (FLICE) with hydrogen fluoride (HF) is an emerging technique for the fabrication of directly buried, three-dimensional microfluidic channels in silica. The procedure, as described in literatu...

  • Article
  • Open Access
2 Citations
2,961 Views
15 Pages

The Fate of Fluorine Post Per- and Polyfluoroalkyl Substances Destruction during the Thermal Treatment of Biosolids: A Thermodynamic Study

  • Savankumar Patel,
  • Pobitra Halder,
  • Ibrahim Gbolahan Hakeem,
  • Ekaterina Selezneva,
  • Manoj Kumar Jena,
  • Ganesh Veluswamy,
  • Nimesha Rathnayake,
  • Abhishek Sharma,
  • Anithadevi Kenday Sivaram and
  • Aravind Surapaneni
  • + 4 authors

15 July 2024

Per- and polyfluoroalkyl substances (PFAS) are a group of fluorinated synthetic chemicals that are highly recalcitrant, toxic, and bio-accumulative and have been detected in biosolids worldwide, posing potential risks to humans and the environment. R...

  • Article
  • Open Access
32 Citations
7,968 Views
15 Pages

Improving Corrosion Resistance and Biocompatibility of Magnesium Alloy by Sodium Hydroxide and Hydrofluoric Acid Treatments

  • Chang-Jiang Pan,
  • Li-Qun Pang,
  • Yu Hou,
  • Yue-Bin Lin,
  • Tao Gong,
  • Tao Liu,
  • Wei Ye and
  • Hong-Yan Ding

28 December 2016

Owing to excellent mechanical property and biodegradation, magnesium-based alloys have been widely investigated for temporary implants such as cardiovascular stent and bone graft; however, the fast biodegradation in physiological environment and the...

  • Article
  • Open Access
1 Citations
2,554 Views
11 Pages

Magnesium Oxide Production by Plasma Chemical Conversion from Fluorine-Containing Industrial Waste

  • Zhuldyz Sagdoldina,
  • Konstantin Shestakov,
  • Michael Yermolenko,
  • Manarbek Kylyshkanov,
  • Mikhail Podoinikov,
  • Bauyrzhan Rakhadilov and
  • Yedilzhan Kambarov

1 November 2022

This work discusses the possibility of decomposing magnesium fluoride by ionized water vapor to form solid magnesium oxide and hydrogen gas in the reaction: MgF2 + H2O → MgO + 2HF. The technology and individual apparatuses of the plasma-chemical...

  • Article
  • Open Access
8 Citations
3,509 Views
18 Pages

Experimental and Density Functional Theory Studies on 1,1,1,4,4,4-Hexafluoro-2-Butene Pyrolysis

  • Neng Tao,
  • Changcheng Liu,
  • Haoran Xing,
  • Song Lu,
  • Siuming Lo and
  • Heping Zhang

21 August 2020

A series of thermal decomposition experiments were conducted over a temperature range of 873–1073 K to evaluate the thermal stability of 1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzz(Z)) and the production of hydrogen fluoride (HF). According to...

  • Feature Paper
  • Article
  • Open Access
6 Citations
3,705 Views
11 Pages

Study on Hazardous Areas of Hydrogen Fluoride Diffusion Based on CFD Simulation

  • Siyan Chen,
  • Zhengqing Zhou,
  • Yong Ma,
  • Li Zhang,
  • Tianyi Wang,
  • Shihao Wang and
  • Yinghua Zhang

30 August 2021

Hydrogen fluoride (HF) is a typical dangerous gas in the fluorine chemical industry. Its leakage is one of the most common types of accidents in this industry, and it poses a serious threat to personnel safety and health, environmental sanitation, an...

  • Article
  • Open Access
18 Citations
4,178 Views
14 Pages

15 February 2022

To guarantee the security of new energy vehicles (NEV), which include energy storage devices such as batteries, a quartz crystal microbalance (QCM) sensor was designed to detect online the HF gas produced from the leakage of electrolyte in the power...

  • Article
  • Open Access
15 Citations
4,003 Views
9 Pages

Surface Properties and Biocompatibility of Anodized Titanium with a Potential Pretreatment for Biomedical Applications

  • Bai-Hung Huang,
  • Yi-Jung Lu,
  • Wen-Chien Lan,
  • Muhammad Ruslin,
  • Hung-Yang Lin,
  • Keng-Liang Ou,
  • Takashi Saito,
  • Hsin-Yu Tsai,
  • Chen-Han Lee and
  • Yung-Chieh Cho
  • + 3 authors

8 July 2021

The effects of anodized titanium (Ti) with a potential hydrogen fluoride (HF) acid pretreatment through cathodization on the formation of nano-porous Ti dioxide (TiO2) layer were characterized using field-emission scanning electron microscopy, grazin...

  • Communication
  • Open Access
2 Citations
2,526 Views
8 Pages

The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored...

  • Article
  • Open Access
1 Citations
1,265 Views
33 Pages

Carbonylation of Polyfluorinated Alkylbenzenes and Benzocycloalkenes at the Benzyl C-F and C-Cl Bonds Under the Action of CO/SbF5

  • Yaroslav V. Zonov,
  • Siqi Wang,
  • Vladislav V. Komarov,
  • Victor M. Karpov,
  • Dmitriy A. Parkhomenko and
  • Tatyana V. Mezhenkova

17 February 2025

The carbonylation at the benzyl C-Hal bonds (Hal = F, Cl) of a number of polyfluorinated alkylbenzenes and benzocycloalkenes using carbon monoxide in the presence of SbF5 is described. The reaction provided the corresponding α-arylcarboxylic ac...

  • Article
  • Open Access
2 Citations
2,001 Views
13 Pages

27 April 2024

Internal discharge and overheating faults in sulfur hexafluoride (SF6) gas-insulated electrical equipment will generate a series of characteristic gas products. Hydrogen fluoride (HF) is one of the main decomposition gases under discharge failure. Be...

  • Article
  • Open Access
2 Citations
1,824 Views
16 Pages

24 December 2024

Silicon tetrafluoride (SiF4), being a toxic gas, contains abundant fluorine and silicon resources. However, at present, the extraction of these resources from SiF4 remains a significant challenge for current technologies. Microwave plasma emerges as...

  • Article
  • Open Access
8 Citations
2,631 Views
10 Pages

Fabrication of a Promising Hierarchical Porous Surface on Titanium for Promoting Biocompatibility

  • Wen-Chien Lan,
  • Chia-Hsien Wang,
  • Bai-Hung Huang,
  • Yen-Chun Cho,
  • Takashi Saito,
  • Chien-Chia Huang and
  • Mao-Suan Huang

17 February 2020

The effects of the nano-titanium hydrides (nano-γ-TiH) phase on the formation of nanoporous Ti oxide layer by the potential approach (hydrogen fluoride (HF) pretreatment and sodium hydroxide (NaOH) anodization) were investigated using scanning...

  • Article
  • Open Access
1 Citations
2,178 Views
9 Pages

29 June 2024

Studies have shown that the incorporation of fluorine into materials can improve their properties, but C–F bonds are not readily formed in nature. Although some researchers have studied the reaction of fluorinating alkenes catalyzed by hyperval...

  • Article
  • Open Access
218 Views
15 Pages

24 November 2025

The fabrication of semiconductor devices with three-dimensional architectures imposes unprecedented demands on advanced plasma dry etching processes. These include the simultaneous requirements of high throughput, high material selectivity, and preci...

  • Article
  • Open Access
7 Citations
2,569 Views
17 Pages

8 November 2021

A multi-technique approach based on Knudsen effusion mass spectrometry, gas phase chromatography, mass spectrometry, NMR and IR spectroscopy, thermal analysis, and quantum-chemical calculations was used to study the evaporation of 1-butyl-3-methylimi...

  • Article
  • Open Access
107 Citations
27,952 Views
13 Pages

Safety issues concerning the use of large lithium-ion (Li-ion) batteries in electrified vehicles are discussed based on the abuse test results of Li-ion cells together with safety devices for cells. The presented abuse tests are: overcharge, short ci...

  • Article
  • Open Access
12 Citations
4,972 Views
14 Pages

Synthesis and Characterization of Barium Hexafluoridoosmates

  • Sergei I. Ivlev,
  • Antti J. Karttunen,
  • Magnus R. Buchner,
  • Matthias Conrad,
  • Roman V. Ostvald and
  • Florian Kraus

29 December 2017

Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2...

  • Article
  • Open Access
1 Citations
968 Views
17 Pages

Water–HCl Sequential Leaching of Waste Barrier Material from Aluminum Electrolysis Cell

  • Yujie Zhao,
  • Saiya Li,
  • Junfeng Cheng,
  • Yuting Chen,
  • Weiping Liu,
  • Wei Sun and
  • Shafiq Alam

11 April 2025

The Hall–Héroult aluminum production process generates lithium-rich waste barrier materials, which are challenging to process using conventional acid leaching due to the environmental risks posed by hydrofluoric acid (HF) emissions. This...

  • Article
  • Open Access
9 Citations
11,669 Views
11 Pages

8 February 2023

As semiconductor devices become miniaturized, the importance of the molecular-level understanding of the fabrication processes is growing. Titanium nitride (TiN) is an important material utilized in various architectural components of semiconductor d...

  • Article
  • Open Access
10 Citations
6,441 Views
16 Pages

Characterization of Lithium-Ion Battery Fire Emissions—Part 2: Particle Size Distributions and Emission Factors

  • Matthew Claassen,
  • Bjoern Bingham,
  • Judith C. Chow,
  • John G. Watson,
  • Pengbo Chu,
  • Yan Wang and
  • Xiaoliang Wang

16 October 2024

The lithium-ion battery (LIB) thermal runaway (TR) emits a wide size range of particles with diverse chemical compositions. When inhaled, these particles can cause serious adverse health effects. This study measured the size distributions of particle...

  • Article
  • Open Access
7 Citations
4,887 Views
13 Pages

The Adsorption Behavior of Moisture on Smelter Grade Alumina during Transportation and Storage—for Primary Aluminum Production

  • Youjian Yang,
  • Wenju Tao,
  • Weicheng Liu,
  • Xianwei Hu,
  • Zhaowen Wang,
  • Zhongning Shi and
  • Xin Shu

29 February 2020

Smelter grade alumina (SGA) plays multiple roles in the Hall–Héroult process for primary aluminum production. Given its very porous nature, one major role of SGA is to adsorb toxic hydrogen fluoride (HF) in the dry scrubber. However, als...

  • Article
  • Open Access
11 Citations
4,239 Views
12 Pages

Innovation Glass-Ceramic Spray Deposition Technology Improving the Adhesive Performance for Zirconium-Based Dental Restorations

  • Chien-Ming Kang,
  • Dan-Jae Lin,
  • Sheng-Wei Feng,
  • Cheng-Yuan Hung,
  • Shogo Iwaguro and
  • Tzu-Yu Peng

24 October 2022

Glass-ceramic spray deposition (GCSD) is a novel technique for coating lithium disilicate (LD) glass-ceramics onto zirconia through simple tempering steps. GCSD has been proven to improve the bonding of zirconia to resin cement, but the effect of etc...

  • Article
  • Open Access
22 Citations
10,917 Views
19 Pages

Lithium-ion batteries (LIBs) have been used as electrochemical energy storage devices in various fields, ranging from mobile phones to electric vehicles. LIBs are composed of a positive electrode, a negative electrode, an electrolyte, and a binder. A...

  • Article
  • Open Access
8 Citations
2,302 Views
23 Pages

26 December 2023

MXene, a two-dimensional (2D) nanomaterial with diverse applications, has gained significant attention due to its 2D lamellar structure, abundance of surface groups, and conductivity. Despite various established synthesis methods since its discovery...

  • Article
  • Open Access
28 Citations
11,725 Views
20 Pages

Self-Assembly of Chip-Size Components with Cavity Structures: High-Precision Alignment and Direct Bonding without Thermal Compression for Hetero Integration

  • Takafumi Fukushima,
  • Takayuki Konno,
  • Eiji Iwata,
  • Risato Kobayashi,
  • Toshiya Kojima,
  • Mariappan Murugesan,
  • Ji-Chel Bea,
  • Kang-Wook Lee,
  • Tetsu Tanaka and
  • Mitsumasa Koyanagi

18 February 2011

New surface mounting and packaging technologies, using self-assembly with chips having cavity structures, were investigated for three-dimensional (3D) and hetero integration of complementary metal-oxide semiconductors (CMOS) and microelectromechanica...

  • Article
  • Open Access
3 Citations
2,824 Views
14 Pages

Hydrofluoric acid (HF) is commonly used as an etchant for the pretreatment of dental computer-aided design/computer-aided manufacturing (CAD-CAM) materials, such as glass-ceramics and resin composites. Despite its effectiveness, the harmful and hazar...

  • Article
  • Open Access
14 Citations
5,307 Views
7 Pages

23 June 2018

Considering the isotropic release process of nanoelectromechanical systems (NEMSs), defining the active region of NEM memory switches is one of the most challenging process technologies for the implementation of monolithic-three-dimensional (M3D) CMO...

  • Review
  • Open Access
66 Citations
16,766 Views
73 Pages

Wearable Nano-Based Gas Sensors for Environmental Monitoring and Encountered Challenges in Optimization

  • Sara Hooshmand,
  • Panagiotis Kassanos,
  • Meysam Keshavarz,
  • Pelin Duru,
  • Cemre Irmak Kayalan,
  • İzzet Kale and
  • Mustafa Kemal Bayazit

23 October 2023

With a rising emphasis on public safety and quality of life, there is an urgent need to ensure optimal air quality, both indoors and outdoors. Detecting toxic gaseous compounds plays a pivotal role in shaping our sustainable future. This review aims...

  • Article
  • Open Access
7 Citations
3,480 Views
13 Pages

The increasing global market size of high-energy storage devices due to the boom in electric vehicles and portable electronics has caused the battery industry to produce a lot of waste lithium-ion batteries. The liberation and de-agglomeration of cat...

  • Article
  • Open Access
1 Citations
3,335 Views
12 Pages

HPLC-MS/MS Analysis for Sphingosine 1-Phosphate after the Dephosphorylation by Hydrogen Fluoride

  • Hee-Jung Kim,
  • Seo-Hyeon Jung,
  • Shokhid Gulyamov,
  • Hyun-Gy Lee,
  • Oybek Boyjigitov and
  • Yong-Moon Lee

Sphingosine 1-phosphate (S1P) is a signaling lipid molecule involved in various cellular processes. It is important to develop a quantitative method for S1P to determine endogenous levels and to investigate its functions. As S1P is a tiny lipid compo...

  • Article
  • Open Access
11 Citations
5,207 Views
26 Pages

Copper and its Isotopes in Organic-Rich Sediments: From the Modern Peru Margin to Archean Shales

  • Emily R. Ciscato,
  • Tomaso R. R. Bontognali,
  • Simon W. Poulton and
  • Derek Vance

The cycling of copper (Cu) and its isotopes in the modern ocean is controlled by the interplay of biology, redox settings, and organic complexation. To help build a robust understanding of Cu cycling in the modern ocean and investigate the potential...

  • Article
  • Open Access
48 Citations
10,251 Views
12 Pages

9 April 2018

The fabrication and testing of spiral microchannels with a trapezoidal cross section for the passive separation of microparticles is reported in this article. In contrast to previously reported fabrication methods, the fabrication of trapezoidal spir...

  • Article
  • Open Access
15 Citations
8,916 Views
16 Pages

The Major Storage Protein in Potato Tuber Is Mobilized by a Mechanism Dependent on Its Phosphorylation Status

  • Javier Bernal,
  • Daniel Mouzo,
  • María López-Pedrouso,
  • Daniel Franco,
  • Lucio García and
  • Carlos Zapata

The role of the protein phosphorylation mechanism in the mobilization of vegetative storage proteins (VSPs) is totally unknown. Patatin is the major VSP of the potato (Solanum tuberosum L.) tuber that encompasses multiple differentially phosphorylate...

  • Feature Paper
  • Article
  • Open Access
9 Citations
3,626 Views
12 Pages

Effects of Sulfuric Acid Treatment on the Performance of Ga-Al2O3 for the Hydrolytic Decomposition of 1,1,1,2-Tetrafluoroethane (HFC-134a)

  • Min-Jae Kim,
  • Yeonjin Kim,
  • Jae-Rang Youn,
  • Il-Ho Choi,
  • Kyung-Ran Hwang,
  • Seung Gon Kim,
  • Young-Kwon Park,
  • Seung-Hyun Moon,
  • Ki Bong Lee and
  • Sang Goo Jeon

9 July 2020

HFC-134a, one of the representative hydrofluorocarbons (HFCs) used as a coolant gas, is a known greenhouse gas with high global warming potential. Catalytic decomposition is considered a promising technology for the removal of fluorinated hydrocarbon...

  • Article
  • Open Access
8 Citations
3,319 Views
13 Pages

16 May 2023

This work demonstrates the corrosion behavior of the AZ31 Mg alloy as a function of an immersion time of 48 h in 0.1 M HCl, H2SO4, H3PO4 and HF solutions, in which pH was adjusted to 6 to exclude the contribution of hydrogen ions (H+) and hydroxide i...

  • Article
  • Open Access
82 Citations
4,477 Views
15 Pages

Impact of Lithium Salts on the Combustion Characteristics of Electrolyte under Diverse Pressures

  • Changcheng Liu,
  • Que Huang,
  • Kaihui Zheng,
  • Jiawen Qin,
  • Dechuang Zhou and
  • Jian Wang

15 October 2020

The electrolyte is one of the components that releases the most heat during the thermal runaway (TR) and combustion process of lithium-ion batteries (LIBs). Therefore, the thermal hazard of the electrolyte has a significant impact on the safety of LI...