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Search Results (1,005)

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Keywords = groundwater potential area

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20 pages, 3033 KiB  
Review
Recharge Sources and Flow Pathways of Karst Groundwater in the Yuquan Mountain Spring Catchment Area, Beijing: A Synthesis Based on Isotope, Tracers, and Geophysical Evidence
by Yuejia Sun, Liheng Wang, Qian Zhang and Yanhui Dong
Water 2025, 17(15), 2292; https://doi.org/10.3390/w17152292 - 1 Aug 2025
Viewed by 208
Abstract
Karst groundwater systems are critical to water supply and ecological sustainability in northern China, yet their heterogeneity poses challenges for flow characterization. The Yuquan Mountain (YM) Spring, historically a major karst spring in western Beijing, has experienced persistent drying, raising concerns about its [...] Read more.
Karst groundwater systems are critical to water supply and ecological sustainability in northern China, yet their heterogeneity poses challenges for flow characterization. The Yuquan Mountain (YM) Spring, historically a major karst spring in western Beijing, has experienced persistent drying, raising concerns about its recharge and flow mechanisms. This study integrates published isotope data, spatial distributions of Na+ and Cl as hydrochemical tracers, groundwater age estimates, and geophysical survey results to assess the recharge sources and flow pathways within the YM Spring catchment area. The analysis identifies two major recharge zones: the Tanzhesi area, primarily recharged by direct infiltration of precipitation through exposed carbonate rocks, and the Junzhuang area, which receives mixed recharge from rainfall and Yongding River seepage. Three potential flow pathways are proposed, including shallow flow along faults and strata, and a deeper, speculative route through the Jiulongshan-Xiangyu syncline. The synthesis of multiple lines of evidence leads to a refined conceptual model that illustrates how geological structures govern recharge, flow, and discharge processes in this karst system. These findings not only enhance the understanding of subsurface hydrodynamics in complex geological settings but also provide a scientific basis for future spring restoration planning and groundwater management strategies in the regions. Full article
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30 pages, 4804 KiB  
Article
Deep Storage Irrigation Enhances Grain Yield of Winter Wheat by Improving Plant Growth and Grain-Filling Process in Northwest China
by Xiaodong Fan, Dianyu Chen, Haitao Che, Yakun Wang, Yadan Du and Xiaotao Hu
Agronomy 2025, 15(8), 1852; https://doi.org/10.3390/agronomy15081852 - 31 Jul 2025
Viewed by 237
Abstract
In the irrigation districts of Northern China, the flood resources utilization for deep storage irrigation, which is essentially characterized by active excessive irrigation, aims to have the potential to mitigate freshwater shortages, and long-term groundwater overexploitation. It is crucial to detect the effects [...] Read more.
In the irrigation districts of Northern China, the flood resources utilization for deep storage irrigation, which is essentially characterized by active excessive irrigation, aims to have the potential to mitigate freshwater shortages, and long-term groundwater overexploitation. It is crucial to detect the effects of irrigation amounts on agricultural yield and the mechanisms under deep storage irrigation. A three-year field experiment (2020–2023) was conducted in the Guanzhong Plain, according to five soil wetting layer depths (RF: 0 cm; W1: control, 120 cm; W2: 140 cm; W3: 160 cm; W4: 180 cm) with soil saturation water content as the irrigation upper limit. Results exhibited that, compared to W1, the W2, W3, and W4 treatments led to the increased plant height, leaf area index, and dry matter accumulation. Meanwhile, the W2, W3, and W4 treatments improved kernel weight increment achieving maximum grain-filling rate (Wmax), maximum grain-filling rate (Gmax), and average grain-filling rate (Gave), thereby enhancing the effective spikes (ES) and grain number per spike (GS), and thus increased wheat grain yield (GY). In relative to W1, the W2, W3, and W4 treatments increased the ES, GS, and GY by 11.89–19.81%, 8.61–14.36%, and 8.17–13.62% across the three years. Notably, no significant difference was observed in GS and GY between W3 and W4 treatments, but W4 treatment displayed significant decreases in ES by 3.04%, 3.06%, and 2.98% in the respective years. The application of a structural equation modeling (SEM) revealed that deep storage irrigation improved ES and GS by positively regulating Wmax, Gmax, and Gave, thus significantly increasing GY. Overall, this study identified the optimal threshold (W3 treatment) to maximize wheat yields by optimizing both the vegetative growth and grain-filling dynamics. This study provides essential support for the feasibility assessment of deep storage irrigation before flood seasons, which is vital for the balance and coordination of food security and water security. Full article
(This article belongs to the Section Water Use and Irrigation)
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24 pages, 20005 KiB  
Article
Zoning Method for Groundwater Pollution Risk Control in Typical Industrial–Urban Integration Areas in the Middle Reaches of the Yangtze River
by Xiongbiao Qiao, Tianwei Cheng, Liming Zhang, Ning Sun, Zhenyu Ding, Zheming Shi, Guangcai Wang and Zongwen Zhang
Water 2025, 17(15), 2249; https://doi.org/10.3390/w17152249 - 28 Jul 2025
Viewed by 378
Abstract
With increasing urban economic development, some industrial parks and residential areas are being situated adjacent to each other, creating a potential risk of soil and groundwater contamination from the wastewater and solid waste produced by enterprises. This contamination poses a threat to the [...] Read more.
With increasing urban economic development, some industrial parks and residential areas are being situated adjacent to each other, creating a potential risk of soil and groundwater contamination from the wastewater and solid waste produced by enterprises. This contamination poses a threat to the health of nearby residents. Currently, groundwater pollution prevention and control zoning in China primarily targets groundwater environmental pollution risks and does not consider the health risks associated with groundwater exposure in industry–city integration areas. Therefore, a scientific assessment of environmental risks in industry–city integration areas is essential for effectively managing groundwater pollution. This study focuses on the high frequency and rapid pace of human activities in industry–city integration areas. It combines health risk assessment and groundwater pollution simulation results with traditional groundwater pollution control classification outcomes to develop a groundwater pollution risk zoning framework specifically suited to these integrated areas. Using this framework, we systematically assessed groundwater pollution risks in a representative industry–city integration area in the middle reaches of the Yangtze River in China and delineated groundwater pollution risk zones to provide a scientific basis for local groundwater environmental management. The assessment results indicate that the total area of groundwater pollution risk control zones is 30.37 km2, accounting for 19.06% of the total study area. The first-level control zone covers 5.38 km2 (3.38% of the total area), while the secondary control zone spans 24.99 km2 (15.68% of the total area). The first-level control zone is concentrated within industrial clusters, whereas the secondary control zone is widely distributed throughout the region. In comparison to traditional assessment methods, the zoning results derived from this study are more suitable for industry–city integration areas. This study also provides groundwater management recommendations for such areas, offering valuable insights for groundwater control in integrated industrial–residential zones. Full article
(This article belongs to the Topic Advances in Groundwater Science and Engineering)
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25 pages, 20396 KiB  
Article
Constructing Ecological Security Patterns in Coal Mining Subsidence Areas with High Groundwater Levels Based on Scenario Simulation
by Shiyuan Zhou, Zishuo Zhang, Pingjia Luo, Qinghe Hou and Xiaoqi Sun
Land 2025, 14(8), 1539; https://doi.org/10.3390/land14081539 - 27 Jul 2025
Viewed by 305
Abstract
In mining areas with high groundwater levels, intensive coal mining has led to the accumulation of substantial surface water and significant alterations in regional landscape patterns. Reconstructing the ecological security pattern (ESP) has emerged as a critical focus for ecological restoration in coal [...] Read more.
In mining areas with high groundwater levels, intensive coal mining has led to the accumulation of substantial surface water and significant alterations in regional landscape patterns. Reconstructing the ecological security pattern (ESP) has emerged as a critical focus for ecological restoration in coal mining subsidence areas with high groundwater levels. This study employed the patch-generating land use simulation (PLUS) model to predict the landscape evolution trend of the study area in 2032 under three scenarios, combining environmental characteristics and disturbance features of coal mining subsidence areas with high groundwater levels. In order to determine the differences in ecological network changes within the study area under various development scenarios, morphological spatial pattern analysis (MSPA) and landscape connectivity analysis were employed to identify ecological source areas and establish ecological corridors using circuit theory. Based on the simulation results of the optimal development scenario, potential ecological pinch points and ecological barrier points were further identified. The findings indicate that: (1) land use changes predominantly occur in urban fringe areas and coal mining subsidence areas. In the land reclamation (LR) scenario, the reduction in cultivated land area is minimal, whereas in the economic development (ED) scenario, construction land exhibits a marked increasing trend. Under the natural development (ND) scenario, forest land and water expand most significantly, thereby maximizing ecological space. (2) Under the ND scenario, the number and distribution of ecological source areas and ecological corridors reach their peak, leading to an enhanced ecological network structure that positively contributes to corridor improvement. (3) By comparing the ESP in the ND scenario in 2032 with that in 2022, the number and area of ecological barrier points increase substantially while the number and area of ecological pinch points decrease. These areas should be prioritized for ecological protection and restoration. Based on the scenario simulation results, this study proposes a planning objective for a “one axis, four belts, and four zones” ESP, along with corresponding strategies for ecological protection and restoration. This research provides a crucial foundation for decision-making in enhancing territorial space planning in coal mining subsidence areas with high groundwater levels. Full article
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1 pages, 120 KiB  
Correction
Correction: Mostafa et al. Groundwater Potential Mapping in Semi-Arid Areas Using Integrated Remote Sensing, GIS, and Geostatistics Techniques. Water 2025, 17, 1909
by Ahmed El-sayed Mostafa, Mahrous A. M. Ali, Faissal A. Ali, Ragab Rabeiy, Hussein A. Saleem, Mosaad Ali Hussein Ali and Ali Shebl
Water 2025, 17(15), 2206; https://doi.org/10.3390/w17152206 - 24 Jul 2025
Viewed by 327
Abstract
In the original publication [...] Full article
31 pages, 7304 KiB  
Article
Integrating Groundwater Modelling for Optimized Managed Aquifer Recharge Strategies
by Ghulam Zakir-Hassan, Jehangir F. Punthakey, Catherine Allan and Lee Baumgartner
Water 2025, 17(14), 2159; https://doi.org/10.3390/w17142159 - 20 Jul 2025
Viewed by 479
Abstract
Managed aquifer recharge (MAR) is a complex and hidden process of storing surplus water under the ground surface and extracting it as, when and where needed. Evaluation of the success of any MAR project is challenging due to uncertainty in estimating the hydrogeological [...] Read more.
Managed aquifer recharge (MAR) is a complex and hidden process of storing surplus water under the ground surface and extracting it as, when and where needed. Evaluation of the success of any MAR project is challenging due to uncertainty in estimating the hydrogeological characteristics of the subsurface media. This paper demonstrates the use of a groundwater model (MODFLOW) to evaluate a new, large-scale regional MAR project in the agricultural heartland in Punjab, Pakistan. In this MAR project, flood waters have been diverted to the bed of an abandoned canal, where 144 recharge wells (the wells for accelerating the recharge into the aquifer) have been constructed to accelerate the recharge to the aquifer. The model was calibrated for a period of five years from October 2015 to June 2020 on a monthly stress period and the resulting water levels were simulated till 2035. The water balance components and future response of the aquifer to different scenarios up to 2035 including with and without MAR situations are presented. The model simulations showed that MAR can contribute to the replenishment of the aquifer and its potential for the case study site to contribute significantly to the management of groundwater and to enhance supplies for intensive agriculture. It was further established that MODFLOW can help in the evaluation of effectiveness of a MAR scheme. This study is unique as it evaluates a significantly large MAR project in an area where this practice has not been developed for improving groundwater access for large scale irrigation. The model provides guidelines for decision makers in the region as well as for the global community and livelihood benefits for rural communities. Full article
(This article belongs to the Special Issue Advances in Surface Water and Groundwater Simulation in River Basin)
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24 pages, 5725 KiB  
Article
Modeling of Hydrological Processes in a Coal Mining Subsidence Area with High Groundwater Levels Based on Scenario Simulations
by Shiyuan Zhou, Hao Chen, Qinghe Hou, Haodong Liu and Pingjia Luo
Hydrology 2025, 12(7), 193; https://doi.org/10.3390/hydrology12070193 - 19 Jul 2025
Viewed by 362
Abstract
The Eastern Huang–Huai region of China is a representative mining area with a high groundwater level. High-intensity underground mining activities have not only induced land cover and land use changes (LUCC) but also significantly changed the watershed hydrological behavior. This study integrated the [...] Read more.
The Eastern Huang–Huai region of China is a representative mining area with a high groundwater level. High-intensity underground mining activities have not only induced land cover and land use changes (LUCC) but also significantly changed the watershed hydrological behavior. This study integrated the land use prediction model PLUS and the hydrological simulation model MIKE 21. Taking the Bahe River Watershed in Huaibei City, China, as an example, it simulated the hydrological response trends of the watershed in 2037 under different land use scenarios. The results demonstrate the following: (1) The land use predictions for each scenario exhibit significant variation. In the maximum subsidence scenario, the expansion of water areas is most pronounced. In the planning scenario, the increase in construction land is notable. Across all scenarios, the area of cultivated land decreases. (2) In the maximum subsidence scenario, the area of high-intensity waterlogging is the greatest, accounting for 31.35% of the total area of the watershed; in the planning scenario, the proportion of high-intensity waterlogged is the least, at 19.10%. (3) In the maximum subsidence scenario, owing to the water storage effect of the subsidence depression, the flood peak is conspicuously delayed and attains the maximum value of 192.3 m3/s. In the planning scenario, the land reclamation rate and ecological restoration rate of subsidence area are the highest, while the regional water storage capacity is the lowest. As a result, the total cumulative runoff is the greatest, and the peak flood value is reduced. The influence of different degrees of subsidence on the watershed hydrological behavior varies, and the coal mining subsidence area has the potential to regulate and store runoff and perform hydrological regulation. The results reveal the mechanism through which different land use scenarios influence hydrological processes, which provides a scientific basis for the territorial space planning and sustainable development of coal mining subsidence areas. Full article
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22 pages, 7529 KiB  
Article
Analysis of Human Health Risk Related to the Exposure of Arsenic Concentrations and Temporal Variation in Groundwater of a Semi-Arid Region in Mexico
by Jennifer Ortiz Letechipia, Miguel Eduardo Pinedo Vega, Julián González Trinidad, Hugo Enrique Júnez-Ferreira, Ana Isabel Veyna Gómez, Ada Rebeca Contreras Rodríguez, Cruz Octavio Robles Rovelo and Sandra Dávila Hernández
Water 2025, 17(14), 2143; https://doi.org/10.3390/w17142143 - 18 Jul 2025
Viewed by 266
Abstract
This study evaluates the human health risks associated with exposure to arsenic in groundwater from a semi-arid region of Mexico, focusing on concentration levels and their temporal variation. Arsenic concentrations were analyzed using ordinary kriging for spatial interpolation, along with descriptive and inferential [...] Read more.
This study evaluates the human health risks associated with exposure to arsenic in groundwater from a semi-arid region of Mexico, focusing on concentration levels and their temporal variation. Arsenic concentrations were analyzed using ordinary kriging for spatial interpolation, along with descriptive and inferential statistical methods. Human health risk was assessed through the following two key indicators: the Hazard Quotient (HQ), which estimates non-carcinogenic risk by comparing exposure levels to reference doses and carcinogenic risk (CR), which represents the estimated lifetime probability of developing cancer due to arsenic exposure. The mean arsenic concentration across both study years was 0.0200 mg/L, with median values of 0.0151 mg/L in 2015 and 0.0200 mg/L in 2020. The average HQ was 2.13 in 2015 and 2.17 in 2020, both exceeding the safety threshold of one. Mean CR values were 0.00096 and 0.00097 for 2015 and 2020, respectively, with a consistent median of 0.00072 across both years. A t-test was applied to compare the distributions between years. Both HQ and CR values significantly exceeded the recommended safety limits (p < 0.05), indicating that groundwater in the study area poses a potential carcinogenic and non-carcinogenic health risk. These findings underscore the urgent need for water quality monitoring and the implementation of mitigation measures to safeguard public health in the region. Full article
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13 pages, 793 KiB  
Article
Environmental Risk and Management of Iron Tailings in Road Subgrade
by Xiaowei Xu, Dapeng Zhang, Jie Cao, Chaoyue Wu, Yi Wang, Jing Hua, Zehua Zhao, Jun Zhang and Qi Yu
Toxics 2025, 13(7), 603; https://doi.org/10.3390/toxics13070603 - 17 Jul 2025
Viewed by 266
Abstract
The utilization of iron tailings in road construction poses significant environmental risks due to the complex release mechanisms of pollutants and varying regional conditions. This study integrates an exponential decay model with an instantaneous pollutant transport model, employing Monte Carlo simulations to assess [...] Read more.
The utilization of iron tailings in road construction poses significant environmental risks due to the complex release mechanisms of pollutants and varying regional conditions. This study integrates an exponential decay model with an instantaneous pollutant transport model, employing Monte Carlo simulations to assess risks and regional characteristics. Results show high Potential Hazard Indices (PHIs) for arsenic, manganese, barium, nickel, and lead, with PHI values between 4.2 and 22.7. Simulations indicate that manganese and nickel concentrations may exceed groundwater standards, particularly in humid areas. The study recommends controlling the iron tailings mixing ratio based on climate, suggesting limits of 35% in humid, 60% in semi-humid, and more lenient ratios in arid and semi-arid regions. It also underscores the need for improved risk assessment methodologies and region-specific management strategies at the national level. Full article
(This article belongs to the Special Issue Soil Heavy Metal Pollution and Human Health)
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16 pages, 3372 KiB  
Article
Monitoring the Time-Lagged Response of Land Subsidence to Groundwater Fluctuations via InSAR and Distributed Fiber-Optic Strain Sensing
by Qing He, Hehe Liu, Lu Wei, Jing Ding, Heling Sun and Zhen Zhang
Appl. Sci. 2025, 15(14), 7991; https://doi.org/10.3390/app15147991 - 17 Jul 2025
Viewed by 302
Abstract
Understanding the time-lagged response of land subsidence to groundwater level fluctuations and subsurface strain variations is crucial for uncovering its underlying mechanisms and enhancing disaster early warning capabilities. This study focuses on Dangshan County, Anhui Province, China, and systematically analyzes the spatio-temporal evolution [...] Read more.
Understanding the time-lagged response of land subsidence to groundwater level fluctuations and subsurface strain variations is crucial for uncovering its underlying mechanisms and enhancing disaster early warning capabilities. This study focuses on Dangshan County, Anhui Province, China, and systematically analyzes the spatio-temporal evolution of land subsidence from 2018 to 2024. A total of 207 Sentinel-1 SAR images were first processed using the Small Baseline Subset Interferometric Synthetic Aperture Radar (SBAS-InSAR) technique to generate high-resolution surface deformation time series. Subsequently, the seasonal-trend decomposition using the LOESS (STL) model was applied to extract annual cyclic deformation components from the InSAR-derived time series. To quantitatively assess the delayed response of land subsidence to groundwater level changes and subsurface strain evolution, time-lagged cross-correlation (TLCC) analysis was performed between surface deformation and both groundwater level data and distributed fiber-optic strain measurements within the 5–50 m depth interval. The strain data was collected using a borehole-based automated distributed fiber-optic sensing system. The results indicate that land subsidence is primarily concentrated in the urban core, with annual cyclic amplitudes ranging from 10 to 18 mm and peak values reaching 22 mm. The timing of surface rebound shows spatial variability, typically occurring in mid-February in residential areas and mid-May in agricultural zones. The analysis reveals that surface deformation lags behind groundwater fluctuations by approximately 2 to 3 months, depending on local hydrogeological conditions, while subsurface strain changes generally lead surface subsidence by about 3 months. These findings demonstrate the strong predictive potential of distributed fiber-optic sensing in capturing precursory deformation signals and underscore the importance of integrating InSAR, hydrological, and geotechnical data for advancing the understanding of subsidence mechanisms and improving monitoring and mitigation efforts. Full article
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16 pages, 3973 KiB  
Article
Toxicological Risk Assessment and Source Identification of Groundwater Pollution: A Case of Sheep Herd Damage in a Pastoral Area
by Wei Wang, Honger Cheng, Yuewei Yang, Jianjun Su, Jialu Sun, Xiaojing Li and Qian Zhao
Environments 2025, 12(7), 240; https://doi.org/10.3390/environments12070240 - 14 Jul 2025
Viewed by 505
Abstract
Improper emissions from industrial activities pose toxicological risks to groundwater safety. Based on an environmental forensic identification case involving livestock (sheep) damage caused by groundwater pollution in a pastoral area, we comprehensively evaluated groundwater quality risks, toxicological risks, and pollution sources using multivariate [...] Read more.
Improper emissions from industrial activities pose toxicological risks to groundwater safety. Based on an environmental forensic identification case involving livestock (sheep) damage caused by groundwater pollution in a pastoral area, we comprehensively evaluated groundwater quality risks, toxicological risks, and pollution sources using multivariate statistical methods, the Nemerow index method, and a non-carcinogenic health risk model. The potential specific pollutants in the region mainly included calcium, potassium, sodium, magnesium, manganese, fluoride, chloride, sulfate, ammonia nitrogen, total dissolved solids, and nitrate. An evaluation of the groundwater health risk factors showed that fluoride, nitrate, and manganese pose higher health risks (HQ > 1), as fluoride > nitrate > manganese. This suggests that these three pollutants were the primary causes of livestock damage. Identification of pollution sources using multivariate statistical analysis revealed that the main pollutants in the groundwater originate from two rare earth enterprises in the surrounding industrial park, followed by the emissions from animal husbandry. This study provides guidelines into comprehensive regional toxicological risk assessment and source tracing, offering an identification method for similar forensic environmental damage cases. Full article
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22 pages, 828 KiB  
Review
Agricultural Irrigation Using Treated Wastewater: Challenges and Opportunities
by Christian C. Obijianya, Elif Yakamercan, Mahmoud Karimi, Sridevi Veluru, Ivan Simko, Sulaymon Eshkabilov and Halis Simsek
Water 2025, 17(14), 2083; https://doi.org/10.3390/w17142083 - 11 Jul 2025
Viewed by 592
Abstract
Reusing and recycling treated wastewater is a sustainable approach to meet the growing demand for clean water, ensuring its availability for both current and future generations. Wastewater can be treated in such advanced ways that it can be used for industrial operations, recharging [...] Read more.
Reusing and recycling treated wastewater is a sustainable approach to meet the growing demand for clean water, ensuring its availability for both current and future generations. Wastewater can be treated in such advanced ways that it can be used for industrial operations, recharging groundwater, irrigation of fields, or even manufacturing drinkable water. This strategy meets growing water demand in water-scarce areas while protecting natural ecosystems. Treated wastewater is both a resource and a challenge. Though it may be nutrient-rich and can increase agricultural output while showing resource reuse and environmental conservation, high treatment costs, public acceptance, and contamination hazards limit its use. Proper treatment can reduce these hazards, safeguarding human health and the environment while enhancing its benefits, including a stable water supply, nutrient-rich irrigation, higher crop yields, economic development, and community resilience. On the one hand, inadequate treatment may lead to soil salinization, environmental degradation, and hazardous foods. Examining the dual benefits and risks of using treated wastewater for agricultural irrigation, this paper investigates the complexities of its use as a valuable resource and as a potential hazard. Modern treatment technologies are needed to address these difficulties and to ensure safe and sustainable use. If properly handled, treated wastewater reuse has enormous potential for reducing water scarcity and expanding sustainable agriculture as well as global food security. Full article
(This article belongs to the Section Soil and Water)
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27 pages, 2740 KiB  
Article
GIS-Based Spatial Autocorrelation and Multivariate Statistics for Understanding Groundwater Uranium Contamination and Associated Health Risk in Semiarid Region of Punjab, India
by Umakant Chaudhari, Disha Kumari, Sunil Mittal and Prafulla Kumar Sahoo
Water 2025, 17(14), 2064; https://doi.org/10.3390/w17142064 - 10 Jul 2025
Viewed by 374
Abstract
To provide safe drinking water in contaminated hydrogeological environments, it is essential to have precise geochemical information on contamination hotspots. In this study, Geographic Information System (GIS) and multivariate statistics were utilized to analyze the spatial patterns, occurrence, and major factors controlling uranium [...] Read more.
To provide safe drinking water in contaminated hydrogeological environments, it is essential to have precise geochemical information on contamination hotspots. In this study, Geographic Information System (GIS) and multivariate statistics were utilized to analyze the spatial patterns, occurrence, and major factors controlling uranium (U) concentrations in groundwater. The global and local Moran’s I indices were utilized to detect hotspots and cool spots of U distribution. The substantial positive global Moran’s I index (at a p-value of 0.05) revealed a geographical pattern in U occurrences. The spatial clusters displayed patterns of drinking water source with U concentrations below and above the WHO limit, categorized as “regional U cool spots” and “regional U hotspots”, respectively. Spatial autocorrelation plots revealed that the high–high potential spatial patterns for U were situated in the northeastern region of the study area. As the order of queen’s contiguity increased, prospective low–high spatial patterns transitioned from the Faridkot district to the Muktsar district for U. Further, the multivariate statistical analysis methods such as correlation and principal component analysis (PCA) plots revealed substantial positive associations (p-value < 0.05) between U and total dissolved solids (TDS), salinity (SL), bicarbonate (HCO3), and sodium (Na) in groundwater from both shallow and deeper depth, indicating that these water quality parameters can significantly influence the occurrence of U in the groundwater. The output of the random forest model shows that among the groundwater parameters, TDS is the most influential variable for enrichment of U in groundwater, followed by HCO3, Na, F, SO42−, Mg, Cl, pH, NO3, and K concentrations. Additionally, the results of health risk assessment indicate that 47.86% and 41.3% of samples pose risks to children and adults, respectively, due to F−contamination. About 93.49% and 89.14% of samples pose a risk to children and adults, respectively, due to U contamination, whereas 51.08% and 39.13% of samples pose a risk to children and adults, respectively, from NO3 contamination. The current data indicates an urgent need to create cost-effective and efficient remediation techniques for groundwater contamination in this region. Full article
(This article belongs to the Special Issue Environmental Fate and Transport of Organic Pollutants in Water)
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20 pages, 4992 KiB  
Article
Spatial Heterogeneity and Controlling Factors of Heavy Metals in Groundwater in a Typical Industrial Area in Southern China
by Jiaxu Du, Fu Liao, Ziwen Zhang, Aoao Du and Jiale Qian
Water 2025, 17(13), 2012; https://doi.org/10.3390/w17132012 - 4 Jul 2025
Viewed by 573
Abstract
Heavy metal contamination in groundwater has emerged as a significant environmental issue, driven by rapid industrialization and intensified human activities, particularly in southern China. Heavy metal pollution in groundwater often presents complex spatial patterns and multiple sources; understanding the spatial heterogeneity and controlling [...] Read more.
Heavy metal contamination in groundwater has emerged as a significant environmental issue, driven by rapid industrialization and intensified human activities, particularly in southern China. Heavy metal pollution in groundwater often presents complex spatial patterns and multiple sources; understanding the spatial heterogeneity and controlling factors of heavy metals is crucial for pollution prevention and water resource management in industrial regions. This study applied spatial autocorrelation analysis and self-organizing maps (SOM) coupled with K-means clustering to investigate the spatial distribution and key influencing factors of nine heavy metals (Cr, Fe, Mn, Ni, Cu, Zn, As, Ba, and Pb) in a typical industrial area in southern China. Heavy metals show significant spatial heterogeneity in concentrations. Cr, Mn, Fe, and Cu form local hotspots near urban and peripheral zones; Ni and As present downstream enrichment along the river pathway with longitudinal increase trends; Zn, Ba, and Pb exhibit a fluctuating pattern from west to east in the piedmont region. Local Moran’s I analysis further revealed spatial clustering in the northwest, riverine zones, and coastal outlet areas, providing insight into potential source regions. SOM clustering identified three types of groundwater: Cluster 1 (characterized by Cr, Mn, Fe, and Ni) is primarily influenced by industrial pollution and present spatially scattered distribution; Cluster 2 (dominated by As, NO3, Ca2+, and K+) is associated with domestic sewage and distributes following river flow; Cluster 3 (enriched in Zn, Ba, Pb, and NO3) is shaped by agricultural activities and natural mineral dissolution, with a lateral distribution along the piedmont zone. The findings of this study provide a scientific foundation for groundwater pollution prevention and environmental management in industrialized areas. Full article
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19 pages, 1369 KiB  
Review
Current State of Arsenic, Fluoride, and Nitrate Groundwater Contamination in Northern Mexico: Distribution, Health Impacts, and Emerging Research
by Mélida Gutiérrez, María Teresa Alarcón-Herrera, María Socorro Espino-Valdés and Luz Idalia Valenzuela-García
Water 2025, 17(13), 1990; https://doi.org/10.3390/w17131990 - 2 Jul 2025
Viewed by 505
Abstract
The plateaus of north-central Mexico have an arid to semiarid climate and groundwater naturally contaminated with inorganic arsenic (iAs) and fluoride (F). Like other arid and semiarid areas, this region faces great challenges to maintain a safe supply of drinking and irrigation water. [...] Read more.
The plateaus of north-central Mexico have an arid to semiarid climate and groundwater naturally contaminated with inorganic arsenic (iAs) and fluoride (F). Like other arid and semiarid areas, this region faces great challenges to maintain a safe supply of drinking and irrigation water. Studies conducted in the past few decades on various locations within this region have reported groundwater iAs, F, and nitrate-nitrogen (NO3-N), and either their source, enrichment processes, health risks, and/or potential water treatments. The relevant findings are analyzed and condensed here to provide an overview of the groundwater situation of the region. Studies identify volcanic rocks (rhyolite) and their weathering products (clays) as the main sources of iAs and F and report that these solutes become enriched through evaporation and residence time. In contrast, NO3-N is reported as anthropogenic, with the highest concentrations found in large urban centers and in agricultural and livestock farm areas. Health risks are high since the hot spots of contamination correspond to populated areas. Health problems associated with NO3-N in drinking water may be underestimated. Removal technologies of the contaminants remain at the laboratory or pilot stage, except for the reverse osmosis filtration units fitted to selected wells within the state of Chihuahua. A recent approach to supplying drinking water free of iAs and F to two urban centers consisted of switching from groundwater to surface water. Incipient research currently focuses on the potential repercussions of irrigating crops with As-rich water. The groundwater predicaments concerning contamination, public health impact, and irrigation suitability depicted here can be applied to semiarid areas worldwide. Full article
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