Search Results (331)

The Chacopampean Plain is a major physiographic unit in Argentina, bounded by the Colorado River to the south, the Sierras Pampeanas and Subandinas to the west, and the Paraná River, Río de la Plata Estuary, and the Argentine Sea to the east. Its subsurface preserves sediments from the Miocene marine transgression, while the surface hosts some of the country’s most productive soils. Two main geomorphological domains are recognized: fluvial systems dominated by alluvial megafans in the north, and aeolian systems characterized by loess accumulation and wind erosion in the south. The southern sector exhibits diverse landforms such as deflation basins, ridges, dune corridors, lunettes, and mantiform loess deposits. Despite their regional extent, the origin and chronology of many aeolian features remain poorly constrained, as previous studies have primarily focused on depositional units rather than wind-sculpted erosional features. This study integrates remote sensing data, field observations, and a synthesis of published chronometric and sedimentological information to characterize these aeolian landforms and elucidate their genesis. Our findings confirm wind as the dominant morphogenetic agent during Late Quaternary glacial stadials. These aeolian morphologies significantly influence the region’s hydrology, as many permanent and ephemeral water bodies occupy deflation basins or intermediate low-lying sectors prone to flooding under modern climatic conditions, which are considerably wetter than during their original formation. Full article

Glaciers are significant sources of fresh water on planet Earth. The Hindukush–Karakoram–Himalayan (HKH) glaciers provide the water supply to more than half of the human population of the globe, for agricultural activities, biodiversity survival, and ecosystem services. In recent years, the loss of glacial ice has been forecasted to cause problems such as sea level rise, changes in water availability, and release of contaminants that reside in the surfaces of glaciers or within them. In this regard, mineralogical sediments play a significant role in the geochemistry of glaciers and element cycling. This study analyzed elemental pollutants found in the glaciers of Pakistan and investigated the diverse bacterial communities residing therein. Samples of ice and sediments were collected from the Gilgit, Hunza, and Swat glaciers in northern Pakistan. Nine elements, including co-factors, heavy metals, and nutrients, were assessed using atomic absorption spectrophotometry. The research findings indicate higher concentrations of the elements K, Fe, Cu, and Cr in Hunza glacier ice (Hgi) and Ni, Zn, As, and Cd in Gilgit glacier ice (Ggi). In terms of glacier sediments, Swat (Sgs), Gilgit (Ggs), and Hunza (Hgs) samples showed the highest concentrations of K, Cu, Ni, Zn, As, Pb, Cd, and, respectively, of Fe, and Cr. The amount of Cu and Cr is the same in Swat glacier ice and Swat glacier foot. However, the concentration of some elements (As, K, Pb, Zn) is higher in Swat glacier ice, while the amount of some elements (Cd, Ni) is greater in Swat glacier foot. Furthermore, microbial cultivation techniques revealed diverse bacterial communities inhabiting the sampled glaciers. Phylogenetic analysis of the bacterial isolates, based on 16S rRNA gene sequences, showed high homology (99–100%) with previously reported species. The resultant phylogenetic tree grouped the bacterial isolates, such as Serratia marcescens, Cupriavidus sp., and Bacillus cereus, with closely related species known for their roles in nutrient cycling, environmental resilience, and metal tolerance. These findings highlight the ecological significance and adaptive potential of microbial communities in glacier environments, emphasizing their role in elemental cycling and environmental resilience. Full article

Despite its broad application due to its affordability, biodegradability, and natural antimicrobial and antioxidant activities, chitosan (CS) still exhibits limitations in mechanical strength and barrier effectiveness. Owing to its unique chemical characteristics, itaconic acid (IT) presents potential as a compatibilizing agent in polymeric blend formulations. Biodegradable polymers composed of chitosan (CS), itaconic acid (IT), and starch (S) were synthesized using two polymerization methods. The first method involved grafting IT onto CS at varying ratios of IT (4%, 6%, and 8% wt.), using 1% v/v acetic acid/water as the solvent and potassium persulfate as the initiator. In the second approach, starch (S) was blended with the copolymer P(CS-g-IT) at concentrations of 1%, 3%, and 5%, utilizing water as the solvent and glacial acetic acid as a catalyst. The resulting biodegradable films underwent characterization through FTIR, TGA, SEM, and mechanical property analysis. To further explore the effects of combining IT, starch, and carbon black, the blends, referred to as P[(CS-g-IT)-b-S], were also loaded with carbon black. This allowed for the evaluation of the materials’ physicomechanical properties, such as viscosity, tensile strength, elongation, and contact angle. The findings demonstrated that the presence of IT, starch, and carbon black collectively improved the films’ mechanical performance, physical traits, and biodegradability. Among the samples, the blended copolymer with 1% starch exhibited the highest mechanical properties, followed by the grafted copolymer with 8% IT and the blended copolymer mixed with carbon black at 7%. In contrast, the blended copolymer with 5% starch showed the highest hydrophilicity and the shortest degradation time compared to the grafted copolymer with 8% IT and the blended copolymer mixed with 7% carbon black. Full article

Clouds play a central role in regulating incoming solar radiation and outgoing terrestrial emission; hence, they must be internally constrained to prognose Earth’s temperature. At the same time, planetary fluids are inherently turbulent, so the climate state would tend toward maximum entropy production—a generalized second law of thermodynamics. Incorporating these requirements, I have previously formulated an aquaplanet model to demonstrate that intrinsic water properties may strongly lower the climate sensitivity to solar irradiance, thereby resolving the faint young Sun paradox (FYSP). In this paper, I extend the model to include other external forcings and show that sensitivity to the reduced outgoing longwave radiation by the elevated pCO₂ can be several times greater, but the global temperature remains capped at ~40 °C by the exponential increase in saturated vapor pressure. I further show that planetary albedo augmented by a tropical supercontinent may cool the climate sufficiently to cause tropical glaciation. And since the glacial edge is marked by above-freezing temperature, it abuts an open, co-zonal ocean, thereby obviating the “Snowball Earth” hypothesis. Our theory thus provides a unified framework for interpreting Earth’s diverse climates, including the FYSP, the warm extremes of the Cambrian and Cretaceous, and the tropical glaciations of the Precambrian. Full article

This study assesses the risks of glacial lake outburst floods (GLOFs) from moraine sediment dams around Gurudongmar Lake in the Northern Sikkim Himalayas at an elevation of 17,800 feet. It focuses on three moraine sediment dams, analysing the implications of slope failure on the upstream side and the downstream stability under steady seepage conditions, as well as the risks posed by permafrost thawing. Using a comprehensive methodology that includes geotechnical evaluations, remote sensing, and digital elevation models (DEMs), the research employs finite element analysis via PLAXIS2D for the stability assessment. The main findings indicate a stratification of sediment types: the upper layers are loose silty sand, while the lower layers are dense silty sand, with significant variations in shear strength, permeability, and other geotechnical properties. Observations of solifluctions suggest that current permafrost conditions enhance the dams’ stability and reduce seepage. However, temperature trends show a warming climate, with the average days below 0 °C decreasing from 314 (2004–2013) to 305 (2014–2023), indicating potential permafrost thawing. This thawing could increase seepage and destabilise the dams, raising the risk of GLOFs. Numerical simulations reveal that scenarios involving water level rises of 5 and 10 m could lead to significant deformation and reduced safety factors on both the upstream lateral dams and downstream front dams. The study emphasises the urgent need for ongoing monitoring and risk assessment to address the potential hazards associated with GLOFs. Full article

Water resources are vital for sustainable development in arid regions, where glacial runoff plays a significant role in maintaining water supply. This study quantitatively assesses the sustainability of water resources in the Manas River Basin (MnsRB) and the Muzati River Basin (MztRB), situated on the northern and southern slopes of the Tianshan Mountains, respectively, over the period from 1991 to 2050. Freshwater availability was simulated and projected using the Variable Infiltration Capacity Chinese Academy of Sciences (VIC-CAS) hydrological model. Furthermore, three development modes—traditional development, economic growth, and water-saving—were established to estimate future water consumption. The levels of water stress were also applied to assess water resources sustainability in the MnsRB and MztRB. Results indicate that from 1991 to 2020, the average annual available freshwater resources were 13.94 × 10⁸ m³ in the MnsRB and 14.27 × 10⁸ m³ in the MztRB, with glacial runoff contributing 20.24% and 65.58%, respectively. Under the SSP5-8.5 scenario, available freshwater resources are projected to decline by 10.94% in the MnsRB and 4.37% in the MztRB by 2050. Total water withdrawal has increased significantly over the past 30 years, with agriculture water demand accounting for over 80%. The levels of water stress during this period were 1.14 for the MnsRB and 0.87 for the MztRB. Glacial runoff significantly mitigates water stress in both basins, with average reductions of 21.16% and 69.84% between 1991 and 2050. Consequently, clear policies, regulations, and incentives focused on water conservation are vital for effectively tackling the increasing challenge of water scarcity in glacier-covered arid regions. Full article

Polychlorinated biphenyls (PCBs) are classified as persistent organic pollutants (POPs) due to their potential threat to both ecosystems and human health. The Tibetan Plateau (TP), characterized by its low temperatures, pristine ecological conditions, and remoteness from anthropogenic influences, serves as the investigation region. This study analyzed water samples from the temperature glacial watershed and employed the risk assessment method established by the United States Environmental Protection Agency (US EPA) to assess both carcinogenic and non-carcinogenic risks of PCBs in five age groups. The total concentrations of PCBs (∑₃PCBs) varied from 738 to 1914 ng/L, with a mean value of 1058 ng/L, which was comparable to or exceeded levels reported in the surface water around the TP. Notably, the riverine sites located near the villages and towns exhibited the highest pollution levels. Our analyses indicated that glacier melting, long-range atmospheric transport (LRAT), reductive dechlorination processes, and various anthropogenic activities might be potential sources of PCB emission in the Meili Snow Mountains. According to the established national and international water quality standards, as well as toxic equivalency concentrations (TEQs) for dioxin-like PCBs (DL PCBs), the PCB concentrations detected in this study could result in serious biological damage and adverse ecological toxicological effects. However, the PCBs in all samples posed a negligible cancer risk to five age groups, and a non-carcinogenic risk to adults. These findings contribute valuable insights into the risks and sources of PCBs and may serve as a foundational reference for subsequent study of these compounds in the Meili Snow Mountains area of the southeastern TP. Full article

Mountain regions are particularly sensitive and vulnerable to the impacts of climate change. Over the past three decades, mountain temperatures have risen significantly faster than those in lowland areas. The Hindu Kush–Karakoram–Himalaya region, often referred to as the “water tower of Asia”, is the largest freshwater source outside the polar regions. However, it is currently undergoing cryospheric degradation as a result of climatic change. In this study, the Normalized Difference Glacier Index (NDGI) was calculated using Landsat and Sentinel satellite images. The results revealed that glaciers in Chitral, located in the Eastern Hindu Kush Mountains of Pakistan, lost 816 km² (31%) of their total area between 1992 and 2022. On average, 27 km² of glacier area was lost annually, with recession accelerating between 1997 and 2002 and again after 2007. Satellite analyses also indicated a significant increase in both maximum (+7.3 °C) and minimum (+3.6 °C) land surface temperatures between 1992 and 2022. Climate data analyses using the Mann–Kendall test, Theil–Sen Slope method, and the Autoregressive Integrated Moving Average (ARIMA) model showed a clear increase in air temperatures from 1967 to 2022, particularly during the summer months (June, July, and August). This warming trend is expected to continue until at least 2042. Over the same period, annual precipitation decreased, primarily due to reduced snowfall in winter. However, rainfall may have slightly increased during the summer months, further accelerating glacial melting. Additionally, the snowmelt season began consistently earlier. While initial glacier melting may temporarily boost water resources, it also poses risks to communities and economies, particularly through more frequent and larger floods. Over time, the remaining smaller glaciers will contribute only a fraction of the former runoff, leading to potential water stress. As such, monitoring glaciers, climate change, and runoff patterns is critical for sustainable water management and strengthening resilience in the region. Full article

Glacial retreat is a widely recognised phenomenon, and yet the processes of glaciofluvial bedload in high-alpine river systems remain largely unobserved. This study investigates the impact of hydrological and climatic changes on bedload and water discharge dynamics in the Rofenache catchment in the Ötztal Alps over a 14-year period. Utilising high-resolution bedload data from plate geophones and direct calibration measurements, we analyse water discharge and bedload transport, focusing on hysteresis events influenced by temperature and precipitation. Our findings reveal that water discharge and bedload transport processes are non-linear, with counterclockwise hysteresis dominating; this is consistent with previous studies in glaciated catchment areas. The inclusion of temperature and precipitation data further highlights the significant influence of temperature on hysteresis events in the catchment area. This research provides insights into the bedload dynamics of a high-alpine river under the effects of climate change, emphasising the need for continued monitoring and analysis to understand the evolving interactions between hydrological and sedimentological processes and climatic factors in partially glaciated catchments. Full article

The remarkable expansion of lake areas across the Changtang Plateau (CTP, located in the central Tibetan Plateau) since the late 1990s has drawn considerable scientific interest, presenting a striking contrast to the global decline in natural lake water storage observed during the same period. This study systematically investigates the mechanisms underlying lake area variations on the CTP by integrating glacierized area changes derived from the Google Earth Engine (GEE) platform with atmospheric circulation patterns from the ERA5 reanalysis dataset. Our analysis demonstrates that the limited glacier coverage on the CTP exerted significant influence only on glacial lakes in the southern region (r = −0.65, p < 0.05). The widespread lake expansion across the CTP predominantly stems from precipitation increases (r = 0.74, p < 0.01) associated with atmospheric circulation changes. Enhanced Indian summer monsoon (ISM) activity facilitates anomalous moisture transport from the Indian Ocean to the southwestern CTP, manifesting as increased specific humidity (Qa) in summer. Simultaneously, the weakened westerly jet stream reinforces moisture convergence across the CTP, driving enhanced annual precipitation. By coupling glacier coverage variations with atmospheric processes, this research establishes that precipitation anomalies rather than glacial meltwater primarily govern the extensive lake expansion on the CTP. These findings offer critical insights for guiding ecological security strategies and sustainable development initiatives on the CTP. Full article

To investigate the changes in heavy metal content in the sub glacial water during the freezing and thawing process of seasonally frozen lakes, the Wuliangsuhai Lake in northern China was taken as the research object. The ice thickness, water depth, and heavy metal content at different depths of the lake were measured during the freezing and thawing periods. Based on a large amount of measured lake heavy metal data, MATLAB 2022b software is used to model data fitting and optimization identification, and wavelet analysis and 24 h sliding average method are used for verification analysis to describe the variation process of heavy metal concentration in ice water with depth and time. The results show that during the freezing and thawing periods of lakes, the water level is constantly changing, but the heavy metal content in the water below the ice follows the same distribution with water depth. During the freezing process, the heavy metal content in the water increases with the increase in ice thickness. A new numerical model describing the spatiotemporal distribution of heavy metals under the ice during the freezing period of the lake was obtained through calculation. The overall trend of the simulated contour lines is consistent with the measured values and has a small error. This study provides a reference for predicting the changes in heavy metal content under the ice cover during the freezing period in cold and arid regions. The model can be used to simulate the content values of heavy metals at different depths and times. Full article

A new TLC method combined with densitometry was developed for the determination of donepezil hydrochloride in Cogiton Biofarm and Donecept Actavis tablets. The analyses were performed on TLC silica gel 60F₂₅₄ plates with mobile phase of n-butanol + n-propanol + acetone + water + glacial acetic acid at ratio of 2:2:1:1:1, v/v. The proposed mobile phase is miscible and after development the chromatographic plate has a homogeneous background in visible light. Densitometric analysis at λ = 319 nm was used for quantitative studies. The method was linear from 1.0 to 5.0 µg/spot and from 0.2 to 1.0 µg/spot and it was validated for both concentration ranges. The presented method is rapid, selective, linear, accurate, precise, robust, and economical. The results of the donepezil content in drugs calculated from both calibration curves were that no statistically significant differences were observed. The obtained content of donepezil in Cogiton (99.2%) and Donecept (99.0%) tablets is within the deviations permitted by the European Pharmacopoeia in relation to the amount declared by the manufacturer. The novelty of the study consists of the development of chromatographic conditions allowing the separation of as many as six donepezil degradation products with the simultaneous use of TLC chromatographic plates. As a result, the proposed method is economical, since it is several times cheaper than using HPTLC plates. While Ali et al. separated a maximum of three degradation products from donepezil, Pandey et al. successfully separated only two donepezil-related substances from donepezil. The proposed new TLC method combined with densitometry can be used for the routine control of donepezil in pharmaceutical preparations (tablets). Since TLC is less sensitive and precise compared to HPLC, it can be used as a complementary technique. Full article

The phytoplankton communities in lakes change seasonally within competitive areas, referred to as seasonal succession, which results in high compositional diversity if conditions remain stable. However, glacial lakes are generally far from human and terrestrial influences due to their location so very few species can be identified and large changes in phytoplankton composition cannot be anticipated. Nonetheless, molecular techniques, as well as classical methods, help us to determine the existence of different species. Additionally, these techniques allow us to evaluate the ecology of glacial lakes from different perspectives with developing technology. Horseshoe Island is located in the area known as Marguerite Bay on the Peninsula region in western Antarctica. This study was carried out to determine phytoplankton genome biodiversity by using the metagenomic analysis method used in 18S rRNA, 16S rRNA, and 23S rRNA gene analyses. 16S rRNA and 23S rRNA gene analyses revealed that bacteria belong to broadly distributed Cyanobacteria taxa, whereas 18S rRNA gene analysis revealed other eukaryotic phytoplankton groups. This method was used for the first time for Horseshoe Island lakes (Col 1, Col 2, Skua, and Zano), and species belonging to Cyanobacteria, Chlorophyta, Ochrophyta, and Bacillariophyta were identified. As a result, the phytoplankton genomic diversity of shallow and oligotrophic glacial lakes was determined, and benthic algal species were also identified in the water samples. These results indicate that benthic algae associated with the sediment can also contribute to aquatic phytoplankton communities in addition to oligotrophic lake phytoplankton biodiversity. Cyanobacterial biodiversity can also be recognized as a sentinel by which to monitor adaptation responses to climate change in this rapidly warming region. Full article

Glacial retreat is a major global challenge, particularly in arid and semi-arid regions where glaciers serve as critical water sources. This research focuses on glacial retreat and its impact on land cover and land use changes (LULC) in the Barroso Mountain range, Tacna, Peru, which is a critical area for water resources in the hyperarid Atacama Desert. Employing advanced remote sensing techniques through the Google Earth Engine (GEE) cloud computing platform, we analyzed historical trends (1985–2022) using Landsat satellite imagery. A normalized index classification was carried out to generate LULC maps for the years 1986, 2001, 2012, and 2022. Future projections until 2042 were developed using Cellular Automata–Markov (CA–Markov) modeling in QGIS, incorporating six predictive environmental variables. The resulting maps presented an overall accuracy (OA) greater than 83%. Historical analysis revealed a dramatic glacier reduction from 44.7 km² in 1986 to 7.4 km² in 2022. In contrast, wetlands expanded substantially from 5.70 km² to 12.14 km², indicating ecosystem shifts potentially driven by glacier meltwater availability. CA–Markov chain modeling projected further glacier loss to 3.07 km² by 2042, while wetlands are expected to expand to 18.8 km² and bodies of water will reach 4.63 km². These future projections (with accuracies above 84%) underline urgent implications for water management, environmental sustainability, and climate adaptation strategies, particularly with regard to downstream hydrological risks and ecosystem resilience. Full article

This study examines adaptation strategies to mitigate the risks posed by Glacial Lake Outburst Floods (GLOFs) in the Hindu Kush Himalayan (HKH) region, encompassing Pakistan, India, Nepal, Bhutan, and Afghanistan. GLOFs occur when water is suddenly released from glacial lakes and they present significant threats to communities, infrastructure, and ecosystems in high-altitude regions, particularly as climate change intensifies their frequencies and severity. While there are many studies on the changes in glacial lakes, studies on adaptation to GLOF risks are scant. Also, these studies tend to focus on case-specific scenarios, leaving a gap in comprehensive, region-wide analyses. This review article aims to fill that gap by synthesizing the adaptation strategies adopted across the HKH region. We conducted a literature review following several inclusion and exclusion criteria and reviewed 23 scholarly sources on GLOF adaptation. We qualitatively synthesized the data and categorized the adaptation strategies into two main types: structural and non-structural. Structural measures include engineering solutions such as lake-level control, channel modifications, and flood defense infrastructure, designed to reduce the physical damage caused by GLOFs. Non-structural measures include community-based practices, economic diversification, awareness programs, and improvements in institutional governance, addressing social and economic vulnerabilities. We found that Afghanistan remains underrepresented in GLOF-related studies, with only one article that specifically focuses on GLOFs, while Nepal and Pakistan receive greater attention in research. The findings underscore the need for a holistic, context-specific approach that integrates both structural and non-structural measures to enhance resilience across the HKH region. Policy-makers should prioritize the development of sustainable mechanisms to support long-term adaptation efforts, foster cross-border collaborations for data sharing and coordinated risk management, and ensure that adaptation strategies are inclusive of vulnerable communities. Practitioners should focus on strengthening early warning systems, expanding community-based adaptation initiatives, and integrating traditional knowledge with modern scientific approaches to enhance local resilience. By adopting a collaborative and regionally coordinated approach, stakeholders can improve GLOF risk preparedness, mitigate socioeconomic impacts, and build long-term resilience in South Asia’s high-altitude regions. Full article